Geochemistry Commons^™

Petrogenesis Of The East Fork Member Rhyolites, Valles Caldera, New Mexico, Usa, Carla Eichler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most recent volcanism in the Valles caldera is represented by the El Cajete Pyroclastic Beds (ECPB), Battleship Rock Ignimbrite (BRI), and Banco Bonito Flow (BBF) as well as the VC-1 rhyolite, which are collectively known as the East Fork Member (EFM) of the Valles Rhyolite. The EFM was erupted at approximately 55 ka and 40 ka after an approximate 460 ka lull in volcanism. Previous studies suggested a mafic intrusion at depth triggered the eruptions. This thesis represents the first detailed study of the EFM.

Crystal assemblages consist of plagioclase, biotite, clinopyroxene, orthopyroxene, amphibole, sanidine, quartz, and oxides. Electron …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Geogram 2012, David J. Keeling, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Investigating The Utility Of Detrital Mineral Microchemistry And Radiogenic Isotope Compositions As Provenance Discriminators, Jack Hietpas

Earth & Environmental Sciences - Dissertations

The provenance of clastic sediments remains one of the key tools for understanding the complex dynamic history of the Earth. Detritus shed from ancient orogens may be the only evidence available for determining the timing, evolution, paleogeography, and existence of tectonic events active over the 4.56 Ga of Earth history. The focus of this dissertation research is to assess the strengths and limitations of existing, as well as novel, tools for determining the provenance of siliciclastic sediments.

The utility of detrital monazite crystallization ages was investigated as a provenance indicator in both modern and ancient sedimentary systems. The results from …

Evaluation Of Possible Source Rocks In Northern Nye County, Nevada: Implications For Hydrocarbon Exploration, Inessa Yurchenko

UNLV Theses, Dissertations, Professional Papers, and Capstones

The presence of oil outside of Railroad Valley, northern Nye County has sparked the interest of exploration companies in Nevada. The geology in this region is very complex and the level of petroleum exploration is low. In order to understand the distribution of oil, a complete petroleum systems analysis is required. Previous studies confirmed that the Mississippian Chainman Shale and Cretaceous to Paleocene Sheep Pass Formation, Member B are source rocks. However, a number of other possible source rocks exist in northern Nye County, but they are not confirmed because of incomplete datasets. The goal of this thesis project is …

The Effects Of Fractures On The Occurrence And Distribution Of Arsenic In The Upper Floridan Aquifer During Aquifer Storage And Recovery, William Charles Hutchings

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Aquifer storage and recovery (ASR) is used world-wide to supplement available water supplies by storing surplus water in aquifers and recovering it during periods of drought and increased demand. The use of ASR as an option for increasing available municipal irrigation and fresh water supplies is threatened as a result of the mobilization of arsenic in some aquifers during ASR. Arsenic is liberated from arsenic-bearing sulfide minerals as a result of the mixing of oxidizing injected water with reducing insitu groundwater. Fracture networks can have significant influence on the migration and distribution of arsenic in the Upper Floridan Aquifer …

A Geochemical Analysis Of Fulgurites: From The Inner Glass To The Outer Crust, Michael L. Joseph

USF Tampa Graduate Theses and Dissertations

Cloud-to-ground lightning strikes produce natural glasses on the surface of the Earth, called fulgurites. These natural glasses are tubular in shape with a central void surrounded by an inner glass, and the inner glass is surrounded by an outer crust or toasted region. Previous studies report different kinds of melts existing in several different types of fulgurites; however, little to no chemical data has been collected that tracks chemical variations from the inner glass to the outer crust of a fulgurite. This study uses microprobe and laser ablation inductively coupled plasma mass spectrometer analytical techniques to collect transects of chemical …

Speciation And Removal Mechanisms Of Rhenium In Anoxic Waters: Roles Of Zero-Valent Sulfur, Mineral Oxide Catalysis, And Pyrite Surfaces, Trent P. Vorlicek

All Private Grants

Global warming is expected to intensify the effects of coastal anoxia. Knowledge of the causes of geohistorical anoxic episodes may prove critical in developing strategies for the mitigation of or adaptation to the consequences of climate change upon the global aquatic environment. The geochemistry of Re provides the means to acquiring this knowledge. Within oxic waters, Re exists as geochemically-inert ReO4-. Under reducing conditions, Re is removed from the aqueous phase and deposited in sediments. Unfortunately, an incomplete understanding of Re geochemistry hampers exploitation of Re as a paleoredox indicator. Authors purport Re sequestration begins in suboxic environments; others produce …

A Study Of Enhanced De-Chlorination And Bio-Remediation: Molasses Injections Into Groundwater, Brent Anderson

Natural Resources Management and Environmental Sciences

No abstract provided.

Estimating Land Surface Temperature Using A Thermal Sharpening Technique, Yitong Jiang, Qihao Weng

Symposium 2012

No abstract provided.

A Mineralogical Textural And Chemical Characterization Of A Hypothesized Kimberlite At White Mountain, Sunlight Basin, Wyoming, Stuart Kenderes

Mahurin Honors College Capstone Experience/Thesis Projects

Geologists have examined the causes and mechanisms responsible for the Heart Mountain detachment for over a century with much debate and discussion. White Mountain is a part of the upper plate, which was emplaced during the detachment event. Within White Mountain, there exist several andesitic dikes and carbonate ultra-cataclasite injectites, which were integral in the emplacement of the Heart Mountain detachment. This research involves the characterization and identification of an enigmatic vertical outcropping of brecciated rock located on White Mountain, Sunlight Basin, Wyoming, which was originally interpreted as a kimberlite. Samples were collected for geochemical and textural comparison, and cut …

Deciphering The Evolution Of Ore Fluids At The Batu Hijau Copper-~Gold Porphyry Deposit, Sumbawa, Indonesia, Jordan Thomas Armstrong

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluid inclusions contained within quartz veins from the Batu Hijau Cu-Au porphyry deposit in Indonesia were analyzed to track the evolution of fluid temperature, pressure, and composition during the formation of the deposit to better understand the formation of this and other Cu-Au porphyry deposits in order aid future exploration. A combination of petrography, microthermometry, synchrotron x-ray fluorescence, and laser ablation-inductively coupled plasma-mass spectrometry were used to determine the temperature, pressure, and compositional aspects of the deposit.

Four types of fluid inclusions were recognized at Batu Hijau based on the volume percent of the vapor bubble; inclusions were classified as …

Evaluating Recharge And Dynamics Of Flow In The Lower Virgin River Basin, Usa: Interpretation Of Hydrochemical And Stable Isotopic Data, Joseph Asante

UNLV Theses, Dissertations, Professional Papers, and Capstones

Because of the complex geologic setting of the Basin and Range province, groundwater flow systems of the Intermountain basins of the southwestern United States are complex and remain poorly understood. Understanding these flow systems is important for water budgeting on a regional and local scale, and development of robust numerical groundwater models for sustainable water use and protection of water-dependent ecosystems. Although for decades hydrochemistry and isotopes have been used to characterize and trace subsurface water and surface water, effectively interpreting these data are still challenging, which can be attributed to existing subjective grouping of these data and the lack …

Chemical Weathering Of The Mafic Minerals Serpentine And Olivine In Natural Environments, Julie Lynn Baumeister

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chemical weathering is a critical process that plays a key role in controlling the chemistry of natural waters, the cycling of atmospheric carbon dioxide, and the formation of soil. The weathering of silicate minerals is important because the Earth's crust is composed of approximately 92 weight percent silicate minerals. Despite an extensive literature on mineral dissolution and kinetics, relatively few studies have examined weathering of the mafic minerals serpentine and olivine, especially in a natural environment. The first chapter of this thesis provides an introduction to the minerals serpentine and olivine. The second chapter of this thesis examines the important …

The Behavior Of Zircon During Partial Melting In Anatectic Migmatites: Insights To Metamorphism, Deformation And Tectonism In The Central Santa Fe Range, Northern New Mexico, Michelle Renee Stropky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Three lithologic assemblages exposed in the central Santa Fe Range, northern New Mexico include (1) a septum of Proterozoic low temperature (~700oC, 5.5 kbars), semi-pelitic anatectic migmatites surrounded by (2) deformed megacrystic biotite granite that is intruded by (3) discrete plutons of largely undeformed hornblende biotite tonalite. Metamorphic fabrics in the migmatite record three deformation events (D1 - D3); a composite S1/S2 fabric (D1 and D2) that formed contemporaneous with anatexis and is folded about a southwest plunging map-scale (D3) antiform. The megacrystic granite exhibits a pervasive S1 subsolidus foliation that parallels the S1/S2 fabric in the migmatite and is …

Bulk Rock Composition And Geochemistry Of Olivine-Hosted Melt Inclusions In The Grey Porri Tuff And Selected Lavas Of The Monte Dei Porri Volcano, Salina, Aeolian Islands, Southern Italy., Angela L. Doherty, Robert J. Bodnar, Benedetto De Vivo, Wendy A. Bohrson, Harvey E. Belkin, Antonia Messina, Robert J. Tracy

All Faculty Scholarship for the College of the Sciences

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical …

Reservoir Potential Of Sands Formed In Glaciomarine Environments: An Analog Study Based On Cenozoic Examples From Mcmurdo Sound, Antarctica, Christopher R. Fielding, Brian A. Blackstone, Tracy D. Frank, Zi Gui

Department of Earth and Atmospheric Sciences: Faculty Publications

This paper provides documentation of unexpectedly high-reservoir-quality glaciomarine sands found in the Cenozoic succession beneath McMurdo Sound, Antarctica, as an analogue study for evaluations of hydrocarbon prospectivity in basins elsewhere. The Oligocene to Lower Miocene succession of the Victoria Land Basin, an extant portion of the West Antarctic Rift System, comprises diamictites, mudrocks, and sandstones with minor conglomerates. These lithologies are arranged in repetitive stacking patterns (cycles), interpreted to record repeated advance and retreat of glaciers into and out of the basin, with attendant eustatic and isostatic effects. Phases of ice retreat within the cycles comprise an array of mudrocks, …

Surficial Redistribution Of Fallout 131iodine In A Small Temperate Catchment, Joshua D. Landis, Nathan T. Hamm, Carl E. Renshaw, W. Brian Dade, Francis J. Magilligan, John D. Gartner

Dartmouth Scholarship

Isotopes of iodine play significant environmental roles, including a limiting micronutrient (¹²⁷I), an acute radiotoxin (¹³¹I), and a geochemical tracer (¹²⁹I). But the cycling of iodine through terrestrial ecosystems is poorly understood, due to its complex environmental chemistry and low natural abundance. To better understand iodine transport and fate in a terrestrial ecosystem, we traced fallout ¹³¹iodine throughout a small temperate catchment following contamination by the 11 March 2011 failure of the Fukushima Daiichi nuclear power facility. We find that radioiodine fallout is actively and efficiently scavenged by the soil system, where it …

Size And Exhumation Rate Of Ultrahigh-Pressure Terranes Linked To Orogenic Stage, Andrew R.C. Kylander-Clark, Bradley R. Hacker, Chris G. Mattinson

All Faculty Scholarship for the College of the Sciences

A growing set of data indicates a stark contrast between the evolution of two types of ultrahigh-pressure (UHP) terranes: large terranes that evolved slowly (over 10–30 Myr), and small terranes that formed and were exhumed on timescales of < 10 Myr. Here we compare the characteristics – area, thickness, formation rate, exhumation rate, age, and tectonic setting – of these two endmember types of UHP terrane worldwide. We suggest that the two UHP terrane types may form during different orogenic stages because of variations in the buoyancy and traction forces due to different proportions of subducting crust and mantle lithosphere or to different rates of subduction. The initial stages of continent collision involve the subduction of thin continental crust or microcontinents, and thus tectonic forces are dominated by the density of the oceanic slab; subduction rates are rapid and subduction angles are initially steep. However, as collision matures, thicker and larger pieces of continental material are subducted, and the positive buoyancy of the down-going slab becomes more prominent; subduction angles become gentle and convergence slows. Assessing the validity of this hypothesis is critical to understanding the physical and chemical evolution of Earth's crust and mantle.

Included here is the post-print copy of this article. The final publication is available via ScienceDirect at http://www.sciencedirect.com/science/article/pii/S0012821X11007564

Geochemical And Strontium Isotope Characterization Of Produced Waters From Marcellus Shale Natural Gas Extraction, Elizabeth C. Chapman, Rosemary C. Capo, Brian W. Stewart, Carl S. Kirby, Richard W. Hammack, Karl T. Schroeder, Harry M. Edenborn

Faculty Journal Articles

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km …