Chemical Engineering Commons^™

Modeling Sex-Specific Changes In Myocardial Fibrosis, Grace Martin

Chemical Engineering Undergraduate Honors Theses

Heart disease the leading cause of death for both men and women in the United States. Cardiac fibrosis, or accumulation of extracellular matrix proteins in the heart, can occur after a heart attack and increase the risk for further complications. Current treatments for heart disease do not include extracellular matrix regulators, partly due to the complicated signaling network responsible for the production of these proteins. By using a computational model of the signaling network in cardia fibroblasts, the relationship between particular molecules and downstream extracellular matrix production can be examined.

Biological sex is an important factor for cardiac health and …

Enhanced Phosphogypsum Thermal Reduction By Carbon In Presence Of Sodium Chloride At High Temperature, Li Chao, An Xuebin, Jing Hu, Yixiao Wang, Shizhao Wang, Yunshan Wang, Gang Yang, Yong Sun

Research outputs 2022 to 2026

This paper reports an enhanced approach of thermal reduction of phosphogypsum (PG) in the presence of sodium chloride (NaCl) in its molten phase. The thermodynamic together with in-situ thermogravimetric-Fourier transform infrared spectroscopy (TG-FTIR) result indicates the yield of CaS (solid) at the investigated temperature range (800–850 °C). Addition of NaCl not only appreciably reduces the activation energy of this reaction (800–850 °C) on average from 315 to 175 (kJ·mol−1) materially, but also significantly improve the conversion from CaSO4 to CaS. Additionally, the NaCl based waste salt (NaCl-WS) containing organic compounds (0.21 wt%) was found to produce similar results when compared …

Study Of Kinetics Of Hydrocarbon Gas Purification With Composite Absorbents, Oybek Aripdjanov, Shavkat Nurullaev, Shodiyakhon Azimova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work is to improve the process of natural gas purification from acidic components using a composite absorbent. To study the sorption of acidic components in the gas composition, a chromatographic analysis method was used. The kinetics and rate of corrosion of carbon steel grade st.10 when using composite absorbents MDEA +DEA + AVRP have been studied. The results of the study show that the volume of absorption increased from 0.55 mol/mol to 0.65 mol/mol, and the amount of H₂S in the purified gas decreased from 0.022 g/m³ to 0.014 g/m³. Corrosion …

Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …

Modeling And Performance Analysis Of Solid Oxide Fuel Cell, Mariya Pecherskaya, Khakimjan Butanov, Suhrob A. Ibodullaev, Olim Ruzimuradov, Shavkat Mamatkulov

CHEMISTRY AND CHEMICAL ENGINEERING

A three-dimensional numerical model of the system configurations of various types of solid oxide fuel cells (SOFCs) is used and the effect of parameters on SOFC performance is numerically investigated using COMSOL Multiphysics. The effect of parameters such as support layer thickness, operating temperature, and electrode porosity are shown in the polarization and power curves for each model. The results of the study showed the advantages of the anode-supported SOFC compared to cathode- and electrolyte-supported SOFC.

Theoretical calculations demonstrate the highest output power density in the anode-supported SOFC at 900 ℃, and reach a value of 0.585 W cm^{-2 …}

Alkynylation Of Benzaldehyde And Its R-Substituted Derivatives Based On Lithium Phenylacetylenide, Sanat B. Samatov, Odiljon E. Ziyadullayev, Abduvakhab Ikramov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research work is for the first time the synthesis of the corresponding acetylene alcohols based on the alkynylation reaction of isolated benzaldehyde and its R-substituted derivatives in the BuLi/TGF system. The study proposed the reaction stages for the synthesis of acetylene alcohols in the selected BuLi/TGF system, the influence of factors influencing the process, including temperature, reaction duration and nature selected solvents. The structure of the synthesized acetylene alcohols was confirmed by modern methods of physicochemical analysis (¹H NMR, ¹³C NMR). In addition, the effect of substituents in benzaldehyde and its R-substituted derivatives …

A Tilted Broad Plume Underneath The Greenland Cratonic Keels, Dan Wang, Stephen S. Gao, Yangyang Liao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To advance our comprehension of the complex geological history and mantle dynamics in the north atlantic region, we employ all available broadband seismic data recorded in greenland to reveal an abnormal mantle transition zone (mtz) structure. Central and eastern greenland exhibits depressed 410 and 660 km discontinuities (d410 and d660, respectively) bordering the mtz, indicative of a substantial thermal anomaly associated with an underlying plume, surpassing the 1,800°c threshold for post-garnet phase transitions at the d660. Variations in mtz thickness across greenland stem from differing temperature anomalies at the d410 and d660, possibly linked to a tilted plume within the …

Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu

Journal of Electrochemistry

Zero-emission of desulfurization wastewater is one of the main demands for coal-fired power plants. As typical high salinity wastewater, it is hard to purify the desulfurization wastewater from coal-fired power plants through traditional physicochemical treatment or biochemical treatment, e.g., COD and Cl^–. A high concentration of Cl^– ion in desulfurization wastewater restricts wastewater reuse and zero-emission. Electrochemical technology is an attractive method for high salinity wastewater zero-emission, which provides a versatile, efficient, cost-effective, easily automatable, and clean industrial process. For advanced treatment of effluent after triple box process treatment in power plants, this paper reports an electrochemical …

Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu

Journal of Electrochemistry

The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.

Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng

Journal of Electrochemistry

Aryl-substituted benzothiophene and phenanthrene are important structural units in medicinal chemistry and materials science. Although extensive effort has been devoted to prepare these compounds and a variety of approaches have been developed to construct the 2-substituted benzothiophene core structure, environmental-friendly and efficient synthetic means are still desired. Based on our previous electrochemical Minisci-type arylation reaction with aryl diazonium salt as the aryl precursor, as well as the work from König’s group, herein, we described the use of paired electrolysis to achieve 2-aryl benzothiophenes and 9-aryl phenanthrenes employing benzenediazonium salts as the aryl radical precursors. Initially, 2-methylthiobenzendiazonium salt 1a and 4-methylbenzene …

Poster Session: Onu Engineering Freshman And Senior Design Projects, Keith Schimmel

Scholar Week 2016 - present

This poster session is held Friday, April 19, 4:45-6:15pm, with food served, in the Reed Hall of Science Tech Center.

The capstone engineering senior design projects at Olivet Nazarene University involve interdisciplinary engineering teams completing real-life projects sponsored by companies, mission organizations, and professional society competitions. The engineering first-year design projects at Olivet Nazarene University involve interdisciplinary engineering teams proposing product improvement designs, using Computer Aided Design (CAD) software. Posters for both the senior and freshman engineering design projects will be presented during this poster session.

Scaling And Optimizing Agitated Tanks For The Homogenization Of Complex Biological Suspensions, Josh Dittmer, Cara Serpe, Sterling Staranchuk

Scholar Week 2016 - present

This study presents an investigation of the agitated tank mixing dynamics across various scales, including lab, two pilot, and full scales, focusing on human blood plasma Kistler-Nitschmann-Cohn (KNC) I+II+III suspensions. The methods employed are empirical tank mixing correlations within the KaeMix software package and Computational Fluid Dynamics (CFD) modeling using ANSYS Fluent. Tank and agitator geometries were generated in ANSYS Workbench and meshed in ANSYS Fluent with varied cell sizes to capture detailed dynamics near the agitators and in the bulk fluid. Kaemix analysis provided rapid computation of bulk mixing times at different scales. Beyond simulations, the project aims to …

Scale-Up And Measurement Enhancements Of A Biogenerator Bioreactor, Jason J. Glas

Electronic Thesis and Dissertation Repository

Renewable energies in the form of wind and solar have seen steadfast growth across the world, however the abundance of these technologies that demonstrate short-term variability in power output threatens power grid stability and necessitates the use of fossil fuels for rapid throttling capability. A requirement for large scale energy storage systems becomes necessary and a system based on hydrogen generation, storage, and consumption for electrical grid supply-demand stabilization using a ferric sulfate oxidant is herein explored, named the BioGenerator. As the name implies, the system functions as an indirect microbial fuel cell using a biologically active broth dominated by …

Investigation Of Segregation In Mixing Pharmaceutical Powders Using Passive Acoustic Emissions In A V-Blender, Omar Salem

Electronic Thesis and Dissertation Repository

Powder mixing is a crucial and complex step in pharmaceutical production. Monitoring of mixing and segregation processes can be achieved using process analytical technologies to improve product quality. Passive acoustic emissions were examined during mixing in a V-blender. Vibrations from the emissions were measured through an accelerometer affixed to the outer V-shell arm lid. Horizontal and vertical loading configurations of particles were examined. Stable mixtures were reached when the measured amplitude plateaued around the approximate weighted average of the particles in the outer V-shell arm. Horizontal loading trials mixed faster and reached stable mixtures in fewer revolutions than vertical loading …

Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Layered Double Hydroxide (LDH) Is Reported To Improve The Durability Of Concretes, Primarily Due To Its Ability To Exchange Anionic Species, Including Chloride, Which Is Implicated In Corrosion-Driven Durability Issues. However, There Is No Comprehensive Study Investigating The Effect Of LDH On The Properties Of Different Cement Systems At Both Early And Mature Ages. In This Study, The Early Age And Mature Age Properties Of Portland Cement (OPC) And Calcium Sulfoaluminate (CSA) Cement Pastes Seeded With Submicron-Sized Calcium Aluminum-NO3 LDH (CaAl-NO3 LDH) Were Investigated. The Effects Of The 1–5%mass Dosage Of LDH On The Hydration Of Both Cement Systems Were …

Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

In recent years, significant attention has been directed toward evaluating the reactivity of diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these polymers, pim-1 has emerged as an exceptional candidate due to its noteworthy attributes including high surface area, excellent solubility, and the capability to fine-tune the nitrile functional groups along its polymeric backbone. In this study, we explored the impact of different functional groups, such as amidoxime (ax), aldoxime (ox), and carboxylate (cooh), on the degradation of dimethyl 4-nitrophenylphosphonate (dmnp) in comparison to pure pim-1 and their respective ce(oh)4-loaded polymer composites. Remarkably, the pim-1-ax analog exhibited …

Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao

LSU Doctoral Dissertations

This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …

Numerical Study Of Ozone Decomposition Reaction Behaviours In Gas-Solids Circulating Fluidized Bed Reactors, Zhengyuan Deng

Electronic Thesis and Dissertation Repository

This study numerically investigated the reaction behaviours of catalytic ozone decomposition reaction in a 10.2-meter-tall gas-solids circulating fluidized bed (CFB) reactor. A pseudo-homogeneous reactive transport model for ozone decomposition, integrated with the two-fluid model, was developed and validated using experimental data. Based on the model, the impacts of turbulence models, specularity coefficients, and simulation methods on reaction behaviours in the CFB riser reactor were explored. These three factors were found to significantly affect the hydrodynamic characteristics and the reaction behaviours in the riser. A comparative study of CFB riser and downer reactors was conducted. Operations in the direction of and …

Dying Of Natural Silk Deglued By Various Methods, Venera Djavdatovna Khamidova

Technical science and innovation

Products made of natural silk are indispensable for their hygienic properties and will always be in great demand. To obtain an even and intense coloration on a textile material, it is necessary to ensure its effective preparation with the most complete removal of hydrophobic contaminants (both natural and silicone oils applied during the weaving process, lubricants, etc.), which hinder the dyeing of the substrate and reduce the color characteristics of the obtained colors. Therefore, the issue of preparing natural silk for dyeing is relevant. In view of the sensitivity of the main fiber-forming component of natural silk - fibroin to …

Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva

Technical science and innovation

The purpose of this work is the chemical modification of cotton fabrics with natural globular protein. Modification was carried out in the process of finishing cotton fabrics, after decoction and bleaching in a continuous mode. The effect of modification on the strength, protein content and functional groups of cotton fabric has been studied. According to the results obtained using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a solution of globular protein increases the strength of the treated fabrics, depending on the concentration of the modifier and the temperature regime. Treatment with a highly …