Solubility Characterization Of Organic Molecules For Aqueous Organic Redox Flow Batteries, 2024 California Polytechnic State University, San Luis Obispo
Solubility Characterization Of Organic Molecules For Aqueous Organic Redox Flow Batteries, Anthony W. Ferrell, Harkeerith K. Vij, Seamus D. Jones
College of Engineering Summer Undergraduate Research Program
The major obstacle to renewable energy sources is a lack of long-term energy storage capabilities. Energy produced during the day dissipates, leaving insufficient electricity for at night. The goal of the project is to design an Aqueous Organic Redox Flow Battery (AORFB) to act as long-term energy storage. Work has been done using machine learning to identify suitable compounds for the batteries. In this work there was no indication as to the aqueous solubility of the molecules; this controls the device’s energy storage capabilities. We used a machine learning model to determine the aqueous solubility of slightly more than 3000 …
Polyvinyl Alcohol–Red Cabbage Nanofibers As Ph-Responsive Freshness Sensors For Advanced Food Packaging Technology, 2024 Nanotechnology of Food Study Program, Polytechnic of AKA Bogor, Bogor 16154, Indonesia
Polyvinyl Alcohol–Red Cabbage Nanofibers As Ph-Responsive Freshness Sensors For Advanced Food Packaging Technology, Foliatini Foliatini, Singgih Wibowo, Henny Rochaeni, Suhartini Suhartini, Fachrurrazie Fachrurrazie, Arzzaq Imanda Prianditya, Pradnadia Putri Hadriansyah, Naura Athira Putri Siregar, Novi Nurpadilah, Putri Alfiani, Maudi Rahim, Endah Sriwahyuni
Makara Journal of Science
The development of innovative food packaging technologies, particularly those capable of monitoring freshness, has become increasingly important in the food industry. This research explores the development of a pH-responsive freshness sensor using polyvinyl alcohol–red cabbage (PVA/RC) nanofibers. The nanofibers are fabricated through the electrospinning technique and meticulously analyzed via scanning electron microscopy, Fourier-transform infrared (FTIR) spectroscopy, and differential scanning calorimetry (DSC). The results underscore the fine structure of the nanofiber matrix, with an average diameter of ~68 nm. FTIR analysis substantiates the presence of anthocyanin compounds from RC within the PVA/RC nanofibers, which confirms the integration of beneficial components into …
Synthesis Of Uv-Blocking Titanium Oxide Films Via Remote-Type Atmospheric Pressure Plasma Cvd, 2024 DaikyoNishikawa
Synthesis Of Uv-Blocking Titanium Oxide Films Via Remote-Type Atmospheric Pressure Plasma Cvd, Hayate Endo, Akira Shirakura, Shinya Kudo, Tetsuya Suzuki
Journal of Applied Packaging Research
This study aims to enhance UV resistance in plastics, focusing on polycarbonate (PC) and polypropylene (PP) commonly used in reuseable packaging. Traditional organic UV absorbers face safety and cost challenges, prompting our investigation into alternative methods. We utilized chemical vapor deposition (CVD), specifically Atmospheric Pressure Plasma Enhanced CVD (AP-PE-CVD), to apply titanium oxide (TiO2) thin films. This innovative approach, using a remote-type AP-PE-CVD technique, enables coating on complex surfaces and 3D objects. The produced TiO2 films, containing over 20% titanium, showed a UV transmittance of 14.5% at 310 nm and effective UV blocking starting at 372 nm. The …
Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, 2024 Clemson University
Extraction Of Neutron-Gamma Irradiated Diffusion Pump Oils, Cooper L. Tillman
All Theses
This work successfully demonstrates solvent extraction methods for separation of oil from the by-products when two commercially available vacuum pump oils were exposed to an intense neutron and gamma-ray radiation environment. Nuclear fusion power at a commercial scale has accelerated the need for radiation resistant vacuum technology, such as oil-based diffusion pumps. Polyphenyl ether and aromatic silicone oils were irradiated at the Rhode Island Nuclear Science Center (RINSC) up to MGy absorbed doses with neutron and gamma-ray radiation. Solvent extractions were performed using hexane and isopropanol to characterize the oil extraction as a function of total absorbed dose. The by-products …
Fabrication And Characterization Of Lignin–Pva Hydrogels With Tunable Network Structures, 2024 Clemson University
Fabrication And Characterization Of Lignin–Pva Hydrogels With Tunable Network Structures, Keturah Bethel
All Dissertations
The ability to directly tune the crosslinked network structure of hydrogels is crucial for their functional applications in various fields, such as water filtration, protein separation, and tissue engineering. By controlling the crosslink density of the hydrogel, one can directly alter the mesh size – i.e., the end-to-end distance between crosslink junctions – and, subsequently, directly alter the hydrogel performance. This work discusses the fabrication and characterization of soft composites containing the biopolymer, lignin, are discussed. Precisely, physically-crosslinked composite lignin–Poly(vinyl alcohol) (PVA) hydrogels were fabricated via the freeze-thaw (F/T) pathway, whereby solutions containing specified amounts of PVA and lignin were …
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), 2024 Department of Biology, University of Indonesia, Depok 16424, West Java
Optimizing The Expression Of Polyethylene Terephtalate Hydrolase-Encoding Synthetic Gene In Escherichia Coli Arctic Express (De3), Jocelyn Nataniel, Maria Ulfah, Dini Achnafani, Niknik Nurhayati, Gabriela Christy Sabbathini, Sri Rezeki Wulandari, Abinawanto Abinawanto, Is Helianti
Makara Journal of Science
The waste of polyethylene terephthalate (PET) plastic waste in Indonesia is a pressing concern due to its slow degradation and potential environmental damage. One promising solution is to utilize polyethylene terephthalate hydrolase from Ideonella sakaiensis (IsPETase), an enzyme that specifically degrades PET. However, inducing the expression of IsPETase synthetic gene in Escherichia coli BL21 (DE3) has been challenging because much of it remains insoluble. This study aimed to express IsPETase in E. coli Arctic Express (DE3) and optimize the conditions to enhance its production. First, pET22b(+)pelB-IsPETase was inserted into E. coli Arctic Express (DE3). The …
Targeted Drug Delivery: Investigating Protein Corona Behavior, 2024 New Jersey Institute of Technology
Targeted Drug Delivery: Investigating Protein Corona Behavior, Atharva Markale
Theses
Due to high specificity and less toxicity, nanoparticles have become promising for targeted drug delivery against cancer, although they face challenges when they enter the bloodstream, making their behavior unpredictable. The deposition of proteins on nanoparticles, the protein corona, changes their biosignature, affecting their circulation, drug release potency, targeting ability, and immunogenicity. The continuous exchange of protein layers on a nanoscale is complex to analyze.
Nanoparticle tracking analysis (NTA) is a method to characterize nanoparticles in blood plasma by combining principles of light scattering microscopy and Brownian motion. In this work, time-dependent experiments with plasma were conducted to analyze the …
Insight Into The Application Of Engineered Phenol Polymer Nanocomposites For Geothermal Well Applications To Modify Fracture Permeability, 2024 University of New Mexico - Main Campus
Insight Into The Application Of Engineered Phenol Polymer Nanocomposites For Geothermal Well Applications To Modify Fracture Permeability, Fatemeh Hamidi
Civil Engineering ETDs
In enhanced geothermal systems, the efficient transfer of heat from the formation to the fluid circulating through the fracture network can be compromised when thermal short-circuiting occurs due to preferential flow through highly conductive fractures. This study introduces a pioneering approach using newly developed phenol polymer nanocomposites as an engineering solution to address the challenges associated with preferential flow in geothermal wells, which can lead to thermal short-circuiting. Multiple phenol polymer nanocomposites were formulated, incorporating aluminum oxide, COOH-functionalized graphitized multi-walled carbon nanotubes (MWCNTs), and graphene nanoparticles, each with a 0.5 wt.% polymer dosage. This research successfully modified the crosslinking process …
Discovery Of Nanostructured Material Properties For Advanced Polymeric Systems, 2024 University of Maine
Discovery Of Nanostructured Material Properties For Advanced Polymeric Systems, Colton Lee Duprey
Electronic Theses and Dissertations
Polymer science has become a well-studied field in recent years. Their tunability, functionalization, and unique intermolecular reactions make them a significant area of interest for materials science. The production and research of polymeric materials has increased ever since their invention, and does look to be slowing down currently. While polymers may be considered macromolecules, their properties can be heavily influenced by the incorporation of nanostructures. Despite their small dimensions, nanostructured materials can have substantial impacts on these systems, even at small loading percentages. Nanomaterials have also become a topic of increasingly large interest in research over the last few decades. …
Spray Drying Of Cellulose Nanofibrils And Cellulose Nanocrystals: Applications In Thermoplastic Nanocomposites And 3d Printing, 2024 university of maine
Spray Drying Of Cellulose Nanofibrils And Cellulose Nanocrystals: Applications In Thermoplastic Nanocomposites And 3d Printing, Sungjun Hwang
Electronic Theses and Dissertations
Cellulose nanocrystals (CNCs) and cellulose nanofibrils (CNFs) are promising alternatives to inorganic fillers in polymer matrix composites (PMCs) attributable to their biodegradability and nanometer-sized fibrils. The drying process is crucial for their incorporation into PMCs, which affects final production cost and performance. The University of Maine has researched spray drying (SD) for CNCs and CNFs, finding that SD is a cost-effective method and enhances the mechanical properties of the thermoplastic matrix attributable to the excellent distribution and dispersion of small particles into plastic matrices. The primary objective of this dissertation is to enhance the viability of spray-dried CNC/CNF powders. Three …
Biomass Derived Lignin Polymer Modification For Sustainable Chemical Engineering Applications, 2024 University of Arkansas, Fayetteville
Biomass Derived Lignin Polymer Modification For Sustainable Chemical Engineering Applications, Samantha Glidewell, Keisha Walters
Chemical Engineering Undergraduate Honors Theses
Lignin is an abundant naturally occurring plant-based polymer that is branched, highly unsaturated, and rich in aliphatic and aromatic hydroxyl groups. Lignin is a significant byproduct of the wood pulp and paper industries; however, it has yet to be widely utilized in commercial applications due to its non-linear structure, broad range of molecular weights, hydrophobicity, high rigidity, and brittleness. Recent investigations into modifying lignin to broaden its potential uses have shown promising results. This thesis explores different modification techniques of the naturally occurring hardwood lignin polymer for specific applications in areas of water treatment and polyurethane (PU) production. The first …
Design And Develop Lignin Based Recyclable Copolymers For Hydrophobic Coatings, 2024 University of Tennessee, Knoxville
Design And Develop Lignin Based Recyclable Copolymers For Hydrophobic Coatings, Di Xie
Doctoral Dissertations
Due to the abundance, renewability, biodegradability, overall hydrophobicity, good compatibility with cellulose, and anti-UV/oxidant abilities, lignin has great application potentials in hydrophobic coatings on cellulose-based substrates. However, lignin's structural heterogeneity and rigidity challenge its value-added utilization. Herein, Kraft lignin (KL), from paper mills, is fractionated into more homogeneous fractions (FL), nanosized into lignin micro-nanospheres (LMNS), chemically modified and copolymerized with other constituents to fabricate hydrophobic coating materials with improved coating performances.
To investigate structure-property relationships of lignin-based copolymers, solvent fractionation is conducted to obtain FLs with different molecular weight (MW) and hydroxyl (OH) contents to prepare copolymers by integrating with …
Study Of Reactive Distillation Equipment For Eterification Process, 2024 Shahrisabz Branch of the Tashkent Institute of Chemical Technology, Shakhrisabz, Uzbekistan
Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …
Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, 2024 Louisiana State University and Agricultural and Mechanical College
Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao
LSU Doctoral Dissertations
This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …
Quasi-Static And Impact Load Response Of Bfrp-Reinforced Concrete Beams And Post-Terrorist-Attack Sub-Assemblages, 2024 Old Dominion University
Quasi-Static And Impact Load Response Of Bfrp-Reinforced Concrete Beams And Post-Terrorist-Attack Sub-Assemblages, José Luis Carrasquillo
Civil & Environmental Engineering Theses & Dissertations
This dissertation presents the outcome of a theoretical and experimental study of Basalt Fiber Reinforced Polymer (BFRP) reinforced concrete beams and post-terrorist-attack subassemblages subjected to either quasi-static or impact load. Both BFRP reinforcement as well as BFRP fabric are used in this investigation. The sub-assemblage consists of an otherwise two-span beam converted to a fixed-end single-span one owing to the loss of a middle column blasted off during the terrorist attack. The simply supported beams are subjected to a midspan quasistatic or an impact load. However, each sub-assemblage is subjected to a quasi-static load up to collapse to simulate the …
Removal Of Residual Stress In 3d Printed Polymers, 2024 The University of Akron
Removal Of Residual Stress In 3d Printed Polymers, Christian Jenkins
Williams Honors College, Honors Research Projects
This project aims to investigate the relationship between stress relaxation and the reduction of dimensional shrinkage and warping in 3D printed polymers produced through fused filament fabrication. The hypothesis suggests that residual stress in 3D printed structures results from factors such as temperature differences, molecular-level contributions, and rapid cooling, causing post-printing warpage and damage. To mitigate these issues, the project proposes annealing 3D printed polymers in a hot sandbath to allow stress relaxation without warping. The study will employ a Dynamic Mechanical Analysis (DMA) machine to assess mechanical properties of relaxed and unrelaxed samples, comparing their effectiveness. The project's timeline …
Optimized Pi Compound Mixing Strategy, 2024 The University of Akron
Optimized Pi Compound Mixing Strategy, Cecilia Mainzer
Williams Honors College, Honors Research Projects
The project focuses on developing an optimal mixing strategy for a polyisoprene (PI) compound at the Goodyear Tire & Rubber Company. The aim is to optimize performance objectives of the compound. The project involved research, design iterations, mixing analyses, and performance evaluations, while adhering to engineering codes and standards.
The design process includes analyzing differences between two mixing technologies, intermesh and tangential rotors; altering mixing conditions; and exploring additional polymer systems and coupling technology of the compound.
Validation data confirms that the mixing technology and compound recipe meets all success metrics, including stiffness, hysteresis, adhesion, cure rate, and tear performance …
Schaeffler Icvd Coating Machine, 2024 The University of Akron
Schaeffler Icvd Coating Machine, Louis Mcgrath
Williams Honors College, Honors Research Projects
Chemical Vapor Deposition (CVD) is mutual technology used to deposit thin film through a gaseous phase by vaporizing the solid materials. This conventional process usually requires high thermal stability of the materials, which is not applicable for most of the polymeric materials. Therefore, a novel process, initiated Chemical Vapor Deposition (iCVD) is developed by introducing the gaseous monument and initiator to form the thin film in-situ. By adjusting the free-radical polymerization in the vapor phase, a variety of thin and uniform polymer films can be achieved. Depending on the chemistry, iCVD has many categories. This report explains the design …
Degradable Staples And Delivery Device, 2024 The University of Akron
Degradable Staples And Delivery Device, Meha Elango, Jessica Cabrera, Makayla Scarpitti, Kareemat Melaiye
Williams Honors College, Honors Research Projects
The scope of this project is to design a method to secure skin grafts to healthy tissue. The ultimate goal for the proposed method is to be dissolvable in some form. Currently, skin grafts procedures utilize staples in most cases to hold a skin graft in place, but there are disadvantages that come with it. Staples are easy to place, but time consuming during the removal procedure. They also cause a lot of pain and discomfort for the patient. The goal of this project is to determine a way a secure skin grafts to healthy skin in order to reduce …
The Effects Of Relative Humidity And Valency On Water Absorption And Structure In Polyelectrolyte Brushes, 2024 The University of Akron
The Effects Of Relative Humidity And Valency On Water Absorption And Structure In Polyelectrolyte Brushes, Andrea Klima
Williams Honors College, Honors Research Projects
The purpose of this project was to understand the relationship between relative humidity, ion valency, and the structure of water on positively (PMETAC) and negatively (PSPMA) charged polyelectrolyte brushes. The polyelectrolyte brushes were synthesized using Activators Regenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP) and were soaked in concentrations containing 0.1 M of the target counterion. The brushes were then exposed to humid vapor, and spectra were collected in 5% intervals between 0% and 85% for each counterion. Two trials were completed for each counterion studied to ensure agreement between datasets. In all spectra, peaks appeared for the …