Physics Commons^™

Correct Spectral Conversion Between Surface‐Enhanced Raman And Plasmon Resonance Scattering From Nanoparticle Dimers For Single‐Molecule Detection, Kyuwan Lee

Kyuwan Lee

Simultaneous measurement of surface-enhanced Raman scattering (SERS) and localized surface plasmon resonance (LSPR) in nanoparticle dimers presents outstanding opportunities in molecular identification and in the elucidation of physical properties, such as the size, distance, and deformation of target species. SERS–LSPR instrumentation exists and has been used under limited conditions, but the extraction of SERS and LSPR readouts from a single measurement is still a challenge. Herein, the extraction of LSPR spectra from SERS signals is reported and a tool for measuring the interparticle distance from Raman enhancement data by the standardization of the SERS signal is proposed. The SERS nanoruler …

Testing Diagnostics Of Nuclear Activity And Star Formation In Galaxies At Z > 1, Jonathan R. Trump, Nicholas P. Konidaris, Guillermo Barro, David C. Koo, Dale D. Kocevski, Stéphanie Juneau, Benjamin J. Weiner, S. M. Faber, Ian S. Mclean, Renbin Yan, Pablo G. Pérez-González, Victor Villar

Physics and Astronomy Faculty Publications

We present some of the first science data with the new Keck/MOSFIRE instrument to test the effectiveness of different AGN/SF diagnostics at z ~ 1.5. MOSFIRE spectra were obtained in three H-band multi-slit masks in the GOODS-S field, resulting in 2 hr exposures of 36 emission-line galaxies. We compare X-ray data with the traditional emission-line ratio diagnostics and the alternative mass-excitation and color-excitation diagrams, combining new MOSFIRE infrared data with previous HST/WFC3 infrared spectra (from the 3D-HST survey) and multiwavelength photometry. We demonstrate that a high [O III]/Hβ ratio is insufficient as an active galactic nucleus (AGN) indicator …

The Central Molecular Gas Structure In Liners With Low-Luminosity Active Galactic Nuclei: Evidence For Gradual Disappearance Of The Torus, F. Müller-Sánchez, M. A. Prieto, M. Mezcua, R. I. Davies, M. A. Malkan, Moshe Elitzur

Physics and Astronomy Faculty Publications

We present observations of the molecular gas in the nuclear environment of three prototypical low-luminosity active galactic nuclei (LLAGNs), based on VLT/SINFONI AO-assisted integral-field spectroscopy of H₂ 1-0 S(1) emission at angular resolutions of ~0.''17. On scales of 50-150 pc, the spatial distribution and kinematics of the molecular gas are consistent with a rotating thin disk, where the ratio of rotation (V) to dispersion (σ) exceeds unity. However, in the central 50 pc, the observations reveal a geometrically and optically thick structure of molecular gas (V/σ < 1 and N _H > 10²³ cm^{–2 …}

Transforming Fabry-Pérot Resonances Into A Tamm Mode, Maxim Durach, Anastasia Rusina

Department of Physics and Astronomy Faculty Publications

We propose an optical structure composed of two metal nanolayers enclosing a distributed Bragg reflector (DBR) mirror. The structure is an open photonic system whose bound modes are coupled to external radiation. We apply the special theoretical treatment based on inversion symmetry of the structure to classify its resonances. We show that the structure supports resonances transitional between Fabry-Pérot modes and Tamm plasmons. When the dielectric contrast of the DBR is removed these modes are a pair of conventional Fabry-Pérot resonances. They spectrally merge into a Tamm mode at high contrast. The optical properties of the structure in the frequency …

Petawatt-Laser-Driven Wakefield Acceleration Of Electrons To 2 Gev In 10^{17} Cm^{-3} Plasma, Xiaoming Wang, Rafal B. Zgadzaj, Neil Fazel, Sunghwan A. Yi, X. Zhang, Watson Henderson, Yen-Yu Zhang, Rick Korzekwa, Hai-En Tsai, C.-H. Pai, Zhengyan Li, Hernan Quevedo, Gilliss Dyer, Erhard W. Gaul, Mikael Martinez, Aaron Bernstein, Ted Borger, M. Spinks, M. Donovan, Serguei Y. Kalmykov, Vladimir N. Khudik, Gennady Shvets, Todd Ditmire, Michael C. Downer

Serge Youri Kalmykov

Electron self-injection into a laser-plasma accelerator (LPA) driven by the Texas Petawatt (TPW) laser is reported at plasma densities 1.7 - 6.2 x 10^{17} cm^{-3}. Energy and charge of the electron beam, ranging from 0.5 GeV to 2 GeV and tens to hundreds of pC, respectively, depended strongly on laser beam quality and plasma density. Angular beam divergence was consistently around 0.5 mrad (FWHM), while shot-to-shot pointing fluctuations were limited to ±1.4 mrad rms. Betatron x-rays with tens of keV photon energy are also clearly observed.

Sub-Millimeter-Scale, 100-Mev-Class Quasi-Monoenergetic Laser Plasma Accelerator Based On All-Optical Control Of Dark Current In The Blowout Regime, Serguei Y. Kalmykov, Xavier Davoine, Bradley A. Shadwick

Serge Youri Kalmykov

It is demonstrated that by negatively chirping the frequency of a 20-fs, 15-TW driving laser pulse with an ultrabroad bandwidth (corresponding to a sub-2-cycle transform-limited duration it is possible to prevent early compression of the pulse into an optical shock, thus reducing expansion of the accelerating plasma bucket (electron density "bubble") and delaying dephasing of self-injected and accelerated electrons. These features help suppress unwanted continuous self-injection (dark current) in the blowout regime, making possible to use the entire dephasing length to generate low-background, quasi-monoenergetic 200-MeV-scale electron beams from sub-mm-length, dense plasmas (n_{e0} = 1.3 x 10^{19} cm^{−3}).

One-Phase Problems For Discontinuous Heat Transfer In Fractal Media, Yang Xiaojun

Xiao-Jun Yang

We first propose the fractal models for the one-phase problems of discontinuous transient heat transfer.The models are taken in sense of local fractional differential operator and used to describe the (dimensionless)melting of fractal solid semi-infinite materials initially at their melt temperatures.

Measures Of Centrality Based On The Spectrum Of The Laplacian, Scott D. Pauls, Daniel Remondini

Dartmouth Scholarship

We introduce a family of new centralities, the k-spectral centralities. k-Spectral centrality is a measurement of importance with respect to the deformation of the graph Laplacian associated with the graph. Due to this connection, k-spectral centralities have various interpretations in terms of spectrally determined information.

We explore this centrality in the context of several examples. While for sparse unweighted net- works 1-spectral centrality behaves similarly to other standard centralities, for dense weighted net- works they show different properties. In summary, the k-spectral centralities provide a novel and useful measurement of relevance (for single network elements as well as whole subnetworks) …

Passive Ranging Using A Dispersive Spectrometer And Optical Filters, Jacob A. Martin

Theses and Dissertations

Monocular passive ranging using atmospheric oxygen absorption has been demonstrated in the past using an FTS. These instruments are very sensitive to vibration making them di cult to use on an airborne platform. This work focuses on whether passive ranging can be done with instruments that are easier to deploy. Two potential instruments are tested and compared: a diffraction grating spectrometer and optical filters. A grating spectrometer was able to estimate range to within 5% for a static solid rocket motor ring at a distance of 910 m using the NIR absorption band of oxygen. Testing at shorter ranges produced …

Oscillator Strength Measurements Of The 5s6s 1s0→5snp 1p1 Rydberg Transitions Of Strontium, S. U. Haq, M. A. Kalyar, M. Rafiq, R. Ali, Naveed K. Piracha, M. A. Baig

Naveed K. Piracha

We report the experimentally determined oscillator strengths for the 5s6s 1S0→5snp 1P1 Rydberg transitions of strontium using two-step excitation in conjunction with a thermionic diode ion detector. The absolute photoionization cross section from the 5s6s 1S0 excited state has been determined by adjusting the polarization vector of the ionizing laser beam parallel, perpendicular, and at the magic angle with respect to that of the exciting dye laser. The measured absolute value of the photoionization cross section 0.9±0.2 Mb at the 5s threshold is used to extract the f values of the 5s6s 1S0→5snp 1P1 (26≤n≤73) Rydberg transitions. The oscillator strength …

Interferometric Synthetic Aperture Sonar Signal Processing For Autonomous Underwater Vehicles Operating Shallow Water, Patricia E. Giardina

University of New Orleans Theses and Dissertations

The goal of the research was to develop best practices for image signal processing method for InSAS systems for bathymetric height determination. Improvements over existing techniques comes from the fusion of Chirp-Scaling a phase preserving beamforming techniques to form a SAS image, an interferometric Vernier method to unwrap the phase; and confirming the direction of arrival with the MUltiple SIgnal Channel (MUSIC) estimation technique. The fusion of Chirp-Scaling, Vernier, and MUSIC lead to the stability in the bathymetric height measurement, and improvements in resolution. This method is computationally faster, and used less memory then existing techniques.

Toward High-Performance Nanostructured Thermoelectric Materials: The Progress Of Bottom-Up Solution Chemistry Approaches, Yixin Zhao, Jeffrey S. Dyck, Clemens Burda

Jeffrey Dyck

Significant research effort has recently gone into the synthesis of thermoelectric nanomaterials through different chemical approaches since nanomaterials chemistry became a promising strategy for improving thermoelectric performance. Different thermoelectric nanocrystals, especially PbTe, Bi2Te3 and CoSb3, with various compositions and morphologies have been successfully prepared by solvo/hydrothermal, electrochemical, and ligand-based synthesis methods. Such nanoscale materials show not only substantial reduction in thermal conductivity due to increased phonon scattering at nanoscale grain boundaries and lower densities of phonon states but possibly also an enhancement in thermopower due to electronic quantum size effects. More recently, the notoriously low power factors of thermoelectric nanomaterials …

Structure Inhomogeneities, Shallow Defects, And Charge Transport In The Series Of Thermoelectric Materials K2bi8−Xsbxse13, Jeffrey S. Dyck, T. Kyratski, E. Hatzikraniotis, K. M. Paraskevopoulos, C. D. Malliakas, C. Uher, M. G. Kanatzidis

Jeffrey Dyck

The charge transport properties of the low-dimensional thermoelectric materials K2Bi8-xSbxSe13 (02Bi8-xSbxSe13 was analyzed on the basis of the classical semiconductor theory and discussed in the context of recent band calculations. The results suggest that the K2Bi8-xSbxSe13 materials possess coexisting domains with semimetallic and semiconducting characters whose ratio is influenced by the value of x and by local defects. The extent and relative distribution of these domains control the charge transport properties. Electron diffraction experiments performed on samples of K2Bi8-xSbxSe13 with x=1.6 show evidence for such domains by indicating regions with long range ordering of K+/Bi3+ atoms and regions with increased …

Epr And Endor Studies Of Point Defects In Lithium Tetraborate Crystals, Douglas A. Buchanan

Theses and Dissertations

Lithium tetraborate (Li2B4O7 or LTB) is a promising material for both radiation dosimetry and neutron detection applications. LTB crystals can be grown pure or doped with different impurities including transition-metal and rare-earth ions. Research in this dissertation focuses on undoped LTB crystals and LTB crystals doped with copper and silver. Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to characterize point defects in the lithium tetraborate crystals. Thermoluminescence (TL), photoluminescence (PL), photoluminescence excitation (PLE), and optical absorption (OA) are also used. An intrinsic hole trap associated with lithium vacancies is characterized with EPR and ENDOR and its …

Fast Absolute Quantification Of In Vivo Water And Fat Content With Magnetic Resonance Imaging, Yifan Cui

Electronic Thesis and Dissertation Repository

Quantitative water fat imaging offers a non-invasive method for monitoring and staging diseases associated with changes in either water or fat content in tissue. In this work absolute water and fat mass density measurement with in vivo Magnetic Resonance Imaging (MRI) is demonstrated. T₁ independent, T₂^* corrected chemical shift based water-fat separated images are acquired. By placing a phantom with known mass density in the field of view for signal intensity calibration, absolute water or fat mass density can be computed, assuming the B₁⁺ (transmit) and B₁^- (receive) fields can be measured. Phantom …

Data Curation Is For Everyone! The Case For Master's And Baccalaureate Institutional Engagement With Data Curation, Yasmeen Shorish

Yasmeen Shorish

This article describes the fundamental challenges to data curation, how these challenges may be compounded for smaller institutions, and how data management is an essential and manageable component of data curation. Data curation is often discussed within the confines of large, research universities. As a result, master’s and baccalaureate institutions may be left with the impression that they cannot engage with data curation. However, by proactively engaging with faculty, libraries of all sizes can build closer relationships and help educate faculty on data documentation and organization best practices. Experiences from one master’s comprehensive institution as it engages with data management …

The Shape And Mechanics Of Curved Fold Origami Structures, Marcelo A. Dias, Christian Santangelo

Christian Santangelo

We develop recursion equations to describe the three-dimensional shape of a sheet upon which a series of concentric curved folds have been inscribed. In the case of no stretching outside the fold, the three-dimensional shape of a single fold prescribes the shape of the entire origami structure. To better explore these structures, we derive continuum equations, valid in the limit of vanishing spacing between folds, to describe the smooth surface intersecting all the mountain folds. We find that this surface has negative Gaussian curvature with magnitude equal to the square of the fold's torsion. A series of open folds with …

A Comparison Of Short-Range Molecular Order In Bent-Core And Rod-Like Nematic Liquid Crystals, S. Chakraborty, J. T. Gleeson, Antal Jákli, Samuel Sprunt

Antal Jakli

Thermotropic liquid crystals exhibit strongly temperature-dependent positional correlations among molecules in the nematic phase above the transition to a smectic-A or C phase. However, even in the absence of a lower temperature smectic phase, nematics composed of reduced symmetry molecules (bent-core mesogens, for example) reveal small angle X-ray scattering (SAXS) patterns with features similar to those associated with pretransitional smectic order. We report on a quantitative analysis and comparison of two-dimensional SAXS data on a bent-core nematic compound (lacking a smectic phase) and a rod-like nematic (exhibiting a nematic to smectic-C transition). This analysis demonstrates that a nanostructure based on …

Investigation Of Low-Stress Silicon Nitride As A Replacement Material For Beryllium X-Ray Windows, David B. Brough

Theses and Dissertations

The material properties of low stress silicon nitride make it a possible replacement material for beryllium in X-ray windows. In this study, X-ray windows made of LPCVD deposited low stress silicon nitride are fabricated and characterized. The Young's modulus of the LPCVD low stress silicon nitride are characterized and found to be 226±23 GPa. The residual stress is characterized using two different methods and is found to be 127±25 MPa and 141±0.28 MPa. Two support structure geometries for the low stress silicon nitride X-ray windows are used. X-ray windows with thicknesses of 100 nm and 200 nm are suspended on …

Synthesis And Characterization Of Copper Nanoparticles And Copper-Polymer Nanocomposites For Plasmonic Photovoltaic Applications, Sabastine Chukwuemeka Ezugwu

Electronic Thesis and Dissertation Repository

Deposition techniques for the fabrication of metal nanostructures influence their morphological properties, which in turn control their optical behavior. Here, copper nanoparticles (np-Cu’s) were grown using a deposition system that was specifically set up during this work, and is based on a radio frequency (RF) sputtering source that can operate at high temperature and under bias voltage. The effect of deposition conditions (RF power, chamber pressure and substrate bias voltage) on RF sputtered np-Cu’s using RF sputtering has been studied. The study included a comparison between the morphological and optical properties of as-grown np-Cu’s and thermally treated samples. The characterization …

Multi-Sensor Calibration And Validation Of The Uwo-Pcl Water Vapour Lidar, Robin Wing

Electronic Thesis and Dissertation Repository

The Purple Crow Lidar (PCL) has recently participated in a water vapour validation cam- paign with the NASA/GSFC Atmospheric Laboratory for Validation/Interagency Collaboration and Education (ALVICE) Lidar. The purpose of this calibration campaign is to insure that PCL water vapour measurements are of sufficient quality for use in scientific investigations of atmo- spheric change, and to be included in the Network for the Detection of Atmospheric Climate Change (NDACC) data base. The detection of long term changes in water vapour concentra- tion, particularly in the upper troposphere and lower stratosphere (UTLS) is an issue of pressing scientific, ecological and societal …

Ferroelectric Instability Under Screened Coulomb Interactions, Yong Wang, Xiaohui Liu, John D. Burton, Sitaram S. Jaswal, Evgeny Y. Tsymbal

Evgeny Tsymbal Publications

We explore the effect of charge carrier doping on ferroelectricity using density functional calculations and phenomenological modeling. By considering a prototypical ferroelectric material, BaTiO₃, we demonstrate that ferroelectric displacements are sustained up to the critical concentration of 0.11 electron per unit cell volume. This result is consistent with experimental observations and reveals that the ferroelectric phase and conductivity can coexist. Our investigations show that the ferroelectric instability requires only a short-range portion of the Coulomb force with an interaction range of the order of the lattice constant. These results provide a new insight into the origin of ferroelectricity …

Thin Films Of Carbon Nanotubes And Nanotube/Polymer Composites, Anthony D. Willey

Theses and Dissertations

A method is described for ultrasonically spraying thin films of carbon nanotubes that have been suspended in organic solvents. Nanotubes were sonicated in N-Methyl-2-pyrrolidone or N-Cyclohexyl-2-pyrrolidone and then sprayed onto a heated substrate using an ultrasonic spray nozzle. The solvent quickly evaporated, leaving a thin film of randomly oriented nanotubes. Film thickness was controlled by the spray time and ranged between 200-500 nm, with RMS roughness of about 40 nm. Also described is a method for creating thin (300 nm) conductive freestanding nanotube/polymer composite films by infiltrating sprayed nanotube films with polyimide.

Simultaneous Radar And Video Meteors, Robert J. Weryk

Electronic Thesis and Dissertation Repository

The goal of this thesis is to better understand the physical and chemical properties of meteoroids by using simultaneous radar and video observations of meteors. The Canadian Meteor Orbit Radar (CMOR) and several Gen-III image-intensified CCD cameras were used to measure common meteors and validate metric errors determined through Monte Carlo modelling and to relate radar electron line density (q) to video photon radiant power (I). By adopting an ionisation coefficient from Jones (1997) and using recorded measurements of q/I, a corresponding estimate of the fraction of meteoroid kinetic energy loss converted into light (luminous efficiency) was found.

It was …

Changes In Thermospheric Temperature Induced By High-Speed Solar Wind Streams, Larry Gardner, Jan Josef Sojka, Robert W. Schunk, Rod Heelis

All Physics Faculty Publications

During high-speed stream (HSS) events the solar wind speed increases, and the cross polar cap potential increases, leading to increased Joule heating at high latitudes. The heat input at high latitudes heats the polar regions, which then conducts to lower latitudes, producing global heating. The heating occurs during the risetime of the cross polar cap potential and throughout the period of high cross polar cap potential as seen in our simulation. These simulations are performed using the Utah State University global thermosphere model driven by Joule heating rates that are consistent with electric fields observed by DMSP-15 observations of HSS …

Comparing Theory And Experiment For Analyte Transport In The First Vacuum Stage Of The Inductively Coupled Plasma Mass Spectrometer, Matthew R. Zachreson

Theses and Dissertations

The Direct Simulation Monte Carlo algorithm as coded in FENIX is used to model the transport of trace ions in the first vacuum stage of the inductively coupled plasma mass spectrometer. Haibin Ma of the Farnsworth group at Brigham Young University measured two radial trace density profiles: one 0.7 mm upstream of the sampling cone and the other 10 mm downstream. We compare simulation results from FENIX with the experimental results. We find that gas dynamic convection and diffusion are unable to account for the experimentally-measured profile changes from upstream to downstream. Including discharge quenching and ambipolar electric fields, however, …

Treatment Of A Ring With Periodic Atomic Placement Through Differential Geometry, Gregory Karjala, Lok Lew Yan Voon

Explorations – The Journal of Undergraduate Research, Scholarship and Creativity at Wright State

Most treatments of Bloch’s Theorem have relied on group theory or other mathematical methods for its proof. In this paper we give a derivation of the quantum number first proposed by Y.C Lee and Wei Z. Lee for the Benzene ring through the use of differential geometry. We also develop a Bloch style relationship relation for the benzene ring with an additional quantum number. Through this treatment we show the usefulness of differential geometry in the theorist’s toolkit when it comes to solid-state problems.

Unresolved Question Of The 10he Ground State Resonance, Z. Kohley, J. Snyder, T. Baumann, G. Christian, P.A. Deyoung, J.E. Finck, R.A. Haring-Kaye, M. Jones, E. Lunderberg, B. Luther, S. Mosby, A. Simon, J.K. Smith, A. Spyrou, Sharon L. Stephenson, M. Thoennessen

Physics and Astronomy Faculty Publications

The group state of ¹⁰He was populated using a 2p2n-removal from a 59 MeV/u ¹⁴Be beam. The decay energy of the three body system, 8He + n + n, was measured and a resonance was observed at E = 1.60(25) MeV with a 1.8(4) MeV width. This result is in agreement with previous invariant mass spectroscopy measurements, using the ¹¹Li(-p) reaction, but is consistent with recent transfer reaction results. The proposed explanation that the difference, about 500 keV, is due to the effect of the extended halo nature of ¹¹Li in the one-proton knockout reaction is …

Advanced Numerical Methods In General Relativistic Magnetohydrodynamics, Michael J. Besselman

Theses and Dissertations

We show our work to refine the process of evolutions in general relativistic magnetohydrodynamics. We investigate several areas in order to improve the overall accuracy of our results. We test several versions of conversion methodologies between different sets of variables. We compare both single equation and two equations solvers to do the conversion. We find no significant improvement for multiple equation conversion solvers when compared to single equation solvers. We also investigate the construction of initial data and the conversion of coordinate systems between initial data code and evolution code. In addition to the conversion work, we have improved some …

Modeling Radial Bernstein Modes In A Finite-Length Axisymmetric Non-Neutral Plasma, Mark Andrew Hutchison

Theses and Dissertations

Axisymmetric radial Bernstein modes are known to exist in non-neutral plasmas and have been studied theoretically and computationally in 1D, but detection of these modes has still proven to be difficult due to self-shielding. To help advance the work on this front we created a 2D particle-in-cell (PIC) code that simulates a non-neutral plasma in a Malmberg-Penning trap. A detailed description of the PIC code itself has been included that highlights the benefits of using an $r^2$--$z$ grid and how it can be tested. The focus of the PIC simulation was to discover how best to drive and detect these …