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Upper Plate And Subduction Interface Deformation Models In The 2022 Revision Of The Aotearoa New Zealand National Seismic Hazard Model, Russ J. Van Dissen, Kaj M. Johnson, Hannu Seebeck, Laura M. Wallace, Chris Rollins, Jeremy Maurer, Matthew C. Gerstenberger, Charles A. Williams, Ian J. Hamling, Andrew Howell, Christopher J. Dicaprio 2024 Missouri University of Science and Technology

Upper Plate And Subduction Interface Deformation Models In The 2022 Revision Of The Aotearoa New Zealand National Seismic Hazard Model, Russ J. Van Dissen, Kaj M. Johnson, Hannu Seebeck, Laura M. Wallace, Chris Rollins, Jeremy Maurer, Matthew C. Gerstenberger, Charles A. Williams, Ian J. Hamling, Andrew Howell, Christopher J. Dicaprio

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

As part of the 2022 revision of the Aotearoa New Zealand National Seismic Hazard Model (NZ NSHM 2022), deformation models were constructed for the upper plate faults and subduction interfaces that impact ground-shaking hazard in New Zealand. These models provide the locations, geometries, and slip rates of the earthquake-producing faults in the NZ NSHM 2022. For upper plate faults, two deformation models were developed: a geologic model derived directly from the fault geometries and geologic slip rates in the NZ Community Fault Model version 1.0 (NZ CFM v.1.0); and a geodetic model that uses the same faults and fault geometries …


Identification Of Early Opportunities For Simultaneous H2 Separation And Co2 Storage Using Depleted Coal Seams, Masoud Aslannezhad, Mohammad Sayyafzadeh, Stefan Iglauer, Alireza Keshavarz 2024 Edith Cowan University

Identification Of Early Opportunities For Simultaneous H2 Separation And Co2 Storage Using Depleted Coal Seams, Masoud Aslannezhad, Mohammad Sayyafzadeh, Stefan Iglauer, Alireza Keshavarz

Research outputs 2022 to 2026

Hydrogen (H2) production by steam methane reforming (SMR) is an economically viable technique on a commercial scale. However, this process produces large amounts of carbon dioxide (CO2), which eventually negates the benefits of employing H2 as an industrial input and clean energy carrier. This issue has led to increasing interest in capturing CO2 emissions from SMR to produce H2. This study proposes and investigates the use of coalbed methane (CBM) resources for separating the mixture of H2 and CO2 gases. The competitive adsorption mechanism in CBM not only can separate the H2 gas from the mixture but also results into …


High Temperatures And Low Soil Moisture Synergistically Reduce Switchgrass Yields From Marginal Field Sites And Inhibit Fermentation, Sarvada Chipkar, Kevin Kahmark, Sven Bohm, Mir Zaman Hussain, Leela Joshi, Karleigh M. Krieg, Jacob Aguado, Jasmine Cassidy, Pablo Lozano, Kevin Garland, Andrea Senyk, Derek J. Debrauske, Elizabeth Whelan, Morgan Davies, Paul Urban, G. Philip Robertson, Trey K. Sato, Stephen K. Hamilton, Kurt D. Thelen, Rebecca Ong 2024 Michigan Technological University

High Temperatures And Low Soil Moisture Synergistically Reduce Switchgrass Yields From Marginal Field Sites And Inhibit Fermentation, Sarvada Chipkar, Kevin Kahmark, Sven Bohm, Mir Zaman Hussain, Leela Joshi, Karleigh M. Krieg, Jacob Aguado, Jasmine Cassidy, Pablo Lozano, Kevin Garland, Andrea Senyk, Derek J. Debrauske, Elizabeth Whelan, Morgan Davies, Paul Urban, G. Philip Robertson, Trey K. Sato, Stephen K. Hamilton, Kurt D. Thelen, Rebecca Ong

Michigan Tech Publications, Part 2

‘Marginal lands’ are low productivity sites abandoned from agriculture for reasons such as low or high soil water content, challenging topography, or nutrient deficiency. To avoid competition with crop production, cellulosic bioenergy crops have been proposed for cultivation on marginal lands, however on these sites they may be more strongly affected by environmental stresses such as low soil water content. In this study we used rainout shelters to induce low soil moisture on marginal lands and determine the effect of soil water stress on switchgrass growth and the subsequent production of bioethanol. Five marginal land sites that span a latitudinal …


Biodiesel Transesterification Of Spent Coffee Grounds Using Dbu As A Catalyst: Using Dbu To Make Biodiesel From Coffee Grounds, Christopher Stepherson, Pericles Karras, Amy Ha, Phuc Tan Nguyen, Abigail Pati, Jacob Hejazi, Soheil Hussain, Elizabeth De Young, Shuaicheng Fu 2024 Purdue University

Biodiesel Transesterification Of Spent Coffee Grounds Using Dbu As A Catalyst: Using Dbu To Make Biodiesel From Coffee Grounds, Christopher Stepherson, Pericles Karras, Amy Ha, Phuc Tan Nguyen, Abigail Pati, Jacob Hejazi, Soheil Hussain, Elizabeth De Young, Shuaicheng Fu

The Journal of Purdue Undergraduate Research

Coffee is one of the most universally consumed beverages. The world produces 60 million tons of spent coffee grounds (SCGs) as waste per year. Biodiesel made from SCGs is an eco-friendly alternative fuel but proves difficult to produce. 1,8-Diazabicyclo[ 5.4.0]undec-7- ene (DBU) was used as both a solvent and a catalyst with methanol to determine the efficiency of biodiesel production from SCGs. The process was completed by extracting coffee oil from acid-washed spent coffee grounds (AWSCGs) using hexane. The two extraction methods that were explored were Soxhlet and agitation. DBU is an interesting choice as a solvent and a catalyst …


The Top Ten Scientific Questions In Electrochemistry, Chinese Society of Electrochemistry 2024 Chinese Chemical Society | Xiamen University

The Top Ten Scientific Questions In Electrochemistry, Chinese Society Of Electrochemistry

Journal of Electrochemistry

No abstract provided.


Rational Design Of Heterostructured Nanomaterials For Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics In Alkaline Media, Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma 2024 Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Rational Design Of Heterostructured Nanomaterials For Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics In Alkaline Media, Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma

Journal of Electrochemistry

Owing to the merits of high energy density, as well as clean and sustainable properties, hydrogen has been deemed to be a prominent alternative energy to traditional fossil fuels. Electrocatalytic hydrogen evolution reaction (HER) has been considered to be mostly promising for achieving green hydrogen production, and has been widely studied in acidic and alkaline solutions. In particular, HER in alkaline media has high potential to achieve large-scale hydrogen production because of the increased durability of electrode materials. However, for the currently most prominent catalyst Pt, its HER kinetics in an alkaline solution is generally 2–3 orders lower than that …


Monodispersed Cu-Tcpp/Cu2O Hybrid Microspheres: A Superior Cascade Electrocatalyst Toward Co2 Reduction To C2 Products, Zi-Xuan Wan, Aidar Kuchkaev, Dmitry Yakhvarov, Xiong-Wu Kang 2024 New Energy Research Institute, School of Environment and Energy, South China University of Technology, Higher Education Mega Center, Guangzhou 510006, Guangdong, China

Monodispersed Cu-Tcpp/Cu2O Hybrid Microspheres: A Superior Cascade Electrocatalyst Toward Co2 Reduction To C2 Products, Zi-Xuan Wan, Aidar Kuchkaev, Dmitry Yakhvarov, Xiong-Wu Kang

Journal of Electrochemistry

The electrochemical conversion of carbon dioxide (CO2) into valuable chemicals is a feasible way to mitigate the negative impacts of overmuch CO2 emissions. Porphyrin-based metal organic frameworks (MOFs) are expected to be used for selective and efficient electrochemical CO2 reduction (ECR) with porous structure and ordered active sites. Herein, we report the synthesis of a monodispersed and spherical organic/inorganic hybrid Cu-TCPP@Cu2O electrocatalyst composed of Cu-TCPP (TCPP=tetrakis (4-carboxyphenyl) porphyrin) and Cu2O, where TCPP plays significant roles in regulating the morphology. In-situ formed Cu during ECR process in combination with Cu-TCPP (Cu-TCPP@Cu) can suppress …


Exploring The Electrochemical Performance Of Calcium-Ion Batteries With Novel Cathodes And Electrolytes, Paul Alexis Chando 2024 Syracuse University

Exploring The Electrochemical Performance Of Calcium-Ion Batteries With Novel Cathodes And Electrolytes, Paul Alexis Chando

Dissertations - ALL

The development of electric vehicles and energy storage devices are part of larger international efforts to create a sustainable future. Lithium-ion batteries have become crucial components to powering these technologies. However, the growing dependence of this singular battery chemistry to power an ever expanding landscape of technologies raises sustainability issues around lithium. Exploration of alternate battery chemistries have become part of research efforts to meet global energy demands. Calcium has emerged as one such battery system that could help alleviate stresses placed on lithium with its energy density and cost. Battery chemistries are unique, and each battery possesses its own …


Design Of Active Pharmaceutical Ingredients Solid States In Crystallization Processes, Weizhong Gong 2024 The University of Western Ontario

Design Of Active Pharmaceutical Ingredients Solid States In Crystallization Processes, Weizhong Gong

Electronic Thesis and Dissertation Repository

Crystallization is an important technique to obtain solid-state drugs from solutions. Physicochemical properties of the active pharmaceutical ingredients (APIs) are determined by crystallization. More than half of the active pharmaceutical ingredients exhibit polymorphism, the phenomenon of chemical species showing more than one unit-cell structure in the solid state. Controlling polymorphism is one of the most important goals during pharmaceutical manufacturing. Nevertheless, the control of polymorphism is sometimes not enough to realize the targeted physicochemical properties. Suitable additives (coformers/salt formers) are explored to generate new multi-component solid phases of poorly soluble/bioavailable active pharmaceutical ingredients (APIs). The design of pharmaceutical cocrystals and …


Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei 2024 Missouri University of Science and Technology

Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Carbon capture, utilization, and storage (CCUS) technologies are pivotal for transitioning to a net-zero economy by 2050. In particular, conversion of captured CO2 to marketable chemicals and fuels appears to be a sustainable approach to not only curb greenhouse emissions but also transform wastes like CO2 into useful products through storage of renewable energy in chemical bonds. Bifunctional materials (BFMs) composed of adsorbents and catalysts have shown promise in reactive capture and conversion of CO2 at high temperatures. In this study, we extend the application of 3D printing technology to formulate a novel set of BFMs composed …


Characterizing Nonlinear Fluid Flow In 3d Printed Rock Fractures: Effects Of Roughness, Aperture, And Intersection Angles, Ghoulem Ifrene, Prasad Pothana, Sven Egenhoff, Nicholas Bittner, Kuldeep Singh 2024 University of North Dakota

Characterizing Nonlinear Fluid Flow In 3d Printed Rock Fractures: Effects Of Roughness, Aperture, And Intersection Angles, Ghoulem Ifrene, Prasad Pothana, Sven Egenhoff, Nicholas Bittner, Kuldeep Singh

Petroleum Engineering Posters and Presentations

Understanding fluid flow behavior at fracture intersections is vital to geothermal energy extraction, underground water flow, and CO2 storage. Here, laboratory experiments were performed to study the effect of surface roughness, intersection angles, and aperture on nonlinear flow behavior in simple fracture networks. A FormLabs (3B+) 3D printer was used to fabricate 8 samples of 38.1mm in diameter and 59.43mm or 54.9mm in length with 2 intersecting fractures of 10o and 40o respectively. The surface roughness of the fractures was based on laser profilometry measurements from two induced mode 1 rock fractures, with a joint roughness coefficient …


Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang 2024 Missouri University of Science and Technology

Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

This article has been retracted: please see Elsevier Policy on Article Withdrawal (https://www.elsevier.com/about/policies/article-withdrawal). This article has been retracted at the request of the Editor-in-Chief. The Editor-in-Chief found that the corresponding author of this article submitted the manuscript to the journal without the consent of the two individuals named as "co-authors", using invented email addresses to impersonate them. In addition, based on the raw materials presented to the journal by the second co-author and the Editor-in-Chief's own investigation, the Editor-in-Chief believes that some results in the paper are fabricated. Based on these two findings, the Editor-in-Chief has decided to retract the …


Physicochemical Characterization Of Metal Organic Framework Materials: A Mini Review, Hussein R. Abid, Muhammad R. Azhar, Stefan Iglauer, Zana H. Rada, Ahmed Al-Yaseri, Alireza Keshavarz 2024 Edith Cowan University

Physicochemical Characterization Of Metal Organic Framework Materials: A Mini Review, Hussein R. Abid, Muhammad R. Azhar, Stefan Iglauer, Zana H. Rada, Ahmed Al-Yaseri, Alireza Keshavarz

Research outputs 2022 to 2026

Metal-organic frameworks (MOFs) are promising materials offering exceptional performance across a myriad of applications, attributable to their remarkable physicochemical properties such as regular porosity, crystalline structure, and tailored functional groups. Despite their potential, there is a lack of dedicated reviews that focus on key physicochemical characterizations of MOFs for the beginners and new researchers in the field. This review is written based on our expertise in the synthesis and characterization of MOFs, specifically to provide a right direction for the researcher who is a beginner in this area. In this way, experimental errors can be reduced, and wastage of time …


The Effect Of Steam Explosion On Lipids Extraction From Microalgae And Derivation Of Pectin Films From Waste Culture, Shahil Chhiba 2024 Western University

The Effect Of Steam Explosion On Lipids Extraction From Microalgae And Derivation Of Pectin Films From Waste Culture, Shahil Chhiba

Electronic Thesis and Dissertation Repository

The objective of this study was to investigate the properties of sustainable replacements for plastics and diesel fuel, derived from microalgae (Chlorella vulgaris) subjected to steam explosion. During the process, oven temperatures of up to 500 °C were reached, with the experiments left for different times after reaching their maximum internal temperature. Lipids were extracted from algal cultures using a modified Folch method. The waste microalgae were combined with pectin and glycerol to form biodegradable films, and their solubilities and tensile strengths were measured. The highest yield was 124 mg lipids/g microalgae from 400 °C steam explosion for …


Development Of A Xenograft For Annular Repair Using Pulsed Electric Field Exposures For Enhanced Decellularization, Prince Mensah Kwaku Atsu 2024 Rowan University

Development Of A Xenograft For Annular Repair Using Pulsed Electric Field Exposures For Enhanced Decellularization, Prince Mensah Kwaku Atsu

Theses and Dissertations

Severe back injuries and chronic pain necessitate surgical replacement of damaged intervertebral disc (IVD) cartilage in advanced disease stages. Bovine IVD tissue has been exposed to an upper threshold pulsed electric field (PEF) dose, causing cell death without thermal damage to the tissue. Subsequent PEF exposures at lower magnitudes have accelerated the removal of immunogenic biomolecules though electrokinetic extraction using optimized aqueous solutions. This approach yields a natural scaffold, ready for biocompatibility and mechanical strength assessment. The effects of microsecond pulsed electric fields (µsPEF) on primary bovine AF fibroblast-like cells have been characterized in vitro. PEFs of 10 and 100 …


Integrated Computer-Aided Design, Experimentation, And Optimization Approach For Perovskites And Petroleum Packaging Processes, Swapana Subbarao Jerpoth 2024 Rowan University

Integrated Computer-Aided Design, Experimentation, And Optimization Approach For Perovskites And Petroleum Packaging Processes, Swapana Subbarao Jerpoth

Theses and Dissertations

According to the World Economic Forum report, the U.S. currently has an energy efficiency of just 30%, thus illustrating the potential scope and need for efficiency enhancement and waste minimization. In the U.S. energy sector, petroleum and solar energy are the two key pillars that have the potential to create research opportunities for transition to a cleaner, greener, and sustainable future. In this research endeavor, the focus is on two pivotal areas: (i) Computer-aided perovskite solar cell synthesis; and (ii) Optimization of flow processes through multiproduct petroleum pipelines. In the area of perovskite synthesis, the emphasis is on the enhancement …


Cancer Treatment By Targeting Hdac4 Translocation Induced By Microsecond Pulsed Electric Field Exposure: Mechanistic Insights Through Kinases And Phosphatases, Zahra Safaei 2024 Rowan University

Cancer Treatment By Targeting Hdac4 Translocation Induced By Microsecond Pulsed Electric Field Exposure: Mechanistic Insights Through Kinases And Phosphatases, Zahra Safaei

Theses and Dissertations

Epigenetic modifications, arising from sub-cellular shifts in histone deacetylase (HDAC) activity and localization, present promising strategies for diverse cancer treatments. HDACs, enzymes responsible for post-translational histone modifications, induce these epigenetic changes by removing acetyl groups from ε-N-acetyl-lysine residues on histones, thereby suppressing gene transcription. Within the HDAC group, class IIa HDACs are notable for their responsiveness to extracellular signals, bridging the gap between external stimuli, plasma membrane, and genome through nuclear-cytoplasmic translocation. This localization offers two significant mechanisms for cancer treatment: nuclear accumulation of HDACs represses oncogenic transcription factors, such as myocyte-specific enhancer factor 2C (MEF2C), triggering various cell death …


A Prediction Of Interfacial Tension By Using Molecular Dynamics Simulation: A Study On Effects Of Cushion Gas (Co2, N2 And Ch4) For Underground Hydrogen Storage, Quoc T. Doan, Alireza Keshavarz, Caetano R. Miranda, Peter Behrenbruch, Stefan Iglauer 2024 Edith Cowan University

A Prediction Of Interfacial Tension By Using Molecular Dynamics Simulation: A Study On Effects Of Cushion Gas (Co2, N2 And Ch4) For Underground Hydrogen Storage, Quoc T. Doan, Alireza Keshavarz, Caetano R. Miranda, Peter Behrenbruch, Stefan Iglauer

Research outputs 2022 to 2026

Carbon Dioxide (CO2) emissions from fossil fuel consumption have caused global warming and remain challenging problems for mitigation. Underground Hydrogen Storage (UHS) provides clean fuel and replaces traditional fossil fuels to reduce emissions of CO2. Geological formations such as depleted oil/gas reservoirs, deep saline aquifers and shale formations have been recognized as potential targets to inject and store H2 into the subsurface formations for large-scale implementation of CCS and UHS. However, the presence of H2 with cushion gas at different fractions under different geo-storage conditions, which can influence Hydrogen's flow properties, was not investigated widely. Until now, studies of interfacial …


Molecular Understanding And Design Of Deep Eutectic Solvents And Proteins Using Computer Simulations And Machine Learning, Usman Lame Abbas 2024 University of Kentucky

Molecular Understanding And Design Of Deep Eutectic Solvents And Proteins Using Computer Simulations And Machine Learning, Usman Lame Abbas

Theses and Dissertations--Chemical and Materials Engineering

Hydrophobic deep eutectic solvents (DESs) have emerged as excellent extractants. A major challenge is the lack of an efficient tool to discover DES candidates. Currently, the search relies heavily on the researchers’ intuition or a trial-and-error process, which leads to a low success rate or bypassing of promising candidates. DES performance depends on the heterogeneous hydrogen bond environment formed by multiple hydrogen bond donors and acceptors. Understanding this heterogeneous hydrogen bond environment can help develop principles for designing high performance DESs for extraction and other separation applications. This work investigates the structure and dynamics of hydrogen bonds in hydrophobic DESs …


Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith 2024 Missouri University of Science and Technology

Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith

Chemical and Biochemical Engineering Faculty Research & Creative Works

Thermogravimetric analysis (TGA) is a powerful technique and useful method for characterizing biomass as a non-conventional fuel. A TGA apparatus has been utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification of hardwood (HW), softwood (SW) pellets, and refuse-derived fuel (RDF) materials. The solid conversion rate and the volatile species formation rate have been estimated to quantify the rates of devolatilization for each material. In addition, the combustion kinetic characteristics of the three biomass feedstocks were investigated using TGA at different heating rates, and a thermal kinetic analysis was conducted to describe the …


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