Power and Energy Commons^™

Perovskite Catalysts For Fuel Reforming In Sofc:A Review And Perspective, Tong Wei, Jian Li, Li-Chao Jia, Bo Chi, Jian Pu

Journal of Electrochemistry

Solid oxide fuel cell (SOFC) is a generating device by electrochemical reaction to transfer the chemical energy of fossil fuels (coal, oil and gas, etc.), the biomass fuel or other hydrocarbon fuels directly into electricity with higher energy conversion efficiency and lower pollution, which is recognized to be efficient green energy technology in the 21st century. However, when hydrocarbons are directly used as fuel, carbon deposition is easy to occur in nickel-based anode, thus, losing electrochemical catalytic activity. Fuel pre-reforming on the outside of the anode is an effective solution, which strongly relies on highly efficient and stable reforming catalysts. …

Research Progress In Ethane Dehydrogenation To Cogenerate Power And Value-Added Chemicals In Solid Oxide Fuel Cells, Yun Fan, Qi Wang, Jun Li, Jing-Li Luo, Xian-Zhu Fu

Journal of Electrochemistry

Increasing supplies of methane/shale gas have promoted global development of higher value chemicals such as ethylene production by ethane, which dramatically changes the markets of petrochemical industry. Clean and efficient transformation of ethane into higher value chemicals has far-reaching significance. Ethylene production through ethane steam cracking is a relatively matured technology for industrial production. However, the process consumes large amounts of energy and the presence of carbon deposition becomes a serious problem which is difficult to be solved. The cogenerated energy-chemicals solid oxide fuel cells have been widely studied because fuel gas can be converted into high-value chemicals via spontaneous …

Preparation And Characterization Of Cathode Supported Solid Oxide Fuel Cell, Xiao-Nan Bao, Guang-Jun Zhang, Shao-Rong Wang

Journal of Electrochemistry

A site deficient (La_0.8Sr_0.2)_0.95MnO₃ (LSM95) powder was synthesized by solid state reaction as a cathode material. The commercial Zr_0.9Sc_0.1SO_1.95 (SSZ) was selected as an electrolyte material and La_0.8Sr_0.2Cr_0.5Mn_0.5O₃- (LSCrM) was synthesized by sol-gel method as an anode material. Accordingly, single cells of LSCrM-CeO₂|SSZ|3YSZ-LSM95 were prepared by tape casting, sintering and impregnation. The single cell test results for LSCrM-CeO₂|SSZ|3YSZ-LSM95 with 0.11 g·cm ^-2 CeO₂ and using CH₄ as a fuel showed the power …

Direct Carbon Solid Oxide Fuel Cells, Jiang Liu, Xiao-Min Yan

Journal of Electrochemistry

Carbon is richly reserved in coal, biomasses, and many other nature resources. It is usually used as an energy source through oxygen oxidation reaction. The oxidation is generally realized through combustion which causes serious air pollution. Besides, the conversion efficiency of generating electricity through the combustion process is limited by Carnot efficiency. A direct carbon solid oxide fuel cell (DC-SOFC) is a solid oxide fuel cell (SOFC) directly operated with solid carbon as the fuel. It can convert the chemical energy of carbon into electricity with high efficiency. The concentration of produced CO₂ from a DC-SOFC is so high …

Research Progress Of Fuel Electrode In Oxide-Ion Conducting Solid Oxide Electrolysers, Ling-Ting Ye, Kui Xie

Journal of Electrochemistry

Solid oxide electrolysers are now attracting much more attentions because they can efficiently produce fuels by electrolyzing H₂O/CO₂. In this paper, a comprehensive introduction to the recent progress in the development of fuel electrode (cathode) materials is provided. The advantages, disadvantages and development trend towards various cathode materials are pointed out. The key scientific and technological problems in this field are emphasized.

Development Status And Prospects Of Hydrogen Production By High Temperature Solid Oxide Electrolysis, Wen-Qiang Zhang, Bo Yu

Journal of Electrochemistry

Solid oxide electrolysis cell is an advanced energy conversion device with high efficiency, simplicity, flexibility, and environmental friendliness. It is currently a research hotspot in the international energy field. This paper introduces and analyzes the basic principles, key materials, system components and developments of solid oxidation electrolysis cells. Furthermore, the recent research progresses, challenges and future development directions in solid oxidation electrolysis cells in the field of high-efficiency hydrogen production are summarized and outlined.

Nio@Rgo Supported Palladium And Silver Nanoparticles As Electrocatalysts For Oxygen Reduction Reaction, Shuo Yao, Tai-Zhong Huang, Rizwan Haider, Heng-Yi Fang, Jie-Mei Yu, Zhan-Kun Jiang, Dong Liang, Yue Sun, Xian-Xia Yuan

Journal of Electrochemistry

For pervasive applications of fuel cells, highly efficient and economical materials are required to replace Pt-based catalysts for oxygen reduction reaction (ORR). In this study, the NiO@rGO, Pd-NiO@rGO and Ag-NiO@rGO nanoparticles were synthesized, and their catalytic performances toward ORR were investigated. The results revealed that all the three materials were capable of catalyzing ORR, but both the Pd-NiO@rGO and Ag-NiO@rGO showed the better performances compared with the NiO@rGO in terms of the reaction pathway being 4-electron process, the increases of the onset potential and the intermediate yielding rate, as well as the extended stability. Moreover, the effect of Pd modification …

On-Site And External Energy Harvesting In Underground Wireless, Usman Raza, Abdul Salam

Faculty Publications

Energy efficiency is vital for uninterrupted long-term operation of wireless underground communication nodes in the field of decision agriculture. In this paper, energy harvesting and wireless power transfer techniques are discussed with applications in underground wireless communications (UWC). Various external wireless power transfer techniques are explored. Moreover, key energy harvesting technologies are presented that utilize available energy sources in the field such as vibration, solar, and wind. In this regard, the Electromagnetic(EM)- and Magnetic Induction(MI)-based approaches are explained. Furthermore, the vibration-based energy harvesting models are reviewed as well. These energy harvesting approaches lead to design of an efficient wireless underground …

A System Dynamic Model For Application Of Blockchain In The United States Electricity Sector, Oluwafemi Ezekiel Oyeniran

Morehead State Theses and Dissertations

A thesis presented to the faculty of the College of Business and Technology at Morehead State University in partial fulfillment of the requirements for the Degree Master of Science by Oluwafemi Ezekiel Oyeniran on April 14, 2020.

Evaluating The Effects Of Electric And Magnetic Loading On The Performance Of Single And Double Rotor Axial Flux Pm Machines, Narges Taran, Greg Heins, Vandana Rallabandi, Dean Patterson, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

Axial flux PM (AFPM) machines are used particularly in applications requiring a compact structure. Their disc shape topology and axial air-gap have led to a variety of configurations including two popular ones: the yokeless and segmented armature (YASA), and the single-stator single rotor or single sided machine. In this study, a comprehensive comparative analysis of these configurations is conducted at different magnetic and electric loadings. It is found that at lower loadings, typically employed for air-cooled machines, the torque/ampere characteristics of the YASA machine are almost identical to those of a single sided machine constructed with half the magnet volume. …

Net Energy Index: A New Way To Measure Energy Efficient Buildings, Dylan Suplee

Senior Honors Theses

Energy efficiency indexes are useful for providing tangible measurements of energy efficiency in buildings. Buildings use approximately 70% of all electricity in the USA. Using that energy efficiently has two primary benefits: limiting greenhouse gas emissions and reducing grid strain. Utilizing local renewable energy sources contributes to the same benefits. Currently, there is no index that considers renewable energy sources when measuring energy efficiency. Therefore, this paper proposes the Net Energy Index, which compares the net power usage of a building to the floor area of the building in order to determine energy efficiency. If renewable energy supplies power to …

Trajectory Simulation With Battery Modeling For Electric Powered Unmanned Aerial Vehicles, Ege Konuk

Mechanical & Aerospace Engineering Theses & Dissertations

Fixed wing electric powered unmanned aerial vehicles (UAVs) has been widely adopted for the last decade in a great number of applications. One of the primary advantages to fixed wing versus multi-rotor designs is the efficiency in forward flight with best possible range and endurance capabilities. In electrically powered air vehicles range and endurance are monitored by the State-of-Charge (SOC) of the battery. To understand the capabilities of the battery, discharge experiments can be conducted in lab environments; however, sometimes the results are difficult to integrate in flight simulations.

In this thesis, a trajectory simulation is developed that can estimate …

Dartmouth Formula Racing: Full Electric Battery System Design, Matt Gardner, Jacob Hagler, Ruthie Nordhoff, Otto Salmi

ENGS 89/90 Reports

Dartmouth Formula Racing (DFR) lacked an electrical energy storage system that was Formula Hybrid rules-compliant, optimized for FH events, safe, reliable, and integrated with the rest of their vehicle. Additionally, the team lacked the academic and professional resources required to bring a thorough, analytical approach to the design, testing, and documentation of the new storage system. Our team designed and built a Lithium-Ion battery pack (accumulator) containing energy storage, active cooling, battery management and temperature monitoring systems, and control circuitry compatible with DFR’s vehicle. Collaboration throughout design, fabrication, assembly and testing processes ensured effective knowledge transfer to the DFR team.

Energy Harvesting From Airports, Deepon Roy

National Training Aircraft Symposium (NTAS)

Airports around the world are primarily powered using the country’s electricity grids, which comes from a large number of powerplants (coal, natural gas, etc.). Due to a high power supply demand by the airports, the sources from which they get their electricity has become non-economical and non-environment friendly.

As a result, many airports around the world have opted for using solar energy grids for their energy generation, in a bid to reduce the airport’s electricity consumption costs. But it has been a slow progress as only a few airports have been able to implement this feature, as their initial setup …

Optimized Off-Grid Energy Systems Using Climate-Based Energy Demand For Soft-Walled Facilities, Jay F. Pearson

Theses and Dissertations

Remote contingency military operations often require the use of temporary facilities powered by inefficient diesel generators that are expensive to operate and maintain. Site planners can reduce operating costs by augmenting generators with hybrid energy systems, but they must select the optimal design configuration based on the region’s climate to meet the power demand at the lowest cost. To assist planners, this paper proposes two innovative, climate-optimized, hybrid energy system selection models. The first model is capable of selecting the facility insulation type, solar array size, and battery backup system to minimize the annual operating cost. The Hybrid Energy Renewable …

Golng Off The Grid: Optimizing Solar Renewable Energy Systems At Remote Locations To Minimize Logistics Requirements, Increase Sustainability, And Strengthen Energy Assurance, Nathanael J. Thomsen

Theses and Dissertations

Grid-based electrical infrastructure is unavailable at many remote locations including developing nation communities, isolated construction sites, and military contingency bases. Powering these locations with diesel generators requires regular fuel resupply, resulting in increased costs, environmental impacts, and burdensome logistics—making generators an obstacle for energy resiliency and sustainability. This research examines using solar renewable energy systems to replace generators at remote locations and presents a multi-objective optimization model that minimizes logistics variables. Replacing a single deployed generator would save over 500,000 gal of fuel annually, eliminating the need for 100 fuel tanker deliveries.

Neca Ghana Project, Michael T. Klee

Construction Management

Cal Poly’s motto is, “Learn by Doing" and for Cal Poly’s NECA Chapter, this isn’t simply a motto, but a directive for proactive change. For my senior project I will be leading the Cal Poly NECA chapter in the design, pre- fabrication and construction of a 5-7kw solar array, community center, ice production room and technology room in the remote fishing village of Agbokpa, Ghana. The solar array will power multiple industrial DC freezers, high efficiency LED lighting and charging stations while additionally powering water filtration and irrigation systems. Like many other fishing villages around the world, Agbokpa has no …

Optimizing Llrf Parameters In The Electron-Ion Collider, William M. Bjorndahl

Physics

To improve particle interaction in the future Electron-Ion Collider (EIC), we investigated different feedback implementations to control the accelerating voltage and examined the power and beam phase for each instance. Using MATLAB, we studied three feedback mechanisms: Direct, One Turn, and Feedforward. Enacting feedforward yielded the best performance. To minimize the klystron power consumption, we analyzed different Low-Level Radio Frequency (LLRF) parameters such as detuning. Combining theory and simulated results, we found the optimal detuning value that minimizes klystron power consumption.

Analyzing Cost Effectiveness Of Photovoltaic Pavements, Ian N. Parks

Theses and Dissertations

The United States Air Force (USAF) is the largest consumer of energy within the Department of Defense (DoD). As such, the USAF is continually looking for ways to reduce consumption, as well improving network resiliency and assuring supply. One potential method for addressing these items is focusing on applications of renewable energy. A specific application of renewable energy that could greatly benefit the USAF if viable would be photovoltaic (PV) pavements. PV pavements would be able to capitalize upon the large swathes of pavements on Air Force (AF) installations, while not being hampered by other concerns such as clear zones …

Structures And Electrochemical Properties Of Sn-Cl Co-Doped Li2Mno3 As Positive Materials For Lithium Ion Batteries, Fei Wang, Huan-Huan Zhai, Du-Dan Wang, Yu-Peng Li, Kang-Hua Chen

Journal of Electrochemistry

Positive material Li₂MnO₃ shows the highest ratio of lithium to manganese among lithium-rich materials and exhibites the theoretical capacity up to 458 mAh·g^-1, making it one of the most promising cathode materials. However, this material has the intrinsic low electrical conductivity and poor cycle stability. In this paper, Li₂MnO₃, the lithium-rich positive material, was prepared by sol-gel method using acetate as raw material and citric acid as a complexing agent. By using SnC₂O₄ as a tin source, Sn⁴⁺ instead of Mn⁴⁺ was introduced to obtain the …

Preparations Of Nickel-Iron Hydroxide/Sulfide And Their Electrocatalytic Performances For Overall Water Splitting, Hang-Shuo Lu, Xiao-Bo He, Feng-Xiang Yin, Guo-Ru Li

Journal of Electrochemistry

The Ni-Fe/Ti oxygen evolution electrode was prepared by electrodeposition on a titanium mesh substrate. Then, the as prepared Ni-Fe/Ti electrode was used to derive the Ni-Fe-S/Ti hydrogen evolution electrode through solid phase sulfuration. The effects of the molar ratio of Ni²⁺ to Fe³⁺ in the electrolyte and the amount of thiourea on the structures and electrochemical performances of Ni-Fe/Ti and Ni-Fe-S/Ti electrodes were investigated. The results show that the oxygen evolution performance of Ni-Fe/Ti electrode was first increased and then decreased with the increase of nickel ion content in the electrolyte. The Ni9Fe1/Ti electrode exhibited the best oxygen …

Electrochemical Preparations And Applications Of Nano-Catalysts With High-Index Facets, Chi Xiao, Na Tian, Zhi-You Zhou, Shi-Gang Sun

Journal of Electrochemistry

The performance of catalysts highly depends on their surface structure and composition. Nanocrystals bounded by high-index facets usually exhibit high catalytic activity due to their high-density low-coordinated step atoms with high reactivity. In this paper, we have reviewed the preparations of noble metals (e.g., Pt, Pd and Rh) nanocatalysts with high-index facets by electrochemical square-wave potential method developed in our group. The square-wave potential method includes a nucleation procedure to generate nuclei, followed by a square-wave potential procedure for a certain period of time for the growth of nuclei into nanocrystals. The formation mechanism of high-index facets is also discussed. …

Recent Progress In The Mechanistic Understanding Of Co2 Reduction On Copper, Matthew M Sartin, Wei Chen, Fan He, Yan-Xia Chen

Journal of Electrochemistry

In this review, we present the major developments in the understanding of the mechanisms of the electrochemical reduction of CO₂ from a historical perspective. Most of the work discussed in this review was carried out at copper electrodes, as this is the only material at which hydrocarbons are produced in reasonable quantities. The emphasis focuses on the differentiation of mechanisms for the generation of C1 and C2 products as well as factors and methods for controlling the product selectivity of CO₂ reduction. We have highlighted ambiguities, assumptions, and important methodologies, such as differential electrochemical mass spectrometry and electrochemical …

Effect Of Nitrogen Content In Catalyst Precursor On Activity Of Fen/C Catalyst For Oxygen Reduction Reaction, Zhi Yang, Ya-Yun Shen, E Zhou, Cheng-Ling Wei, Hao-Li Qin, Juan Tian

Journal of Electrochemistry

Non-noble metal catalysts with high activity and low cost have attracted increasing interest as potential catalysts for oxygen reduction reaction (ORR) to replace Pt-based catalysts. In this paper, the effect of nitrogen content in catalyst precursor on ORR activity of FeN/C catalyst was investigated by X-ray diffraction (XRD), Brunauer-Emmet-Teller (BET) surface area and pore size distribution measurements, transmission electron microscope (TEM), thermogravimetric analysis (TGA), and rotating disk electrode (RDE) techniques. The results show that the most active catalyst was obtained by pyrolysis in argon at 1050 °C with a catalyst precursor containing 20wt% 1,10-phenanthroline, 1wt% Fe and Black Pearl 2000. …

Challenges In The Activity And Stability Of Pt-Based Catalysts Toward Orr, Tuo Zhao, Er-Gui Luo, Xian Wang, Jun-Jie Ge, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The development of highly efficient oxygen reduction reaction (ORR) catalysts is the key to the commercialization of fuel cells, where the sluggish ORR reaction rate needs to be overcome by adjusting the intermediates adsorption energies on the catalytic surfaces. To-date, platinum (Pt)-based materials are the-state-of-the-art catalysts in terms of both activity and stability in ORR, making them the preferred choice for commercial applications. However, the high cost of Pt-based catalysts limits their widespread use, leading to massive effects paid in reducing Pt loading, improving catalyst activity and stability. This article illustrates the challenges in the ORR reaction and introduces the …

Research Progresses In Polymeric Proton Exchange Membranes For Fuel Cells, Xu-Po Liu, Yun-Feng Zhang, Shao-Feng Deng, De-Li Wang, Han-Song Cheng

Journal of Electrochemistry

Proton exchange membrane (PEM) is one of the key components in PEM fuel cells, which possesses the function of separating the cathode and anode, affording proton transport channels and preventing fuel permeability. The property of PEM significantly influences the performance and service life of fuel cells. Nowadays, the commercially used Nafion membranes have the shortcomings of serious fuel permeability, low proton conductivity at elevated temperature and high price, which limits the rapid development of PEM fuel cells. Therefore, it seems to be urgent to develop novel PEMs with low cost and good comprehensive properties. Polymeric proton exchange membrane is an …

Lithium Storage Performance Of High Capacity Material Si@CPzs In Lithium Ion Batteries, Qing-Nuan Zhang, Fang-Fang Zhang, Hong-Xia Li, Bing-Jun Yang, Xiao-Cheng Li, Juan Yang

Journal of Electrochemistry

Carbon layers with different thicknesses were introduced into the surfaces of silicon (Si) nanoparticles by sol-gel method using poly (cyclotriphosphazene-co-4, 4'-sulfonyldiphenol) as the carbon source. Technologies of X-ray diffraction, thermo-gravimetric analysis, Brunauer-Emmett-Teller and transmission electron microscopy were employed to analyze the structures and components of the as-prepared Si@C_PZS composites. Electrochemical performance of Si@C_PZS with different carbon thicknesses was studied. The results showed that Si@C_PZS with carbon thickness of 10 nm possessed the best performance. Its capacity remained 940 mAh·g^-1 after 290 cycles under 500 mA·g^-1. As the addictive, the graphite-based anode contained 30% of …

Atomic Force Microscopic Characterization Of Solid Electrolyte Interphase In Lithium Ion Batteries, Qing-Yu Dong, Yan-Li Chu, Yan-Bin Shen, Li-Wei Chen

Journal of Electrochemistry

In recent years, the rapid growing in the electric vehicle market has raised higher requirement on the lithium-ion batteries (LIBs) performance towards energy density and safety. However, considering the successful development of LIBs techniques in the past 30 years, there is little room left for improving the LIBs performance on the aspects related to the electrode materials, battery structure design and production processes. It is important to pursue more comprehensive fundamental understanding in the entire system and working principle of LIBs. Solid electrolyte interphase (SEI), existing between the electrode material and the electrolyte, has been proved to be an important …

Research Progresses In Ni-Co-Mn/Al Ternary Concentration Gradient Cathode Materials For Li-Ion Batteries, Chun-Fang Zhang, Wen-Gao Zhao, Shi-Yao Zheng, Yi-Xiao Li, Zheng-Liang Gong, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

Nickel-rich ternary materials with large reversible capacity as well as high operating voltage are considered as the most promising candidate for next generation lithium-ion batteries (LIBs). However, the inferior cycle stability and thermal stability have limited their widely commercial applications. Concentration gradient design of Ni-Co-Mn/Al ternary concentration gradient materials have been extensively studied in the past decade, which can ensure high cycle capacity while maintaining excellent cycle stability. In this paper, the latest research progresses in Ni-Co-Mn/Al ternary concentration gradient materials for LIBs are reviewed. Firstly, we summarize the different synthesis methods of ternary concentration-gradient materials, especially focusing on the …

Preparation And Electrocatalytic Performance Of Nico2O4/Ni Foam For Hydrogen Peroxide Electrooxidation, Wei-Wei Chen, Fei-Fan Zhang, Jia-Liang Du, Yi Wang, Chun-Lin Zhao, Kai Zhu, Dian-Xue Cao, Gui-Ling Wang

Journal of Electrochemistry

The electrodes of Ni foam supported NiCo₂O₄ nanowires were prepared by hydrothermal method, followed by a thermal treatment in air, and were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It was found that the NiCo₂O₄ nanowires had a diameter of about 50 nm with a length up to 3 ~ 5 μm. The catalytic performances of the Ni foam supported NiCo₂O₄ nanowires for H₂O₂ electrooxidation were studied by cyclic voltammetry and chronoamperometry. The results show that the Ni foam supported NiCo …