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Photoluminescence

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Full-Text Articles in Physics

Fast Neutron & Gamma-Ray Scintillation And Broadband Photoluminescence From Gallium Nitride & Gallium Oxide: Developing Radiation-Hard Diagnostic Platforms, Daniel Jesus Valdes Dec 2024

Fast Neutron & Gamma-Ray Scintillation And Broadband Photoluminescence From Gallium Nitride & Gallium Oxide: Developing Radiation-Hard Diagnostic Platforms, Daniel Jesus Valdes

UNLV Theses, Dissertations, Professional Papers, and Capstones

Integrated scintillation and electronics processing materials are of critical importance in environments exposed to high levels of radiation, such as nuclear fusion diagnostics and space missions. This dissertation focuses on the radiation detection capabilities of gallium oxide (Ga2O3) and gallium nitride (GaN), exploring their responses to fast neutrons and gamma rays. Using high-energy neutron beam facilities at Los Alamos Neutron Science Center (LANSCE) Flight Path 4FP60R, we exposed both Ga2O3 and GaN crystals to neutron irradiation spanning an energy spectrum ranging from 1 to 400 MeV. A Pi-Max 4 fast-gated Intensified CCD (ICCD) camera captured the transient scintillation responses for …


Crystalline Colloidal Arrays: Exploring Light-Matter Interactions, Haley W. Jones May 2024

Crystalline Colloidal Arrays: Exploring Light-Matter Interactions, Haley W. Jones

All Dissertations

Understanding and manipulating quantum light-matter interactions, especially in the context of nanostructured environments, is highly critical for technological progress and inventive solutions in the fields of telecommunications, energy-efficient lighting, and cutting-edge quantum computing technologies. The fundamental interactions of photons with a surrounding environment directly impact the performance and efficiency of devices such as lasers, light-emitting diodes (LEDs), and quantum computing elements, which leverage the unique properties of confined structured environments. Since the late 1980s, the connection between a structured environment and the decay kinetics of an embedded fluorophore has been a highly debated and unresolved topic in the literature. More …


An Efficiently Excited Eu3+ Luminescent Site Formed In Eu,O-Codoped Gan, Takenori Iwaya, Shuhei Ichikawa, Volkmar Dierolf, Brandon Mitchell, Hayley Austin, Dolf Timmerman, Jun Tatebayashi, Yasufumi Fujiwara Feb 2024

An Efficiently Excited Eu3+ Luminescent Site Formed In Eu,O-Codoped Gan, Takenori Iwaya, Shuhei Ichikawa, Volkmar Dierolf, Brandon Mitchell, Hayley Austin, Dolf Timmerman, Jun Tatebayashi, Yasufumi Fujiwara

Physics & Engineering Faculty Publications

For the development of III-nitride-semiconductor-based monolithic micro-light-emitting diode (LED) displays, Eu,O-codoped GaN (GaN:Eu,O) is a promising material candidate for the red LEDs. The luminescence efficiency of Eu-related emission strongly depends on the local atomic structure of Eu ions. Our previous research has revealed that post-growth thermal annealing is an effective method for reconfiguring luminescent sites, leading to a significant increase in light output. We observed the preferential formation of a site with a peak at similar to 2.004 eV by the annealing process. In this study, we demonstrate that it is a previously unidentified independent site (OMVPE-X) using combined excitation-emission …


Effect Of Annealing On Photoluminescence From Defects In Gan, Oleksandr Andrieiev Jan 2024

Effect Of Annealing On Photoluminescence From Defects In Gan, Oleksandr Andrieiev

Theses and Dissertations

Annealing is a critical process in modern GaN technology, essential for achieving p-type conductivity by activating the MgGa acceptor, as first demonstrated by Shuji Nakamura in the early 1990s. Despite the omnipresence of hydrogen as an impurity in GaN crystals, the precise mechanisms governing hydrogen diffusion and acceptor passivation remain only partially understood. The presented research investigates the effects of annealing-induced activation and hydrogen passivation on C and Be acceptors in GaN grown by MOCVD, HVPE, and MBE methods. We explored these effects by using several annealing techniques, gas compositions, and thermal regimes. A transient behavior between the C …


Photoluminescence Of Beryllium-Related Defects In Gallium Nitride, Mykhailo Vorobiov, Mykhailo Vorobiov Jan 2024

Photoluminescence Of Beryllium-Related Defects In Gallium Nitride, Mykhailo Vorobiov, Mykhailo Vorobiov

Theses and Dissertations

This study explores the potential of beryllium (Be) as an alternative dopant to magnesium (Mg) for achieving higher hole concentrations in gallium nitride (GaN). Despite Mg prominence as an acceptor in optoelectronic and high-power devices, its deep acceptor level at 0.22 eV above the valence band limits its effectiveness. By examining Be, this research aims to pave the way to overcoming these limitations and extend the findings to aluminum nitride and aluminum gallium nitride (AlGaN) alloy. Key contributions of this work include. i)Identification of three Be-related luminescence bands in GaN through photoluminescence spectroscopy, improving the understanding needed for further material …


Designing Noncentrosymmetric Multifunctional Materials, Ebube Oyeka May 2023

Designing Noncentrosymmetric Multifunctional Materials, Ebube Oyeka

All Dissertations

Noncentrosymmetric (NCS) materials with crystal lattices lacking spatial inversion symmetry display a wide range of exciting functionalities. This dissertation covers two classes of functional NCS materials: magnetic skyrmion-host compounds and multifunctional materials. Magnetic skyrmion and multifunctional materials combining optical and magnetic responses are providing avenues for developing and optimizing the performance of electronic devices that can have uses in memory storage, laser technology, medicine, sensors, etc. The formation of skyrmions is driven by asymmetric Dzyaloshinskii–Moriya (DM) interaction facilitated by broken spatial inversion symmetry and large spin-orbit coupling (SOC), while multiple functionalities arise when spin carriers and optical chromophores are optimally …


Characterizing Gesn Alloys By Sem/Eds And Photoluminescence Spectroscopy, Christopher M. Sutphin Mar 2023

Characterizing Gesn Alloys By Sem/Eds And Photoluminescence Spectroscopy, Christopher M. Sutphin

Theses and Dissertations

Germanium tin (GeSn) alloys are being studied as potential transition metal (Group IV) photoelectric semiconductors or optical detectors. GeSn alloys could be employed as an optically active material within a computer. Compared to current technologies, a direct band gap GeSn alloy can be engineered to operate with higher thermal stability and efficiency. The GeSn alloy studied was composed of Ge and Si substrates with various Sn percentages grown using remote plasma-enhanced chemical vapor deposition (RPECVD). Photoluminescence spectroscopy (PL) techniques were initially used to determine the GeSn properties, including the band gap. The Ge91.2Sn8.8 PL spectra suggested the …


Optical Studies Of Wide Bandgap Photonic Materials, Nikesh Maharjan Jun 2022

Optical Studies Of Wide Bandgap Photonic Materials, Nikesh Maharjan

Dissertations, Theses, and Capstone Projects

In this dissertation work, optical properties of wide bandgap materials such as hexagonal Boron Nitride (h-BN) and Zinc Oxide (ZnO) have been studied. Deep UV photoluminescence spectroscopy was employed to study the optical properties of bulk h-BN and powder crystals using a laser of wavelength 200 nm, which is the fourth harmonic of Ti:Sapphire laser as excitation source. The properties and chemical compositions of annealed and unannealed bulk h-BN were investigated. The PL spectra from h-BN samples annealed at 900 ºC in ambient air, had strong phonon assisted band edge emissions along with a sharp atomic-like emission line at 4.09 …


Electronic Structure Of Early Transition Metal Complexes Supported By Pyridine Polypyrrolide Ligands, Dylan Connor Leary Jan 2022

Electronic Structure Of Early Transition Metal Complexes Supported By Pyridine Polypyrrolide Ligands, Dylan Connor Leary

Graduate Theses, Dissertations, and Problem Reports (ETD)

A thorough study of photoluminescent molecules involving the pyridine polypyrrole(ide) ligand platform has been conducted. A detailed analysis on speciation of the proligand H2(MesPDPPh) (H2MesPDPPh = 2,6-bis(5-mesityl-3-phenyl-1H-pyrrol-2-yl)-pyridine) and its dilithium salt Li2(MesPDPPh) revealed temperature- and solvent-dependent effects. These molecules, along with the hydrochloric acid adduct [H3(MesPDPPh)]Cl were found to exhibit short-lived photoluminescence in both tetrahydrofuran and benzene solution. These findings confirm the hypothesis that heavy-atom involvement is crucial for the favorable photophysical properties observed for the Zr(PDP)2 …


Photoluminescence Spectra Of Silicon Doped With Cadmium, N A. Sultanov, E T. Rakhimov, Z Mirzajonov, F T. Yusupov Aug 2021

Photoluminescence Spectra Of Silicon Doped With Cadmium, N A. Sultanov, E T. Rakhimov, Z Mirzajonov, F T. Yusupov

Scientific-technical journal

Cadmium and zinc, as transition metals, are deep-level impurities (DL) and have a significant effect on the electrical, photoelectric, recombination, and other properties of semiconductor crystals.This paper presents the results of experimental studies of the optical and electrical properties of silicon crystals containing impurity atoms of cadmium and zinc using DLTS and low-temperature photoluminescence (PL).


Аn Optical Study Of Strain Relaxation And Interdiffusion In Znse/Zncdse Quantum Wells Modified By Γ-Irradiation, Muratbay B. Sharibaev, Kanatbay A. Ismailov, Ibrohim N. Karimov, Murodjon Z. Nosirov Dec 2020

Аn Optical Study Of Strain Relaxation And Interdiffusion In Znse/Zncdse Quantum Wells Modified By Γ-Irradiation, Muratbay B. Sharibaev, Kanatbay A. Ismailov, Ibrohim N. Karimov, Murodjon Z. Nosirov

Scientific Bulletin. Physical and Mathematical Research

If we turn to the literature data, it is known that the degradation of CdZnTe / ZnTe and CdZnSe /ZnSe quantum wells and usually includes two types of processes: (i) fast (as called dynamic, by analogy with the degradation of heterostructures based on A3B5 materials) - germination and propagation of extended defects from a GaAs substrate. This process in CdZnSe / ZnSe is slowed down by various technological methods (treatment of a substrate in sulfur; reduction of a damaged layer in a GaAs substrate; deposition of a GaAs epitaxial buffer layer; use of the concept of compensation of bipolar stresses; …


Optical Properties Of Ultrathin In(Ga)As/Gaas And In(Ga)N/Gan Quantum Wells, Yurii Maidaniuk Dec 2020

Optical Properties Of Ultrathin In(Ga)As/Gaas And In(Ga)N/Gan Quantum Wells, Yurii Maidaniuk

Graduate Theses and Dissertations

Recently, structures based on ultrathin quantum wells (QWs) began to play a critical role in modern devices, such as lasers, solar cells, infrared photodetectors, and light-emitting diodes. However, due to the lack of understanding of the formation mechanism of ultrathin QWs during the capping process, scientists and engineers cannot fully explore the potential of such structures. This study aims to investigate how structural parameters of ultrathin QWs affect their emission properties by conducting a systematic analysis of the optical properties of In(Ga)As/GaAs and In(Ga)N/GaN ultrathin QWs. Specifically, the analysis involved photoluminescence measurements combined with effective bandgap simulation, x-ray diffraction, and …


Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh Nov 2020

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …


Luminescence Emission In A Nanocrystal Doped By A Transition Metal Impurity, George Chappell Jr. Jan 2020

Luminescence Emission In A Nanocrystal Doped By A Transition Metal Impurity, George Chappell Jr.

Theses, Dissertations and Capstones

In this thesis we consider the structure of magnetic ion centers with 3d-electrons in quantum dots under the effects of Coulomb and exchange interaction between the 3d-electrons of the impurity centers and the confined electrons (or holes) existing inside the nanocrystals. In particular, we are interested how this interaction changes the photoluminescence properties of those materials. We will make use of representation theory and the symmetry of the crystal structure to find the orthonormal wave functions that make up the wave functions of the outer, 3d-electrons inside our dot. The Coulomb and exchange interaction …


Definition Of Extended Structural Defects In Epitaxial Films Of Znteg‘Gaas Grown By Mbe, Muratbay B. Sharibaev, Kanatbay A. Ismailov, Ibrohim N. Karimov, Murodjon Z. Nosirov Dec 2019

Definition Of Extended Structural Defects In Epitaxial Films Of Znteg‘Gaas Grown By Mbe, Muratbay B. Sharibaev, Kanatbay A. Ismailov, Ibrohim N. Karimov, Murodjon Z. Nosirov

Scientific Bulletin. Physical and Mathematical Research

The last three decades of the development of solid state physics are characterized by the fact that the main objects of research are increasingly not massive crystals, but thin films, multilayer thin-film systems, conducting filaments and crystallites of small size. Epitaxial films are grown on a substrate of a single crystal of the same or another material. In the first case, the epitaxial layer with the correct technology becomes a natural extension of the substrate. Epitaxial film can be doped with various impurities. To introduce an alloying admixture into the epitaxial film, three methods are used. According to the first …


Deep Donors And Acceptors In Β-Ga2O3 Crystals: Determination Of The Fe2+/3+ Level By A Noncontact Method, Christopher A. Lenyk, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles Dec 2019

Deep Donors And Acceptors In Β-Ga2O3 Crystals: Determination Of The Fe2+/3+ Level By A Noncontact Method, Christopher A. Lenyk, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

Electron paramagnetic resonance (EPR), infrared absorption, and thermoluminescence (TL) are used to determine the Fe2+/3+ level in Fe-doped β-Ga2O3 crystals. With these noncontact spectroscopy methods, a value of 0.84 ± 0.05 eV below the conduction band is obtained for this level. Our results clearly establish that the E2 level observed in deep level transient spectroscopy (DLTS) experiments is due to the thermal release of electrons from Fe2+ ions. The crystals used in this investigation were grown by the Czochralski method and contained large concentrations of Fe acceptors and Ir donors, and trace amounts of Cr …


Near-Field And Far-Field Microscopic And Spectroscopic Characterizations Of Coupled Plasmonic, Excitonic And Polymeric Materials, Chih-Feng Wang Nov 2019

Near-Field And Far-Field Microscopic And Spectroscopic Characterizations Of Coupled Plasmonic, Excitonic And Polymeric Materials, Chih-Feng Wang

Optical Science and Engineering ETDs

The properties of localized surface plasmons (LSP) have been broadly utilized for chemical sensing, surface enhanced Raman spectroscopy, biomedical imaging and photothermal treatments. By exploiting well-established plasmonic effects, the spectroscopic investigation of intriguing quantum phenomena, such as excitonic interband and intersubband (ISB) transitions in semiconductor heterostructures, was examined and extended in both far- and near-field optical measurements. For far-field characterization, we used colloidal plasmonic Au nanorods (AuNRs) to increase the quantum efficiency of InGaAs/GaAs single quantum well. By analyzing the temperature-dependent photoluminescence enhancement as a function of GaAs capping layer thickness, we attributed the mechanism of the LSP enhancement to …


Tip-Enhanced Nano-Optical Imaging Of Superacid Treated Bilayer Mos2-Ws2 2d Lateral Heterostructures, Amala Dixit Mar 2019

Tip-Enhanced Nano-Optical Imaging Of Superacid Treated Bilayer Mos2-Ws2 2d Lateral Heterostructures, Amala Dixit

USF Tampa Graduate Theses and Dissertations

Nanoscale optical characterization of two-dimensional (2D) materials and heterostructures is important for the design of novel optoelectronic flexible nano-devices. Nano-optical photoluminescence (PL) and Raman imaging of bilayer 2D materials has been a challenging problem due to weak signals. The exciton-dominated light emission of two-dimensional (2D) transition metal dichalcogenide (TMDC) materials is affected by the formation of defects and doping states. Previous studies have shown that chemical treatment modifies the defect and doping states of chemical vapor deposition (CVD)-grown monolayers of MoS2 and WS2, which provides a promising possibility for engineering the optoelectronic properties of these 2D TMDCs. …


Plasmonic Enhancement Of Photoluminescence And Photobrightening In Cdse Quantum Dots, David Alan French Dec 2018

Plasmonic Enhancement Of Photoluminescence And Photobrightening In Cdse Quantum Dots, David Alan French

Graduate Theses and Dissertations

Quantum dots are gaining recognition not just in the physics and chemistry community, but in the public eye as well. Quantum dot technologies are now being used in sensors, detectors, and even television displays. By exciting quantum dots with light or electricity, they can be made to emit light, and by altering the quantum dot characteristics the wavelength can be finely tuned. The light emitted can be also be made more intense by an increase in the excitation energy. The excitation light can be increased via plasmonic enhancement, leading to increased luminescence. Aside from the relatively steady-state response, quantum dots …


Spectra Of One – And Two Photon Excited Luminescence Of Medical Drugsin Photon Traps, A.K. Kubanov, D.I. Semenov Oct 2018

Spectra Of One – And Two Photon Excited Luminescence Of Medical Drugsin Photon Traps, A.K. Kubanov, D.I. Semenov

Scientific Journal of Samarkand University

A technique for studying the photoluminescence spectra of pharmaceuticals (analgin, paracetamol) was developed for single- and two-photon excitation by a pulse-periodic laser. The technique is based on the fiber-optic recording of photoluminescence spectra using a small-size spectrometer, quartz light guides, and mini cavity cuvettes, which makes it possible to compare the analyzed spectrum with the spectrum of the reference substance.


Near Bandgap Two-Photon Excited Luminescence Of Inas Quantum Dots, Xian Hu May 2018

Near Bandgap Two-Photon Excited Luminescence Of Inas Quantum Dots, Xian Hu

Graduate Theses and Dissertations

Semiconductor quantum dots (QDs) confine carriers in three dimensions, resulting in atomic-like energy levels as well as size-dependent electrical and optical properties. Self-assembled III-V QD is one of the most studied semiconductor QDs thanks to their well-established fabrication techniques and versatile optical properties. This dissertation presents the photoluminescence (PL) study of the InAs/GaAs QDs with both above bandgap continuous-wave excitation (one-photon excitation) and below-bandgap pulse excitation (two-photon excitation). Samples of ensemble QDs, single QD (SQD), and QDs in a micro-cavity, all grown by molecular beam epitaxy, are used in this study. Morphology of these samples was examined using atomic force …


Copper-Doped Lithium Triborate (Lib3o5) Crystals: A Photoluminescence, Thermoluminescence, And Electron Paramagnetic Resonance Study, Brant E. Kananen, John W. Mcclory, Nancy C. Giles, Larry E. Halliburton Feb 2018

Copper-Doped Lithium Triborate (Lib3o5) Crystals: A Photoluminescence, Thermoluminescence, And Electron Paramagnetic Resonance Study, Brant E. Kananen, John W. Mcclory, Nancy C. Giles, Larry E. Halliburton

Faculty Publications

When doped with copper ions, lithium borate materials are candidates for use in radiation dosimeters. Copper-doped lithium tetraborate (Li2B4O7) crystals have been widely studied, but little is known thus far about copper ions in lithium triborate (LiB3O5) crystals. In the present investigation, Cu+ ions (3d10) were diffused into an undoped LiB3O5 crystal at high temperature. These ions occupy both Li+ and interstitial positions in the crystal. A photoluminescence (PL) band peaking near 387 nm and a photoluminescence excitation (PLE) band peaking near 273 nm verify that a portion of these Cu+ ions are located at regular Li+ sites. After an …


Photoluminescence From Gan Co-Doped With C And Si, Mykhailo Vorobiov Jan 2018

Photoluminescence From Gan Co-Doped With C And Si, Mykhailo Vorobiov

Theses and Dissertations

This thesis devoted to the experimental studies of yellow and blue luminescence (YL and BL relatively) bands in Gallium Nitride samples doped with C and Si. The band BLC was at first observed in the steady-state photoluminescence spectrum under high excitation intensities and discerned from BL1 and BL2 bands appearing in the same region of the spectrum. Using the time-resolved photoluminescence spectrum, we were able to determine the shape of the BLC and its position at 2.87 eV. Internal quantum efficiency of the YL band was estimated to be 90\%. The hole capture coefficient of the BLC …


Determination Of The Energy Band Gap Of Bi₂Se₃, G. Martinez, B. A. Piot, M. Hakl, M. Potemski, Yew San Hor Jul 2017

Determination Of The Energy Band Gap Of Bi₂Se₃, G. Martinez, B. A. Piot, M. Hakl, M. Potemski, Yew San Hor

Physics Faculty Research & Creative Works

Despite intensive investigations of Bi2Se3 in past few years, the size and nature of the bulk energy band gap of this well-known 3D topological insulator still remain unclear. Here we report on a combined magneto-transport, photoluminescence and infrared transmission study of Bi2Se3, which unambiguously shows that the energy band gap of this material is direct and reaches Eg = (220 ± 5) meV at low temperatures.


Thermal Quenching Of Photoluminescence In Zno And Gan, Nahla Albarakati Jan 2017

Thermal Quenching Of Photoluminescence In Zno And Gan, Nahla Albarakati

Theses and Dissertations

Investigation of the thermal quenching of photoluminescence (PL) in semiconductors provides valuable information on identity and characteristics of point defects in these materials, which helps to better understand and improve the properties of semiconductor materials and devices. Abrupt and tunable thermal quenching (ATQ) of PL is a relatively new phenomenon with an unusual behavior of PL. This mechanism was able to explain what a traditional model failed to explain. Usually, in traditional model used to explain “normal” quenching, the slope of PL quenching in the Arrhenius plot determines the ionization energy of the defect causing the PL band. However, in …


A Transfer Matrix Approach To Aid In The Design And Optimization Of Hybrid Advanced Passive Structures For Enhancing Photovoltaic Efficiency, James Walshe, Sarah Mccormack, Hind Ahmed, John Doran Jan 2017

A Transfer Matrix Approach To Aid In The Design And Optimization Of Hybrid Advanced Passive Structures For Enhancing Photovoltaic Efficiency, James Walshe, Sarah Mccormack, Hind Ahmed, John Doran

Conference Papers

The addition of a luminescent down-shifting (LDS) layer directly onto a photovoltaic (PV) cell introduces additional loss mechanisms within the system. The combination of non-ideal photo-luminescent materials encapsulated within a limited range of viable host materials, with the increased reflection losses arising from the newly created interface represent losses which must be overcome for LDS to offer an enhancement to the underlying cells efficiency. Exploiting the interaction between the highly enhanced electric fields established close to a metal nanoparticles (MNP’s) surface is one route aimed at mitigating the poor optical properties of the luminophore-host combinations available. Alternative approaches, aimed at …


Study Of The Photoluminescence Spectra Of Mg-Doped Gan, Puranjan Ghimire Jan 2017

Study Of The Photoluminescence Spectra Of Mg-Doped Gan, Puranjan Ghimire

Theses and Dissertations

We have studied luminescence properties of Mg-doped GaN grown by hydride vapor phase epitaxy. Steady state photoluminescence (PL) spectra have been analyzed. Exciton, ultraviolet luminescence (UVL) and blue luminescence (BL) bands are the dominant PL bands in the spectra. At low temperature, Exciton and UVL bands show almost no shift with excitation intensity, whereas the BL band blueshifts by almost 0.4 ���� with increasing excitation intensity by seven orders of magnitude. Such shifting nature of bands with excitation intensity is explained by assuming that the BL band is detected from the region of the sample where potential fluctuations are very …


Light Soaking Phenomena In Organic-Inorganic Mixed Halide Perovskite Single Crystals, Hye Ryung Byun, Dae Young Park, Hye Min Oh, Gon Namkoong, Mun Seok Jeong Jan 2017

Light Soaking Phenomena In Organic-Inorganic Mixed Halide Perovskite Single Crystals, Hye Ryung Byun, Dae Young Park, Hye Min Oh, Gon Namkoong, Mun Seok Jeong

Electrical & Computer Engineering Faculty Publications

Recently, organic inorganic mixed halide perovskite (MAPbX3; MA = CH3NH3+, X = Cl-, Br-, or I-) single crystals with low defect densities have been highlighted as candidate materials for high-efficiency photovoltaics and optoelectronics. Here we report the optical and structural investigations of mixed halide perovskite (MAPbBr3-xIx) single crystals. Mixed halide perovskite single crystals showed strong light soaking phenomena with light illumination conditions that were correlated to the trapping and detrapping events from defect sites. By systematic investigation with optical analysis, we found that the …


Quantum Dot Band Gap Investigations, John Ryan Peterson Nov 2016

Quantum Dot Band Gap Investigations, John Ryan Peterson

Student Works

Improving solar panel efficiency has become increasingly important as the world searches for cheap renewable energy. Recent developments in the industry have focused on multi-layer cells, some of which use semiconducting dyes to absorb light in place of crystalline solids. In this paper, I characterize various dyes recently synthesized for use in solar panels. These dyes contain semiconducting nanoparticles enclosed primarily by the protein ferritin to limit particle size. The band gaps were measured using either optical absorption spectroscopy or measuring the photoluminescence spectrum, depending on the type of semiconductor. The results indicate that both manganese oxide and lead sulfide …


Direct Bandgap Cross-Over Point Of Ge1-YSnY Grown On Si Estimated Through Temperature-Dependent Photoluminescence Studies, Thomas R. Harris, Mee-Yi Ryu, Yung Kee Yeo, Buguo Wang, C. L. Senaratne Aug 2016

Direct Bandgap Cross-Over Point Of Ge1-YSnY Grown On Si Estimated Through Temperature-Dependent Photoluminescence Studies, Thomas R. Harris, Mee-Yi Ryu, Yung Kee Yeo, Buguo Wang, C. L. Senaratne

Faculty Publications

Epitaxial Ge1-ySny (y = 0%–7.5%) alloys grown on either Si or Ge-buffered Si substrates by chemical vapor deposition were studied as a function of Sn content using temperature-dependent photoluminescence (PL). PL emission peaks from both the direct bandgap (Γ-valley) and the indirect bandgap (L-valley) to the valence band (denoted by ED and EID, respectively) were clearly observed at 125 and 175 K for most Ge1-ySny samples studied. At 300 K, however, all of the samples exhibited dominant ED emission with either very weak or no measureable EID emission. At 10 K, …