Geochemistry Commons^™

Cave Ventilation Is Influenced By Variations In The Co2-Dependent Virtual Temperature, Enrique P. Sánchez-Cañete, Penélope Serrano-Ortiz, Francisco Domingo, Andrew S. Kowalski

International Journal of Speleology

Dynamics and drivers of ventilation in caves are of growing interest for different fields of science. Accumulated CO₂ in caves can be exchanged with the atmosphere, modifying the internal CO₂ content, affecting stalagmite growth rates, deteriorating rupestrian paintings or creating new minerals. Current estimates of cave ventilation neglect the role of high CO₂ concentrations in determining air density – approximated via the virtual temperature (T_v) –, affecting buoyancy and therefore the release or storage of CO₂. Here we try to improve knowledge and understanding of cave ventilation through the use of T …

Natural And Anthropogenic Factors Which Influence Aerosol Distribution In Ingleborough Show Cave, Uk, Andrew C. Smith B.S.C, Peter M. Wynn, Philip A. Barker Professor

International Journal of Speleology

Monitoring in Ingleborough Show Cave (N. Yorkshire, UK) reveals the influence of tourism and cave management techniques on different parameters of the cave atmosphere. Exploratory aerosol monitoring identified a 0.015 ± 0.03 mg/m³ (≈70%) reduction in airborne particulates within the first 75 meters of cave passage and two major aerosol sources within this artificially ventilated show cave. Autogenic aerosol production was identified close to active stream ways (increases of

In-Situ, Integrated U-Pb, Hf And O Isotopic Study Of Igneous, Metamorphic And Detrital Zircons. Implications To Crustal Evolution And Geodynamics, Munazzam Ali Mahar

Open Access Theses & Dissertations

Zircon data from South Karakoram gneiss dome provide evidence for Proterozoic inherited cores (1.8-1.9 Ga and 2.3-.2.5 Ga) surrounded by migmatitic overgrowth with ages ranging from ~6 to ~20Ma. Oxygen isotopic data of Neogene migmatite and inherited core is similar and indistinguishable ranging from 7.5 to 9.5 /. However, Neogene overgrowth is significantly less evolved than the inherited core in terms of Hf composition. This implies that the Hf composition of the migmatitic zircons is not controlled exclusively by the dissolution of the inherited cores and that contamination by external melts is likely. Isotopic data from the Baltoro plutonic unit …

Modeling Of Co2-Water-Rock Interactions In A Mississippian Sandstone Reservoir Of Kentucky, Anne M. Schumacher

Theses and Dissertations--Earth and Environmental Sciences

This study examined CO₂-water-rock interactions occurring during a carbon sequestration pilot test into a Mississippian oil reservoir in western Kentucky. New samples (n=62) and archived data, both collected from oil wells, were used to characterize the chemistry of formation waters from the Sugar Creek field in Hopkins County. In addition, core and cuttings samples (n=17) from the reservoir and overlying cap-rocks in, or near, the field were analyzed for bulk and clay mineralogy using X-ray diffraction. Electric logs were used to select sample intervals within the overlying cap-rocks and the center of the producing zones in the Jackson …

Effects Of Chiloquin Dam On Spawning Distribution And Larval Emigration Of Lost River, Shortnose, And Klamath Largescale Suckers In The Williamson And Sprague Rivers, Oregon, Barbara A. Martin, David A. Hewitt, Craig M. Ellsworth

United States Geological Survey: Publications

Chiloquin Dam was constructed in 1914 on the Sprague River near the town of Chiloquin, Oregon. The dam was identified as a barrier that potentially inhibited or prevented the upstream spawning migrations and other movements of endangered Lost River (Deltistes luxatus) and shortnose (Chasmistes brevirostris) suckers, as well as other fish species. In 2002, the Bureau of Reclamation led a working group that examined several alternatives to improve fish passage at Chiloquin Dam. Ultimately it was decided that dam removal was the best alternative and the dam was removed in the summer of 2008. The U.S. …

The Mineral Industry Of Nebraska

United States Geological Survey: Publications

In 2013, the value of the nonfuel mineral production1 in the State of Nebraska was $166 million,2 0.2% of the total U.S. nonfuel mineral production, ranking it 39th in the country. In 2012, the corresponding value was $160 million,2 0.2% of the Nation’s total nonfuel mineral production, ranking it 36th among the 50 States. In 2013, on a per capita basis, nonfuel mineral production in Nebraska in 2013 had a value of $89 compared with the national average of $238. In 2012, the per capita value was $86 compared with the national average of $241. The value of nonfuel mineral …

Lithogeochemical And Stable Isotope Characteristics Of Bristol And Northern Thorneloe Townships And Its Correlation With Gold Mineralization, Zachary Grant Stevison

Wayne State University Theses

The Porcupine Mining Camp located in the southwestend of the Abitibi Greenstone Belt has been mined extensively for its prolific precious and base metal enrichment. This study targeted Bristol and Northern Thorneloe, fifteen kilometers southwest of Timmins, ON, an area that is of economic interest for its gold mineralization. Rock samples were collected (drill- core and outcrop) throughout both townships and analyzed for their major and trace element composition, These were used to determine hydrothermal alteration signatures as well as specific elemental enrichment that relate to gold mineralization in Bristol-Thorneloe Township. Quartz-carbonate and quartz-carbonate-tourmaline vein samples were also collected near …

Distribution And Impacts Of Petroleum Hydrocarbons In Louisiana Tidal Marsh Sediments Following The Deepwater Horizon Oil Spill, Rachel S. Hatch

Theses and Dissertations--Earth and Environmental Sciences

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide ²³⁴Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using ²¹⁰Pb, with verification from ¹³⁷Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon …

A Model For The Formation Of Layered Soda-Straw Stalactites, Bence Paul, Russell Drysdale, Helen Green, Jon Woodhead, John Hellstrom, Rolan Eberhard

International Journal of Speleology

Climate records based upon instrumental data such as rainfall measurements are usually only available for approximately the last 150 years at most. To fully investigate decadal-scale climate variation, however, these records must be extended by the use of climate proxies. Soda-straw stalactites (straws) are a previously under-utilised potential source of such data. In this contribution we investigate the structure and formation of straws and look at some issues that may affect the reliability of straw-based palaeoclimate records. We use laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) trace element analysis to document surface contamination features that have the potential to obscure annual …

The Relative Contribution Of Methanotrophs To Microbial Communities And Carbon Cycling In Soil Overlying A Coal-Bed Methane Seep, Christopher T. Mills, Gregpry F. Slater, Robert F. Dias, Stephanie A. Carr, Christopher M. Reddy, Raleigh Schmidt, Kevin W. Mandernack

Chemistry & Biochemistry Faculty Publications

Seepage of coal-bed methane (CBM) through soils is a potential source of atmospheric CH₄ and also a likely source of ancient (i.e. ¹⁴C-dead) carbon to soil microbial communities. Natural abundance ¹³C and ¹⁴C compositions of bacterial membrane phospholipid fatty acids (PLFAs) and soil gas CO₂ and CH₄ were used to assess the incorporation of CBM-derived carbon into methanotrophs and other members of the soil microbial community. Concentrations of type I and type II methanotroph PLFA biomarkers (16:1ω8c and 18:1ω8c, respectively) were elevated in CBM-impacted soils compared with a control site. Comparison …

Rare Earth Element Geochemistry Of The Sierra Blanca Laccoliths, Texas, Amed Gomez

Open Access Theses & Dissertations

No abstract provided.

Abiotic Nitrate And Nitrite Reactivity With Iron Oxide Minerals, Prakash Dhakal

Theses and Dissertations--Plant and Soil Sciences

Under iron (Fe³⁺)-reducing conditions where aqueous Fe²⁺ and unreduced solid Fe³⁺-oxides commonly coexist, soil Fe²⁺ oxidation has been shown to be coupled with nitrate (NO₃^-) reduction. One possible secondary reaction is the involvement of NO₃^- and nitrite (NO₂^-) with Fe-oxide minerals found in many natural environments. Yet, spectroscopic measurements and kinetic data on reactivity of NO₃^- and NO₂^- with Fe-containing oxide minerals such as goethite (a-FeOOH), and magnetite (Fe₃O­₄) are not found in the literature. The reactivity of …

Stromatolites And Miss—Differences Between Relatives, N. Noffke, S. M. Awramik

OES Faculty Publications

Benthic microorganisms form highly organized communities called “biofilms.” A biofilm consists of the individual cells plus their extracellular polymeric substances (EPS). In marine and non-marine environments, benthic microbial communities interact with the physical sediment dynamics and other factors in the environment in order to survive. This interaction can produce distinctive sedimentary structures called microbialites. Binding, biostabilization, baffling, and trapping of sediment particles by microorganisms result in the formation of microbially induced sedimentary structures (MISS); however, if carbonate precipitation occurs in EPS, and these processes happen in a repetitive manner, a multilayered build-up can form—stromatolites. Stromatolites and MISS are first found …

Are 34s-Enriched Authigenic Sulfide Minerals A Proxy For Elevated Methane Flux And Gas Hydrates In The Geologic Record?, Walter S. Borowski, Nancy M. Rodriguez, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

The sulfate–methane transition (SMT) zone is a diagenetic transition within anoxic marine sediments created by the metabolic activity of a consortium of sulfate-reducing bacteria and methane-oxidizing Archaea. As interstitial dissolved sulfate is consumed by microbially mediated sulfate reduction of sedimentary organic matter (SOM) and anaerobic oxidation of methane (AOM) large enrichments of ³⁴S occur in the interstitial sulfate pool. These isotopic enrichments are transmitted to the dissolved sulfide pool (∑HS⁻) and subsequently into sulfide minerals (So, ∼FeS, FeS₂).

We investigate the sulfur isotopic composition of pore-water sulfate and sulfide minerals at three sites underlain …

Geochemical Evidence For Vertical Migration Of Deep Formation Fluids Through The Baton Rouge -Denham Springs Fault System, Lesley C. Prochaska

LSU New Orleans Theses and Dissertations

Accumulations of brackish groundwater exist across south Louisiana within the shallow, south-dipping Pleistocene to Upper Miocene Baton Rouge Aquifer System (BRAS). This research investigates the source of brackish groundwater through geochemical analysis of representative groundwater samples by comparing the following geochemical ratios along with other trace elements. Low Bromide (Br)/Chloride (Cl) and Potassium (K) /Cl ratios, high Sodium (Na) /Cl ratios, trace Magnesium (Mg) concentrations, and low Strontium (Sr) ⁸⁷/Sr⁸⁶ in brackish waters from the BRAS are inconsistent with in situ saline water from marine formation fluids of similar age. The ratios are consistent with in situ saline-water …

Early Permian Seawater From The Delta18o Record Of Fossil Bivalves: Seasonality And A Latitudinal Gradient, James Andrew Beard

Earth & Environmental Sciences - Theses

The transition from a glaciated world to one that was ice-free makes the early Permian a time interval that in many ways mirrors the present, and hence there is great interest in constraining paleoclimate conditions over that transition. A common method for estimating ancient temperatures uses the oxygen isotope composition of marine carbonate, but this approach becomes significantly more complicated prior to the Cretaceous due to uncertainties about diagenesis and the isotopic composition of seawater, which has been hypothesized to be more depleted than during the Cenozoic. I use stable isotope compositions of sequentially microsampled accretionary calcite from fossil bivalves …

Chemical Contaminants As Stratigraphic Markers For The Anthropocene, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Thousands and even millions of years from now, widespread anthropogenic contaminants in sediments would likely persist, incorporated into the geological record. They would inadvertently preserve evidence of our present era (informally designated as the Anthropocene Epoch) characterized by large human populations engaged in intensive industrial and agricultural activities.

Hypothetical geologists in the distant future would likely find unusually high concentrations of a wide variety of contaminants at stratigraphic levels corresponding to our present time, analogous to the iridium anomaly marking the bolide impact event at the close of the Cretaceous Period. These would include both organic and inorganic substances, such …

Assessing Eolian Dust Inputs To Soils In Dry Creek Experimental Watershed, Sw Idaho, Brian Jameson Stark

Boise State University Theses and Dissertations

A geochemical investigation of upland soils in the Dry Creek Experimental Watershed (DCEW) near Boise, Idaho was conducted to assess the potential contributions of eolian dust. Major and trace element compositions of soils within the watershed, loess deposits in the adjacent Western Snake River Plain (WSRP), and underlying granodiorite bedrock were evaluated. Multiple lines of evidence suggest a significant contribution of dust in the soils. Plots of Co/Ti, V/Ti and Cr/Ti indicate that the loess and bedrock occupy distinctly different compositional spaces and that the soils are of intermediate composition, suggesting that the soils are a mixture of the loess …

Glacial Shortcut Of Arctic Sea-Ice Transport, Michael Stärz, Xun Gong, Rüdiger Stein, Dennis A. Darby, Frank Kauker, Gerrit Lohmann

OES Faculty Publications

Due to the lack of data, the extent, thickness and drift patterns of sea ice and icebergs in the glacial Arctic remains poorly constrained. Earlier studies are contradictory proposing either a cessation of the marine cryosphere or an ice drift system operating like present-day. Here we examine the marine Arctic cryosphere during the Last Glacial Maximum (LGM) using a high-resolution, regional ocean-sea ice model. Whereas modern sea ice in the western Arctic Basin can circulate in the Beaufort Gyre for decades, our model studies present an extreme shortcut of glacial ice drift. In more detail, our results show a clockwise …

Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis

All Master's Theses

Groundwater, the primary source for potable water in the Columbia Plateau, has experienced significant declines over the past 25 years. Groundwater geochemistry and multivariable statistics were employed to identify and characterize the hydrofacies present, constrain recharge sources, and assess mixing of groundwater in the Royal Slope area of the Columbia Plateau. Geochemical analyses for major ions, stable isotopes, and radiogenic isotopes (14C and tritium) for age dating were performed on groundwater samples collected in 2010 from 24 wells in the study area. The results confirmed that the groundwater evolution in the study area follows the typical Columbia River Basalt Group …