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Full-Text Articles in Physics

Time Resolved X-Ray Spectroscopy Of Highly Charged Ar, Nd, And Pr, Timothy Burke May 2024

Time Resolved X-Ray Spectroscopy Of Highly Charged Ar, Nd, And Pr, Timothy Burke

All Dissertations

Highly Charged Ions (HCIs) may be considered ideal mini-laboratory in which one can study the physics of matter and light in an environment of high internal electric field that can not be recreated with standard lab equipment. The remaining electron(s) exist in the extremely large electric field of the nucleus and therefore measurements of electronic transitions in these systems provide stringent tests of our understanding of physics in extreme conditions. Quantum electrodynamics (QED) despite being a powerful theory exhibits large discrepancies for systems under extreme conditions. The work here investigates the atomic properties within non-Maxwellian plasmas. The HCI plasmas studied …


Design, Fabrication, And Characterization Of Advanced High-Power Single-Mode 9xxnm Semiconductor Lasers, Xiaolei Zhao May 2024

Design, Fabrication, And Characterization Of Advanced High-Power Single-Mode 9xxnm Semiconductor Lasers, Xiaolei Zhao

All Dissertations

This thesis presents the comprehensive design, fabrication, and demonstration of advanced high-power, high-efficiency single-mode semiconductor lasers operating at a wavelength of 9xxnm. We begin with the design of the laser epitaxial structure, serving as the cornerstone for achieving high-power high-efficiency lasers. Our methodology integrates a semi-analytical calculation model, which accounts for Longitudinal Spatial Hole Burning (LSHB) and Two-Photon Absorption (TPA) effects, facilitating a thorough exploration of how design parameters influence output power and conversion efficiency. This approach offers an effective and time-efficient epitaxial structure optimization strategy compared to conventional full 3D simulation models.

Subsequently, we demonstrate high-power, high-efficiency ridge waveguide …


Photobiomodulation Of Bovine Oocytes During Maturation Increases Atp Content And Enhances Subsequent Embryonic Development, Kendall Richey May 2024

Photobiomodulation Of Bovine Oocytes During Maturation Increases Atp Content And Enhances Subsequent Embryonic Development, Kendall Richey

All Theses

Bovine in-vitro production(IVP) of embryos is a growing field for producing offspring with desirable genetics in the cattle industries. While IVP is effective, oocyte cytoplasmic maturation is compromised, and bovine oocytes matured in-vitro have reduced metabolic activity than those matured in-vivo. Mitochondria are the central unit of oocyte metabolism, producing ATP through OXPHOS. Photobiomodulation is a light treatment reported to improve metabolic activity. In five experiments, we measured the effects of photobiomodulation treatment with red LED at 16-(L-16) and 20 h(L-20) of bovine oocyte in-vitro maturation on subsequent embryonic development, mitochondrial activity and nuclear progression. Bovine COCs were aspirated …


Oscillations Of Capillary Surfaces With Volume And Edge Effects, Dingqian Ding May 2024

Oscillations Of Capillary Surfaces With Volume And Edge Effects, Dingqian Ding

All Dissertations

Capillary surfaces are defined by an interface endowed with surface tension that is partially supported by a solid substrate and are susceptible to oscillations reflecting a balance between fluid inertia and the restorative force of surface tension. The wave dynamics strongly depend upon volume change within the domain and edge effects through the boundary conditions applied at the contact-line formed at the liquid-gas-solid interface, while the spatial wave structure conforms to the geometry of the capillary surface. This dissertation develops mathematical models to address these effects for several canonical capillary surfaces, which are organized into two parts that are focused …


Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei May 2024

Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei

All Dissertations

In an era of intensified market competition, the demand for cost-effective, high-quality, high-performance, and reliable products continues to rise. Meeting this demand necessitates the mass production of premium products through the integration of cutting-edge technologies and advanced materials while ensuring their integrity and safety. In this context, Nondestructive Testing (NDT) techniques emerge as indispensable tools for guaranteeing the integrity, reliability, and safety of products across diverse industries.

Various NDT techniques, including ultrasonic testing, computed tomography, thermography, and acoustic emissions, have long served as cornerstones for inspecting materials and structures. Among these, ultrasonic testing stands out as the most prevalent method, …


Experimental Analyses Of Emission Lines In The Uv/Vis/Nir Range For Astrophysically-Important Elements: From The Iron Group To R-Process Elements, Brynna Neff May 2024

Experimental Analyses Of Emission Lines In The Uv/Vis/Nir Range For Astrophysically-Important Elements: From The Iron Group To R-Process Elements, Brynna Neff

All Dissertations

Analysis of astrophysical phenomena requires an understanding of the electronic

structure and transition probabilities of the elements present in that environment,

yet there are still many charge states of heavy elements whose electronic

structures and spectroscopic properties are not yet well understood. To address this,

we investigated the spectroscopic properties of three different elements through an

analysis of spectra collected from three different experimental apparatuses.

In order to better understand the spectroscopic properties of Ni I and II, we

analyzed spectra collected from the Compact Toroidal Hybrid (CTH) apparatus at

Auburn University. In this experiment, a nickel sample was inserted …


Study Of Morphology, Structure, And Magnetic Properties Of High Entropy Alloy Systems, Matthew G. Guerrero May 2024

Study Of Morphology, Structure, And Magnetic Properties Of High Entropy Alloy Systems, Matthew G. Guerrero

Open Access Theses & Dissertations

Abstract:This thesis presents an investigation into the magnetic properties of high entropy alloy (HEA) samples, focusing primarily on compositions within the FeNiCoMn system and their gallium/chemically doped derivatives. High entropy alloys represent a promising class of materials with unique properties resulting from their complex composition and structural arrangements. The behavior of these alloys, particularly in their magnetic properties, remains an area of significant interest due to their potential applications in magnetic storage, sensing, and other technological domains. The study encompasses an examination of seven distinct HEA samples: FeNiCo, FeNiCoMn0.2, FeNiCoMn0.4, FeNiCoMn0.6, FeNiCoMn0.2Ga0.1, FeNiCoGa0.2, FeNiCoMn0.2Ga0.3. Furthermore, three samples of FeNiCoMn0.2 and …


Manipulation Of The Magnetic Properties Of Van Der Waals Materials Through External Stimuli, Luis Martinez May 2024

Manipulation Of The Magnetic Properties Of Van Der Waals Materials Through External Stimuli, Luis Martinez

Open Access Theses & Dissertations

A new revolutionary application dependent on the electron spin to carry information with greater efficiency in data storage, transfer, and processing, will rely heavily on 2D magnets and the ability to effectively control their electron spins and engineer their properties. Previously, magnetic thin films were heavily studied to achieve this goal, however, these materials came with pitfalls and lacked naturally occurring 2D magnetism. The recent discovery of intrinsic magnetism in few-layered van der Waals (vdW) magnets has inspired researchers to extensively study them because of the feasibility to exfoliate them down to a monolayer. Due to this dimensionality factor, vdW …


Particle Classification Of Electromagnetic Clusters Using The Sphenix Detector, Fredrick J. Melhorn May 2024

Particle Classification Of Electromagnetic Clusters Using The Sphenix Detector, Fredrick J. Melhorn

Chancellor’s Honors Program Projects

No abstract provided.


Exploring The Coronal Magnetic Field With Galactic Cosmic Rays: The Sun Shadow Observed By Hawc, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, K. P. Arunbabu, D. Avila Rojas, R. Babu, Et Al. May 2024

Exploring The Coronal Magnetic Field With Galactic Cosmic Rays: The Sun Shadow Observed By Hawc, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, K. P. Arunbabu, D. Avila Rojas, R. Babu, Et Al.

Michigan Tech Publications, Part 2

Galactic cosmic rays (GCRs) are charged particles that reach the heliosphere almost isotropically in a wide energy range. In the inner heliosphere, the GCR flux is modulated by solar activity so that only energetic GCRs reach the lower layers of the solar atmosphere. In this work, we propose that high-energy GCRs can be used to explore the solar magnetic fields at low coronal altitudes. We used GCR data collected by the High-Altitude Water Cherenkov observatory to construct maps of GCR flux coming from the Sun’s sky direction and studied the observed GCR deficit, known as Sun shadow (SS), over a …


An Evaluation Of Spectroscopic Databases: Content, Structure, Toolsets, Usability, And Documentation, Joseph William Braker May 2024

An Evaluation Of Spectroscopic Databases: Content, Structure, Toolsets, Usability, And Documentation, Joseph William Braker

Masters Theses

Spectroscopic databases provide a critical service in the greater field of spectroscopy. Many subdisciplines of spectroscopists use the data contained within, whether calculating theoretical models, evaluating the atmosphere of a planet in the furthest reaches of the galaxy, or monitoring the emission levels of a chemical process. The intention of this research is to seek a deeper level of understanding of spectroscopy and the resources available while providing a comparison of the databases, the content within, and their peripheral tools and features. An experimental effort was derived to utilize existing experimental data from multiple sources and determine which data source …


Geomagnetic Substorms Prediction Model Using Combined Physics-Based And Deep Learning Modeling Techniques, Ruthba Yasmin May 2024

Geomagnetic Substorms Prediction Model Using Combined Physics-Based And Deep Learning Modeling Techniques, Ruthba Yasmin

<strong> Theses and Dissertations </strong>

This thesis aims to develop a hybrid physics-incorporated neural network model (PINN) for classifying geomangnetic substorms in Earth's Magnetosphere. The model is trained using a comprehensive list of substorm onsets, ground magentometer data from a global network, and solar wind parameters from the Advanced Composition Explorer (ACE) satellite. Two different neural network architectures are used, and the physics model used for training is called WINDMI. The magnetic field components on the ground, which are a function of the ionospheric currents, are captured by the SML index. The methodology involves using 60-minute data segments preceding an event to train the hybrid …


Jet Production And Rppb In Pp Collisions At Sqrt(S) = 8 Tev And P--Pb Collisions At Sqrt(Snn) = 8.16 Tev Using The Alice Detector, Austin Schmier May 2024

Jet Production And Rppb In Pp Collisions At Sqrt(S) = 8 Tev And P--Pb Collisions At Sqrt(Snn) = 8.16 Tev Using The Alice Detector, Austin Schmier

Doctoral Dissertations

At the CERN Large Hadron Collider, protons and heavy ions are collided at relativistic
speeds in order to study the behavior and processes of Quantum Chromodynamics (QCD). One such process is the production of collimated sprays of particles called jets resulting from the hard scattering of two partons. Jets are an important probe that provide a window into the early stages of the collision.

Measurements in small systems such as proton-proton (pp) and proton-lead (p–Pb)
collisions are important in order to provide constraints on nuclear parton distribution
functions and the strong coupling constant αS [55]. Measurements at different center of …


Towards Continuous Variable Quantum Computation Of Lattice Gauge Theories, Shane Nicklaus Thompson May 2024

Towards Continuous Variable Quantum Computation Of Lattice Gauge Theories, Shane Nicklaus Thompson

Doctoral Dissertations

The calculation of physical quantities in a relativistic quantum field theory (rQFT) is a computationally demanding task due to the presence of an infinite number of degrees of freedom. This problem carries over to discretized versions of these theories, i.e. lattice field theories, where the Hilbert space size increases exponentially with the size of the lattice. Despite the success of some classical techniques such as Monte Carlo, their applicability is limited. For instance, Monte Carlo is associated with a sign problem that makes real-time evolution and high-fermion-density systems particularly challenging to compute. Quantum computation is a promising avenue thanks to …


Understanding The Impact Of Divertor And Main Chamber Ion Fluxes On Divertor Closure In The Diii-D Tokamak, Kirtan M. Davda May 2024

Understanding The Impact Of Divertor And Main Chamber Ion Fluxes On Divertor Closure In The Diii-D Tokamak, Kirtan M. Davda

Doctoral Dissertations

The diverted tokamak redirects extreme heat and particles to targets, a plasma-facing component designed for such loads. Here, the local fluxes produce strong particle recycling and sputtering. Recycled neutrals can “leak” into the region between the core and wall, the scrape-off-layer (SOL), impacting plasma performance. Increasing divertor closure can reduce leakage by containing neutrals within the divertor. However, there exists a need to quantify divertor baffle restrictions and understand closure directly from empirical data as opposed to indirectly through modeling.

Our study introduces the Geometric Restriction Parameter (GRP) based on simplifying neutral transport to ballistic pathways. Specifically, it considers the …


Novel Energy Scale Calibration Strategies For The Prospect-Ii Experiment, Xiaobin Lu May 2024

Novel Energy Scale Calibration Strategies For The Prospect-Ii Experiment, Xiaobin Lu

Doctoral Dissertations

Nuclear reactors contributed to the first discovery of the elusive neutrino particle and continue to play a significant role in our understanding of neutrino masses and oscillations. The PROSPECT reactor neutrino experiment, the Precision Reactor Oscillation and SPECTrum Experiment, took data at the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory. This work discusses calibration procedures and the establishment of an energy scale model, and details the development of efficient analysis cuts and subsequent selection cut optimization. The precise energy scale calibration and efficient analysis cuts produced a high quality dataset of neutrino interactions of more than 50,000 …


Experimental Quantum Key Distribution In Turbulent Channels, Kazi Mh Reaz May 2024

Experimental Quantum Key Distribution In Turbulent Channels, Kazi Mh Reaz

Doctoral Dissertations

Quantum Key Distribution (QKD) ensures security by relying on the laws of quantum physics rather than the mathematical intricacy of encryption algorithms. The transmission medium is a critical restricting factor for any quantum communication protocol. Fiber-based optical networks suffer great losses, making quantum communication impossible beyond metropolitan scales. Here free-space quantum communication can be a great alternative for long-distance communication. Even though modern Communications are mostly wireless the atmosphere poses a challenge for QKD. So QKD must be resistant to both atmospheric loss and variations in transmittance. In this thesis we conduct an experiment to strengthen the BB84 protocol's resistance …


Better Light Than Never: A New Radiative Mechanism For Observing Binary Black Holes, Paul Rioles May 2024

Better Light Than Never: A New Radiative Mechanism For Observing Binary Black Holes, Paul Rioles

Graduate Masters Theses

Black holes are notoriously elusive, they are impossible to observe directly, and cur- rent methods of extracting information from behind their cosmic camouflage are both limited in number and experimentally difficult. The scope of this investigation is to ex- plore a proposed novel radiative mechanism for active similar mass binary black holes, affording new observational methods to investigate frequency inspirals of BH mergers. The explored mechanism is a result of each BH’s accretion of the surrounding plasma, creating voids that orbit throughout the plasma. The significant results described in this thesis include expressions for the frequency, power radiated per unit …


Dimensional Regularization And Two-Loop Vacuum Polarization Operator: Master Integrals, Analytic Results, And Energy Shifts, Stefano Laporta, Ulrich D. Jentschura May 2024

Dimensional Regularization And Two-Loop Vacuum Polarization Operator: Master Integrals, Analytic Results, And Energy Shifts, Stefano Laporta, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

We Present a Complete Reevaluation of the Irreducible Two-Loop Vacuum-Polarization Correction to the Photon Propagator in Quantum Electrodynamics, i.e. with an Electron-Positron Pair in the Fermion Propagators. the Integration is Carried Out by Reducing the Integrations to a Limited Set of Master Integrals, Which Are Calculated using Integration-By-Parts Identities. Dimensional Regularization is Used in D=4-2ϵ Dimensions, and On-Mass Shell Renormalization is Employed. the One-Loop Effect is Given to Order ϵ, to Be Combined with the 1/ϵ Divergence of the Two-Loop Amplitude. Master Integrals Are Given. Final Evaluations of Two-Loop Energy Shifts for 1S, 2S, and 2P States Are Done Analytically, …


Crystallographic Defects In Weyl Semimetal Laalge, Inseo Kim, Byungkyun Kang, Hyunsoo Kim, Minseok Choi May 2024

Crystallographic Defects In Weyl Semimetal Laalge, Inseo Kim, Byungkyun Kang, Hyunsoo Kim, Minseok Choi

Physics Faculty Research & Creative Works

Crystallographic Defects in a Topological Semimetal Can Result in Charge Doping and Scattering Centers Which May Mask the Exotic Spectroscopic and Transport Properties, respectively. Here, We Investigate the Possible Crystallographic Defects Including Vacancy and Antisite in Weyl Semimetal LaAlGe using Hybrid-Density-Functional Theory Calculations. We Show that a Considerable Concentration of Al- and Ge-Related Defects Naturally Form during Growth Due to their Low Formation Enthalpy. Specifically, Al Can Be Easily Replaced by Ge in the I41md Phase of LaAlGe, Forming the Ge-On-Al Antisite, GeAl. the Counterpart, Al-On-Ge (AlGe), is Also Probable. the Most Abundant Defect GeAl is Donorlike, Effectively Electron Doping, …


Scalar Susceptibility Of A Diluted Classical Xy Model, Reece Beattie-Hauser, Thomas Vojta May 2024

Scalar Susceptibility Of A Diluted Classical Xy Model, Reece Beattie-Hauser, Thomas Vojta

Physics Faculty Research & Creative Works

We Analyze the Amplitude Fluctuations in a Diluted 3D Classical XY Model Near the Magnetic Phase Transition, motivated by the Unusual Localization Properties of the Amplitude (Higgs) Mode Recently Found at the Disordered Superfluid-Mott Glass Quantum Phase Transition. We Calculate the Amplitude Correlation Function and the Corresponding Scalar Susceptibility by Means of Monte Carlo Simulations. in Contrast to the Quantum Case, in Which the Scalar Susceptibility Was Found to Violate Naive Scaling, We Find that the Scalar Susceptibility of the Classical System Fulfills Naive Scaling (Employing the Clean Critical Exponents, as Expected from the Harris Criterion) as the Temperature is …


Divergence-Free Tensor Densities In Two Dimensions, Tyler Hansen May 2024

Divergence-Free Tensor Densities In Two Dimensions, Tyler Hansen

All Graduate Theses and Dissertations, Fall 2023 to Present

In physics, a common method for exploring the way a physical system changes over time is to look at the system’s energy. Roughly speaking, the energy in these systems are either motion-based (kinetic energy, a bullet in flight) or position-based (potential energy, a rock sitting at the top of a hill). The difference between the system’s total kinetic and potential energies is quantified by an expression called the Lagrangian. Using a special procedure, this Lagrangian is massaged to produce a group of equations called the Euler-Lagrange equations; if the initial configuration of the system is provided, the solution to these …


Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma May 2024

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …


Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh May 2024

Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh

Electronic Theses and Dissertations

This research documents steps towards building a novel spectroscopic technique, namely, cavity-enhanced double-resonance (CEDR) spectroscopy, for investigating methane (CH4) and other molecules with significance in astrochemistry. These efforts focus on tackling the complexities of their ro-vibrational energy levels and the inefficiencies in analyzing vibrational spectra, particularly for molecules with high symmetry and strong intramolecular interactions. In the CEDR spectroscopy, the first photon, generated by a continuous-wave optical parametric oscillator (CW-OPO) locked to a Doppler-free saturation absorption line, excites the molecule from its ground level to a selected excited ro-vibrational (rotational-vibrational) level, e.g., that of the asymmetric CH-stretch mode. …


Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat May 2024

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …


A Comparative Analysis Of Field Electron Emission From Carbon Black Embedded Within Insulated Copper Hollowed Wires And Glass Tubes, Hatem A. Al-Braikat, Ahmad M D Jaber, Adel M. Abuamr, Mazen A. Madanat, Aseel A. Al-Jbarart, M-Ali H. Al-Akhras, Marwan S. Mousa Apr 2024

A Comparative Analysis Of Field Electron Emission From Carbon Black Embedded Within Insulated Copper Hollowed Wires And Glass Tubes, Hatem A. Al-Braikat, Ahmad M D Jaber, Adel M. Abuamr, Mazen A. Madanat, Aseel A. Al-Jbarart, M-Ali H. Al-Akhras, Marwan S. Mousa

Karbala International Journal of Modern Science

In this study, two different methods are used to investigate carbon black as a cold field electron emitter. The first method is to incorporate carbon black into a specially designed insulated copper hollowed wire. The wire has a cup-shaped structure created by electrochemical etching. The second method involves the incorporation of carbon black into narrow glass tubes. A Comparative analyses is carried out to evaluate the effectiveness of each method. To evaluate the performance of the samples, the current-voltage characteristics will be examined using field electron microscopes. This analysis will provide an understanding of the emission of the carbon black …


Classification Of Topological Defects In Cosmological Models, Abigail Swanson Apr 2024

Classification Of Topological Defects In Cosmological Models, Abigail Swanson

Student Research Submissions

In nature, symmetries play an extremely significant role. Understanding the symmetries of a system can tell us important information and help us make predictions. However, these symmetries can break and form a new type of symmetry in the system. Most notably, this occurs when the system goes through a phase transition. Sometimes, a symmetry can break and produce a tear, known as a topological defect, in the system. These defects cannot be removed through a continuous transformation and can have major consequences on the system as a whole. It is helpful to know what type of defect is produced when …


Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang Apr 2024

Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang

Karbala International Journal of Modern Science

Biaxial-oriented polypropylene (BOPP) films are characterized by unfavorable aging behavior because of their poor susceptibility to high temperatures, humidity, and high electric fields. This makes them unqualified to withstand harsh operating conditions, such as in capacitor applications. This study investigates the impact of annealing BOPP samples at 100 °C for five hours after fluorination at different times (15, 30, and 60 minutes) on their electrical and mechanical performance under electro-thermal stresses. Scanning electron microscope (SEM) images confirm that there is an increase in surface roughness and the formation of a dense layer of fluorine-containing groups monotonically with fluorination time. So, …


Simulating Ice Particle Properties Under Varying Electric Fields, Joseph Cooney Apr 2024

Simulating Ice Particle Properties Under Varying Electric Fields, Joseph Cooney

Physics Capstone Projects

In this study, the interactions between atmospheric water molecules and an electrically charged dust particle were simulated in python to determine the role of electric charge and electric fields in atmospheric ice formation. Multiple levels of electric charge were tested, corresponding to different strengths of atmospheric electric fields. The TIP4P-2005 model for water was used to simulate these molecules under the influence of a central electric potential to represent the charged dust particle. These included a control group with no electric field (0 C), a group under a fair-weather strength of electric field (1.6*10-14 C), a foul-weather electric field (1.6*10-12 …


Piezochromic Behavior Of 2,4,6-Triphenylpyrylium Tetrachloroferrate, Princess Canasa, David King, Petrika Cifligu, Adrian F. Lua Sanchez, Si L. Chen, Haesook Han, Trimaan Malik, Brant Billinghurst, Jianbao Zhao, Changyong Park, George R. Rossman, Michael Pravica, Pradip K. Bhowmik, Egor Evlyukhin Apr 2024

Piezochromic Behavior Of 2,4,6-Triphenylpyrylium Tetrachloroferrate, Princess Canasa, David King, Petrika Cifligu, Adrian F. Lua Sanchez, Si L. Chen, Haesook Han, Trimaan Malik, Brant Billinghurst, Jianbao Zhao, Changyong Park, George R. Rossman, Michael Pravica, Pradip K. Bhowmik, Egor Evlyukhin

Chemistry and Biochemistry Faculty Research

In advanced photonics, there is a growing interest in piezochromic luminescent materials that exhibit multicolor switching, driven by their potential applications in optical recording, memory, and sensors. Here, the piezochromic behavior of 2,4,6-triphenylpyrylium tetrachloroferrate (Py-FeCl4) under high pressures from 0 to 9 GPa is reported. The observed multicolor changing properties of Py-FeCl4 (yellow–orange–red–maroon–black) are found to be fully reversible upon decompression to ambient conditions. The mechanism of Py-FeCl4 piezochromism is investigated via Raman, infrared, and UV–vis spectroscopy combined with powder X-ray Diffraction. The absence of structural phase transitions as well as the abrupt shifts of bandgap …