Geochemistry Commons^™

Depositional Facies Analysis Of The Cotton Valley Group Sandstones Of The Blackburn Field, Northern Louisiana Using Well Logs And Cores; Implications For Carbon Sequestration, Frederick Owusu

Electronic Theses and Dissertations

The Cotton Valley Group (CVG) consists of tight sandstones with heterogeneous reservoir properties due to variations in depositional environments and diagenesis, spanning across eastern Texas through the Florida panhandle. It has served as a hydrocarbon target since the 1940s, and with recent technological advances, there is renewed exploration of the tight reservoirs within the group. Across northern Louisiana, the CVG has moderate to good reservoir properties, whereas those south extending westward across the Sabine uplift into east Texas decrease in porosity and permeability. With reservoir depletion coupled with its relatively simple mineralogy, these sandstone units may serve as good, localized …

Investigation Of Residual Mineral Content Of Bauxite Stockpiles, Saline Mining District, Arkansas, U.S.A., Melanie L. Ertons

Electronic Theses and Dissertations

The former mining town of Bauxite is in the Saline County Mining District, in central Arkansas. Bauxite is located approximately 40 km (25 mi) southwest of Little Rock just east of Benton, Arkansas. This area contains extensive deposits of bauxite ore and nepheline syenite previously mined by Aluminum Company of America using open pit and subsurface mining techniques. This study incorporates five bauxite stockpiles (SP1, Clay, SP2, SP3, SP4) with varying amounts of alumina content situated on approximately 10 acres of land within an area of the former mine recognized as Section 20. Over the past several years, there has …

The Geology And Geochemistry Of The Western Iron Ore Group Greenstone Belt, Singhbhum Craton, Eastern India, Jordan Wright

Earth Sciences Theses and Dissertations

This thesis presents new data on the origin of the Western Iron Ore Group (W-IOG), a Paleoarchean succession deposited on sialic rocks of the Singhbhum Craton. U-Pb ages from zircons from a tuff overlying the Lower Shales just below a banded iron formation (BIF) pin the age of the section to 3.39 Ga. Unconformably overlying the whole IOG section is the Darjing Group, which contains the Birtola Sandstone (on the basis of this work, now estimated to be 2.35 Ga). The lack of penetrative deformation and low-grade metamorphism makes these rocks excellent subjects for combined radiogenic and stable isotope studies. …

The Effects Of Amphibole- And Sulfide-Producing Melts On Crustal Strength In Gabbros Of Lower Oceanic Crust In Oceanic Core Complexes, Mid-Atlantic And Southwest Indian Ridges, Trevor Hoffmann

Master's Theses

This study investigates gabbro-cored oceanic core complexes in the slow-spreading Mid-Atlantic Ridge (MAR) and the ultraslow spreading Southwest Indian Ridge (SWIR). Dikelets are a texture found in thin section samples from these systems that form as a result of crystal-plastic deformation. Thin section samples from the Atlantis Massif, MARK Area, and 13˚-15˚ North of the MAR and the Atlantis Bank of the SWIR were observed with petrography to find these dikelets and identify what type of dikelet is present. SEM-EDS is used to identify the mineral assemblages present in the dikelets. LA-ICP-MS is used on amphibole to determine if its …

Evaluation Of Heavy Metal Pollution, Water Quality, And The Effectiveness Of Remedial Sediment Dredging In The Lower Passaic River, New Jersey, Oluwafemi Soetan

Theses, Dissertations and Culminating Projects

Toxic metal pollution is a leading environmental concern for aquatic systems globally and remedial dredging has been widely employed to mitigate its harmful impacts. In terms of the short-term impacts of remedial dredging, mixed results are reported in several studies. Despite its immediate negative impacts including saturation of water with toxic metals, increased turbidity, and sediment resuspension, positive impacts can be recorded over a stabilization period of 6 – 24 months after dredging. Nevertheless, the sustainability of these recorded positive effects cannot be ascertained as some studies have reported long-term regression in remediated sites’ conditions. Evaluation of success determinants, site-measure …

Investigating Changes In Surface Water Chemistry Across The Llano Uplift And The Balcones Fault Zone In Central Texas Using Strontium And Uranium Isotopes, Hao Tuan Pham

Open Access Theses & Dissertations

The landscape of central Texas is shaped by over one billion years of Earth's history. An array of lithology lies within central Texas along with two large geological structures. The Llano Uplift, characterized by Proterozoic metamorphic and igneous rocks dating back to 1.37 billion years ago, is encircled by Paleozoic and Mesozoic sedimentary rocks. To the southeast of the Llano Uplift lies the Balcones Fault Zone (BFZ), an extensional structural system of mostly normal faults that delineates the transition between Paleozoic-Mesozoic sedimentary rocks and Cenozoic sedimentary cover, which are influential to the regional hydrogeology. This study investigates the hydrogeological dynamics …

Introduction To Nuclear Magnetic Resonance Spectroscopy In A Geochemical Setting, Evan Mack

University Honors College

Nuclear magnetic resonance (NMR) spectroscopy is a powerful analytical tool that is heavily employed in organic chemistry, but lacks use in geochemistry. The technique is most useful for characterization and structural analysis of analytes, but also sees use in kinetics analysis, speciation, and detection. This work aims to answer these questions regarding NMR spectroscopy’s use in geochemical settings: Which nuclei are studied? For what purposes is each nucleus studied? What affects the scope of the technique and has caused it to not be widely used? How often is NMR spectroscopy used? What trends are there in the technique’s use? The …

Determining The Climatic Effects Of The Central Atlantic Magmatic Province Across The End Triassic Mass Extinction In The Elliot Formation, Southern Africa, Danielle Elizabeth Oberg

Graduate Theses and Dissertations

Understanding the intricate relation between carbon-cycle perturbations, climate change, and biodiversity stability is crucial in the face of ongoing anthropogenic greenhouse-gas emissions. This thesis explores the impacts of rapid climate change induced by carbon-cycle perturbations and their potential repercussions on global climate. Large igneous provinces, particularly the Central Atlantic Magmatic Province, offer a lens through which to examine the nexus of volcanic activity, mass extinctions, and climate change. The emplacement of Central Atlantic Magmatic Province, covering vast regions across continents, emitted substantial amounts of carbon dioxide, profoundly impacting global climate and ecosystems. The end-Triassic Mass Extinction, attributed to Central Atlantic …

Geochemical Analysis Of Basement Rock As A Potential Metal Source In Mississippi Valley-Type Ores, Southern Midcontinent U.S.A., Mackenzie Moorhead

Graduate Theses and Dissertations

Mississippi Valley-Type (MVT) ores are epigenetic, sedimentary hydrothermal base metal deposits that exist worldwide with type localities in the midcontinent United States. These Permian-aged sulfide ores represent an extraordinary concentration of economic metals, Pb and Zn. Ore deposits occur in vast districts that have a rich mining history. The Pb and Zn from these deposits account for 24% of worldwide reserves. The geologic processes responsible for MVT ore genesis are not fully understood, especially the sourcing of ore constituents. In the midcontinent, the Ouachita Orogeny expelled saline hydrothermal brines in response to high rates of subsidence. These fluids migrated through …

Investigating Controls On Temporal And Spatial Variation Of Dissolved Uranium At Springs In Horn Creek Drainage, Grand Canyon National Park, Arizona, Usa, Collin Davidson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is a critical resource in the Grand Canyon, providing water to local communities, millions of annual visitors, and ecosystems. One major concern for this critical resource is the potential for uranium contamination in conjunction with uranium mining efforts. Upper Horn Bedrock Spring (UHB) in the Horn Creek drainage of the Grand Canyon sits below the oldest uranium mine in the region, Orphan Lode mine. UHB spring contains the highest concentration of dissolved uranium in the region, eclipsing the Maximum Contaminant Level (MCL) set by the USEPA by an order of magnitude on average. This research and recent collaboration with …

Terrestrial Exchange Of Atmospheric Metals: Insights From Fallout Radionuclides, Joshua D. Landis

Dartmouth College Ph.D Dissertations

Forests mediate the exchange of gases and particulate matter (PM2.5 and PM10) between terrestrial ecosystems and the atmosphere over 30% of global land area. Because forest foliage efficiently absorbs PM with persistent pollutants including metals Pb and Hg, as well as CO₂ and gaseous elemental mercury (GEM), this exchange profoundly influences the composition of the atmosphere as well as terrestrial biogeochemical cycles. The processes by which PM is absorbed remain enigmatic, however, due to the complexity of micrometeorological physics and submicron physical scale of the interaction. Here, measurements of fallout radionuclides (FRNs) beryllium-7 and lead-210, which are quintessential tracers …

Evaluating Reclaimed Mines And Heavy Metal Soil Contamination, Torin A. Matthews

ATU Scholars Symposium

Arkansas has a rich history of lead and zinc mining. While there are still some active mines, many historical mines have been abandoned and/or reclaimed. Although most reclamation procedures result in the burial and containment of target minerals, accessory minerals and elements can be leached out of waste materials/tailings piles and include heavy metals (i.e., Pb, As, Cd). We aim to evaluate the soil and watershed of a few abandoned/reclaimed mines in Pope County, AR, for the presence of heavy metals/source minerals. Soil and stream sediment geochemistry will be conducted using a portable x-ray fluorescence analyzer. Field work and sampling …

Investigation Of Temporal Variation In Sediment Deposition Within The Tropical Wouri Estuary Cameroon Using Fourier Transform Infrared Spectroscopy, Olumide Ajulo, Dr. Henry Agbogun, Dr. Hendratta Ali

SACAD: Scholarly Activities

In this study, Fourier Transform Infrared Spectroscopy (FTIR) was employed to qualitatively analyze organic and mineral components of the sediment core collected from the Wouri Estuary. The FTIR spectra revealed distinct transmittance corresponding to different organic and mineral phases, allowing for the characterization of sediment composition. The FTIR spectra showed changes and variation progressively from the bottom to the top. These sediments are proxies for time this can be inferred to say deposition in the Wouri Estuary has always changed.

Qualitative Analysis Of Selected Hydrocarbon Produced In Kansas Using Ftir: An Oil-Oil Correlation Study, Oluwaseun Omoyemi, Henry Agbogun, James Titah

SACAD: Scholarly Activities

Hydrocarbons have been produced in Kansas since the 1860s, however, the properties and characteristics of the produced oil are still poorly understood.

An oil-oil correlation analysis has been conducted on twelve hydrocarbon samples from three subbasins and from five producing intervals within the State of Kansas. Fourier Transform Infrared Radiation (FTIR) was used to characterize the organic functional groups present within the samples and Thin Layer Chromatography (TLC) was used to assess the hydrocarbon fractions in the samples. The FTIR spectrum of all the samples exhibit similar peaks implying similar functionally groups were present in all the samples. The TLC …

Applied Depositional Geosystems Of The Coos Bay Basin, Oregon: Organic Geochemistry, Maturation, Paleoenvironmental Reconstruction And Biostratigraphy Of The Coaledo Delta During The Middle Eocene Climatic Optimum (Meco), Allison K. Barbato

LSU Doctoral Dissertations

The Coos Bay Basin on the southwestern coast of Oregon is a forearc basin that contains exceptionally preserved Eocene to Miocene, tidal to wave-dominated, shallow deltaic to deep marine sediments of the Coaledo Delta. Coastal depositional environments are known to host source, reservoir, and seal rocks. Climate, topographic relief, and geographical position all play an important role in regional vegetation development and oceanic setting. This study assesses 84 outcrop and 12 core samples from Coos Bay for their organic geochemical characteristics and microfossil assemblage to provide source rock characterization information, organofacies descriptions, environmental reconstructions, and age control.

Results indicate the …

Unearthing The Past: A Comprehensive Study Of Natural And Anthropogenic Changes At An Archaeological Site Through Hydrogeologic Connectivity Utilizing Gis, Mehlich Ii Phosphorus Extractant, And Ph, Dana L. F. Herren

Theses

This thesis aims to thoroughly analyze the Mehlich II Phosphorus Extractant and pH levels at the Bains Gap Village Site in Anniston, AL., while examining the impact of various environmental factors and human activities on them. Phosphorus is often used in archaeology as an indicator of human activity. Soil core samples were collected to analyze anomalies in phosphorus levels.

To establish any relationships, phosphorus and pH levels from soil cores were correlated with findings from past excavation units and features. The potential effects of hydrogeologic connectivity on soil phosphorus and pH levels were investigated. Geospatial technologies were used to manage …

Transport Of Multi-Phase Multi-Component Fluids In The Shallow Subsurface Influenced By Soil And Surface Boundary Conditions: Experimental And Numerical Study With Application To Natural Gas Leakage, Navodi Jayarathne

Civil and Environmental Engineering Theses and Dissertations

With the increased use of Natural Gas (NG) as a source of fuel, underground leak-related events are increasingly reported, and some are fatal. Subsurface migration and development up to flammable limits are highly dependent on leak characteristics, soil, atmospheric variables, and other surface and subsurface structural complexities. Although few studies have characterized the transient behavior of leaked NG in the shallow subsurface, the underlying mechanisms and their interactions are not well understood, which prevents prediction of the impact of environmental and operating conditions on gas migration. The study conducted a series of field scale-controlled release experiments and numerical simulations to …

Remote Sensing Techniques To Determine Volcanic Gas Components And Fluxes: Application For Lascar, Chile And Fagradalsfjall, Iceland Volcanos., Felipe S. Rojas Vilches

Earth and Planetary Sciences ETDs

Volcanic plumes allow us to understand different aspects of a volcanic system including magma movements, dynamics, mass transfer, overall gas emissions to the atmosphere, and many processes that impact human life. However, the H₂O gas is poorly constrained due to the intrinsic difficulties of this gas, with high background values and easily dispersed/integrated into the background. In this work we study the gas emissions from Lascar volcano, and Fagradalsfjall volcano, in Chile and Iceland, respectively, using a combination of different ground-based remote sensing techniques and in situ plume measurements, we measure H₂O, SO₂, CO₂, CO, and H₂S from longer and …

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …

Correlation Of Geochemical Zones In Great Onyx Cave, Mammoth Cave National Park, To Surficial Geological Units, William Strehl

Mahurin Honors College Capstone Experience/Thesis Projects

Cave passages in Great Onyx Cave, developed within the Girkin and Ste. Genevieve Limestones of Mammoth Cave National Park, contain a variety of secondary features on cave walls, including speleothems such as stalactites, stalagmites, and flowstone, evaporite minerals, and dissolution features such as pits and domes. What secondary features are present on the walls of a cave passage depends on the flow and geochemistry of capillary water that has interacted with the cave passage. In the Mammoth Cave aquifer, five distinct geochemical zones have been broadly defined and each typically contains a particular set of secondary features. Geochemical zonation in …