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Articles 421 - 450 of 37176
Full-Text Articles in Electrical and Computer Engineering
Laser-Induced Acoustic Signal Generation, Resonance Characterization, And Optical Sensing In Metallic Plates, Xinghang Zhao
Laser-Induced Acoustic Signal Generation, Resonance Characterization, And Optical Sensing In Metallic Plates, Xinghang Zhao
All Theses
This thesis investigates laser-induced acoustic signal generation, resonance characterization, and optical sensing in metallic plates as a foundational study for damage-sensitive inspection. Rather than presenting a complete defect-detection system, the work focuses on how measurable acoustic responses can be generated, amplified, and interpreted in a controlled laboratory setting. Experiments showed that pulsed-laser excitation can produce strong and repeatable acoustic responses in metallic structures. Repetition-rate sweeping identified narrow resonant responses, including a cantilever resonance at 57.862 kHz and a maximum circular-disk response at an FFT frequency of 48.8 kHz with a laser repetition rate of about 49.1 kHz. High-Q resonances exceeding …
Enhanced Situational Awareness Of Solar Pv Plants For Near Real-Time Planning And Operation In Modern Power Systems, Michael A. Walters
Enhanced Situational Awareness Of Solar Pv Plants For Near Real-Time Planning And Operation In Modern Power Systems, Michael A. Walters
All Theses
Solar photovoltaic (PV) plant development and utilization is increasing worldwide but remains intrinsically challenged by its large dependence on highly variable weather conditions and operating states. This paper presents a framework to leverage three new situational awareness indices (SAIs), namely: weather condition index (WCI) to gauge operational performance based on environmental states, operational complexity index (OCI) to indicate the severity of power generation reductions, and photovoltaic generation index (PVGI) to provide a final determination of the impact on power generation and to bolster situational awareness in planning and operational contexts for solar PV plants. This is accomplished by exploiting the …
Development Of Low-Cost Triaxial Force Sensor For Measurement Of Human-Exoskeleton Interaction Forces, Hamdan Khan Sarvathullah
Development Of Low-Cost Triaxial Force Sensor For Measurement Of Human-Exoskeleton Interaction Forces, Hamdan Khan Sarvathullah
All Theses
Contemporary research suggests that shear force is a major contributor to discomfort and pressure injury. However, the variation of shear forces during human-exoskeleton interaction dynamics is a highly unexplored field. The high cost of commercial triaxial force sensors may be a major factor in the notable lack of research in this field. Therefore, in this paper, we present a low-cost, 3D-printed triaxial force sensor designed specifically to measure the triaxial interaction forces between an exoskeleton and its user. The triaxial force sensor uses Carbon-Black/Silicone Rubber (CB/SR) strings to measure shear forces, whereas the normal force is measured with a Force …
Design And Optimization To Advance Silicon Carbide Modules For Medium Voltage High Power Applications, Ahmed Ismail
Design And Optimization To Advance Silicon Carbide Modules For Medium Voltage High Power Applications, Ahmed Ismail
Graduate Theses and Dissertations
The commercial availability of the first 10 kV silicon carbide (SiC) MOSFET removes the principal semiconductor barrier to medium-voltage power conversion, enabling converter topologies that are structurally inaccessible to silicon IGBT solutions at this voltage class. This dissertation presents the characterization infrastructure, device-level data, and preliminary system-level validation needed to advance the deployment of the third-generation 10 kV SiC MOSFET in converter applications. A custom-built 10 kV double-pulse test platform is developed with a fully documented component-sizing methodology, custom medium-voltage magnetics, and a measurement infrastructure capable of high bandwidth waveform capture at kilovolt common-mode potentials. On this platform, the third-generation …
Simultaneous Carrier, Cargo, And Functional Tracking Of Lipid Nanoparticles, Hannia Vanessa Balcorta Muñoz
Simultaneous Carrier, Cargo, And Functional Tracking Of Lipid Nanoparticles, Hannia Vanessa Balcorta Muñoz
Open Access Theses & Dissertations
Lipid nanoparticles (LNPs) have become effective delivery vehicles in nanomedicine, particularly for nucleic acid-based treatments. However, a major limitation remains in the field regarding the simultaneous monitoring of the nanoparticle carrier, its encapsulated payload, and the resulting functional protein production in both in vitro and in vivo systems. Furthermore, traditional lipophilic dyes employed for labeling LNPs frequently exhibit incompatibility with tissue-clearing methods, such as CLARITY, due to signal loss following lipid removal. This research developed and evaluated a new fluorescent labeling method using CM-DiI, a dye that reacts with thiols, for multimodal tracking of LNPs. CM-DiI was included in the …
Quantifying Spatiotemporal Ev In-Motion Load Dynamics For Flexible Distribution Grid Operations, Travis Newbolt
Quantifying Spatiotemporal Ev In-Motion Load Dynamics For Flexible Distribution Grid Operations, Travis Newbolt
Open Access Theses & Dissertations
The emergence of novel in-motion Electric Vehicle (EV) charging through Dynamic Wireless Power Transfer (DWPT) technology is enabling the transformation of traditional roadway infrastructures into fully integrated Electrified Transportation Networks (ETNs) by the direct coupling of roadways with electric power grids. This paradigm has the potential to improve charging safety, extend driving ranges, reduce EV manufacturing costs through smaller battery sizes, and shift EV charging demand to periods when Distributed Energy Resources (DERs) are more readily available. In addition, the transition to ETNs can improve air quality and reduce noise pollution by displacing fossil fuel consumption from vehicles to centralized …
Design And Simulation Of Anti-Resonant Hollow-Core Fiber For Sensing Applications, Pravallika Kante
Design And Simulation Of Anti-Resonant Hollow-Core Fiber For Sensing Applications, Pravallika Kante
Theses and Dissertations
This thesis presents the design and simulation of an 8-tube single-ring anti-resonant hollow-core fiber for sensing applications, with particular emphasis on methane gas detection at the fundamental absorption wavelength of 3.3 µm. Conventional solid-core silica optical fibers exhibit strong multi-phonon material absorption beyond 2.5 µm, rendering them fundamentally unsuitable for efficient light guidance and direct gas sensing at mid-infrared wavelengths. Anti-resonant hollow-core fibers overcome this limitation by guiding light predominantly through an air-filled hollow core via the anti-resonant reflecting optical waveguide mechanism, in which the thin silica glass walls of the cladding tubes act as Fabry-Pérot etalons that confine the …
Optimization-Based Power Management For Hybrid Towing Vessels: A Comparative Framework Toward Mission-Aware Control, Rachel K. Burchill
Optimization-Based Power Management For Hybrid Towing Vessels: A Comparative Framework Toward Mission-Aware Control, Rachel K. Burchill
LSU New Orleans Theses and Dissertations
This thesis presents an optimization-based framework for power management in hybrid towing vessels operating under dynamic mission conditions. A physically consistent modeling approach is developed, incorporating battery state-of-charge dynamics (SOC), unified power flow, and operational constraints. The framework evaluates rule-based control using fixed heuristic thresholds, Particle Swarm Optimization (PSO), Genetic Algorithm (GA), and multi-objective Non-Dominated Sorting Genetic Algorithm II (NSGA-II) under a representative harbor-assist mission profile. Results show that optimization-based methods significantly outperform rule-based control. PSO achieves the lowest fuel consumption and near-perfect tracking with minimal battery use, while GA provides balanced performance with moderate battery utilization. NSGA-II reveals a …
Experimental Data-Driven System Identification Of Scale-Model Airboat Dynamics For Control And Autonomy Applications, Miguel A. Trejos
Experimental Data-Driven System Identification Of Scale-Model Airboat Dynamics For Control And Autonomy Applications, Miguel A. Trejos
LSU New Orleans Theses and Dissertations
To achieve autonomous control of a surface watercraft requires an accurate model describing the dynamics of the system. To this end, the modeling of dynamics of an airboat with a combustion engine-based propulsion system is investigated. Specifically, a black-box data-based approach using neural networks. To facilitate this, a custom data collection system was developed to record linear and rotational motion during field tests. Due to the airboats unique ability to traverse different terrains, not just water, the modeling of dynamics on different terrains was investigated.
Power System Small-Signal Stability Migration And Metric Trends In A Test System With Increasing Ibr Penetration, Brandon Marshall
Power System Small-Signal Stability Migration And Metric Trends In A Test System With Increasing Ibr Penetration, Brandon Marshall
LSU New Orleans Theses and Dissertations
With the increasing demand of cleaner energy, inverter-based resources (IBRs) provide a greener alternative to traditional generation methods. IBRs fundamentally work different from traditional generators, though, and power system stability will change as IBRs are integrated into the system. The limitations of IBRs include providing less reactive power support to the system and lacking a spinning rotor for inertia to dampen disturbances. This study examines how small-signal stability is impacted when increasing IBR penetration on a test system. Stability impacts are realized by the migration of eigenvalues and relationships between power system metrics and small-signal stability metrics.
A Low Power Fpga Compute Array For Machine Learning And Artificial Intelligence Applications, Todd Wilson
A Low Power Fpga Compute Array For Machine Learning And Artificial Intelligence Applications, Todd Wilson
All Graduate Theses and Dissertations, Fall 2023 to Present
Modern small satellites often lack the ability to analyze their data in real time, relying instead on downlinking raw measurements to Earth before any scientific interpretation can occur. This delay restricts missions that require rapid awareness of environmental or space-weather events. This thesis presents the Low-power Array for Cubesat Edge Computing Architecture, Algorithms, and Applications (LACE-C3A), a hardware platform designed to enable in-orbit data processing within the power and volume limits of CubeSat-class spacecraft.
LACE-C3A uses a modular cluster of flash-based FPGAs, which offer low power consumption, radiation resilience, and in-flight reconfigurability. The system consists of a Controller board responsible …
Dynamic Load Assessment Of Pem Fuel Cell Systems Under Pid-Based Control Strategies For Sustainable Operation, Tarek Abedin, Paw, Normy Norfiza Abdul Razak, Chen Chai Phing, Yaw Chong Tak, Monowar Mahmud, Manzoore Elahi M. Soudagar, T. M. Yunus Khan, Mohammad Tariqul Islam, Mohammad Nur-E-Alam
Dynamic Load Assessment Of Pem Fuel Cell Systems Under Pid-Based Control Strategies For Sustainable Operation, Tarek Abedin, Paw, Normy Norfiza Abdul Razak, Chen Chai Phing, Yaw Chong Tak, Monowar Mahmud, Manzoore Elahi M. Soudagar, T. M. Yunus Khan, Mohammad Tariqul Islam, Mohammad Nur-E-Alam
Research outputs 2022 to 2026
Proton exchange membrane fuel cell (PEMFC) systems’ reliable operation under variable load conditions is a significant challenge because of voltage fluctuations, transient variations, and the high computational requirements of sophisticated control techniques like intelligent and model predictive controllers. Even while these state-of-the-art methods provide great precision, complexity and cost often limit their real-time applicability, underscoring the need for a simpler but efficient control solution. To achieve effective voltage regulation in PEMFC systems, this study suggests a DC–DC buck converter in conjunction with a comparator-based proportional–integral–derivative (PID) control technique. In order to provide stable operation under both constant and changing load …
A Low-Cost Motion Classification System For A Stuffed Animal Using An Imu And Machine Learning, Rachel N. Guynes
A Low-Cost Motion Classification System For A Stuffed Animal Using An Imu And Machine Learning, Rachel N. Guynes
Honors Theses
One of the many fields that has seen the integration of robots is therapy. Zoomorphic robots (ZR) are designed to look and behave like animals to assist in Animal Assisted Therapy (AAT) practices. Studies show that ZRs can provide benefits similar to working with an actual animal; however, their high cost limits their accessibility. This thesis documents the process of building a real-time, low-cost motion classification system that can be attached to a stuffed animal to make it more interactive. Using a Random Forest (RF) classifier, the system identifies movements with approximately 81.67% accuracy.
Increasing The Prediction Accuracy Of Plant Oil Production Processes Through Adjusting The Parameters Of Machine Learning Models, Umidjon Ruziev, M.K. Shodiev, A.T. Rajabov
Increasing The Prediction Accuracy Of Plant Oil Production Processes Through Adjusting The Parameters Of Machine Learning Models, Umidjon Ruziev, M.K. Shodiev, A.T. Rajabov
Chemical Technology, Control and Management
Vegetable oil production is characterized by high variability in output indicators due to nonlinear interactions between raw material parameters, equipment modes, and heat and mass transfer conditions. Existing approaches to applying machine learning in this field, as a rule, do not account for the impact of hyperparameter adjustments on forecasting quality across specific technological stages. The article presents a systematic methodology for adjusting model parameters (Ridge regression, SVR, GBM, LSTM) applied to three key tasks: predicting residual oil content in oil cake, color index during bleaching, and free fatty acid content during deodorization. In a set of 1000 observations, including …
Intelligent Manufacturing Of Edible Oil: From Smart Sensing To Big Data Platform, Ru Jiang, Nadirbek Yusupbekov
Intelligent Manufacturing Of Edible Oil: From Smart Sensing To Big Data Platform, Ru Jiang, Nadirbek Yusupbekov
Chemical Technology, Control and Management
With the rapid advancement of Industry 4.0 technologies, intelligent manufacturing and big data platforms are profoundly transforming the production models of the traditional edible oil industry. The edible oil production process involves multiple complex unit operations such as refining, decolorization, and deodorization, which impose high requirements on process control and product quality monitoring. This paper presents a systematic review of key technological advances in the field of intelligent manufacturing of edible oil, establishing a comprehensive technical framework encompassing four dimensions: smart sensing, artificial intelligence applications, IoT communication, and big data platforms. The review begins by analyzing the global background and …
Reliability Analysis Of Separator Control Systems, D.P. Muxitdinov, O.U. Sattarov, M.Sh. Nematov
Reliability Analysis Of Separator Control Systems, D.P. Muxitdinov, O.U. Sattarov, M.Sh. Nematov
Chemical Technology, Control and Management
This article aims to enhance the reliability, efficiency, and diagnostic capabilities of gas-liquid separators operating in hazardous technological processes. In the study, the separator is considered as a critical functional unit of an industrial system and is analyzed through structural and functional decomposition. The main operating parameters of the separator, including pressure drop (ΔP), separation efficiency and operational state are described on the basis of a mathematical model. In addition, a state model is developed for normal operation, foaming, liquid droplet carryover with the gas flow, and failure conditions. Emphasis is placed on diagnostic and monitoring issues, …
Data-Driven Neuro-Fuzzy Modeling And Rule Optimization For Intelligent Prediction Of Bioreactor Dynamics, Kamala Najaf Mammadzada
Data-Driven Neuro-Fuzzy Modeling And Rule Optimization For Intelligent Prediction Of Bioreactor Dynamics, Kamala Najaf Mammadzada
Chemical Technology, Control and Management
Modeling wastewater bioreactors is a challenging problem in environmental engineering because the processes are constantly changing and the microorganisms do not behave in a linear or predictable way. This makes it difficult to predict and control the system behavior. This research investigates three artificial intelligence approaches for modeling wastewater bioreactors: the Mamdani Fuzzy Inference System (FIS), the Adaptive Neuro-Fuzzy Inference System (ANFIS), and clustering-based fuzzy models. These models help us predict what is happening in the bioreactors. For instance they help us predict how the amount of substances in the water is changing over time like dS0/dt dSs/dt …
Analysis Of Automatic Control Of The Channels And Ditches Cleaning Mechanism Based On Dynamic Indicators, Nasiba Siraj Amirbayova
Analysis Of Automatic Control Of The Channels And Ditches Cleaning Mechanism Based On Dynamic Indicators, Nasiba Siraj Amirbayova
Chemical Technology, Control and Management
The article deals with the automated design and experimental investigation of reinforced concrete irrigation channels and ditches, their interrelated channel-cleaning mechanisms, which are complex mechatronic systems integrating hydraulic, mechanical, and electronic components. A thorough methodology is suggested, hydrodynamic modeling, combining parametric analysis, and information-based design support to enhance channel concrete cover thickness, geometry, and cleaning system performance. Main structural parameters—involving channel depth, slope, bottom width, and concrete cover—are systematically defined and shown in matrix form to facilitate automated calculation and decision-making. Experimental prototypes and Solid Edge-based digital models are employed to verify the methodology, revealing vital interdependencies between structural parameters, …
Regular Synthesis Algorithms Of Control Devices In Nonlinear Control Systems, Husan Zakirovich Igamberdiyev, Iskandar Yusupovich Abdurakhmanov, Uktam Farkhodovich Mamirov
Regular Synthesis Algorithms Of Control Devices In Nonlinear Control Systems, Husan Zakirovich Igamberdiyev, Iskandar Yusupovich Abdurakhmanov, Uktam Farkhodovich Mamirov
Chemical Technology, Control and Management
This paper examines the development of regularized algorithms for synthesizing control devices in control systems for polynomial objects, described by multidimensional Volterra functional series. The synthesis problem is solved using a two-stage procedure. In the first stage, the optimization problem is initially solved for an open-loop system. The second stage involves determining the parameters of the control device, i.e., its impulse response functions, by using the relationship between the characteristics of the open-loop and closed-loop systems. Regular algorithms are presented for finding the impulse response functions of the control device based on methods for regularizing the solution of operator equations …
Rdm Interval Arithmetic Based Weapon System Evaluation, Konul Imran Jabbarova Phd
Rdm Interval Arithmetic Based Weapon System Evaluation, Konul Imran Jabbarova Phd
Chemical Technology, Control and Management
For solving this issue, the paper considers a hierarchical multi-criteria decision-making problem, where the choice of a company that corresponds best to the criteria is required. Data used in this problem are presented in the form of intervals, which makes it possible to cope with uncertainty in the problem solution. Several companies working in missile production industry are chosen as alternatives for analysis. Evaluation of the selected alternatives is made based on five criteria clusters. More than twenty criteria are taken into account during evaluation.
Solving this problem is achieved with the help of the technique based on computation of …
Structural Decomposition-Based Control Synthesis For Multivariable Systems Using Oblique Projection Operators, Abdukaxxarov Inomjon Ilxom Ugli Mr, Oripjon Olimovich Zaripov, Jasur Usmonovich Sevinov
Structural Decomposition-Based Control Synthesis For Multivariable Systems Using Oblique Projection Operators, Abdukaxxarov Inomjon Ilxom Ugli Mr, Oripjon Olimovich Zaripov, Jasur Usmonovich Sevinov
Chemical Technology, Control and Management
This paper proposes a novel approach to control synthesis for multivariable systems with algebraic constraints using oblique projection operators and their structural decomposition. The method transforms a standard control law into a structured form by decomposing the control input into constraint-satisfying and null-space components. A generalized oblique projector is constructed using a dual matrix, ensuring flexibility in shaping system properties. Furthermore, a recursive decomposition algorithm is developed, allowing the global projector to be represented as a sum of local operators corresponding to subsystem structures. The proposed framework enables modular control design, decoupling of interactions, and efficient implementation for large-scale systems. …
Conceptual Model For Protecting Personal Data By Depersonalization In Information Systems: Principles, Components, And Life Cycle, Zarina Ildarovna Azizova
Conceptual Model For Protecting Personal Data By Depersonalization In Information Systems: Principles, Components, And Life Cycle, Zarina Ildarovna Azizova
Chemical Technology, Control and Management
This article presents a systematic approach to personal data protection through depersonalization in the context of regulatory pressure and growing cyber threats. It proposes a comprehensive conceptual model that formalizes the de-identification process as a manageable sequence of steps, from attribute classification and method selection to mandatory verification of the result. The article also provides a comparative analysis of existing depersonalization methods in terms of their applicability within the proposed model. The model serves as a basis for the development of specific algorithms, as demonstrated by the example of a data shuffling approach.
Efficient Energy Management In Networked Microgrids Using Multi-Agent Deep Reinforcement Learning In The Presence Of Uncertainties, Ayodele Benjamin Chukwuyem
Efficient Energy Management In Networked Microgrids Using Multi-Agent Deep Reinforcement Learning In The Presence Of Uncertainties, Ayodele Benjamin Chukwuyem
Thesis/ Dissertation Defenses
Microgrid technology is essential in facilitating the transition to smart energy grids in developed countries and mitigating energy poverty in developing countries, particularly in areas where grid extensions are not feasible. Recently, the concept of networked microgrids (NMGs) has garnered tremendous attention due to the plausibility of interactions among interconnected microgrids leading to power networks that are more resilient, reliable, and stable. However, because each microgrid has diverse distributed generation resources (renewables and controllable generators) and each microgrid operator (MO) has different objectives, coordinated energy management is required to satisfy local and system-wide goals under conditions with significant uncertainty. Existing …
The Pid-Based Three Quadcopter Uavs Formation Control Under External Disturbance, Vo Van An, Trinh Luong Mien
The Pid-Based Three Quadcopter Uavs Formation Control Under External Disturbance, Vo Van An, Trinh Luong Mien
Makara Journal of Technology
This paper presents the design and evaluation of a formation control strategy for three quadcopter UAVs, based on a PID controller in a leader–follower structure, under the influence of external disturbances. Each UAV employs a six-degree of-freedom dynamic model and utilises a cascade PID control architecture, in which the inner control loop stabilises the attitude. In contrast, the outer control loop regulates position and maintains the formation. The PID parameters are tuned using the Ziegler–Nichols method to ensure simple implementation and low computational cost. The performance of the control system is evaluated through simulations in the MATLAB environment for two …
A Low-Noise And High-Gain Integrated Photoplethysmography Sensor For Continuous Vital Signs Monitoring, Neethu Mohan
A Low-Noise And High-Gain Integrated Photoplethysmography Sensor For Continuous Vital Signs Monitoring, Neethu Mohan
Thesis/ Dissertation Defenses
Photoplethysmography (PPG) sensing is an important technology used for measuring health parameters like, heart rate, respiratory rate, blood oxygen saturation, and blood pressure (BP). The PPG sensing is used for individuals who have to periodically monitor their health due to chronic health conditions. The basic requirements of a wearable PPG sensor include non-invasiveness, prolonged battery life, and being user-friendly. These type of sensors have great demand in the healthcare applications and there is a significant rise in the demand of these sensors. The basic objective of these PPG sensors is to make the continuous vital health monitoring easier without the …
Wavetable Modification In Frequency Domain: Fourier Analysis With Matlab Implementation, Caleb Kortens
Wavetable Modification In Frequency Domain: Fourier Analysis With Matlab Implementation, Caleb Kortens
Senior Honors Theses
One of the challenges in creating computer generated music is producing life-like sounds. Music produced through computer synthesis can often sound thin and synthetic rather than vibrant and energetic. Wavetable synthesis is a method of waveform generation that uses a wavetable, which is a set of single period waves, or frames, that have varying characteristics. This method allows a synthesizer to transition between waveforms to produce a sound with time varying tone and harmonic characteristics. This adds life and movement to computer generated sounds. Wavetable synthesis is often used to imitate actual instruments, but unique wavetables can be created that …
On Time-Series Analysis By Structured Matrix Decompositions With Applications To Signal Direction-Of-Arrival Estimation, Georgios Ierotheos Orfanidis
On Time-Series Analysis By Structured Matrix Decompositions With Applications To Signal Direction-Of-Arrival Estimation, Georgios Ierotheos Orfanidis
Electronic Theses and Dissertations 2020 - Present
Modern autonomous systems operating in highly dynamic, non-stationary environments require reliable inference from short, potentially corrupted time-series measurements, where conventional statistical methods relying on large-sample support and stationarity assumptions become fundamentally inapplicable. This dissertation develops a unified, model-free theoretical framework for time-series analysis, with a particular application to signal Direction-of-Arrival (DoA) estimation, grounded in structured matrix decompositions under both the L2-norm and L1-norm formulations.
We first approach the problem from a conventional viewpoint by carrying out standard matrix analysis directly on Hankel-structured representations of time-series data. In this context, we demonstrate that L1-norm decompositions of Hankel matrices offer strong resistance …
Insertion Of Noble Metal Free Cathodic Catalyst Layer With Fe-N-C Catalyst For Boosted Performance Of Pemfc, Shi Zhou, Muhammad Tariq, Asif Nadeem Tabish, Muhammad Salman, Fan-Di Ning, Muhammad Rayyan Tayyab, Ran-Ran Peng, Meng-Geng Hao, Wen-Mu Li, Xiao-Chun Zhou
Insertion Of Noble Metal Free Cathodic Catalyst Layer With Fe-N-C Catalyst For Boosted Performance Of Pemfc, Shi Zhou, Muhammad Tariq, Asif Nadeem Tabish, Muhammad Salman, Fan-Di Ning, Muhammad Rayyan Tayyab, Ran-Ran Peng, Meng-Geng Hao, Wen-Mu Li, Xiao-Chun Zhou
Journal of Electrochemistry
Economical Fe-N-C catalysts are considered as promising alternatives to platinum group metal catalysts for proton exchange membrane fuel cells (PEMFCs). Despite exhibiting robust activity on rotating disk electrodes, their performance within membrane electrode assemblies often experiences limitations, such as decreased O2 diffusion, high H2O2 formation, low proton conduction, and a lower electron transfer number. In this study, key factors, including proton transport, electron conduction, and gas diffusion within air-breathing PEMFCs, have been investigated by adjusting cathode catalyst layer (CCL) compositions. From the experimental results, the optimal peak power density was obtained when the loading of Fe-N-C …
Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu
Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu
Journal of Electrochemistry
Homogeneous electrocatalytic nitrogen reduction reaction (NRR) provides a powerful framework to interrogate molecular nitrogen-fixation pathways under mild conditions. By tuning the metal center, ligand architecture, and reaction medium, these systems enable capturing key intermediates and delivering mechanistic insight at the molecular-level resolution. Nevertheless, advances remain constrained by highly reduced operating potentials, intense competition from the hydrogen evolution reaction (HER), limited durability in turnover, and inadequate long-term stability.
In this review, we take electron delivery to the molecular active site as the guiding principle for organizing homogeneous electrochemical N2 activation and transformation. We classify reported systems into direct electron transfer …
Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li
Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li
Journal of Electrochemistry
Flow-cell architectures have emerged as a powerful platform for continuous and stable lithium-mediated nitrogen reduction (Li-NRR), enabling ambient-condition electrochemical ammonia synthesis and offering a promising alternative to Haber-Bosch processes. However, Li-NRR is exceptionally sensitive to trace water, and even minor variations in water content can profoundly alter interfacial chemistry. Here, we systematically investigate how initial water concentration affects Li-NRR performance in a continuous-flow cell. Excess water drives the formation of a thick solid electrolyte interphase (SEI) layer, which may impede nitrogen access to metallic lithium and hinder lithium-ion transport. As a result, the ammonia Faradaic efficiency collapses from ~61% to …