Chemical Engineering Commons^™

Chromatographic Analysis Of The Chemical Composition Of Pyrolysis Distillate, Sh.T. Juraev, B.F. Muxiddinov, U.T. Tailakov

Chemical Technology, Control and Management

The paper presents the results of a study of the physico-chemical characteristics of the liquid fraction of products of thermal oxidative pyrolysis of worn tires. The mass fraction of the volatile gas compounds, the optimal boiling points of the obtained condensates and the flashpoint of pyrolysis liquids, together with the mass composition of cracking products of rubber products at high-temperature pyrolysis at a temperature of 800-900 °C, were determined. Chromatographic analysis allowed us to determine the composition, mainly the mass composition of pyrolysis products, which consisted of carbon (42.8%), higher aliphatic and aromatic hydrocarbons (17.0%), methane (10.2%), benzene (4.2%) and …

Identification Of Faults In Highways Using Approximation Methods And Algorithms, Khudayberdiyev Khakkulmirzayevich Mirzaakbar, Anvar Asatilloyevich Ravshanov

Chemical Technology, Control and Management

Many fast Fourier transforms are used to identify defective parts of uneven surfaces on roads and send information to relevant organizations on the road, using the " RAVON YO‘LLAR" application installed on a mobile device during car movement. We determine the uneven parts of the road. Smooth and well-maintained roads reduce the risk of vehicle collisions, skidding and other road-related incidents. Timely measures contribute to overall safety, comfort and economic efficiency.

Analytical-Critical Review Of Widely Used Industrial Devices For Drying Mineral Fertilizers, Djalolitdin Paxritdinovich Mukhitdinov, Aleksey Viktorovich Schulz

Chemical Technology, Control and Management

The article is devoted to the review of the modern state of research in the mineral fertilizers drying field, critical analysis and comparison of widely used drying apparatuses. There are procedures of preliminary equipment selection for soluble fertilizers industrial drying on the basis of such criteria as productivity, efficiency, energy saving, environmental impact degree, indicating the possible advantages and disadvantages of different application variants.

Calculation Of Hydraulic Resistance Of A Tubular-Gridse Nozzle With Spiral Turbulizers, Nurmukhamedov Habibulla Sagdullaevich, Mavlonov Elbek Tulkinovich, S.Kh. Nishonova, Kh.S. Nurmukhamedov

Chemical Technology, Control and Management

The article presents the results of an experimental study on the hydraulic resistance of a tubular-grid nozzle made of smooth pipes and pipes with spiral turbulators. Experiments were carried out with nozzles made of smooth pipes and pipes with turbulators. Spiral turbulators are placed discretely with a step t/d=0,3125-0,9375 and installed on a tube sheet in a checkerboard pattern with a step s/d=1,15-10. Experimental studies were carried out with air flow in the transition region.

It has been established that with increasing numerical values of the dimensionless parameter s/d, the resistance of the pipe package decreases from 1,3 to 1,8 …

Development Of A Mathematical Model Of Magnetic Field Distribution In Magnetic Conductors Of A Wide-Range Current Transformer, Abdurauf Safarov

Chemical Technology, Control and Management

The article is devoted to the analysis of the distribution of the magnetic field in the magnetic conductors of a wide-range current transformer for the development of a mathematical model that can be used as the basis for calculating its static characteristics and error. The design, replacement circuits and design model of a current transformer are given. The relations of magnetic induction and tension from the coordinate of the position of the primary winding are obtained. It is shown that the conversion range can be adjusted depending on the different positions of the bus with current, as a result of …

Synthesize A Neural Network Parameter Optimizer For An Adaptive Pid Controller, Nashvandova Gulruxsor Murot Qizi

Chemical Technology, Control and Management

Wide application of proportional-integral-differential (PID)-regulator in industry requires constant improvement of methods of its parameters superstructuring. In the paper, the questions of optimization of PID-regulator parameters with application of methods of neural network technology are considered. A methodology for selecting the architecture of neural network optimizer designed to determine the tuned parameters of PID regulator is proposed. The algorithm of training of the neural network, with the set on the basis of the method of inverse gradient propagation is offered. The proposed improved PID-neural regulator allowed to provide stabilization of neural network operation and its trainability in the control loop …

Development Of A Criterion Assessing The Level Of Relationship Of Multiple Identified Characteristics For Classification, Mirzoyan Mirzaaxmedovich Kamilov, Oybek Zokirovich Koraboshev, Bobomurod Mamitjonovich Tojiboev

Chemical Technology, Control and Management

This article discusses an optimized version of the standard design developed by Yu.I.Zhuravlev, an optimization procedure through an algebraic approach based on precedent algorithms that solves the problem of pattern identification. The formation of the convex hull of the recognition operator and corrective procedures of information models by mutual compensation of each other was also studied. In addition, the functional connection of recognition operators and the definition of idempotent connection of operators are analyzed.

In Situ Chlorine Generation And Rare Earth Chlorination By Molten Salt Electrolysis, Mark Schvaneveldt, Tyler Williams, Ranon Fuller, Devin Rappleye

Faculty Publications

Chloride volatility processes for purifying actinide and rare earth elements have historically required the use of Cl₂ tanks. To minimize the hazards associated with these processes, an apparatus was designed to produce Cl₂ via molten salt electrolysis. Within this apparatus, one can generate Cl₂, chlorinate metals, and consume excess Cl₂. Here, electrode materials were tested for their ability to generate Cl₂, the composition of the gaseous electrolysis product was evaluated using a quadrupole mass spectrometer, and a Ce foil sample was successfully chlorinated using the electrochemically generated Cl₂.

Influence Of Alkali Metal Cations On The Oxygen Reduction Activity Of Pt5Y And Pt5Gd Alloys, Kun-Ting Song, Alexandra Zagalskaya, Christian M. Schott, Peter M. Schneider, Batyr Garlyyev, Vitaly Alexandrov, Aliaksandr S. Bandarenka

Department of Chemical and Biomolecular Engineering: Faculty Publications

Electrolyte species can significantly influence the electrocatalytic performance. In this work, we investigate the impact of alkali metal cations on the oxygen reduction reaction (ORR) on active Pt₅Gd and Pt₅Y polycrystalline electrodes. Due to the strain effects, Pt alloys exhibit a higher kinetic current density of ORR than pure Pt electrodes in acidic media. In alkaline solutions, the kinetic current density of ORR for Pt alloys decreases linearly with the decreasing hydration energy in the order of Li⁺ > Na⁺ > K⁺ > Rb⁺ > Cs⁺, whereas Pt shows the opposite trend. To gain …

Investigation Of Fault Detection And Redundant Control Strategy For Model Predictive Control Of Distillation Column, Rajalakshmi R

Theses and Dissertations

Model Predictive Controller (MPC) is one of the industrial-ready control systems and an ideal choice for complex, slow-varying, and energy-intense Distillation Columns (DC). However, MPCs are subjected to failures and their performance degrades with faults and disturbances. Hence, there is a need for a redundant control strategy to ensure the continuous operation of MPC-controlled DC, which is investigated in this work.

A pilot-plant binary DC used to separate methanol and water is implemented with a computer-controlled system and is subjected to Pseudorandom Binary Excitation Signals (PRBS). The output response acquired is used to develop a MIMO (Multi-Input Multi- Output) state-space …

Artificial Neural Network Modeling Applied For Predicting Reformate Yield And Research Octane Number In The Reforming Process, Badiea S. Babaqi, Abdelrigeeb Ali Al-Gathe, Mohd S. Takriff, Hassimi Abu Hasan, Mohammed H. Al-Douh

Hadhramout University Journal of Natural & Applied Sciences

The prediction model of the continuous catalytic regeneration reforming process was developed for expecting the reformate yield and research octane number using an Artificial Neural Network technique (ANN) to improve the process performance. The proposed model includes temperatures, pressures, and hydrogen to hydrocarbon molar ratio as input parameters while the output of the process represents reformate yield and research octane number. The ANN model was carried out to estimate the process behavior based on the Levenberg-Marquardt Algorithm, which included the nine input parameters, two hidden layers (10-5 neurons), and two parameters as network outputs. The results obtained were that the …

Evaluation Of Environmental Management System For Small And Medium Enterprises In Dar Es Salaam, Tanzania, Juma M. Matindana

Tanzania Journal of Engineering and Technology (TJET)

A system that manages environmental issues of Small and Medium Enterprises (SMEs) from the time of acquisition of raw materials up to disposal of the product is not well clear, especially in Tanzania. Most of the studies have been conducted in the field of environment management but few of them address the evaluation of the management of SMEs activities with respect to the environment. Although the nature of activities of SMEs has little noticeable environmental implications at the individual level but the impact is large due to diversification and labour intensity of these SMEs. SMEs employ about 20% of the …

A Two-Stage Based Life Cycle And Principal Component Analysis For Decision Support Of Potential Municipal Solid Wastes Management Scenarios, Case Study Dar Es Salaam, Tanzania, Edwin Richard Ndibalema Dr

Tanzania Journal of Engineering and Technology (TJET)

In most of the urban areas of Tanzania, poor and inadequate solid waste management is a growing environmental and public health concern. Despite an array of solid waste management options, choosing an appropriate one remains a challenge. This study applied a novel two-stage-based approach to assess the environmental impacts and sustainability performance of the 27 scenarios for municipal solid wastes (MSW) management of Dar es Salaam City, Tanzania. In the first stage, the study utilized a life cycle analysis (LCA) to quantify the environmental impacts of MSW scenarios. In the second stage, the study used the principal component analysis (PCA) …

An Overview Of Maternity Healthcare Monitoring In Developing Nations, Godphrey Kyambille

Tanzania Journal of Engineering and Technology (TJET)

A healthcare monitoring arrangement is essential for frequently monitoring a patient's health status. Specifically, maternal healthcare systems for tracking are utilized to evaluate the clinical status and monitor any abnormal condition changes during all three trimesters. This paper's objective is to conduct an extensive literature review and acknowledge earlier initiatives and studies conducted previously in maternal health care monitoring. This review focuses on accumulating information from earlier work and presents a general overview of previous studies concerning maternal health care monitoring (MHCM). The paper focuses on the maternal healthcare systems in developing countries accessed by pregnant women during the antenatal …

Augmented Finite Control Set Mpc Design Technique For Wide Speed Range Control Of Permanent Magnet Synchronous Motor Drives, Francis Mwasilu

Tanzania Journal of Engineering and Technology (TJET)

The effective motion control task is highly influencing the final drive performance in wide-range motor drives applications such as electric vehicles (EVs), washing machines, compressors, elevators and lathe machines. Recently, permanent magnet synchronous motor (PMSM) drive has been widely employed in these applications to achieve desired performances such as high efficiency, high torque requirements with minimum size “occupancy”. The PMSM drive features combining with these modern drive applications are highly nonlinear and the desired operation requirements demand high-performance control schemes with fast system response and robustness features. Linear control schemes are usually implemented to drive the PMSM that entail trade …

Cost Estimation Proxy Models For Economic Evaluations In Petroleum Projects: A Case Study From The Onshore Gas Field In The Southern Coastal Tanzania Basin, Fulmence Kaborogo

Tanzania Journal of Engineering and Technology (TJET)

Petroleum economic evaluation involves estimating revenues from forecasted production profiles and field costs including capital expenditures (CAPEX), drilling expenses (DRILLEX), and operating expenses (OPEX). The existing cost-estimating tool requires several inputs making it time-intensive and difficult to use with few data during the early stages of projects. Majority of the previously developed time saving cost estimations proxy models rely on unrealistic assumptions that include uniform operational costs for different fields with a different number of wells, casings, and drilled depths. This work focused at developing proxy models that consider the variability of the development costs with different parameters. The developed …

Steminism: Analyzing Factors That Improve Retention Of Women In Stem, Kira Carter, Jane Kelley, Jason Vasser-Elong, Rc Patterson

Dissertations

Our co-authored research ‘Steminism: Analyzing Factors That Improve Retention for Women as STEM Majors’ analyzed factors that contributed to the retention of women in science, technology, engineering, and mathematics (STEM) programs at Missouri University of Science & Technology (Missouri S&T). Women make up half of the US population, and while careers in (STEM) are an integral part of the US economy, women are underrepresented in these career fields. The purpose of our dissertation is to address the underrepresentation of women in STEM majors. Our methodology included homogeneous sampling to collect qualitative data. More specifically, we consulted with academic advisors and …

Fabricating A 3d Floating Porous Pdms − Ag/Agbr Decorated G-C3n4 Nanocomposite Sponge As A Re-Usable Visible Light Photocatalyst, Maryam Galal Elmahgary, Mohamed Taha, A Kalid, Shymaa Madany, Yasser Attia

Chemical Engineering

No abstract provided.

Design And Development Of Deep Eutectic Solvent Assisted Pressurized Liquid Extraction Of Nutraceuticals, Harish Babu B

Theses and Dissertations

Over recent decades, the usage of nutraceuticals has been exponentially increasing as alternates to pharmaceutical drugs. However, extraction of these therapeutically significant compounds from their corresponding sources requires the use of volatile organic solvents like hexane, ethanol and chloroform which increases the global warming potential. This problem has been overcome in recent decades by the use of supercritical carbon dioxide (SCO2) as the extraction solvent. Since SCO2 is non-polar in nature, the extraction of polar compounds with better efficiency is questionable.

On the other hand, modernization in solvent engineering has created generations of green solvents like ionic liquids (ILs), deep …

A Review Of Proton Exchange Membrane Degradation Pathways, Mechanisms, And Mitigation Strategies In A Fuel Cell, Dharmjeet Madhav, Junru Wang, Rajesh Keloth, Jorben Mus, Frank Buysschaert, Veerle Vandeginste

Department of Chemical and Biomolecular Engineering: Faculty Publications

Proton exchange membrane fuel cells (PEMFCs) have the potential to tackle major challenges associated with fossil fuel-sourced energy consumption. Nafion, a perfluorosulfonic acid (PFSA) membrane that has high proton conductivity and good chemical stability, is a standard proton exchange membrane (PEM) used in PEMFCs. However, PEM degradation is one of the significant issues in the long-term operation of PEMFCs. Membrane degradation can lead to a decrease in the performance and the lifespan of PEMFCs. The membrane can degrade through chemical, mechanical, and thermal pathways. This paper reviews the different causes of all three routes of PFSA degradation, underlying mechanisms, their …