Geochemistry Commons^™

A Geochemical Analysis Of Fulgurites: From The Inner Glass To The Outer Crust, Michael L. Joseph

USF Tampa Graduate Theses and Dissertations

Cloud-to-ground lightning strikes produce natural glasses on the surface of the Earth, called fulgurites. These natural glasses are tubular in shape with a central void surrounded by an inner glass, and the inner glass is surrounded by an outer crust or toasted region. Previous studies report different kinds of melts existing in several different types of fulgurites; however, little to no chemical data has been collected that tracks chemical variations from the inner glass to the outer crust of a fulgurite. This study uses microprobe and laser ablation inductively coupled plasma mass spectrometer analytical techniques to collect transects of chemical …

Speciation And Removal Mechanisms Of Rhenium In Anoxic Waters: Roles Of Zero-Valent Sulfur, Mineral Oxide Catalysis, And Pyrite Surfaces, Trent P. Vorlicek

All Private Grants

Global warming is expected to intensify the effects of coastal anoxia. Knowledge of the causes of geohistorical anoxic episodes may prove critical in developing strategies for the mitigation of or adaptation to the consequences of climate change upon the global aquatic environment. The geochemistry of Re provides the means to acquiring this knowledge. Within oxic waters, Re exists as geochemically-inert ReO4-. Under reducing conditions, Re is removed from the aqueous phase and deposited in sediments. Unfortunately, an incomplete understanding of Re geochemistry hampers exploitation of Re as a paleoredox indicator. Authors purport Re sequestration begins in suboxic environments; others produce …

A Study Of Enhanced De-Chlorination And Bio-Remediation: Molasses Injections Into Groundwater, Brent Anderson

Natural Resources Management and Environmental Sciences

No abstract provided.

Estimating Land Surface Temperature Using A Thermal Sharpening Technique, Yitong Jiang, Qihao Weng

Symposium 2012

No abstract provided.

A Mineralogical Textural And Chemical Characterization Of A Hypothesized Kimberlite At White Mountain, Sunlight Basin, Wyoming, Stuart Kenderes

Mahurin Honors College Capstone Experience/Thesis Projects

Geologists have examined the causes and mechanisms responsible for the Heart Mountain detachment for over a century with much debate and discussion. White Mountain is a part of the upper plate, which was emplaced during the detachment event. Within White Mountain, there exist several andesitic dikes and carbonate ultra-cataclasite injectites, which were integral in the emplacement of the Heart Mountain detachment. This research involves the characterization and identification of an enigmatic vertical outcropping of brecciated rock located on White Mountain, Sunlight Basin, Wyoming, which was originally interpreted as a kimberlite. Samples were collected for geochemical and textural comparison, and cut …

The Behavior Of Zircon During Partial Melting In Anatectic Migmatites: Insights To Metamorphism, Deformation And Tectonism In The Central Santa Fe Range, Northern New Mexico, Michelle Renee Stropky

UNLV Theses, Dissertations, Professional Papers, and Capstones

Three lithologic assemblages exposed in the central Santa Fe Range, northern New Mexico include (1) a septum of Proterozoic low temperature (~700oC, 5.5 kbars), semi-pelitic anatectic migmatites surrounded by (2) deformed megacrystic biotite granite that is intruded by (3) discrete plutons of largely undeformed hornblende biotite tonalite. Metamorphic fabrics in the migmatite record three deformation events (D1 - D3); a composite S1/S2 fabric (D1 and D2) that formed contemporaneous with anatexis and is folded about a southwest plunging map-scale (D3) antiform. The megacrystic granite exhibits a pervasive S1 subsolidus foliation that parallels the S1/S2 fabric in the migmatite and is …

Deciphering The Evolution Of Ore Fluids At The Batu Hijau Copper-~Gold Porphyry Deposit, Sumbawa, Indonesia, Jordan Thomas Armstrong

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fluid inclusions contained within quartz veins from the Batu Hijau Cu-Au porphyry deposit in Indonesia were analyzed to track the evolution of fluid temperature, pressure, and composition during the formation of the deposit to better understand the formation of this and other Cu-Au porphyry deposits in order aid future exploration. A combination of petrography, microthermometry, synchrotron x-ray fluorescence, and laser ablation-inductively coupled plasma-mass spectrometry were used to determine the temperature, pressure, and compositional aspects of the deposit.

Four types of fluid inclusions were recognized at Batu Hijau based on the volume percent of the vapor bubble; inclusions were classified as …

Evaluating Recharge And Dynamics Of Flow In The Lower Virgin River Basin, Usa: Interpretation Of Hydrochemical And Stable Isotopic Data, Joseph Asante

UNLV Theses, Dissertations, Professional Papers, and Capstones

Because of the complex geologic setting of the Basin and Range province, groundwater flow systems of the Intermountain basins of the southwestern United States are complex and remain poorly understood. Understanding these flow systems is important for water budgeting on a regional and local scale, and development of robust numerical groundwater models for sustainable water use and protection of water-dependent ecosystems. Although for decades hydrochemistry and isotopes have been used to characterize and trace subsurface water and surface water, effectively interpreting these data are still challenging, which can be attributed to existing subjective grouping of these data and the lack …

Chemical Weathering Of The Mafic Minerals Serpentine And Olivine In Natural Environments, Julie Lynn Baumeister

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chemical weathering is a critical process that plays a key role in controlling the chemistry of natural waters, the cycling of atmospheric carbon dioxide, and the formation of soil. The weathering of silicate minerals is important because the Earth's crust is composed of approximately 92 weight percent silicate minerals. Despite an extensive literature on mineral dissolution and kinetics, relatively few studies have examined weathering of the mafic minerals serpentine and olivine, especially in a natural environment. The first chapter of this thesis provides an introduction to the minerals serpentine and olivine. The second chapter of this thesis examines the important …

Bulk Rock Composition And Geochemistry Of Olivine-Hosted Melt Inclusions In The Grey Porri Tuff And Selected Lavas Of The Monte Dei Porri Volcano, Salina, Aeolian Islands, Southern Italy., Angela L. Doherty, Robert J. Bodnar, Benedetto De Vivo, Wendy A. Bohrson, Harvey E. Belkin, Antonia Messina, Robert J. Tracy

All Faculty Scholarship for the College of the Sciences

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical …

Reservoir Potential Of Sands Formed In Glaciomarine Environments: An Analog Study Based On Cenozoic Examples From Mcmurdo Sound, Antarctica, Christopher R. Fielding, Brian A. Blackstone, Tracy D. Frank, Zi Gui

Department of Earth and Atmospheric Sciences: Faculty Publications

This paper provides documentation of unexpectedly high-reservoir-quality glaciomarine sands found in the Cenozoic succession beneath McMurdo Sound, Antarctica, as an analogue study for evaluations of hydrocarbon prospectivity in basins elsewhere. The Oligocene to Lower Miocene succession of the Victoria Land Basin, an extant portion of the West Antarctic Rift System, comprises diamictites, mudrocks, and sandstones with minor conglomerates. These lithologies are arranged in repetitive stacking patterns (cycles), interpreted to record repeated advance and retreat of glaciers into and out of the basin, with attendant eustatic and isostatic effects. Phases of ice retreat within the cycles comprise an array of mudrocks, …

Surficial Redistribution Of Fallout 131iodine In A Small Temperate Catchment, Joshua D. Landis, Nathan T. Hamm, Carl E. Renshaw, W. Brian Dade, Francis J. Magilligan, John D. Gartner

Dartmouth Scholarship

Isotopes of iodine play significant environmental roles, including a limiting micronutrient (¹²⁷I), an acute radiotoxin (¹³¹I), and a geochemical tracer (¹²⁹I). But the cycling of iodine through terrestrial ecosystems is poorly understood, due to its complex environmental chemistry and low natural abundance. To better understand iodine transport and fate in a terrestrial ecosystem, we traced fallout ¹³¹iodine throughout a small temperate catchment following contamination by the 11 March 2011 failure of the Fukushima Daiichi nuclear power facility. We find that radioiodine fallout is actively and efficiently scavenged by the soil system, where it …

Geochemical And Strontium Isotope Characterization Of Produced Waters From Marcellus Shale Natural Gas Extraction, Elizabeth C. Chapman, Rosemary C. Capo, Brian W. Stewart, Carl S. Kirby, Richard W. Hammack, Karl T. Schroeder, Harry M. Edenborn

Faculty Journal Articles

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km …

Size And Exhumation Rate Of Ultrahigh-Pressure Terranes Linked To Orogenic Stage, Andrew R.C. Kylander-Clark, Bradley R. Hacker, Chris G. Mattinson

All Faculty Scholarship for the College of the Sciences

A growing set of data indicates a stark contrast between the evolution of two types of ultrahigh-pressure (UHP) terranes: large terranes that evolved slowly (over 10–30 Myr), and small terranes that formed and were exhumed on timescales of < 10 Myr. Here we compare the characteristics – area, thickness, formation rate, exhumation rate, age, and tectonic setting – of these two endmember types of UHP terrane worldwide. We suggest that the two UHP terrane types may form during different orogenic stages because of variations in the buoyancy and traction forces due to different proportions of subducting crust and mantle lithosphere or to different rates of subduction. The initial stages of continent collision involve the subduction of thin continental crust or microcontinents, and thus tectonic forces are dominated by the density of the oceanic slab; subduction rates are rapid and subduction angles are initially steep. However, as collision matures, thicker and larger pieces of continental material are subducted, and the positive buoyancy of the down-going slab becomes more prominent; subduction angles become gentle and convergence slows. Assessing the validity of this hypothesis is critical to understanding the physical and chemical evolution of Earth's crust and mantle.

Included here is the post-print copy of this article. The final publication is available via ScienceDirect at http://www.sciencedirect.com/science/article/pii/S0012821X11007564

Geochemical Classification Of Placer And Lode Gold Deposits Within The Northern Dome Rock Mountains Of The Quartzsite Mining District, Az, Christina Marie Lopez Velasquez

Theses Digitization Project

In this study the geochemistry and distribution of placer and lode gold deposits of the northern Dome Rock Mountains near Quartzsite, Arizona wre studied. The primary objectives of this study were to geochemically classify the placer and lode gold deposits of the Quartzsite Mining District, Arizona. Additional objectives were to determine estimates of the economic value and quantity of production of placer and lode gold deposits. Addressing the economic geology of placer gold deposits, the ultimate goal for this geochemical study is to determine the source(s) of the placer gold and determining the economic potential.

A Five-Year Analysis Of Carbon Stock Plots In The Gordon Natural Area’S Big Woods, Cathy Spahr, Chad Hudson, Andy Tamez

Forest Carbon Storage Study Documents

No abstract provided.

Geology Of National Parks Modules For The Spreadsheets Across The Curriculum Library, H. L. Vacher, Thomas C. Juster, Judy Mcllrath, Mark Rains

Geology Faculty Publications

No abstract provided.

Evolution With Depth From Detrital To Authigenic Smectites In Sediments From And-2a Drill Core (Mcmurdo Sound, Antarctica), Francesco Iacoviello, Giovanna Giorgetti, Fernando Nieto, Isabella Turbanti Memmi

ANDRILL Research and Publications

We have examined the nature and origin of smectites in glaciomarine sediments of the AND-2A drill core (McMurdo Sound, Antarctica) by means of X-ray diffraction (XRD) analyses on the clay fraction, field emission scanning electron microscopy (FESEM), scanning electron microscopy (SEM) observations and SEM-EDS microanalyses on smectite particles. Relying on the smectite variation throughout the drill core it was possible to split the sequence into three units. Smectites throughout the core are either detrital or authigenic. Detrital smectites are close to montmorillonite-beidellite in composition while newly-formed smectites frequently have higher Fe-Mg contents and intermediate compositions between the saponite and nontronite …

Assessing Delta Oxygen-18 In The Coral Genus Isopora For Reconstructing Indo-Pacific Regional And Seasonal Climate, Gavin Lemley

Legacy Theses & Dissertations (2009 - 2024)

Paleoclimate reconstructions often utilize coral reefs with very long time spans such as the genus Porites and Diploastrea, because of their potential to provide centuries of continuous climate records via geochemical signatures. Smaller corals, such as the genus Isopora, have been essentially unexplored as climate archives because their small skeletons (<1 m) and short lifespans (years to decades) do not provide such continuous geochemical records. There has not been a practical application for such corals until recently. In early 2010, the Integrated Ocean Drilling Program Leg 325 (IODP-325) cored drowned fossil reefs off the Great Barrier Reef (GBR) with the objectives of reconstructing sea level and surface ocean conditions since the Last Glacial Maximum. Out of 213 massive fossil corals that were recovered, most were massive Isoporan colonies. A 30-specimen subset of these fossils range in age from ~32,000 to ~11,500 years before present with even temporal spacing, based on preliminary U/Th dating of core catcher samples. This age distribution is excellent for meeting IODP-325 objectives, but the suitability of Isopora for paleoclimate analyses remains unknown.

Assessing The Reproducibility Of Coral Oxygen And Carbon Isotope Time Series From Fiji And Tonga And Their Application To The Reconstruction Of South Pacific Convergence Zone Movements Since The Mid-1800s, Emilie Pauline Dassie

Legacy Theses & Dissertations (2009 - 2024)

A major feature affecting the hydrology of the southern hemisphere is the South Pacific Convergence Zone (SPCZ); a band of high rainfall extending southeastward from the Western Pacific Warm Pool (WPWP). It is a key source of atmospheric water vapor and latent heating. While it is clear that the SPCZ plays a fundamental role in Earth's climate, little is known about the patterns and mechanisms responsible for interannual to century-scale changes in its position and how it may respond to global climate change.