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2018

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Articles 1 - 30 of 1644

Full-Text Articles in Electrical and Computer Engineering

Wireless Coverage Using Unmanned Aerial Vehicles, Hazim Shakhatreh Dec 2018

Wireless Coverage Using Unmanned Aerial Vehicles, Hazim Shakhatreh

Dissertations

The use of unmanned aerial vehicles (UAVs) is growing rapidly across many civilian application domains including real-time monitoring, search and rescue, and wireless coverage. UAVs can be used to provide wireless coverage during emergency cases where each UAV serves as an aerial wireless base station when the cellular network goes down. They can also be used to supplement the ground base station in order to provide better coverage and higher data rates for the users. During such situations, the UAVs need to return periodically to a charging station for recharging, due to their limited battery capacity. Given the recharging requirements, …


Impairments In Ground Moving Target Indicator (Gmti) Radar, Phuoc Doan Huu Vu Dec 2018

Impairments In Ground Moving Target Indicator (Gmti) Radar, Phuoc Doan Huu Vu

Dissertations

Radars on multiple distributed airborne or ground based moving platforms are of increasing interest, since they can be deployed in close proximity to the event under investigation and thus offer remarkable sensing opportunities. Ground moving target indicator (GMTI) detects and localizes moving targets in the presence of ground clutter and other interference sources. Space-time adaptive processing (STAP) implemented with antenna arrays has been a classical approach to clutter cancellation in airborne radar. One of the challenges with STAP is that the minimum detectable velocity (MDV) of targets is a function of the baseline of the antenna array: the larger the …


Optimizing Resource Allocation In Eh-Enabled Internet Of Things, Ali Shahini Dec 2018

Optimizing Resource Allocation In Eh-Enabled Internet Of Things, Ali Shahini

Dissertations

Internet of Things (IoT) aims to bridge everyday physical objects via the Internet. Traditional energy-constrained wireless devices are powered by fixed energy sources like batteries, but they may require frequent battery replacements or recharging. Wireless Energy Harvesting (EH), as a promising solution, can potentially eliminate the need of recharging or replacing the batteries. Unlike other types of green energy sources, wireless EH does not depend on nature and is thus a reliable source of energy for charging devices. Meanwhile, the rapid growth of IoT devices and wireless applications is likely to demand for more operating frequency bands. Although the frequency …


Characterization Of Self-Heating Effects And Assessment Of Its Impact On Reliability In Finfet Technology, Peter Christopher Paliwoda Dec 2018

Characterization Of Self-Heating Effects And Assessment Of Its Impact On Reliability In Finfet Technology, Peter Christopher Paliwoda

Dissertations

The systematically growing power (heat) dissipation in CMOS transistors with each successive technology node is reaching levels which could impact its reliable operation. The emergence of technologies such as bulk/SOI FinFETs has dramatically confined the heat in the device channel due to its vertical geometry and it is expected to further exacerbate with gate-all-around transistors.

This work studies heat generation in the channel of semiconductor devices and measures its dissipation by means of wafer level characterization and predictive thermal simulation. The experimental work is based on several existing device thermometry techniques to which additional layout improvements are made in state …


Load Balancing And Scalable Clos-Network Packet Switches, Oladele Theophilus Sule Dec 2018

Load Balancing And Scalable Clos-Network Packet Switches, Oladele Theophilus Sule

Dissertations

In this dissertation three load-balancing Clos-network packet switches that attain 100% throughput and forward cells in sequence are introduced. The configuration schemes and the in-sequence forwarding mechanisms devised for these switches are also introduced. Also proposed is the use of matrix analysis as a tool for throughput analysis.

In Chapter 2, a configuration scheme for a load-balancing Clos-network packet switch that has split central modules and buffers in between the split modules is introduced. This switch is called split-central-buffered Load-Balancing Clos-network (LBC) switch and it is cell based. The switch has four stages, namely input, central-input, central-output, and output stages. …


Storage Systems For Mobile-Cloud Applications, Nafize R. Paiker Dec 2018

Storage Systems For Mobile-Cloud Applications, Nafize R. Paiker

Dissertations

Mobile devices have become the major computing platform in todays world. However, some apps on mobile devices still suffer from insufficient computing and energy resources. A key solution is to offload resource-demanding computing tasks from mobile devices to the cloud. This leads to a scenario where computing tasks in the same application run concurrently on both the mobile device and the cloud.

This dissertation aims to ensure that the tasks in a mobile app that employs offloading can access and share files concurrently on the mobile and the cloud in a manner that is efficient, consistent, and transparent to locations. …


Sistem Buka Tutup Pintu Otomatis Berbasis Suara, Sinta Ariyanti, Slamet Seno Adi, Sugeng Purbawanto Dec 2018

Sistem Buka Tutup Pintu Otomatis Berbasis Suara, Sinta Ariyanti, Slamet Seno Adi, Sugeng Purbawanto

Elinvo (Electronics, Informatics, and Vocational Education)

Biometric identification is one of the media on the operation of the system of home automation are much sought after.This is because conventional identification such as the use of your PIN, password, and a key card is already not enough reliable, in terms of security and how to operate.Biometrics is essentially an introduction to someone based on the unique personality of each person owned such as facial recognition, fingerprints, voice recognition, the introduction of the retina, and signature.Voice recognition is a process to identify a person by recognizing speech from that person.The purpose of this research is to know the …


Rancang Bangun Alarm Deteksi Asap Rokok Dan Kebisingan Pada Ruang Kelas Secara Otomatis Berbasis Mikrokontroler, Imas Dian Ratnasari Dec 2018

Rancang Bangun Alarm Deteksi Asap Rokok Dan Kebisingan Pada Ruang Kelas Secara Otomatis Berbasis Mikrokontroler, Imas Dian Ratnasari

Elinvo (Electronics, Informatics, and Vocational Education)

Abstrak- Asap rokok dan kebisingan merupakan masalah yang sering terjadi di sekolah, sedangkan dalam penanganan masalah asap rokok dan kebisingan di sekolah belum maksimal karena belum terdapat alat yang mampu mendeteksi asap rokok sekaligus kebisingan yang diterapkan di sekolah. Pemantauan kondisi ruang kelas agar tetap kondusif perlu diadakan, maka dari itu dilakukan pengembangan alarm deteksi asap rokok dan kebisingan pada ruang kelas secara otomatis. Penelitian ini bertujuan untuk membantu guru dalam memonitoring kondisi di ruang kelas ketika ruang kelas sedang tidak ada guru. Metode penelitian yang digunakan adalah Research and Development (R&D), yang terdiri dari beberapa tahapan mulai yaitu dari …


Modifikasi Alat Medis Stetoskop Untuk Monitoring Suara Jantung Menggunakan Tampilan Gui Matlab, Dessy Irmawati, Ridho Prasakti Dec 2018

Modifikasi Alat Medis Stetoskop Untuk Monitoring Suara Jantung Menggunakan Tampilan Gui Matlab, Dessy Irmawati, Ridho Prasakti

Elinvo (Electronics, Informatics, and Vocational Education)

Heart sounds are very important for the initial diagnosis of a disease. This article aims to modify the stethoscope's medical device by adding a Low Pass Filter (LPF) and a condenser sensor so that data can be recorded in a digital device. The stages of tool development begin with analysis, design, development and testing. At the analysis stage, it was stated that a conventional medical stethoscope can only be done by a medical expert directly, where data cannot be stored for detailed analysis purposes, the device is not equipped with LPF which can limit the frequency in a certain range, …


Pengatur Suhu Dan Kelembaban Kumbung Jamur Otomatis, Aji Nugroho Dec 2018

Pengatur Suhu Dan Kelembaban Kumbung Jamur Otomatis, Aji Nugroho

Elinvo (Electronics, Informatics, and Vocational Education)

Temperature and humidity have an important role in the cultivation of oyster mushrooms to obtain optimal growth of oyster mushrooms. The optimum temperature required ranges from 24 ° C - 27 ° C and 80% - 90% humidity. The watering of mushroom kumbung should be done regularly, in order to maintain the temperature and humidity of the surrounding air, then conducted research that aims to create a tool that can regulate the temperature and humidity kumbung mushrooms automatically to facilitate farmers keep the temperature and humidity stability continuously. This automatic adjustment system uses DHT-11 sensors as air and humidity and …


Otomasi Sistem Hidroponik Dft (Deep Flow Technique) Berbasis Arduino Android Dengan Memanfaatkan Panel Surya Sebagai Energi Alternatif, Eko Agus Suprayitno Mt, Rohman Dijaya M. Kom, M. Atho㢂¬„¢Illah St Dec 2018

Otomasi Sistem Hidroponik Dft (Deep Flow Technique) Berbasis Arduino Android Dengan Memanfaatkan Panel Surya Sebagai Energi Alternatif, Eko Agus Suprayitno Mt, Rohman Dijaya M. Kom, M. Atho㢂¬„¢Illah St

Elinvo (Electronics, Informatics, and Vocational Education)

The application of hydroponic farming methods has been widely applied by the community, the system used is still manual so that it lacks quality, both in terms of humidity and growth. For that we need a system that is able to regulate the time of watering and the provision of nutritional solutions automatically without disturbing the activity. In the design of an automatic DFT hydroponic system using an Android Arduino based solar panel. Where the solar panel system functions as a renewable energy substitute for PLN which will fill the accumulator. The accumulator filling process is equipped with a solar …


Desain Dan Implementasi Real-Time Visible Light Communication System Berbasis Bpsk, Trio Adiono, Syifaul Fuada Dec 2018

Desain Dan Implementasi Real-Time Visible Light Communication System Berbasis Bpsk, Trio Adiono, Syifaul Fuada

Elinvo (Electronics, Informatics, and Vocational Education)

Salah satu teknik multiplexing yang saat ini populer digunakan untuk aplikasi akses komunikasi cepat berbasis cahaya tampak adalah Orthogonal Frequency Division Multiplexing (OFDM). Meskipun lebih kompleks dibandingkan modulasi berbasis Pulse Time Modulation (PTM), teknik OFDM disinyalir dapat lebih menghemat bandwidth komunikasi karena membagi bandwidth lebar menjadi spektrum yang sempit (sub-carrier) dan saling overlap. Sebagai akibat, transfer data akan lebih cepat dibandingkan PTM. Pada penelitian sebelumnya, penulis telah berhasil mendesain sistem low-cost VLC dengan modulasi digital 1-PWM (3,3 kbps) dan 2-PWM (6,2 kbps). Motivasi dari penelitian ini adalah menigkatkan laju data dengan menggunakan OFDM. Modulasi binary shift-keying modulation …


Reosquido Desalinasi Metode Evaporasi Dengan Ultraviolet Berbasis Mikrokontroller, Muhammad Abdul Azis, Nuryake Fajaryati Dec 2018

Reosquido Desalinasi Metode Evaporasi Dengan Ultraviolet Berbasis Mikrokontroller, Muhammad Abdul Azis, Nuryake Fajaryati

Elinvo (Electronics, Informatics, and Vocational Education)

This research aims to create a Reosquido desalination tool for evaporation methods using a microcontroller. This tool can control the temperature to speed up the evaporation process in producing fresh water. The method applied to Reosquido desalination uses Evaporation. The first process before evaporation is the detection of temperature in sea water that will be heated using an element heater. The second process of temperature measurement is to turn off and turn on the Arduino Uno controlled heater, when the temperature is less than 80 ° then the heater is on. The third process is evaporation during temperatures between 80 …


Orbital Angular Momentum Generation Using Composite Quasi-Continuous Metasurfaces With Perfect Efficiency, Menglin L.N. Chen, Li (Lijun) Jun Jiang Dec 2018

Orbital Angular Momentum Generation Using Composite Quasi-Continuous Metasurfaces With Perfect Efficiency, Menglin L.N. Chen, Li (Lijun) Jun Jiang

Electrical and Computer Engineering Faculty Research & Creative Works

A composite perfect electric conductor (PEC)-perfect magnetic conductor (PMC) metasurface is proposed for orbital angular momentum (OAM) generation. Each scatterer on the metasurface consists of an anisotropic PEC layer and an isotropic PMC layer. Unlike conventional metasurfaces that composed of discrete scatterers, the scatterers on the proposed metasurface form a quasi-continuous pattern. Therefore, negative consequences of periodicity breaking from the patterned scatterers with varying sizes or orientations and their mutual coupling are avoided. We model the scatterer using Jones matrix. Its design is based on the features of PEC and PMC, which abandons complicated optimization process. The patterning of scatterers …


Numerical Modeling Of Graphene Nano-Ribbon By Dgtd Taking Into Account The Spatial Dispersion Effects, Ping Li, L. (Lijun) J. Jiang, H. Baǧci Dec 2018

Numerical Modeling Of Graphene Nano-Ribbon By Dgtd Taking Into Account The Spatial Dispersion Effects, Ping Li, L. (Lijun) J. Jiang, H. Baǧci

Electrical and Computer Engineering Faculty Research & Creative Works

It is well known that graphene demonstrates spatial dispersion properties [1]-[3], i.e., its conductivity is nonlocal and a function of spectral wave number (momentum operator) q. In this work, to fully account for effects of spatial dispersion on transmission of high-speed signals along graphene nanoribbon (GNR) interconnects, a discontinuous Galerkin time-domain (DGTD) algorithm is proposed. The atomically thick GNR is modeled using a nonlocal transparent surface impedance boundary condition (SIBC) [4] incorporated into the DGTD scheme. Since the conductivity is a complicated function of q (and one cannot find an analytical Fourier transform pair between q and spatial differential operators), …


Theory Of Potential-Based Integral-Form A-Φ Formulation In Electromagnetic Applications, Qin S. Liu, Li (Lijun) Jun Jiang, Sheng Sun, Qi Dai, Weng Cho Chew Dec 2018

Theory Of Potential-Based Integral-Form A-Φ Formulation In Electromagnetic Applications, Qin S. Liu, Li (Lijun) Jun Jiang, Sheng Sun, Qi Dai, Weng Cho Chew

Electrical and Computer Engineering Faculty Research & Creative Works

Recent progress on the theory of potential-based A-φ formulationin the integral form and its electromagnetic applications are summarized and presented here. By using Lorenz gauge and solving the vector and scalar potential formulations in tandem, the A-φ formulationac-curately captures the correct physics of both electrostatics and magnetostatics. The wide-band stable, dense-discretization breakdown free and structure-independent solver provides an alternative solution to various electromagnetic scattering and circuital problems. Also, the A-φformulationis applied to solve the characteristic modes at low frequencies.


Icing Thickness Prediction Model For Overhead Transmission Lines, Yue Ming Dec 2018

Icing Thickness Prediction Model For Overhead Transmission Lines, Yue Ming

Theses

Failures in a large electric power system are often inevitable. Severe weather conditions are one of the main causes of transmission line failures. Using the fault data of transmission lines of Shaanxi Power Grid from 2006 to 2016, in conjunction with meteorological information, this paper analyses the relationship between the temporal-spatial distribution characteristics of meteorological disasters and the fault of transmission lines in Shaanxi Province, China.

In order to analyze the influence of micro-meteorology on ice coating, a grey correlation analysis method is proposed. This thesis calculates the grey relational between ice thickness and micro-meteorological parameters such as ambient temperature, …


Amorphous Metal Oxide Semiconductor Thin Film Transistors For Printed Electronics, Mustafa Mohammad Yousef Dec 2018

Amorphous Metal Oxide Semiconductor Thin Film Transistors For Printed Electronics, Mustafa Mohammad Yousef

Theses

There is an acute market need for solution-processable semiconductor inks that can form the essential components of the printed analog and digital circuits. Currently, the industry is migrating beyond simply printing conductive metals for interconnects and embracing higher integration by printing transistors directly on the same substrate. This thesis focuses on investigating solution-processed amorphous indium gallium zinc oxide (IGZO) as a semiconducting channel layer of a field-effect transistor to enable low-cost, large-area printed electronics that are physically flexible and optically transparent. Specifically, we aim to achieve field-effect mobility exceeding 1 cm2/Vs, to overcome the limits faced in existing …


Profiling And Identifying Individual Usersby Their Command Line Usage And Writing Style, Darusalam Darusalam, Helen Ashman Dec 2018

Profiling And Identifying Individual Usersby Their Command Line Usage And Writing Style, Darusalam Darusalam, Helen Ashman

Knowledge Engineering and Data Science

Profiling and identifying individual users is an approach for intrusion detection in a computer system. User profiles are important in many applications since they record highly user-specific information - profiles are basically built to record information about users or for users to share experiences with each other. This research extends previous research on re-authenticating users with their user profiles. This research focuses on the potential to add psychometric user characteristics into the user model so as to be able to detect unauthorized users who may be masquerading as a genuine user. There are five participants involved in the investigation for …


Energy Efficiency Metrics Of University Data Centers, Leonel Hernandez, Genett Jimenez, Piedad Marchena Dec 2018

Energy Efficiency Metrics Of University Data Centers, Leonel Hernandez, Genett Jimenez, Piedad Marchena

Knowledge Engineering and Data Science

The data centers are fundamental pieces in the network and computing infrastructure,and evidently today more than ever they are relevant. Since they support the processing, analysis, assurance of the data generated in the network and by the applications in the cloud, which every day increases its volume thanks to technologies such as Internet of Things, Virtualization, and cloud computing, among others. Precisely the management of this large volume of information makes the data centers consume a lot of energy, generating great concern to owners and administrators. Green Data Centers offer a solution to this problem, reducing the impact produced by …


Signature Pattern Recognition Using Kohonen Network, Nadia Roosmalita Sari, Mohammad Zoqi Sarwani, Yudha Alif Aulia, Wayan Firdaus Mahmudy Dec 2018

Signature Pattern Recognition Using Kohonen Network, Nadia Roosmalita Sari, Mohammad Zoqi Sarwani, Yudha Alif Aulia, Wayan Firdaus Mahmudy

Knowledge Engineering and Data Science

A signature is a special form of handwriting that used for human identification process. The current identification process is extremely ineffective. People have to manually compare signatures with the previously stored data. This study proposed SOM Kohonen algorithm as the method of signature pattern recognition. This method has able to visualize high-dimensional data. The image processing method is used in this study in pre-processing data phase. The accuracy of SOM Kohonen was 70 %, indicated the method used was good enough for pattern recognition.


Digit Classification Of Majapahit Relic Inscriptionusing Glcm-Svm, Tri Septianto, Endang Setyati, Joan Santoso Dec 2018

Digit Classification Of Majapahit Relic Inscriptionusing Glcm-Svm, Tri Septianto, Endang Setyati, Joan Santoso

Knowledge Engineering and Data Science

A higher level of image processing usually contains some kind of classification or recognition. Digit classification is an important subfield in handwritten recognition.Handwritten digits are characterized by large variations so template matching, in general, is inefficient and low in accuracy. In this paper, we propose the classification of the digit of the year of a relic inscription in the Kingdom of Majapahit using Support Vector Machine (SVM). This method is able to cope with very large feature dimensions and without reducing existing features extraction. While the method used for feature extraction using the Gray-Level Co-Occurrence Matrix (GLCM), special for texture …


Change Vulnerability Forecasting For Southeast Asiausing Deep Learning Algorithm, Amelia Ritahani Ismail, Nur 'Atikah Binti Mohd Ali, Junaida Sulaiman Dec 2018

Change Vulnerability Forecasting For Southeast Asiausing Deep Learning Algorithm, Amelia Ritahani Ismail, Nur 'Atikah Binti Mohd Ali, Junaida Sulaiman

Knowledge Engineering and Data Science

Climate change is expected to change people’s livelihood in significant ways. Several vulnerability factors and readiness factors used for measuring the prediction index of that particular country on how vulnerable of a country towards global change. Primary data was collected from University of Notre Dame Global Adaptation Index (NDGAIN). The data has been trained for the forecasting purpose with support from the validated statistical analysis. The summary of the predicted index is visualized using machine learning tools. The results developed the correlation between vulnerability and readiness factors and shows the stability of the country towards climate change. The framework is …


Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang Dec 2018

Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang

Journal of Electrochemistry

In this work, the self-adaptive characteristics of self-humidifying air-cooled PEMFC stack was investigated. The performance and the unit-cell voltage distribution of the stack were measured and analyzed through the unit-cell I-V curve fitting. The operating conditions for this experimental study were set as follows: hydrogen pressure at the anode was 2 bar, the fan power used for the reactant oxygen feed and stack cooling was at 0.3 W, and the duration and time gap of water purged from hydrogen chamber were 1 s and 10 s, respectively. The experimental results showed that the self-humidifying air-cooled PEMFC stack used for this …


Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing Dec 2018

Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

Hydrogen energy technology with hydrogen as an energy carrier is gaining more and more attention due to its cleanliness and high energy density. Hydrogen fuel cell vehicles have been listed as one of the ultimate energy technologies in the 21st century. Among them, sustainable hydrogen production technology is a necessary prerequisite for the future development of hydrogen energy economy. Electrolyzed water technology driven by renewable resources represents an important way to support the sustainable development of hydrogen energy economy. The development and utilization of high activity, low cost hydrogen evolution catalysts is a key factor in improving the efficiency and …


Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan Dec 2018

Fuel Cell Performance Curve After Mea Optimization Structural Optimization Of Low Pt Membrane Electrode Assembly, Yan Rao, Shang Li, Fen Zhou, Tian Tian, Qing Zhong, Zhao-Hui Wan, Jin-Ting Tan, Mu Pan

Journal of Electrochemistry

Membrane electrode assemblies (MEAs) are the key component of proton exchange membrane fuel cell. For a long time, much attention has been paid to develop MEA technology. At present, the research, development and industrialization of fuel cell has entered a new era. More strict requirements for MEA, especially for the reduction of Pt loading with a challenging target of 0.125 mg·W-1 have to be met. In this paper, the performance losses under low Pt loading are analyzed in terms of activation polarization, ohm polarization and mass-transfer polarization. It is proposed that research should be focused on the activity of …


Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao Dec 2018

Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao

Journal of Electrochemistry

The self/non-humidification membrane electrode assembly(SH-MEA)is an important pathway towards the self- humidification fuel cell and plays a crucial role for the large scale commercialization of low temperature proton exchange membrane fuel cell (LT-PEMFC), because it not only can reduce the volume and complexity of fuel cell system, resulting in the decrease of the cost, but also can improve the output power density of the fuel cell system. Currently, the researches on the self-humidifying MEA of LT-PEMFC mainly focus on three aspects: the preparation of self-humidification proton exchange membrane, the construction of self-humidification catalyst layer, and the construction of composite self-humidifying …


Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang Dec 2018

Fe-N Doped Hollow Carbon Nanospheres Linked By Carbon Nanotubes For Oxygen Reduction Reaction, Ya-Lin Zhang, Chi Chen, Liang-Liang Zou, Zhi-Qing Zou, Hui Yang

Journal of Electrochemistry

The development of non-precious metal catalysts for oxygen reduction reaction (ORR) is essential for large-scale application of proton exchange membrane fuel cells. Herein, we present the in situ formed Fe-N doped hollow carbon nanospheres linked by carbon nanotubes composite, synthesized by using ZIF-8 as sacrificed template to form polydopamine (PDA) hollow nanospheres, followed by complexing with FeCl3, high temperature heat-treatment and NH3-etching. ZIF-8 was gradually decomposed simultaneously with PDA coating due to the loss of Zn2+ grabbed by PDA. NH3 etching resulted in the improved surface area, while the reducibility of NH3 resulted in …


Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao Dec 2018

Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao

Journal of Electrochemistry

Palladium (Pd) is a good catalyst for ethanol electro-oxidation in alkaline solutions. The activity of Pd is further improved in this study by modifying the gold (Au) nanoparticles with Pd adatoms using a simple spontaneous deposition process. The Pd overlayer on the Au core (Au@Pd) is un-uniform with some Au atoms exposed to the electrolyte. The activity of Au@Pd/C toward ethanol oxidation reaction (EOR) is much higher than that of Pd/C in an alkaline solution. The peak current density of Au@Pd/C is 4.6 times higher than that of Pd/C with a 100 mV lower onset potential. The enhanced activity may …


Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei Dec 2018

Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei

Journal of Electrochemistry

One major challenge for a large-scale commercialization of the proton-exchange membrane fuel cells (PEMFCs) technologies that enable a shift to ‘zero-emission’ personal transportation, is the expensive and unstable Pt catalysts, which are mainly used to catalyze the sluggish kinetics of the oxygen reduction reaction (ORR) occurred on the air electrode of PEMFCs. Many research works have targets to improve the stability of Pt-based catalysts and to construct Pt/transitional metal alloys with low Pt loading amount. Herein, we provide a minireview for the Pt-based ORR catalysts based on our recent work, which covers a brief background introduction, the stability improvement of …