Geochemistry Commons^™

Stable Isotope Analysis Of Busycon Sinistrum To Determine Fort Walton-Period Seasonality At St. Joseph Bay, Northwest Florida, Ryan Michael Harke

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Recent archaeological investigations indicate that coastal Fort Walton cultures in the St. Joseph Bay region of northwest Florida emphasized marine and estuarine foraging. These late prehistoric (A.D. 1000-1500) peoples collected fish, shellfish, and other aquatic resources. At the Richardson's Hammock site (8Gu10), radiocarbon-dated to about A.D. 1300, as at dozens of other shell middens around this salty bay, large gastropods were a major subsistence component. This adaptation is in sharp contrast with that of contemporaneous inland Fort Walton societies, who relied on maize agriculture. It is unknown whether coastal groups represent separate hunter-gatherer-fisher populations or seasonal migrations by inland …

Atr-Ftir Studies On The Kinetics Of Dimethylarsinic Acid (Dma) Surface Complexation With Iron(Oxyhydr)Oxides, Julia Tofan-Lazar Miss

Theses and Dissertations (Comprehensive)

Dimethylarsinic acid (DMA) is an organoarsenical compound that, along with monomethylarsonic acid, poses a health and an environmental risk, and a challenge to the energy industry. Little is known about the surface chemistry of DMA at the molecular level with materials relevant to geochemical environments and industrial sectors. The surface chemistry of phosphorus and arsenic compounds in their organic and inorganic forms is of great interest due to its role in controlling their transport, bioaccessibility and speciation. This thesis reports the first in-situ and surface-sensitive rapid kinetic studies on the adsorption and desorption of DMA to and from Fe-(oxyhydr)oxide films …

Mineralogy And Geochemistry Of Anorogenic Granitic Miarolitic Pegmatites Associated With The White Mountain Intrusive Suite, New Hampshire, Kristen F. Camp

LSU New Orleans Theses and Dissertations

Subvolcanically emplaced granitic, miarolitic pegmatites associated with the White Mountain Igneous Province (WMIP), New Hampshire, were sampled and analyzed using modern analytical techniques including X-ray fluorescence, electron microprobe, scanning electron microscopy, and direct-coupled plasma spectrophotometry. Analytical results suggest that all the sampled miarolitic pegmatites from this study are petrogenetically related to the same intrusive suite, the WMIP. Based on the geochemical data, all the samples formed in an anorogenic tectonic setting and are rift-related. They are classified as NYF-type and plot in the “within plate granite” field on tectonic discrimination diagrams. The majority of the samples are peraluminous, A_{1 …}

Paired Positive Carbonate Carbon Isotope, Organic Carbon Isotope, And Oxygen Isotope Composition Study Across The Lower Mississippian Positive Carbon Isotope Excursion, Southeastern Nevada, Usa, Robert Alan Henry

UNLV Theses, Dissertations, Professional Papers, and Capstones

A prominent positive carbonate carbon isotope (delta13Ccarb) excursion of Early Mississippian age (ca 351 Ma) has been documented by previous studies from numerous sites globally. This delta13Ccarb excursion has been interpreted as resulting from enhanced organic carbon burial that removed 13C-depleted carbon from the ocean and atmosphere. Anticipated outcomes from enhanced organic carbon burial would include a similar positive excursion in organic carbon isotopes (delta13Corg) and a global cooling event resulting from reduced CO2 in the atmosphere and ocean. These predictions, however, were not tested sufficiently in previous studies. This research has tested these predictions through an integrated study of …

Magma Chamber Processes At Mutnovsky Volcano, Russia, Kelly L. Robertson

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is composed of two manuscripts about the evolution of Mutnovsky Volcano in Kamchatka, Russia. Mutnovsky has been active for the past approximately 80,000 years, during which there was the formation and subsequent eruption of four major stratocones. These four eruptive centers, named Mutnovsky I, II, III, and IV from oldest to youngest, have a range of erupted product compositions from basalt to dacite. The first major goal of this project was to investigate the melt source for Mutnovsky. Whole rock trace element and Nd, Sr, and Pb isotopic data were used to determine that the melt source was …

Microstructural Characterization Of Kinked Germanate Olivine Grains, Alex Gregory Drue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Olivine is the most common and the weakest mineral in the upper mantle. Thus the strength of olivine controls the rheology of the earth's upper mantle. The rheology of olivine in the upper mantle has important implications for mantle flow, mountain building, and rates of isostatic adjustment. Recent experimental measurements of the flow strength of deformed olivine polycrystals have assumed a homogeneous state of stress. X-ray synchrotron diffraction experiments have implied that this assumption is not always valid. Elastic Plastic Self Consistent (EPSC) modeling offers an approach to estimating the flow strength of olivine that does not assume a homogeneous …

Spatial And Temporal Variations In The Air-Sea Carbon Dioxide Fluxes Of Florida Bay, Christopher Michael Dufore

USF Tampa Graduate Theses and Dissertations

The flux of CO2 between the ocean and the atmosphere is an important measure in determining local, global, and regional, as well as short term and long term carbon budgets. In this study, air-sea CO2 fluxes measured using a floating chamber were used to examine the spatial and temporal variability of CO2 fluxes in Florida Bay. Measurements of dissolved inorganic carbon and total alkalinity obtained concurrently with chamber measurements of CO2 flux allowed calculation of ΔpCO2 from flux measurements obtained at zero wind velocity. Floating chamber measurements of ΔpCO2 were subsequently coupled with wind speed data to provide a simple …

Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott

Publications and Research

Test boring associated with the recently accomplished City Water Tunnel # 3 in Manhattan, New York City revealed moderately to highly weathered marble with insoluble silicate residues composed mostly of phlogopite, chlorite, and tremolite. Apparent control on the weatherability of the marble was in response to original mineral constituents dominating this lithology. Encountered marble samples ranged between pure calcitic to mixed dolomitic/siliceous types. Fresh marble samples collected from adjacent boring locations revealed characteristic geochemical data: Lime (25-45%), Silica (4-7%), Alumina (1-3%), MgO (5-20%), and LOI (35-42%); compressive strength of unweathered marble varied between 2000-3000 Kg/cm². Relict foliations with …

Geogram 2011, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Mobile Technology As A Tool For Enhancing Student Learning In Geosciences, Sam Matson

Mobile Learning Symposium

Incorporation of mobile technology into the post-secondary classroom is becoming increasingly common as universities seek to facilitate active, student-centered learning through rapid access to information, connect students with course content through social media, and evaluate digital alternatives to conventional instructor-student interaction. The m-Learning Scholars Program at Boise State University was initiated during the 2010 – 2011 academic year, and provides a venue for exploring the potential of mobile technology to enhance student learning in the geosciences. Through this program, 38 students in an introductory Earth History course for non-geoscience majors each purchased a subsidized handheld device (iPod touch) that they …

Magnetic Properties Of Ilmenite‐Hematite Single Crystals From The Ecstall Pluton Near Prince Rupert, British Columbia, Sarah J. Brownlee, Joshua M. Feinberg, Takeshi Kasama, Richard J. Harrison, Gary R. Scott, Paul R. Renne

Environmental Science and Geology Faculty Research Publications

Paleomagnetic studies of the 91 Ma Ecstall pluton and other Cretaceous plutons of British Columbia imply large northward tectonic movements (>2000 km) may have occurred during the tectonic evolution of western North America. However, more recent studies have shown that the eastern edge of the Ecstall pluton experienced considerable mineralogical changes as younger Eocene plutons, such as the ∼58 Ma Quottoon Pluton, were emplaced along its margins. We investigated changes in the rock magnetic properties associated with this reheating event by examining isolated grains of intergrown ilmenite and hematite, the primary paleomagnetic recorder in the Ecstall pluton. Measurements of …

Effects Of Weathering On Aromatic Compounds In Beach Tars From The Deepwater Horizon Disaster, Gulf Of Mexico Coast, Usa, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Operators aboard the Deepwater Horizon drilling platform lost control of the Macondo No. 1 well about 90 km southwest of the Louisiana coast on April 20, 2010, leading to a catastrophic release of ca. 550 Gg of crude oil over the next 86 days [1]. Oil from the spill soon found its way to nearby coastal areas, leaving tarry deposits on beaches and marshes. Oil was reported on the beach at Gulf Shores, Alabama (180 km northeast of the well) on June 5 and the relatively fresh sample discussed herein (GSA) was collected that same day. Oil reached the beach …

The Vinylguaiacol/Indole Or Vgi ("Veggie") Ratio: Assessing Relative Contributions Of Terrestrial And Aquatic Organic Matter To Sediments, Michael A. Kruge, Kevin K. Olsen, Jaroslaw W. Slusarczyk, Elaine Gomez

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

In studies of the organic matter (OM) fraction of marine, estuarine, fluvial, or lacustrine sediments, one of the most fundamental distinctions to be made is that between terrestrial and aquatic OM. To supplement the parameters commonly used for this purpose (e.g., C/N and stable isotope ratios), we proposed the Vinylguaiacol/Indole or VGI ("Veggie") ratio, defined as [vinylguaiacol / (indole + vinylguaiacol)] using data produced by analytical pyrolysis-gas chromatography/mass spectrometry of dried, homogenized sediment samples [1]. The ratio employs the peak areas of these two compounds on the mass chromatograms of their molecular ions (m/z 150 and 117, respectively). Major pyrolysis …

Predicted Velocity And Density Structure Of The Exhuming Papua New Guinea Ultrahigh‐Pressure Terrane, Sarah J. Brownlee, Bradley R. Hacker, Matthew Salisbury, Gareth Seward, Timothy A. Little, Suzanne A. Baldwin, Geoffrey A. Abers

Environmental Science and Geology Faculty Research Publications

New electron backscatter diffraction measurements show that the Papua New Guinea (PNG) ultrahigh‐pressure (UHP) terrane is dominated by rocks with weakly oriented quartz and feldspar and less abundant strongly oriented hornblende, clinopyroxene, and mica. Velocities measured at high pressures (600 MPa) show that V_P is 5.8–6.3 km/s for gneiss samples, 6.5–7.7 km/s for amphibolite, and 7.7–8.2 km/s for eclogite and V_S is 3.4–3.9 km/s for gneiss, 4.0–4.4 km/s for amphibolite, and 4.5–4.6 km/s for eclogite. Velocities and anisotropies calculated from mineral crystal preferred orientations (CPOs) are equivalent to within 5% of the measured values. The highest seismic anisotropy …

Assessing Ageing At Beaver Reservoir, Northwest Arkansas: Limnological, Geochemical & Paleolimnological Approach, Byron Anthony Winston

Graduate Theses and Dissertations

Access to potable water has been arguably one of the most important requisites for the advancement of human civilization on earth. As a result, man in his infinite wisdom devised the dam and formed reservoirs, (man- made lakes), to exploit water resources at will. In all natural lakes and reservoirs changes occur in the water quality parameters as it relates to chemical nutrients, temperature and turbidity over time. These changes are collectively referred to as "Reservoir Ageing", of which sedimentation and eutrophication are primary. Reservoir Ageing has consequences which adversely affect and defeat many of the intended uses of the …

Solving The Mystery Of The Atacama Nitrate Deposits: The Use Of Stable Oxygen Isotope Analysis And Geochemistry, Ji-Hye Seo

The Journal of Purdue Undergraduate Research

The Atacama Desert, Chile, one of the oldest and driest deserts on Earth, is unique because it contains the largest known nitrate deposits in the world. The origin of these nitrate deposits has been a mystery since their discovery in the 1800s. There are two possible sources of natural nitrate: microbiological processes and photochemical reactions. The majority of material on Earth follows mass-dependent fractionation between stable oxygen isotopes with the abundance of ¹⁷Ο (denoted by δ) as half that of ¹⁸O. This relationship is quantified by Δ¹⁷O = δ¹⁷O – ½ δ¹⁸O, …

Evaluation Of The Carbon Budgets In The Forested And Agricultural Soils Of The Semi-Arid Mogollon-Datil Highlands And Rio Grande Basin, Ryan Reeves^, Lixin Jin*

COURI Symposium Abstracts, Summer 2011

No abstract provided.

Insights Into Chemical Structure Changes Of Kerogen From Bituminous Coal In Response To Dike Intrusions Investigated By Advanced Solid-State 13C Nmr, Yuan Li

Chemistry & Biochemistry Theses & Dissertations

Variations in the chemical structures of kerogens From highly volatile bituminous coal located near two igneous dike intrusions in the Illinois Basin were examined in detail by advanced solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Spectral-editing techniques were used to identify specific functional groups. Direct polarization was used to quantify different functional groups. ¹H-¹³C two- dimensional heteronuclear NMR was used to examine connectivities and proximities, and ¹H-¹³C long-range recoupled dipolar dephasing was used to estimate aromatic cluster sizes. With decreasing distance to dike contacts and increasing thermal maturity (vitrinite reflectance R₀ from …

Environmental History Of A Closed-Basin Lake In The Us Great Plains: Diatom Response To Variations In Groundwater Flow Regimes Over The Last 8500 Cal. Yr Bp, William O. Hobbs, Sherilyn C. Fritz, Jeffery R. Stone, Joseph J. Donovan, Eric C. Grimm, James E. Almendinger

Department of Earth and Atmospheric Sciences: Faculty Publications

Sediment records from closed-basin lakes in the Northern Great Plains (NGP) of North America have contributed significantly to our understanding of regional paleoclimatology. A high-resolution (near decadal) fossil diatom record from Kettle Lake, ND, USA that spans the last 8500 cal. yr BP is interpreted in concert with percent abundance of aragonite in the sediment as an independent proxy of groundwater flow to the lake (and thus lake water level). Kettle Lake has been relatively fresh for the majority of the Holocene, likely because of the coarse substrata and a strong connection to the underlying aquifer. Interpretation of diatom assemblages …

The Nature, Origin And Preservation Of Amide Organic Nitrogen In Organic Matter, Georgina Anne Mckee

Chemistry & Biochemistry Theses & Dissertations

Past studies have found much of nonliving sedimentary/aqueous nitrogen-containing organic matter (NCOM) is composed of amides, assumed to be peptides/proteins. Their lability calls into question their survival, and several hypotheses have been suggested to explain this. Using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and nuclear magnetic resonance (NMR) spectroscopy I investigated the molecular amide composition in sedimentary/aqueous systems while reassessing their preservation and formation routes.

Development of a suitable methodology is essential for successful NCOM study due to electrospray ionisation source requirements: sediment samples need to be rendered into solution. Based on NMR and FT-ICR-MS analysis, I determined …