Geochemistry Commons^™

Pfas In Naturally Occurring Surface Water Foams, Donovan S. Vitale

Masters Theses

Surface Water Foam (SWF) and underlying Surface Water (SW) were collected from six distinct sites across Michigan using a novel sampling device. PFAS were detected in all SWF samples with total PFAS concentrations (Σ41 compounds, n=14) varying widely from 2,693 to 402,172 ng/L .SWF samples were enriched in high and intermediate molecular volume PFAS relative to SW samples (n=10) which were dominated by low molecular volume, short-chain PFAS with total PFAS concentrations ranging from 4.4 to 31 ng/L. Wet and dry SWFs were distinguished by appearance, liquid content, and PFAS composition. Dry SWFs had higher total PFAS concentrations than wet …

Insights Into Fluid-Rock Interactions On The Cv3 Chondrite Parent Body Through The Use Of Secondary Garnets In The Allende Cv3 Chondrite And Terrestrial Skarns, Jessica Marie Johnson

Earth and Planetary Sciences ETDs

Garnets are valuable for studying geologic processes, particularly fluid-rock interactions in terrestrial skarns. This dissertation examines secondary garnets and associated Ca-Fe silicates in Allende-like CV3 chondrites and terrestrial skarns to assess garnets as recorders of fluid-rock interactions. Chapter 2 investigates garnets from the Willsboro-Lewis skarn, revealing that mineral separate techniques misrepresent rare earth element (REE) signatures. Chapter 3 examines garnets and clinopyroxenes from the Victorio Mining District skarn, showing that REE incorporation was controlled by fluid composition rather than crystal chemistry. Chapters 4 and 5 focus on extraterrestrial samples. Chapter 4 finds that garnets and pyroxenes in Allende CV3 matrix …

Temperature-Driven Air Circulation In Caves With Blind Passages, Chris Hendy Dr, David J. Merritt, Shannon Corkill, Cross Cross

International Journal of Speleology

Two blind-passage show-caves in the Waitomo district of New Zealand, Ruakuri Cave and Aranui Cave, have been monitored for the impact of visitors on their environment, especially focusing on partial pressures of carbon dioxide because high levels cause speleothem degradation. In Ruakuri Cave, annual cycles of daily mean pCO₂ correspond with annual cycles of visitor numbers, both peaking in summer. The origin of the high pCO₂ had been assumed to be anthropogenic due to respiration from visitors. Prolonged intervals with no visitation during the Covid-19 pandemic saw the daily mean pCO₂ continuing to show the annual cycle, …

Body Size Trends Of Late Devonian Dacryoconarid Tentaculitoids And Protocol Development For I/Ca Analysis In Corals By La-Icp-Ms, Ashley Prow-Fleischer

Dissertations - ALL

Paleoclimatology provides context for understanding the timescales and animal responses to environmental change under modern climate change scenarios. The key drivers of climate variability are identified using proxies for environmental conditions. Biological archives are especially useful for linking changing conditions to ecosystem responses. This dissertation establishes the foundation for utilizing dacryoconarid microfossils as biostratigraphic indicators of environmental change in the Paleozoic. It also presents a protocol for measuring iodine-to-calcium (I/Ca) ratios—an established proxy for localized hypoxia—in coral skeletons using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Studying Paleozoic microfossils presents challenges due to the high degree of induration of …

Unraveling The Causal Influences Of Drought And Crop Production On Groundwater Levels Across The Contiguous United States, Nitin K. Singh, Sheila M. Saia, Ruchi Bhattacharya, Hoori Ajami, David M. Borrok

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Groundwater depletion in agricultural-dominated regions is attributed to climate and irrigation withdrawals that support crop production. However, despite decades of effort, knowledge gaps remain in understanding the relative influence of drought and crop production on groundwater levels at the continental scale. Here, utilizing empirical observations, we simultaneously track how long-term trajectories of groundwater levels, crop production of seven crops, and drought have evolved over time, and then integrate these observations with a causality-based attribution framework to unravel the relative impact of drought and crop production on groundwater levels across the contiguous United States (CONUS). We find a dominant pattern of …

Characterization Of Residual Mineral Content Of Bauxite Stockpiles In Saline County, Arkansas: An Xrd Analysis Approach, Andrew Kaze Sezibera

Electronic Theses and Dissertations

The Saline Mining District of central Arkansas once led U.S. alumina production and hosts extensive bauxite and nepheline syenite deposits. With the depletion of highgrade ore, renewed interest in bauxite stockpiles has focused on critical mineral potential. Previous X-ray Fluorescence studies have identified critical elements in significant concentrations, including uranium (U), thorium (Th), gallium (Ga), molybdenum (Mo), and lanthanides (Ln). This study examines five stockpiles (SP1, Clay, SP2, SP3, and SP4) in Section 20 of the Aluminum Company of America (ALCOA) Saline County bauxite mine, using Xray Diffraction (XRD) on 25 samples to characterize mineral phases and compare them with …

Evidence For Distal Bolide Impact And Tsunami Deposits In The Upper Atlantic Coastal Plain Of Moore County (North Carolina, Usa) Generated By The Eocene Chesapeake Bay Bolide Impact, G. Robert Ganis, Ralph H. Willoughby, David J. Cicimurri, G. Richard Whittecar, Steven J. Hageman

OES Faculty Publications

Beds interpreted as Eocene bolide-generated impact and tsunami deposits occur at Paint Hill in the Upper Atlantic Coastal Plain of Moore County, North Carolina, USA. These strata, herein named the Mount Helicon Formation, consist of four distinct beds comprising about one meter of total section. Bed 1 (the basal bed) is approximately 43 cm thick and consists of sandy carbonaceous clay with carbon glass and rock fragments and contains 14-18 parts per billion (ppb) iridium (interpreted as bolide impact ejecta). Bed 2 is approximately 9 cm thick and consists of non-cohesive silt-size particles and loosely bound sand-size accretionary lapilli-like masses …

Rectifying The Tephrostratigraphic Record Of The Pacific Northwest, Casey J. Crawford

Boise State University Theses and Dissertations

The Mid-Miocene Climatic Optimum (~17-14Ma) marks the last time that Earth’s atmospheric CO₂ concentrations were as high as modern levels, correlating to a peak of significant warming during an otherwise cooling trend through the Cenozoic. To understand how modern ecological systems may respond to CO₂ -induced climate change, paleontologists are studying how plant type and diversity changed with the rise and fall of CO₂ concentrations over the ~3Ma interval, and utilize intercalated tephras amenable to radioisotope geochronology to bracket fossiliferous horizons in time. The legacy model for tephrostratigraphy in the Pacific Northwest utilized Fe and Ca concentrations …

Optimizing Nitrogen Management: Assessing Nitrate Transport In The Deep Vadose Zone And Its Impact On Groundwater Quality In East-Central Nebraska, Muili O. Lawal

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Groundwater contamination by nitrate (NO₃-N) is a growing environmental and public health concern driven largely by intensive agricultural fertilizer applications. The vadose zone plays an important role in NO₃-N transport, influencing groundwater quality and agricultural sustainability. This study investigated NO₃-N leaching dynamics in the deep vadose zone of Water Quality Sub-Area 30 (WQA30) within the Lower Loup Natural Resources District (LLNRD), northeast of Columbus, Nebraska (mean groundwater NO₃-N: 20.3 mg/L), using soil cores from 16 shallow (to 6.1 m) and four deep (down to 25.9 m) across four zones, two with inorganic fertilizer (Zones 1 and 4) and two with …

A Mineralogical And Geochemical Investigation Of The Influence Of Tectonic Setting On Accessory Mineral Assemblages In Serpentinites Along The Western North American Margins, Bryan H.T. Seymour

Electronic Theses, Projects, and Dissertations

Serpentinites are metamorphic rocks typically produced by hydrating mantle peridotites to form assemblages containing one or more serpentine minerals. They occur in various tectonic and geologic settings, such as submarine hydrothermal systems, ophiolite sequences, and the forearc mantle. Serpentinites are associated with highly reduced conditions, as indicated by low oxygen fugacity (ƒO₂) values. Previous investigations suggest that oxygen fugacity varies with tectonic setting due to differences in environmental conditions. To test this hypothesis, we analyzed serpentinites from a wide variety of tectonic settings in western North America: The New Idria forearc diapir (CA), Canyon Mountain Island arc complex (OR), Josephine …

The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski

Climate Change and the Individual, 2025-26

The Paleocene-Eocene Thermal Maximum (PETM) is not just an event that occurred in Earth’s distant past (~55 million years ago) but is a crucial lesson for today’s meteoric climate change. The PETM offers a historical parallel of rapid flux of greenhouse gases into the atmosphere that caused global warming, ocean acidification, dramatic changes in weather, and extinctions. This global warming event was the result of 20,000 years of “rapid” warming (in geological terms) however, we are experiencing rates of warming that are 5-10x higher than PETM levels. We are not experiencing rapid warming today, in comparison to the past, we …

08 - Blue Carbon Sequestration And Sediment Storage In Seagrass Meadows Of South Bay, Luke C. Clements, Adriana Amrhein, Richard P. Hale

Undergraduate Research Symposium

Blue carbon is stored in coastal and marine ecosystems like seagrass meadows and salt marshes, which helps combat climate change by preventing greenhouse gas emissions. This study examines the role of seagrass in carbon storage by comparing sediment cores from a mud channel and a seagrass meadow in South Bay.

We collected a 100 cm core from the mud channel and a 55 cm core from the seagrass area, taking samples every 10 cm to analyze grain size and organic carbon content. Using a wet sieving method, we separated sand from mud and measured organic carbon through loss on ignition. …

Per- And Polyfluoroalkyl Substance (Pfas) Degradation In Water And Soil Using Cold Atmospheric Plasma (Cap): A Review, Victor Somtochukwu Mbanugo, Boluwatife Stephen Ojo, Ta Chun Lin, Yue-Wern Huang, Marek Locmelis, Daoru Han

Biological Sciences Faculty Research & Creative Works

Per- and polyfluoroalkyl substances (PFASs) are persistent organic chemicals found in numerous industrial applications and everyday products. The excessive amounts of PFASs in water and soil, together with their link to severe health issues, have prompted substantial public concerns, making their removal from the environment a necessity. Existing degradation techniques are frequently lacking due to their low efficiency, cost-effectiveness, and potential for secondary contamination. Cold Atmospheric Plasma (CAP) technology has emerged as a promising alternative, utilizing energized reactive species to break down PFASs under ambient conditions. Therefore, this review examines the efficacy and effectiveness of CAP in degrading PFASs by …

Glacial Isostatic Adjustments And Their Impact On Sea-Level Predictions, Dayne M. Williams, Jeanne Sumrall

SACAD: Scholarly Activities

Relative sea level adjustments and their effects directly contribute to modern day climate change and ocean knowledge. This is shown through Glacial isostatic adjustment models which depend on ice thickness, time period, and core analyzations within a local region. These models demonstrate a direct correlation between RSL, era of retreat, and ice thickness even with comparison of other similar models, with some minor discrepancies. These discoveries led to several new advancements within the field of glaciology regionally and nationally. Generally concluding that the research done isn’t sufficient and more data regionally is needed to study its impacts more detailed.

Mineralogic Control On The Calcium And Magnesium Stable Isotopic Compositions Of Modern Microbial Carbonates, Elizabeth M. Griffith, Matthew S. Fantle, Brittan V. Wogsland, Zijian Li, Majie Fan, David J. Wronkiewicz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Modern microbialites grow in a variety of environments including the hypersaline, turbid, low alkalinity, high magnesium (Mg) and calcium (Ca) concentrations (and Mg/Ca ∼ 4.5 mol/mol), shallow (less than 2 m deep) Storr's Lake on San Salvador Island, The Bahamas. Rather than growing via the trapping and binding of sediments, these largely micritic microbialites form via microbial processes creating crusts and mounds with laminated to clotted structures comprised of both high-Mg calcite and aragonite. The primary objective of this study was to determine whether the mineralogy of representative microbialite mounds dictates their pre-burial metal isotopic compositions. The Mg and Ca …

Spatial Analysis Of Heavy Metal Enrichment In A Historic Appalachian Mining Stream, Eric M. Torres

Research and Creativity Symposium

This study examined the spatial distribution of heavy metals along the Levisa Fork and primary tributaries in Buchanan County, VA and Pike County, KY. Buchanan and Pike Counties have a long history of coal mining, a process known to release heavy metals into surrounding waterways. Exposure to certain heavy metals, such as arsenic and lead, has been known to cause health problems, such as cancer and organ damage. The study looked at concentrations in riverine sediments, surface water and groundwater for As, Al, Cr, Cu, Fe, Li, Mg, Mn, Ni, Pb and Zn. Sediment samples were collected, dried and digested …

Cold Atmospheric Plasma Induced Degradation Of Organophosphate Pesticides On Kevlar Swatches, Ta Chun Lin, Victor Somtochukwu Mbanugo, Boluwatife Stephen Ojo, Yue-Wern Huang, Marek Locmelis, Frank Daoru Han

Biological Sciences Faculty Research & Creative Works

Cold atmospheric plasma (CAP) was evaluated for degrading organophosphate pesticide (OP) residues (acephate, malathion, and dimethoate) from Kevlar fabrics. Fourier transform-Infrared (FTIR) spectroscopy, scanning electron microscope (SEM) imaging and tensile strength testing confirmed that CAP treatment preserved Kevlar's structural integrity and mechanical properties. Results show degradation efficiency increased with higher power, shorter discharge gaps, and longer exposure duration. Hyperspectral imaging supported the detection of plasma-induced spectral changes, reinforcing the presence of reactive species. The strong oxidative potential of CAP facilitated the rapid breakdown of OPs into nontoxic byproducts. These findings demonstrate the potential of CAP as a portable, energy-efficient solution …

Sedimentary Archives Of Late Quaternary Limnological, Ecological, And Environmental Change In The Eastern Sierra Nevada (California, Usa), Bailee Hodelka

Theses and Dissertations--Earth and Environmental Sciences

The Sierra Nevada essentially serve as the headwaters of California, providing crucial freshwater to the state through seasonal snowmelt. This water supply is threatened by climate change in complex ways that are not fully understood. Geological records provide a valuable source of information on how the hydrology, limnology, and ecology of the Sierra Nevada region has responded to climate changes of the past. This dissertation presents new sedimentary and paleoecological research from Mono Lake and Convict Lake (Mono County, California) and aims to shed light on environmental changes in the eastern Sierra Nevada from ~16 ka to present.

At Mono …

Characterization And Leaching Feasibility Studies Of Copper Flue Dust For The Recovery Of Main And Trace Metals, Fardis Nakhaei, Marek Locmelis, Lana Alagha, Michael S. Moats, Carlos Eyzaguirre, Cory Smith

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Although copper smelter dust (CSD) is classified as hazardous waste, it also serves as a valuable secondary resource, offering potential for the recovery of critical elements. In this study, CSD samples were collected from the waste heat boiler (WHB) and electrostatic precipitator (ESP) units connected to the flash smelting furnace at a copper smelter. The representative samples were extensively characterized by particle size, and chemical and mineralogical analyses. Following sample characterization, leaching experiments were performed to evaluate the potential extraction of Cu, Fe, As, Zn, Pb, In, Ga, and Ge from the flue dusts. Distilled water, H2SO4, and HCl were …

Yukon Dust From Source To Sink: Characterizing The St. Elias Mountains As A High-Latitude Dust Source, Audrey Y. Lemoine

Honors Theses

High-latitude dust is an important, yet poorly understood, component of Earth’s climate system. It impacts weather and albedo by acting as cloud condensation nuclei, directly affects Earth’s radiative balance, and can enhance productivity by supplying nutrients to ecosystems. In order to better understand high-latitude dust dynamics and impacts, we sampled glacial meltwater, surface sediment, and Holocene loess in the Łhù’ààn Mân (Kluane Lake) region of the Yukon Territory, Canada. We found that suspended sediment concentration is correlated with average slope and glaciation within a catchment, and is influenced by river morphology. We present new εNd and ⁸⁷Sr/⁸⁶Sr …