Chemical Engineering Commons^™

Waste Biomass-Derived Ultraporous Functionalized Superactivated Hydrochars For Hydrogen Storage And Carbon Capture, Al Ibtida Sultana

Theses and Dissertations

Accelerating world population and simultaneous growth in economic race has resulted in parallel rise of waste generation where the necessity of mitigating the climate change, via transitioning towards a clean energy economy and minimization of greenhouse gas from atmosphere, is in urgent need of attention. Hence, the objectives of this dissertation comprised of firstly upcycling waste biomass into low-cost and effective adsorbent material such that, secondly, its surface could be tailored by modulating its synthesis conditions (hydrothermal carbonization and chemical activation) to be developed into ultraporous and functionalized adsorption medium in order to, thirdly, assess its application as adsorbents for …

Hydrogen Storage In Depleted Gas Reservoirs: A Comprehensive Review, Nasiru S. Muhammed, Md Bashirul Haq, Dhafer A. Al Shehri, Amir Al-Ahmed, Mohammad M. Rahman, Ehsan Zaman, Stefan Iglauer

Research outputs 2022 to 2026

Hydrogen future depends on large-scale storage, which can be provided by geological formations (such as caverns, aquifers, and depleted oil and gas reservoirs) to handle demand and supply changes, a typical hysteresis of most renewable energy sources. Amongst them, depleted natural gas reservoirs are the most cost-effective and secure solutions due to their wide geographic distribution, proven surface facilities, and less ambiguous site evaluation. They also require less cushion gas as the native residual gases serve as a buffer for pressure maintenance during storage. However, there is a lack of thorough understanding of this technology. This work aims to provide …

Application Of Pinch Analysis For Energy Saving And Reducing Gas Emissions Based On Mathematical Model In The Hydrocracking Unit, Badiea S. Babaqi

Hadhramout University Journal of Natural & Applied Sciences

Pinch analysis approach of the heat exchanger network in the hydrocracking unit was carried out to save the energy consumption and reduce the gas emissions simultaneously. This method based on mathematical model of the hydrocracking unit for a heat exchanger network using LINGO program to achieve the minimization of environmental impacts and the reduction of energy cost. The presented energy demands for the heat exchanger network are 20.38 MMBtu/hr and 26.52 MMBtu/hr for heating and cooling loads, respectively. The current analysis shows a huge opportunity in order to decrease energy consumption of the hydrocracking process at a minimum temperature difference …

Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane, Baitang Jin, Kaiying Wang, Han Yu, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Atomic Layer Deposition (ALD) Was Applied to Develop CeO_x-Overcoated Ni/Al₂O₃ Catalyst for Bi-Reforming of Methane (BRM), as the Combination of Dry Reforming of Methane (DRM) and Steam Reforming of Methane (SRM). Non-Stoichiometric CeO_x Thin Films Were Successfully Deposited on Ni/Al₂O₃ Particles by ALD, Which Constructed a Beneficial Ni-CeO_x Interface and Modified the Catalyst Property. Ascribed to the Unique ALD Growth Mode, a High Amount of Ce(III) and Oxygen Vacancies Existed in the ALD-Deposited CeO_x overcoating. a Reduction Process Before the BRM Reaction Contributed to the Further Reduction of Ce(IV) …

A Review Of Hydrogen/Rock/Brine Interaction: Implications For Hydrogen Geo-Storage, Masoud Aslannezhad, Muhammad Ali, Azim Kalantariasl, Mohammad Sayyafzadeh, Zhenjiang You, Stefan Iglauer, Alireza Keshavarz

Research outputs 2022 to 2026

Hydrogen (H₂) is currently considered a clean fuel to decrease anthropogenic greenhouse gas emissions and will play a vital role in climate change mitigation. Nevertheless, one of the primary challenges of achieving a complete H₂ economy is the large-scale storage of H₂, which is unsafe on the surface because H₂ is highly compressible, volatile, and flammable. Hydrogen storage in geological formations could be a potential solution to this problem because of the abundance of such formations and their high storage capacities. Wettability plays a critical role in the displacement of formation water and determines …

Model For Calculating The Static Characteristics Of Hydraulic Systems Of Hydro Technical Buildings, Mirkhalil Ismailov, Dong Zhang, Farkhod Kasimov

Chemical Technology, Control and Management

Hydraulic mechanisms that actuate flat gates, widely used in hydraulic structures, are studied as hydraulic actuators of the system. Their static mathematical models are developed using an integrated methodology with a hydraulic pump, inlet and suction pipes, and internal and external resistance factors. Unlike existing mathematical models, the model developed in this paper allows a detailed description of the characteristics of hydraulic drives due to the fact that pressure losses in the throttle, regulator, and power amplifier, as well as local resistances in hydraulic pipelines, are taken into account.

Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov

Chemical Technology, Control and Management

The article reveals the meaning and essence of the modeling method in the study of complex technological processes based on the problematic aspects of building multifactorial relationships and the principles for their elimination. In the case of non-linearity of multifactorial connections of a complex system, the expediency of approximating such functions by polynomials is substantiated. The authors' ideas about the increasing importance of interpolation methods in practice against the background of the possibility of simplification based on the use of modern mathematical hardware and software for integration into the process of modeling and optimizing technological processes due to the complexity …

Structural Model Of The Technological Process Of Storage And Processing Of Oil Raw Materials, N.A Kabulov

Chemical Technology, Control and Management

The technological method of storing and processing oilseed raw materials is structurally modelled in the article. Additionally, it is suggested that the generalized structure be presented as a three-part scheme, consisting of a raw material department, a processing shop, and transportation networks. On the basis of a thorough examination of the characteristics of the constituent parts of the technological complex, a practical model for the problem of the general characteristics of the technological complex is proposed.

Analysis Of Vegetable Oil Refining Technology, Elyor Samadov

Chemical Technology, Control and Management

Innovative technologies for refining vegetable oils are presented, as well as the qualitative characteristics of raw vegetable oils obtained by extraction and mechanical methods. A general review of the chemical composition and impurities of vegetable oils resulting from the reaction between glycerol and fatty acids is carried out, and a brief review of the study to determine the effect of refining on biologically active components.

The analytical review is devoted to a comparative comparison of two types of refining - chemical and physical refining.

Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva

Chemical Technology, Control and Management

The requirements of high operational reliability are most fully met by automated monitoring and control systems, the elements of which are magnetoelastic sensors. Such sensors, due to their metrological characteristics, have found application in electrified railway transport, in the metallurgical, metalworking, mining and other industries. The principle of operation of such sensors is based on the fact that in the process of influencing the magnetic core of the sensor by force, there is a change in the magnetic permeability of the material, a change in the magnetic resistance of the circuit, a change in the mutual inductance coefficient of the …

Method For Solving The Kinematics Inverse Problem For Moving Along A Trajectory Objects (As An Example Of Assembly Industrial Robots), Oripjon Olimovich Zaripov, Dildora Usmonovna Sevinova

Chemical Technology, Control and Management

The task of performing a technological operation in kinematic calculation of industrial robots and determining various kinematic parameters describing the efficiency of robots is solved. Among them, one of the urgent problems based on the analysis of the entire kinematics of the assembly industrial robot is the problem of solving the inverse problem of the kinematics of the manipulator positions, that is, the problem of determining the relative parameters that change the coordinates of the gripper according to the given position. The article presents a scheme that allows solving the inverse kinematics problem of an industrial robot manipulator moving in …

Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov

Chemical Technology, Control and Management

In the article given materials of developing of three-phase electromagnetic current transducers of reactive power, using with asynchronous motor, methods connecting of two sensing element, series, parallel and differential and loops suitable for each phase, dynamic characteristics of output signals of three-phase electromagnetic current transducers asynchronous motor.

On the basis of modern calculation and design complexes are of great importance in the research variable sizes of three-phase current electromagnetic transducers of filter-compensation devices of reactive power of asynchronous motors. Presented mathematical model of research of electrical, electromagnetic and magnetic elements of electromagnetic current transducers in the …

Modeling Of The Process Of Measuring Conversion Of The Flow Of Liquid And Gaseous Media By The Method Of Variable Pressure Drop, Shukhrat Manapovich Gulyamov, Elbek Elmirza O'G'Li Ortiqov

Chemical Technology, Control and Management

On the basis of material and heat balances, taking into account the initial and boundary conditions, a mathematical model of the process of measuring the transformation of liquid and gaseous technological media by the method of variable pressure drop is constructed. The analysis of the results of studying the influence of non-stationary flows of a controlled medium on the uncertainty of the results of measuring the flow rate of liquids and gaseous mixtures with a changing hydrodynamic structure of the flow of a controlled medium is performed. A comparative analysis of the calculated and experimental transient processes in the measuring …

Virtual Potassium Chloride Analyzer In The System Of Advanced Control Of Potash Fertilizer Production Processes, Umidjon Ruziev, Jahongir Sherboyevich Bekqulov

Chemical Technology, Control and Management

It is proposed to include virtual instrumental quality analyzers of potash fertilizers in the composition of the advanced (advanced) management system. The structure of the virtual analyzer is substantiated using mathematical models of the technological process of drying potassium chloride in its composition. Based on the results of fuzzy clustering, the parameters of the modes of the technological process of drying potassium chloride are determined.

Synchronization Of The Training Of Specialists In The Automation Of Technological Processes In Accordance With The Dynamics Of The Taxonomy Of Learning Goals, Yusuf Shodievich Avazov, Kamola Abdullaeva

Chemical Technology, Control and Management

Changes in the characteristics of modern ones, reflecting them as the "digital generation", inevitably necessitate electronic interactive, mobile and mixed, machine learning, especially in the field of automation and control of technological processes and production. As a consequence of reflecting these realities, there have been parallel changes in the taxonomy of learning objectives - from the classical to the revised rethought and digital.

In order to study the problem of synchronizing the training of future specialists in the field of automation and control of technological processes and production and funny knowledge in accordance with the dynamics of the taxonomy of …

Algorithmic Methods For Developing The Structure Of A Thyristor Electric Drive For Mining Machines, N.R Yusupbekov, O.A. Jumaev, S.S. Turaev

Chemical Technology, Control and Management

The article discusses the creation of algorithmic structures and the development of digital control systems for electric drives of mine-lifting machines, provides some concepts for creating digital control systems using thyristor converters. The analysis of the static volt-ampere characteristics of the thyristor is given, some calculations of the circuits and circuits of the thyristor converter (TP) corresponding to the different modes of operation of the TP are given, and also, based on the synthesis of the dynamic properties and characteristics of the thyristor, an algorithmic structure of the model of the thyristor converter is proposed.

Design And Performance Analysis Of Dry Gas Fishbone Wells For Lower Carbon Footprint, Habib Ouadi, Aimen Laalam, Amjed Hassan, Abderraouf Chemmakh, Vamegh Rasouli, Mohamed Mahmoud

Petroleum Engineering Student Publications

Multilateral well drilling technology has recently assisted the drilling industry in improving borehole contact area and reducing operation time, while maintaining a competitive cost. The most advanced multilateral well drilling method is Fishbone drilling (FbD). This method has been utilized in several hydrocarbon fields worldwide, resulting in high recovery enhancement and reduced carbon emissions from drilling. FbD involves drilling several branches from laterals and can be considered as an alternative method to hydraulic fracturing to increase the stimulated reservoir volume. However, the expected productivity of applying a Fishbone well from one field to another can vary due to various challenges …

A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Pulmonary arterial hypertension (PAH) features pathogenic and abnormal endothelial cells (ECs), and one potential origin is clonal selection. We studied the role of p53 and toll-like receptor 3 (TLR3) in clonal expansion and pulmonary hypertension (PH) via regulation of bone morphogenetic protein (BMPR2) signaling. ECs of PAH patients had reduced p53 expression. EC-specific p53 knockout exaggerated PH, and clonal expansion reduced p53 and TLR3 expression in rat lung CD117+ ECs. Reduced p53 degradation (Nutlin 3a) abolished clonal EC expansion, induced TLR3 and BMPR2, and ameliorated PH. Polyinosinic/polycytidylic acid [Poly(I:C)] increased BMPR2 signaling in ECs via enhanced binding of interferon regulatory …

A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Pulmonary arterial hypertension (PAH) features pathogenic and abnormal endothelial cells (ECs), and one potential origin is clonal selection. We studied the role of p53 and toll-like receptor 3 (TLR3) in clonal expansion and pulmonary hypertension (PH) via regulation of bone morphogenetic protein (BMPR2) signaling. ECs of PAH patients had reduced p53 expression. EC-specific p53 knockout exaggerated PH, and clonal expansion reduced p53 and TLR3 expression in rat lung CD117+ ECs. Reduced p53 degradation (Nutlin 3a) abolished clonal EC expansion, induced TLR3 and BMPR2, and ameliorated PH. Polyinosinic/polycytidylic acid [Poly(I:C)] increased BMPR2 signaling in ECs via enhanced binding of interferon regulatory …

Evaluation Of Liquid Loading In Gas Wells Using Machine Learning, Abderraouf Chemmakh, Olusegun Stanley Tomomewo, Kegang Ling, Ahmed Shammari

Petroleum Engineering Student Publications

The inevitable result that gas wells witness during their life production is the liquid loading problem. The liquids that come with gas block the production tubing if the gas velocity supplied by the reservoir pressure is not enough to carry them to surface. Researchers used different theories to solve the problem naming, droplet fallback theory, liquid film reversal theory, characteristic velocity, transient simulations, and others. While there is no definitive answer on what theory is the most valid or the one that performs the best in all cases. This paper comes to involve a different approach, a combination between physics-based …

Effect Of Process Parameters On The Mechanical Properties Of Carbon Fiber Epoxy Composites By Wet Compression Molding, Saboora Ayatollahi

Electronic Thesis and Dissertation Repository

In recent years, due to growing environmental concerns, composite materials have emerged as a promising lightweight alternative for metals in structural applications in automobiles. Among composite manufacturing processes, Wet Compression Molding (WCM) is a new method of producing Carbon Fiber Reinforced Polymer (CFRP) components. For similar processes like RTM, operating conditions are always one of the factors that impact the mechanical performance of CFRP parts. Thus, this thesis aimed to investigate the effects of operating conditions, including resin temperature, mold temperature, resin set time, gap closure speed, and mold curing time on the mechanical property of the composite parts. In …

Applications Of Underbalanced Fishbone Drilling For Improved Recovery And Reduced Carbon Footprint In Unconventional Plays, Habib Ouadi, Siamak Mishani, Vamegh Rasouli

Petroleum Engineering Student Publications

Fishbone Drilling (FbD) consists of drilling several micro-holes in different directions from the main vertical or deviated wellbore. Similar to multilateral micro-hole drilling, FbD may be used to enhance hydrocarbon production in naturally fractured formations or in refracturing operations by interconnecting the existing natural fractures. When combined with underbalanced drilling using a coiled tubing rig, FbD enhances the production further by easing the natural flow of the hydrocarbon from the reservoir to the wellbore. The design aspects of the Fishbones include determining the number, length, distance between the branches, and the angle of sidetracking of the branches from the main …

Seismic Azimuthal Anisotropy Beneath A Fast Moving Ancient Continent: Constraints From Shear Wave Splitting Analysis In Australia, Kailun Ba, Stephen S. Gao, Jianguo Song, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seismic Azimuthal Anisotropy Beneath Australia is Investigated using Splitting of the Teleseismic PKS, SKKS, and SKS Phases to Delineate Asthenospheric Flow and Lithospheric Deformation Beneath One of the Oldest and Fast-Moving Continents on Earth. in Total 511 Pairs of High-Quality Splitting Parameters Were Observed at 116 Seismic Stations. Unlike Other Stable Continental Areas in Africa, East Asia, and North America, Where Spatially Consistent Splitting Parameters Dominate, the Fast Orientations and Splitting Times Observed in Australia Show a Complex Pattern, with a Slightly Smaller Than Normal Average Splitting Time of 0.85 ± 0.33 S. on the North Australian Craton, the Fast …

Effect Of Class C And Class F Fly Ash On Early-Age And Mature-Age Properties Of Calcium Sulfoaluminate Cement Paste, Sukanta K. Mondal, Carrie Clinton, Hongyan Ma, Aditya Kumar, Monday Uchenna Okoronkwo

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

To Promote the Sustainable Development of Eco-Efficient Calcium Sulfoaluminate (CSA) Cements through the Partial Replacement of the CSA Clinker with Supplementary Cementitious Waste Products, the Effects of Coal Fly Ashes on the Early-Age and Mature-Age Properties of a Calcium Sulfoaluminate (CSA)-Based Cement Paste Were Investigated. the Impacts of Both Class C and Class F Fly Ashes on the Rheological Properties, Hydration Kinetics, and Compressive Strength Development of CSA Cement Paste Were Studied. Rheology-Based Workability Parameters, Representing the Rate of Loss of Flowability, the Rate of Hardening, and the Placement Limit, Were Characterized for the Pastes Prepared with Fixed Water-To-Cement (W/c) …

Sra Inhibition Improves Antitumor Potency Of Antigen-Targeted Chaperone Vaccine, Jie Qian, Xiaofei Yu, Zheng Liu, Jinyang Cai, Masoud H. Manjili, Hu Yang, Chunqing Guo, Xiang Yang Wang

Chemical and Biochemical Engineering Faculty Research & Creative Works

We Have Previously Demonstrated that Scavenger Receptor a (SRA) Acts as an Immunosuppressive Regulator of Dendritic Cell (DC) Function in Activating Antitumor T Cells. Here We Investigate the Potential of Inhibiting SRA Activity to Enhance DC-Targeted Chaperone Vaccines Including One that Was Recently Evaluated in Melanoma Patients. We Show that Short Hairpin RNA-Mediated SRA Silencing Significantly Enhances the Immunogenicity of DCs that Have Captured Chaperone Vaccines Designed to Target Melanoma (I.e., Hsp110-Gp100) and Breast Cancer (I.e., Hsp110-HER/Neu-ICD). SRA Downregulation Results in Heightened Activation of Antigen-Specific T Cells and Increased CD8+ T Cell-Dependent Tumor Inhibition. Additionally, Small Interfering RNA (SiRNA) Complexed …

Modeling And Multi-Objective Optimization Of Wastewater Treatment Process, Navneet Kaur

Electronic Thesis and Dissertation Repository

Wastewater is water that has already been used and requires treatment before releasing it into natural water bodies like lakes and rivers. Wastewater treatment is the process of removing impurities from wastewater. In this treatment process, the impurities are removed and converted to effluent. This effluent is returned to the water cycle with minimum impact on the environment. Conventional treatment plants consist of three stages: primary, secondary, and tertiary treatment. Treatment of wastewater is quite complicated because of the number of stages involved in this process. Most wastewater treatment plants are operated manually therefore at times it becomes difficult for …

Lysine Crosslinked Polyacrylamide─A Novel Green Polymer Gel For Preferential Flow Control, Tao Song, Baojun Bai, Yugandhara Eriyagama, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Acrylamide-based polymer gels have been applied to control the preferential flow in the subsurface for decades. However, some commonly used crosslinkers, such as Cr (III) and phenol-formaldehyde, are highly toxic and are being phased out because of stringent environmental regulations. This work uses l-lysine as the green crosslinker to produce acrylamide-based polymer gels. This article systematically studied the effect of lysine and polymer concentration, salinity, pH, and temperature on gelation behavior and thermal stability. Besides, the gelation mechanism and crosslinking density were elucidated in this work. A high-permeability sandstone core was used to test the plugging efficiency of this novel …

Direct Synthesis Of Ethylene And Hydrogen From Co2 And Ethane Over A Bifunctional Structured Cao/Cr2o3-V2o5/Zsm-5 Adsorbent/Catalyst Monolith, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, we synthesized bifunctional adsorbent/catalyst materials (BFMs) consisting of a C_aO adsorbent admixed with Cr₂O₃-V₂O₅/ZSM-5 catalysts. The obtained BFMs were further formulated, processed, and shaped through additive manufacturing (3D printing) method. The physical and chemical properties of structured C_aO/Cr₂O₃-V₂O₅/ZSM-5 adsorbent/catalyst monoliths were thoroughly characterized and evaluated. The effects of operating conditions including reaction temperature, ethane composition, and space velocity on single-bed CO₂ capture and selective formation of ethylene and hydrogen were systematically investigated. The adsorption-reaction experiments revealed …

Development Opportunities And Technical Challenges Of Industrialization For Hydrogen Production From Bio-Ethanol Reforming, Xue Han, Hong He, Guojun Yue, Hailong Lin, Jinsong Liu, Bin Yu

Bulletin of Chinese Academy of Sciences (Chinese Version)

Bio-ethanol reforming for hydrogen production, using renewable raw materials and adopting mature and efficient chemical processes, is an important source of green hydrogen supply to achieve the goals of carbon peaking and carbon neutrality. Bio-ethanol is a widely used substitute for fossil fuels. With the continuous progress of cellulosic ethanol technology in recent years, bio-ethanol will gradually break through the constraints of starch-based raw material supply. Based on the industrialization achievements of hydrogen production and bio-ethanol, bio-ethanol reforming can realize a rapid linkage with the existing hydrogen energy industry. However, the existence of a carbon-carbon signal bond in ethanol poses …

Development Of Battery Materials To Function As Corrosion Protection On Car Body Plates, Tubagus Noor Rohmannudin, Sulistijono Sulistijono, Noval Adrinanda, Faridz Wira Dharma, Samuel Areliano

Journal of Materials Exploration and Findings (JMEF)

Most car bodies made for mass production are made from steel or aluminum. Both are strong metals, but steel is cheaper than aluminum and is more commonly used in lower-end cars for a broader consumer range. The weakness of steel compared to aluminum is that it is susceptible to corrosion under certain conditions, and thus it may deteriorate over time without proper care. To prevent corrosion, modern cars are coated with paint to prevent direct contact with the environment. As a second line of protection, a car battery can be connected to the body to create an impressed current cathodic …