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Full-Text Articles in Physics

The Sliding Aperture Transform: A Mathematical Method Applied To Radiation-Induced Dlts Capacitance Transients, Md Abu Bakkar Siddique Aug 2026

The Sliding Aperture Transform: A Mathematical Method Applied To Radiation-Induced Dlts Capacitance Transients, Md Abu Bakkar Siddique

Graduate Masters Theses

This thesis presents the Sliding Aperture Transform (SLAPt), a novel mathematical technique for extracting exponential argument and pre-factor  from experimental data. The method transforms measured waveforms into an inverse-domain representation where exponential decay processes appear as distinct peaks, simplifying data analysis and reducing the effects of baseline offsets and noise. The technique is here applied to time dependent capacitance transients associated with irradiated and non-irradiated silicon pn junction diodes. The technique is further developed and applied to positive argument exponentials using an axillary function. This allows forward bias  current-voltage measurements, and forward pulse-bias current transient measurements to be SLAP analyzed, …


Exploring Red Palm Oil As A Sustainable Plasticizer For Carbon Black-Filled Ssbr/Br Tire Tread Compounds: A Comparative Evaluation Of Commercial Alternatives, Norma Arisanti Kinasih, Mohamad Irfan Fathurrohman, Santi Puspitasari, Dewi Kusuma Arti, Abdulhakim Masa Aug 2026

Exploring Red Palm Oil As A Sustainable Plasticizer For Carbon Black-Filled Ssbr/Br Tire Tread Compounds: A Comparative Evaluation Of Commercial Alternatives, Norma Arisanti Kinasih, Mohamad Irfan Fathurrohman, Santi Puspitasari, Dewi Kusuma Arti, Abdulhakim Masa

Journal of Materials Exploration and Findings

This study investigates the application of red palm oil (RPO) as an alternative vegetable oil resource to substitute petroleum-based plasticizers, which have environmental and health concerns, in carbon black (CB)-filled SSBR/BR tire tread compounds. The plasticizing effects of RPO were thoroughly evaluated by comparing them with a commercial bio-based plasticizer, Epoxidized Soybean Oil (ESBO), and two safer petroleum-based oils, Naphthenic Oil (NYNAS) and Treated Distillate Aromatic Extract (TDAE). The initial investigation shows that fatty acid composition is imposing regarding the plasticizing effect. The higher unsaturated fatty acid content in RPO than in ESBO improved tensile strength and degraded rolling resistance …


Metallurgical Investigation Of A Modified Eye Bolt Failure Caused By Improper Weld Extension, Specification Deviation, And Crevice Corrosion, Dimas Muhammad Fawwaz, Reza Miftahul Ulum, Johny Wahyuadi Soedarsono, Yudha Pratesa Aug 2026

Metallurgical Investigation Of A Modified Eye Bolt Failure Caused By Improper Weld Extension, Specification Deviation, And Crevice Corrosion, Dimas Muhammad Fawwaz, Reza Miftahul Ulum, Johny Wahyuadi Soedarsono, Yudha Pratesa

Journal of Materials Exploration and Findings

A modified eye bolt from the David Arm Manhole Storage Tank underwent thorough metallurgical study due to the consequences of the bolt's malfunction during operation. Safety issues arose when the manhole door detached during operation. The mechanical testing and chemical composition analysis of the bolts indicated they were manufactured from an ASTM A193 Grade B7 material used for high-temperature bolting. This material did not conform to the engineering drawing, which mentioned SA 563A, which is about nuts, not bolts. This contradiction clearly shows that the eye bolt which was installed does not conform to the intended design. Welded connections of …


Rejection Of Fe (Iron) And Kmno4 (Organic Substance) Parameters In Peat Water Using Organic Membranes, Muhamad Rafli Sakti Mulia Gonera, Siti Umi Kalsum, Sarah Fiebrina Heraningsih Aug 2026

Rejection Of Fe (Iron) And Kmno4 (Organic Substance) Parameters In Peat Water Using Organic Membranes, Muhamad Rafli Sakti Mulia Gonera, Siti Umi Kalsum, Sarah Fiebrina Heraningsih

Journal of Materials Exploration and Findings

Peat water is a surface water source widely used by people in swampy and lowland areas, but it has poor quality characteristics such as high organic matter content, low pH, and dissolved metal levels such as iron that exceed the threshold. These conditions can cause health problems and reduce the quality of clean water so that effective treatment technology is needed. This study aims to analyze the effectiveness of ultrafiltration membranes made from chitosan from shrimp shell waste in rejecting iron (Fe) and organic substances in peat water, and to determine the effect of pressure on separation performance. This study …


Website: Home, Zhiqu Lu, Likun Zhang, Lei Cao Aug 2026

Website: Home, Zhiqu Lu, Likun Zhang, Lei Cao

Gulf Research Program Data Sets

No abstract provided.


Website: Latest Results, Zhiqu Lu, Likun Zhang, Lei Cao Aug 2026

Website: Latest Results, Zhiqu Lu, Likun Zhang, Lei Cao

Gulf Research Program Data Sets

No abstract provided.


Website: News And Events, Zhiqu Lu, Likun Zhang, Lei Cao Aug 2026

Website: News And Events, Zhiqu Lu, Likun Zhang, Lei Cao

Gulf Research Program Data Sets

No abstract provided.


Characterization Of An Ambe Tagged Neutron Source For A 30-Ton Wbls Detector, Rylee Grover Aug 2026

Characterization Of An Ambe Tagged Neutron Source For A 30-Ton Wbls Detector, Rylee Grover

Discovery Day - Daytona Beach

Understanding the detection capabilities of water-based liquid scintillator (WbLS) is critical for its deployment in next-generation neutrino detectors such as THEIA and Phase II of the Deep Underground Neutrino Experiment (DUNE). This study focuses on the characterization and alignment testing of an Americium-Beryllium (AmBe) radioactive neutron source. We plan to dope the 30-ton WbLS detector at Brookhaven National Laboratory (BNL) with Gadolinium (Gd) to improve neutron detection capabilities. This will be tested by the implementation of an AmBe source as a calibration metric. The AmBe source emits neutrons coincident with a 4.4 MeV gamma ray, making it possible to perform …


M.O.D.U.S. Modular Optical Design Using Specular Film, Mario Gutierrez, Robert Thibodeau, Emma Show, Desiree Robinson, Lingyuan Meng, Sean Martin, Conner Beeson Aug 2026

M.O.D.U.S. Modular Optical Design Using Specular Film, Mario Gutierrez, Robert Thibodeau, Emma Show, Desiree Robinson, Lingyuan Meng, Sean Martin, Conner Beeson

Discovery Day - Daytona Beach

High-quality parabolic mirrors, which are vital components in reflecting telescopes, are typically bulky, costly, and highly fragile. This experiment explores the feasibility of using specular Class B Mylar as an unconventional, lightweight, and cost-effective alternative. This approach could enable new telescope designs by greatly reducing weight and manufacturing expenses, while also opening options for potential adaptability.   This approach involves using Mylar, a flexible, reflective style of plastic. The mylar is formed into a concave mirror by stretching a sheet over a chamber and depressurizing one side to force the sheet into the necessary curved shape. Multiple designs are being created …


From Code To Cube: Interactive Fluid Simulation With Real Time Motion Control, Dominic Ziccardi, Carter Groezinger Aug 2026

From Code To Cube: Interactive Fluid Simulation With Real Time Motion Control, Dominic Ziccardi, Carter Groezinger

Discovery Day - Daytona Beach

This research project explores the use of FluidX3D, an open-source lattice Boltzmann method (LBM) solver, to simulate fluid behavior within a three-dimensional cube container. The system supports both standard water models and rheoscopic fluid visualization, allowing detailed observation of complex flow dynamics in real time. The simulation accurately represents fluid motion, gravity-driven behavior, and rotational response within a bounded cubic domain. The longterm objective is to extend this digital simulation into a physical installation consisting of six synchronized square displays arranged to form a cube. This configuration will create a volumetric illusion of fluid occupying a tangible, handheld structure. An …


String-Of-Pearls Measurements Of Supersonic Plasma Jets Using Magnetospheric Multiscale Satellites, Amelia Koth Aug 2026

String-Of-Pearls Measurements Of Supersonic Plasma Jets Using Magnetospheric Multiscale Satellites, Amelia Koth

Discovery Day - Daytona Beach

High-energy supersonic plasma jets form when the solar wind, which is a flow of charged particles from the Sun, slows down as it encounters Earth’s magnetic shield. Occasionally, the solar wind remains at supersonic speeds as it enters this region. This forms plasma jets that propagate toward Earth; these jets can carry strong magnetic fields, drive magnetic reconnection, and potentially initiate substorms that lead to auroral activity.   Previously studied plasma jets occurred when the interplanetary magnetic field (IMF) points southward. In contrast, this study focuses on northward IMF conditions, which are less understood, yet still capable of producing supersonic jets. …


Extending The Essentially Entropic Lattice Boltzmann Method To Three-Dimensional Turbulent Flows, Michael Derderian Aug 2026

Extending The Essentially Entropic Lattice Boltzmann Method To Three-Dimensional Turbulent Flows, Michael Derderian

Discovery Day - Daytona Beach

The Entropic Lattice Boltzmann Method (EELBM) has demonstrated strong numerical stability and accuracy for two-dimensional simulations, particularly at higher resolutions where the entropic formulation introduces only minimal stabilizing turbulent viscosity and eventually converges to the Lattice Bhatnagar–Gross–Krook (LBGK) formulation. This built-in stabilization can be interpreted as an implicit large-eddy simulation (LES) model, allowing EELBM to capture complex turbulent behavior without requiring explicit subgrid-scale closures. While these advantages have been thoroughly validated in 2D, understanding how the entropic constraint regulates dissipation in three dimensions is essential for assessing EELBM’s suitability for practical, turbulence-dominated applications. This work focuses on the development and …


Multi-Dimensional Particle-In-Cell With Monte Carlo Collisions (Pic-Mcc) Simulation For Visualizing Plasma Flow And Secondary Ionization In Constricted-Anode Geometries, Parth Thakar Aug 2026

Multi-Dimensional Particle-In-Cell With Monte Carlo Collisions (Pic-Mcc) Simulation For Visualizing Plasma Flow And Secondary Ionization In Constricted-Anode Geometries, Parth Thakar

Discovery Day - Daytona Beach

Constricted-anode plasma sources generate locally intensified electric fields that enhance ionization near the anode, making them valuable in propulsion and laboratory plasma systems. However, the narrow geometry produces complex charge accumulation and secondary ionization effects that remain difficult to measure experimentally. To address this challenge, our research develops and applies a multi-dimensional Particle-in-Cell with Monte Carlo Collisions (PIC-MCC) simulation of a DC discharge in 1-D, 2-D, and 3-D configurations that model a constricted-anode device. PIC-MCC is a first-principles method that tracks electrons and ions individually while computing self-consistent electric fields and incorporating energy-dependent collision processes. This approach enables direct visualization …


Effect Of Anode Size On The Properties Of Constricted Hollow Anode Pulsed Plasma Source, Nirav Patel, Garret Seckinger Aug 2026

Effect Of Anode Size On The Properties Of Constricted Hollow Anode Pulsed Plasma Source, Nirav Patel, Garret Seckinger

Discovery Day - Daytona Beach

With the advent of ion thrusters, burns requiring large velocity changes can be performed with a fraction of the propellant required by traditional chemical rocket engines. However, current ion thrusters produce thrust in the order of millinewtons and thus cannot be viable for launching vehicles or burns requiring velocity changes in a small amount of time. Furthermore, current ion thrusters experience grid and component erosion, where the two grids at the termination of the nozzle slowly erode due to particle impact, and the hot electrodes degrade due to high thermal load. This limits the life of ion engines, which require …


A Feedback Loop Control To Automate Cold Atmospheric Pressure Plasma Based Additive Manufacturing, Arineh Shahbazi Aug 2026

A Feedback Loop Control To Automate Cold Atmospheric Pressure Plasma Based Additive Manufacturing, Arineh Shahbazi

Discovery Day - Daytona Beach

Currently, nanoparticle annealing based additive manufacturing process requires high temperatures, making them unsuitable for a broad range of applications. By lowering the temperature and developing a process to use Cold Atmospheric Pressure Plasma (CAPP) for annealing, many more doors are opened to a wide range of materials, films, and environments for space, communication, and microelectronics. CAPP-based additive manufacturing technology is continually evolving, making projects like nanoparticle annealing more feasible. In this work, we designed a CAPP jet printer assembly consisting of a 0.25-inch outer diameter glass tube connected to a 3D printing nozzle. The flow of Argon gas in the …


Navier Stokes Pressure Drop Derivation, Brayden Benedetti, Gedaliah Dimbert, Jaden Turobiner Aug 2026

Navier Stokes Pressure Drop Derivation, Brayden Benedetti, Gedaliah Dimbert, Jaden Turobiner

Discovery Day - Daytona Beach

Accurate prediction of pressure losses in propellant and fluid feed systems is essential for reliable design and operation of aerospace and industrial flow networks. This project presents a systematic derivation of a practical pressure drop calculator for a feed system using isopropyl alcohol, beginning from the fundamental conservation laws and culminating in an engineering-level computational model. Starting with the differential form of the Navier–Stokes equations for incompressible flow, the governing equations are simplified through a series of physically justified assumptions, including steady-state flow, negligible body forces, and fully developed internal flow within circular piping. The resulting momentum balance is reduced …


Application Of Navier Stokes In Cfd, Hayden Kerkhoff, Gavin Palmer, Garret Seckinger Aug 2026

Application Of Navier Stokes In Cfd, Hayden Kerkhoff, Gavin Palmer, Garret Seckinger

Discovery Day - Daytona Beach

This project investigates the use of 2-Dimensional Computational Fluid Dynamics (CFD) to analyze aerodynamic behavior, then compare data with the numerical solution of the Navier–Stokes equations run by MATLAB. By leveraging open‑source and possible industry CFD platforms—including OpenFOAM and commercial solvers such as ANSYS Fluent and Inventor Professional—the study evaluates how computational methods simulate, optimize, and predict key aerodynamic quantities such as lift, drag, stall angle, and Reynolds number.   The project focuses on modeling an airflow over specific parameters, such as different angles of attacks and ISA Atmospheric Conditions. Parametric variations in density, angle of attack, chord length, and temperature …


Motion With Air Resistance, Gauge Mccain, Jacob Bealefeld, Francesca Wise Aug 2026

Motion With Air Resistance, Gauge Mccain, Jacob Bealefeld, Francesca Wise

Discovery Day - Daytona Beach

The motion of objects moving through air is influenced not only by gravity but also by air resistance, which affects the speed and acceleration of the object over time. This project examines the motion of a falling object by modeling it with an ordinary differential equation that accounts for both gravitational force and a resistive drag force proportional to velocity. Using Newton’s Second Law, a first-order differential equation is derived to describe how the velocity of the object changes as it falls. The solution of this equation demonstrates how the velocity increases initially and gradually approaches a constant value known …


Engineering Path Trajectories With Gravitational Fields, Eliane Dean, Aidan Hart, Isabel Noot, Nathan Browning, Valeria Villazon Fito Aug 2026

Engineering Path Trajectories With Gravitational Fields, Eliane Dean, Aidan Hart, Isabel Noot, Nathan Browning, Valeria Villazon Fito

Discovery Day - Daytona Beach

This project explores how vector calculus concepts play a role in aerospace engineering though spacecraft trajectory design. In particular, the notion of vector fields is used to model the gravitational force, whose work done is expressed through line integrals. By taking the curl of the gravitational field and showing it is zero, the field is recognised as conservative, implying that the work done by gravity is path independent. This property is conceptually linked to gravitational potential energy and the principle of energy conservation. The results are then applied to spacecraft motion, where engineers use energy-base methods to determine efficient trajectories …


Visualizing The Invisible: Simulating Electromagnetic Field In 3d Space With Matlab, Aashman Gupta, Eliane Dean, Riley Esperanca, Hailey Grabinski, Jacob Summerhays, Ameya Sute Aug 2026

Visualizing The Invisible: Simulating Electromagnetic Field In 3d Space With Matlab, Aashman Gupta, Eliane Dean, Riley Esperanca, Hailey Grabinski, Jacob Summerhays, Ameya Sute

Discovery Day - Daytona Beach

Electromagnetic field behaviours in free space are defined by Maxwell’s Equations, which couple the temporal and spatial variations of electric and magnetic fields through partial derivatives. These derivatives quantify the rate of change of each field’s vector component with respect to position and time in a 3D lattice, forming the basis for numerical field analysis. This research will develop a mathematical and computational framework using multivariable calculus to model, simulate, and visualize electromagnetic wave propagation in free space using MATLAB. Gradient, divergence, and curl operations are implemented to compute local field variations and energy transfer. The resulting data are used …


Simulations Of Phugoid Motion Of Jal 123, Dereth J J. Drake Scheuermann Aug 2026

Simulations Of Phugoid Motion Of Jal 123, Dereth J J. Drake Scheuermann

Georgia Journal of Science

Airplanes rely on a balance between the four forces of flight: lift, weight, thrust, and drag. If these forces are balanced, the airplane will remain stable. However, if structurally or systematically compromised, the motion can rapidly become unstable. In the aviation industry, mistakes in repairs and aircraft design can lead to accidents causing the loss of life in some cases. In this article, we will be analyzing what happened 70 Japan Airlines flight 123 and how the flight’s motion deteriorated due to a defective repair. More specifically, we will discuss the aerodynamic effects of phugoid motion and how it developed …


Rockin’ Rover On The Rainbow Road, Michael Kolta, Lawrence Burgee, Ying Yuan Aug 2026

Rockin’ Rover On The Rainbow Road, Michael Kolta, Lawrence Burgee, Ying Yuan

Transformations

This paper presents a progressive series of age-appropriate lesson plans for grades K-12 that all use the same interdisciplinary activity to educate students about Science, Technology, Engineering, Art, and Mathematics (STEAM) simultaneously. Technology from Texas Instruments (TI) was employed including a TI Nspire graphing calculator that can run Python programs, a TI Innovator Hub, and a TI Rover. The TI Rover is a small, robotic car that has sensors and is controlled by the calculator via the Hub hardware interface. A Python program was developed that uses the color sensor in the Rover to detect the color on colored paper …


65th Annual Rocky Mountain Conference On Magnetic Resonance Aug 2026

65th Annual Rocky Mountain Conference On Magnetic Resonance

Rocky Mountain Conference on Magnetic Resonance

Conference program, abstracts, and information about the 65th annual meeting of the Rocky Mountain Conference on Magnetic Resonance. Held in the Snowbird Resort and Conference Center, Snowbird, Utah, August 2-6, 2026.


Single Fluorogens And Orientation-Localization Microscopy For Quantifying Chemical And Biomolecular Dynamics At The Nanoscale, Yiyang Chen, Yuanxin Qiu, Matthew D. Lew Aug 2026

Single Fluorogens And Orientation-Localization Microscopy For Quantifying Chemical And Biomolecular Dynamics At The Nanoscale, Yiyang Chen, Yuanxin Qiu, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Many chemical systems look uniform only because ensemble measurements average over their most interesting molecules. Electron-transfer rates vary across electrode surfaces; lipid membranes contain nanodomains with distinct packing and fluidity; peptide aggregates exhibit local polymorphism; and biomolecular condensates contain transient networks of interactions that are blurred in ensemble images. A central challenge in chemical imaging is not simply to see smaller structures, but to measure chemical variables such as polarity, redox potential, and molecular confinement at the single-molecule level. In this Account, we describe how fluorogens, molecules whose brightness, blinking, spectral shifts, orientation, rotational mobility, and motion are directly shaped …


Synthesis And Characterization Of Carbon Quantum Dots And Gold Nanoparticles For Norovirus Biosensing Applications In Water Systems, Breanne Evans Aug 2026

Synthesis And Characterization Of Carbon Quantum Dots And Gold Nanoparticles For Norovirus Biosensing Applications In Water Systems, Breanne Evans

Master's Theses

Rapid, reliable detection of viral pathogens remains a significant challenge across water-treatment and environmental monitoring systems, including drinking-water, wastewater, water reuse, and environmental surveillance applications. Waterborne viral contamination can pose substantial public-health risks, making early detection essential for protecting water quality and responding quickly to treatment failures or contamination events. Direct potable reuse (DPR) is one particularly demanding example because it requires continuous verification of treatment performance and the broader need for rapid virus monitoring extends across many water-treatment and environmental surveillance applications. Norovirus is a priority target because of its widespread occurrence in wastewater, environmental persistence, and exceptionally low …


Emergent De Sitter Expansion And Closed Topology From The Cosmic Fabric Model As An Open Thermodynamic System: Resolving The Negative Bulk Modulus Paradox, T G. Tenev, C B. Ward, T F. Tenev, M F. Horstemeyer Jul 2026

Emergent De Sitter Expansion And Closed Topology From The Cosmic Fabric Model As An Open Thermodynamic System: Resolving The Negative Bulk Modulus Paradox, T G. Tenev, C B. Ward, T F. Tenev, M F. Horstemeyer

Faculty Publications and Presentations

The Cosmic Fabric Model establishes a continuum-mechanics isomorphism to General Relativity by representing physical space as an elastic three-dimensional hyperplate embedded in a four-dimensional spatial bulk. Reproducing vacuum kinematics requires a vanishing P-wave modulus, which in turn implies a negative bulk modulus—an apparent thermodynamic instability in a closed system. This paradox is resolved by recasting the framework as an open system: the instability is not pathological but instead drives cosmic expansion. In this interpretation, the observable universe is a lower-energy solid formed through continuous solidification from a higher-dimensional precursor fluid. Using multiplicative kinematics from finite-growth mechanics, the model shows that …


Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo Jul 2026

Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo

Chemical and Biological Engineering ETDs

Photosynthetic light-harvesting complexes harvest solar energy and direct electronic excitations toward reaction centers with exceptional efficiency. This dissertation models the Fenna--Matthews--Olson complex of green sulfur bacteria, coupled to the PscA1 reaction center, as a chromophoric network. Forster resonance energy transfer theory, validated against numerically exact hierarchical equations of motion, was implemented in kinetic Monte Carlo simulations to resolve fine-grained excitation-transport pathways. The predicted charge-transfer efficiency of 77\% agrees with experiment, with the FMO2 monomer and its gateway pigment governing interfacial transfer. Systematic single, multi, and symmetry-preserving site removals, interpreted through Mobius inversion, identify critical pigments and show that cooperative effects …


Global Time-Resolved Measurements Of Inlet/Isolator Unstart Induced By Mass Injection, Andrew N. Bustard, Benjamin L. Bemis, Aaron Marques, Matthew J. Zahr, Thomas J. Juliano Jul 2026

Global Time-Resolved Measurements Of Inlet/Isolator Unstart Induced By Mass Injection, Andrew N. Bustard, Benjamin L. Bemis, Aaron Marques, Matthew J. Zahr, Thomas J. Juliano

Publications

The inner surface pressure of an axisymmetric inlet/isolator model was measured using anodized-aluminum pressure-sensitive paint (PSP) viewing through cast acrylic. Temperaturesensitive paint was utilized to correct for the PSP’s temperature sensitivity. The model was tested under Mach 5.7 flow at 𝑹𝒆 = 7.1 ×106 /m under conventional noise conditions. Transverse jet injection with jet-to-inlet mass-flow ratios up to 0.8 was used to induce unstart in the inlet/isolator. Background-oriented schlieren visualization of the inlet shocks was collected simultaneously with the PSP to determine when the inlet unstarted. Computational fluid dynamics results were used to determine off-wall flow structures and quantify approach …


Coherent Two-Photon Backscattering And Induced Angular Quantum Correlations In Multiple-Scattered Two-Photon States Of The Light, Nooshin M. Estakhri, Theodore B. Norris Jul 2026

Coherent Two-Photon Backscattering And Induced Angular Quantum Correlations In Multiple-Scattered Two-Photon States Of The Light, Nooshin M. Estakhri, Theodore B. Norris

Engineering Faculty Articles and Research

We present the emergence of coherent two-photon backscattering, a manifestation of weak localization, in multiple scattering of maximally entangled pure and fully mixed two-photon states and examine the effect of entanglement and classical correlations. Quantum correlations in backscattering are investigated for finite three-dimensional disordered structures in the weak localization regime, as well as systems of a small number of scatterers with specified spatial arrangements. No assumptions are made about the statistical behavior of the scattering matrix elements. Furthermore, we study the interplay between quantum correlations induced by multiple scattering and the correlations that may be present in the illumination fields, …


Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas Jul 2026

Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas

Physics & Astronomy Faculty Publications

We develop a surfactant-free synthesis method for gold nanoparticles (AuNPs) using 2-propynylamine-functionalized silicon nanoparticles as integrated redox-active supports. Surface-anchored amine groups act as built-in reducing sites for Au3+ precursors at the hexane–water interface under ambient conditions, enabling in situ AuNP nucleation and growth. Time-resolved UV-vis spectroscopy and dynamic light scattering track the emergence of plasmonic AuNPs, while quantitative morphology analysis reveals a final population dominated by spherical and near-spherical nanoparticles (∼74%), with faceted polyhedral structures (∼4%) and dendritic, hollow, irregular, and rod-like morphologies (∼22%) as minority species. The temporal evolution proceeds from early dendritic and irregular aggregates to a …