Chemical Engineering Commons^™

Strategy For Predictive Control Of The Rectification Process Based On A Model Controller With A Given Forecast, Ildar Rafkatovich Sultanov

Chemical Technology, Control and Management

A method is being developed to optimize the generated controls for the multicomponent distillation process with prediction, based on predictive data with a moving horizon. The difference between this method and the classical modeling approach, in which the percentage of the degree of opening of valves installed on the output streams of the column is used as control actions, is that control occurs on the feedback principle. The proposed method is based on the use of a dynamic process model to optimize control actions in real time in order to achieve certain production targets. The essence of the MPC approach …

A Neural Network Model For Monitoring And Forecasting The Process Of Storing Oilseeds, N.A. Kabulov

Chemical Technology, Control and Management

The paper presents the results of research on the control, forecasting and management of the storage process of oilseeds. Vegetable oil production and energy consumption are two important factors of oilseed storage systems. The first ones should meet the needs of the population quantitatively and qualitatively. As a result, in order to properly control these two important aspects, it is necessary to maintain an appropriate microclimatic environment using a computational decision support system (DSS) that is able to adapt to changes in environmental characteristics. The multilayer perceptron neural network (MLP-NN) was developed to simulate the temperature and relative humidity profiles …

Synthesize A Neural Network Parameter Optimizer For An Adaptive Pid Controller, Nashvandova Gulruxsor Murot Qizi

Chemical Technology, Control and Management

Wide application of proportional-integral-differential (PID)-regulator in industry requires constant improvement of methods of its parameters superstructuring. In the paper, the questions of optimization of PID-regulator parameters with application of methods of neural network technology are considered. A methodology for selecting the architecture of neural network optimizer designed to determine the tuned parameters of PID regulator is proposed. The algorithm of training of the neural network, with the set on the basis of the method of inverse gradient propagation is offered. The proposed improved PID-neural regulator allowed to provide stabilization of neural network operation and its trainability in the control loop …

Development Of A Criterion Assessing The Level Of Relationship Of Multiple Identified Characteristics For Classification, Mirzoyan Mirzaaxmedovich Kamilov, Oybek Zokirovich Koraboshev, Bobomurod Mamitjonovich Tojiboev

Chemical Technology, Control and Management

This article discusses an optimized version of the standard design developed by Yu.I.Zhuravlev, an optimization procedure through an algebraic approach based on precedent algorithms that solves the problem of pattern identification. The formation of the convex hull of the recognition operator and corrective procedures of information models by mutual compensation of each other was also studied. In addition, the functional connection of recognition operators and the definition of idempotent connection of operators are analyzed.

In Situ Chlorine Generation And Rare Earth Chlorination By Molten Salt Electrolysis, Mark Schvaneveldt, Tyler Williams, Ranon Fuller, Devin Rappleye

Faculty Publications

Chloride volatility processes for purifying actinide and rare earth elements have historically required the use of Cl₂ tanks. To minimize the hazards associated with these processes, an apparatus was designed to produce Cl₂ via molten salt electrolysis. Within this apparatus, one can generate Cl₂, chlorinate metals, and consume excess Cl₂. Here, electrode materials were tested for their ability to generate Cl₂, the composition of the gaseous electrolysis product was evaluated using a quadrupole mass spectrometer, and a Ce foil sample was successfully chlorinated using the electrochemically generated Cl₂.

Influence Of Alkali Metal Cations On The Oxygen Reduction Activity Of Pt5Y And Pt5Gd Alloys, Kun-Ting Song, Alexandra Zagalskaya, Christian M. Schott, Peter M. Schneider, Batyr Garlyyev, Vitaly Alexandrov, Aliaksandr S. Bandarenka

Department of Chemical and Biomolecular Engineering: Faculty Publications

Electrolyte species can significantly influence the electrocatalytic performance. In this work, we investigate the impact of alkali metal cations on the oxygen reduction reaction (ORR) on active Pt₅Gd and Pt₅Y polycrystalline electrodes. Due to the strain effects, Pt alloys exhibit a higher kinetic current density of ORR than pure Pt electrodes in acidic media. In alkaline solutions, the kinetic current density of ORR for Pt alloys decreases linearly with the decreasing hydration energy in the order of Li⁺ > Na⁺ > K⁺ > Rb⁺ > Cs⁺, whereas Pt shows the opposite trend. To gain …

Investigation Of Fault Detection And Redundant Control Strategy For Model Predictive Control Of Distillation Column, Rajalakshmi R

Theses and Dissertations

Model Predictive Controller (MPC) is one of the industrial-ready control systems and an ideal choice for complex, slow-varying, and energy-intense Distillation Columns (DC). However, MPCs are subjected to failures and their performance degrades with faults and disturbances. Hence, there is a need for a redundant control strategy to ensure the continuous operation of MPC-controlled DC, which is investigated in this work.

A pilot-plant binary DC used to separate methanol and water is implemented with a computer-controlled system and is subjected to Pseudorandom Binary Excitation Signals (PRBS). The output response acquired is used to develop a MIMO (Multi-Input Multi- Output) state-space …

Artificial Neural Network Modeling Applied For Predicting Reformate Yield And Research Octane Number In The Reforming Process, Badiea S. Babaqi, Abdelrigeeb Ali Al-Gathe, Mohd S. Takriff, Hassimi Abu Hasan, Mohammed H. Al-Douh

Hadhramout University Journal of Natural & Applied Sciences

The prediction model of the continuous catalytic regeneration reforming process was developed for expecting the reformate yield and research octane number using an Artificial Neural Network technique (ANN) to improve the process performance. The proposed model includes temperatures, pressures, and hydrogen to hydrocarbon molar ratio as input parameters while the output of the process represents reformate yield and research octane number. The ANN model was carried out to estimate the process behavior based on the Levenberg-Marquardt Algorithm, which included the nine input parameters, two hidden layers (10-5 neurons), and two parameters as network outputs. The results obtained were that the …

Evaluation Of Environmental Management System For Small And Medium Enterprises In Dar Es Salaam, Tanzania, Juma M. Matindana

Tanzania Journal of Engineering and Technology (TJET)

A system that manages environmental issues of Small and Medium Enterprises (SMEs) from the time of acquisition of raw materials up to disposal of the product is not well clear, especially in Tanzania. Most of the studies have been conducted in the field of environment management but few of them address the evaluation of the management of SMEs activities with respect to the environment. Although the nature of activities of SMEs has little noticeable environmental implications at the individual level but the impact is large due to diversification and labour intensity of these SMEs. SMEs employ about 20% of the …

A Two-Stage Based Life Cycle And Principal Component Analysis For Decision Support Of Potential Municipal Solid Wastes Management Scenarios, Case Study Dar Es Salaam, Tanzania, Edwin Richard Ndibalema Dr

Tanzania Journal of Engineering and Technology (TJET)

In most of the urban areas of Tanzania, poor and inadequate solid waste management is a growing environmental and public health concern. Despite an array of solid waste management options, choosing an appropriate one remains a challenge. This study applied a novel two-stage-based approach to assess the environmental impacts and sustainability performance of the 27 scenarios for municipal solid wastes (MSW) management of Dar es Salaam City, Tanzania. In the first stage, the study utilized a life cycle analysis (LCA) to quantify the environmental impacts of MSW scenarios. In the second stage, the study used the principal component analysis (PCA) …

An Overview Of Maternity Healthcare Monitoring In Developing Nations, Godphrey Kyambille

Tanzania Journal of Engineering and Technology (TJET)

A healthcare monitoring arrangement is essential for frequently monitoring a patient's health status. Specifically, maternal healthcare systems for tracking are utilized to evaluate the clinical status and monitor any abnormal condition changes during all three trimesters. This paper's objective is to conduct an extensive literature review and acknowledge earlier initiatives and studies conducted previously in maternal health care monitoring. This review focuses on accumulating information from earlier work and presents a general overview of previous studies concerning maternal health care monitoring (MHCM). The paper focuses on the maternal healthcare systems in developing countries accessed by pregnant women during the antenatal …

Augmented Finite Control Set Mpc Design Technique For Wide Speed Range Control Of Permanent Magnet Synchronous Motor Drives, Francis Mwasilu

Tanzania Journal of Engineering and Technology (TJET)

The effective motion control task is highly influencing the final drive performance in wide-range motor drives applications such as electric vehicles (EVs), washing machines, compressors, elevators and lathe machines. Recently, permanent magnet synchronous motor (PMSM) drive has been widely employed in these applications to achieve desired performances such as high efficiency, high torque requirements with minimum size “occupancy”. The PMSM drive features combining with these modern drive applications are highly nonlinear and the desired operation requirements demand high-performance control schemes with fast system response and robustness features. Linear control schemes are usually implemented to drive the PMSM that entail trade …

Cost Estimation Proxy Models For Economic Evaluations In Petroleum Projects: A Case Study From The Onshore Gas Field In The Southern Coastal Tanzania Basin, Fulmence Kaborogo

Tanzania Journal of Engineering and Technology (TJET)

Petroleum economic evaluation involves estimating revenues from forecasted production profiles and field costs including capital expenditures (CAPEX), drilling expenses (DRILLEX), and operating expenses (OPEX). The existing cost-estimating tool requires several inputs making it time-intensive and difficult to use with few data during the early stages of projects. Majority of the previously developed time saving cost estimations proxy models rely on unrealistic assumptions that include uniform operational costs for different fields with a different number of wells, casings, and drilled depths. This work focused at developing proxy models that consider the variability of the development costs with different parameters. The developed …

Steminism: Analyzing Factors That Improve Retention Of Women In Stem, Kira Carter, Jane Kelley, Jason Vasser-Elong, Rc Patterson

Dissertations

Our co-authored research ‘Steminism: Analyzing Factors That Improve Retention for Women as STEM Majors’ analyzed factors that contributed to the retention of women in science, technology, engineering, and mathematics (STEM) programs at Missouri University of Science & Technology (Missouri S&T). Women make up half of the US population, and while careers in (STEM) are an integral part of the US economy, women are underrepresented in these career fields. The purpose of our dissertation is to address the underrepresentation of women in STEM majors. Our methodology included homogeneous sampling to collect qualitative data. More specifically, we consulted with academic advisors and …

Fabricating A 3d Floating Porous Pdms − Ag/Agbr Decorated G-C3n4 Nanocomposite Sponge As A Re-Usable Visible Light Photocatalyst, Maryam Galal Elmahgary, Mohamed Taha, A Kalid, Shymaa Madany, Yasser Attia

Chemical Engineering

No abstract provided.

Design And Development Of Deep Eutectic Solvent Assisted Pressurized Liquid Extraction Of Nutraceuticals, Harish Babu B

Theses and Dissertations

Over recent decades, the usage of nutraceuticals has been exponentially increasing as alternates to pharmaceutical drugs. However, extraction of these therapeutically significant compounds from their corresponding sources requires the use of volatile organic solvents like hexane, ethanol and chloroform which increases the global warming potential. This problem has been overcome in recent decades by the use of supercritical carbon dioxide (SCO2) as the extraction solvent. Since SCO2 is non-polar in nature, the extraction of polar compounds with better efficiency is questionable.

On the other hand, modernization in solvent engineering has created generations of green solvents like ionic liquids (ILs), deep …

A Review Of Proton Exchange Membrane Degradation Pathways, Mechanisms, And Mitigation Strategies In A Fuel Cell, Dharmjeet Madhav, Junru Wang, Rajesh Keloth, Jorben Mus, Frank Buysschaert, Veerle Vandeginste

Department of Chemical and Biomolecular Engineering: Faculty Publications

Proton exchange membrane fuel cells (PEMFCs) have the potential to tackle major challenges associated with fossil fuel-sourced energy consumption. Nafion, a perfluorosulfonic acid (PFSA) membrane that has high proton conductivity and good chemical stability, is a standard proton exchange membrane (PEM) used in PEMFCs. However, PEM degradation is one of the significant issues in the long-term operation of PEMFCs. Membrane degradation can lead to a decrease in the performance and the lifespan of PEMFCs. The membrane can degrade through chemical, mechanical, and thermal pathways. This paper reviews the different causes of all three routes of PFSA degradation, underlying mechanisms, their …

Permeability Enhancement And Coal Fines Removal Through Oxidation Treatment In Coalbed Methane Reservoirs, Yu Lu, Yili Kang, Chengzhong Bu, Ying Li, Chong Lin, Zhenjiang You

Research outputs 2022 to 2026

This study utilized anthracite coal samples from Zhijin Block and applied NaClO as the oxidant to investigate the effects of oxidation treatment on permeability enhancement and coal fines migration. Subsequent to oxidation treatment, the coal samples demonstrated an average increase of 42.17% in the equivalent hydraulic aperture (EHA). This treatment also resulted in the expansion of fluid flow channels, contributing to an average permeability enhancement of 108.85% in the coal samples. Resulting from the non-uniform dissolution of the oxidant on the fracture surface of coal, self-propping fractures were formed, effectively maintaining the conductivity of fractures. The oxidation treatment converted the …

Application Of Foam Assisted Water-Alternating-Gas Flooding And Quantification Of Resistivity And Water Saturation By Experiment And Simulation To Determine Foam Propagation In Sandstone, Javed A. Khan, Jong Kim, Sonny Irawan, Karina A. Permatasar, Patrick G. Verdin, Baoping Cai, Nurudeen Yekeen

Research outputs 2022 to 2026

Foam flooding by Foam Assisted Water-Alternating-Gas (FAWAG) is an important enhanced oil recovery method that has proven successful in experimental and pilot studies. The present study is carried out to monitor the movement of the foam front once injected into the porous medium. This study aims to investigate applications of resistivity waves to monitor foam propagation in a sandstone formation. In the present lab-scale experiments and simulations, resistivity measurements were carried out to monitor the progression of foam in a sand pack, and the relationships between foam injection time and resistivity, as well as brine saturation, were studied. The brine …

Development Of Inorganically Cross-Linked Sulfonated Polyacrylamide Preformed Particle Gels For Conformance Control: Impact Of Anionic Groups, Reem Elaf, Ahmed Hamza, Hassan Nimir, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Modern oil and gas extraction faces challenges, notably from the surplus of produced water, hampering hydrocarbon recovery and raising environmental and economic concerns. A promising solution is the injection of preformed particle gels (PPGs) into the reservoir's fractures and high permeability zones, facilitating production processes. This study introduces a novel class of inorganically cross-linked PPGs with exceptionally high swelling capacities, comprising sulfonated polyacrylamide cross-linked with aluminum attached to acetate, nitrate, sulfate, and lactate anions individually. These PPGs function as superabsorbents, capable of absorbing water at a ratio of 100-700 times their dry weight while maintaining adequate gel strength up to …