Open Access. Powered by Scholars. Published by Universities.®

Thermodynamics Commons

Open Access. Powered by Scholars. Published by Universities.®

439 Full-Text Articles 634 Authors 216,360 Downloads 65 Institutions

All Articles in Thermodynamics

Faceted Search

439 full-text articles. Page 1 of 17.

The Influence Of Heat And Mass Transfer On The Setting Rate Of Adhesives Between Porous Substrates, Mubarak Mohammed Khlewee 2023 The University of Maine

The Influence Of Heat And Mass Transfer On The Setting Rate Of Adhesives Between Porous Substrates, Mubarak Mohammed Khlewee

Electronic Theses and Dissertations

The dynamic penetration of fluid into a porous media where other changes are occurring such as temperature or concentration is of interest to a number of situations. However, little experimental and theoretical analysis of this situation is found in the literature where most of the previously published works have studied the penetration with constant physical properties, where there is no change of the fluid as it enters the pores. This situation is important in the setting of adhesives in porous medium such as in the setting of hot melt and water-based adhesives in the production of paper based packaging. The …


Efficient Sintering Of Lunar Soil Using Concentrated Sunlight, Diprajit Biswas 2023 University of Maine

Efficient Sintering Of Lunar Soil Using Concentrated Sunlight, Diprajit Biswas

Electronic Theses and Dissertations

Construction material is one crucial need for long-term habitation on the moon. When concentrated for high heat flux, solar radiation can heat lunar soil or regolith until it sinters at temperatures above 900°C. The solid, sintered soil simulant can be used as construction material. This work explores the conditions leading to effective lunar soil sintering for both direct and indirect irradiated sintering. Lunar soil simulants were sintered using concentrated light from a xenon-arc lamp with varying heat flux intensity. During direct sintering of LHS-1, a sintering range of 860°C-1140°C corresponding to a peak heat flux of 105-120 kW/m2 was identified …


Heat Transfer From Plates, Leanza Trevino 2023 University of Arkansas, Fayetteville

Heat Transfer From Plates, Leanza Trevino

Chemical Engineering Undergraduate Honors Theses

The purpose of this honors thesis is to create an experiment for the CHEG Lab I course. This is a continuation of work done by Alexa Moreno. She created an experiment to model free convection of a horizontal plate. In this report, free and forced convection of a vertical and horizontal plate, respectively are modeled. This report explains the motivation for creating this heat convection experiment, the results of performing the experiment, and provides recommendations for future work on this experiment. Lab handouts are included in the Appendix.


A Molecular Dynamics Study Of Structural Modifications Of Perarylphosphonium Based Ionic Liquids On The Melting Point, Johnathan Anderson 2023 University of South Alabama

A Molecular Dynamics Study Of Structural Modifications Of Perarylphosphonium Based Ionic Liquids On The Melting Point, Johnathan Anderson

Theses and Dissertations

Several perarylphosphonium based mesothermal ionic liquids (ILs) have been shown to be stable at high temperatures for prolonged periods of time and with high heat capacities making them good candidates for use in many processes such as usage as a heat transfer fluid, as an absorbent for separation of aromatics from aliphatics, and as a solvent for high temperature reactions. Many, however, have melting points above 100o C, limiting their use. Recently, it was shown that the melting point of an IL can be lowered by simply increasing the dipole moment of the cation or by structurally rigidifying the …


Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors, Graham Tindall 2023 Clemson University

Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors, Graham Tindall

All Dissertations

As a category of materials, engineered carbons, specifically carbon fibers, are first-in-class for properties such as modulus, specific strength, and thermal resilience; however, the inability to directly process atomic carbon necessitates the development and optimization of carbonaceous precursors. Because the structure and properties of carbon are highly dependent on the precursors and requisite processing, numerous materials have been investigated as feedstocks for large-scale production. Although cellulose and rayon were among the first investigated, polyacrylonitrile (PAN) is the current hegemon of carbon fiber precursors. PAN feeds 90% of this market, but it is neither inexpensive nor renewable. Because a significant fraction …


Probing The Structure Of Water On Surfaces: From Water Absorption To Ice Nucleation, Jiarun Zhou 2023 Clemson University

Probing The Structure Of Water On Surfaces: From Water Absorption To Ice Nucleation, Jiarun Zhou

All Dissertations

Water, essential for all life forms, is the most abundant, simple, yet mysterious molecule in the world. This molecule, consisting of only three atoms, behaves in unexpectedly different ways with the change of environment. In the past, studies of water under different conditions (temperature, pressure, on the surfaces, with confinement) have been conducted using experimental and computational methods. However, the influence of a given environment on water properties is yet to be fully understood. This dissertation studies water at complex interfaces (surfaces with various chemistry and physics properties) in both the liquid and crystalline states. Various heterogeneous systems used to …


More On The Demons Of Thermodynamics, Daniel P. Sheehan, Garret Moddel, James W. Lee 2023 University of San Diego

More On The Demons Of Thermodynamics, Daniel P. Sheehan, Garret Moddel, James W. Lee

Chemistry & Biochemistry Faculty Publications

No abstract provided.


Teflon Replacement In Pans, Teodora Neamtu 2023 The University of Akron

Teflon Replacement In Pans, Teodora Neamtu

Williams Honors College, Honors Research Projects

The purpose of the project is to determine an optimal prepping method of common cooking oils for pans that will be as effective as Teflon non-stick pans. The reason for this is to replace Teflon coating in pans, which can be very toxic for humans and the environment. Teflon has been a common coating for non-stick surfaces that is useful when cooking things such as eggs. To determine an optimal cooking method, three different oils were used: olive oil, vegetable oil, and shortening. The oils were tested on an aluminum pan by cooking egg whites at various temperatures, cooking times, …


Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, Muzammil Soomro, Luis F. Ayala, Cheng Peng, Orlando M. Ayala 2023 Old Dominion University

Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, Muzammil Soomro, Luis F. Ayala, Cheng Peng, Orlando M. Ayala

Engineering Technology Faculty Publications

The free-energy model can extend the lattice Boltzmann method to multiphase systems. However, there is a lack of models capable of simulating multicomponent multiphase fluids with partial miscibility. In addition, existing models cannot be generalized to honor thermodynamic information provided by any multicomponent equation of state of choice. In this paper, we introduce a free-energy lattice Boltzmann model where the forcing term is determined by the fugacity of the species, the thermodynamic property that connects species partial pressure to chemical potential calculations. By doing so, we are able to carry out multicomponent multiphase simulations of partially miscible fluids and generalize …


Diseño Conceptual De La Recuperación De Galactooligosacáridos (Gos) De Hidrolizados Enzimáticos Por Adsorción Con Carbón Activado, Juan Sebastián Delgado Burgos, Julián Felipe Duque Romero 2023 Universidad de La Salle, Bogotá

Diseño Conceptual De La Recuperación De Galactooligosacáridos (Gos) De Hidrolizados Enzimáticos Por Adsorción Con Carbón Activado, Juan Sebastián Delgado Burgos, Julián Felipe Duque Romero

Ingeniería de Alimentos

Los galactooligosacáridos (GOS) son un tipo de oligosacáridos prebióticos compuestos por unidades de galactosa y glucosa, que tienen propiedades benéficas para la salud intestinal y usualmente son utilizados en la formulación de alimentos funcionales. Estos compuestos se obtienen por medio de la transgalactosilación de lactosa presente en el lactosuero (un subproducto de la industria láctea que representa una problemática ambiental) que resulta en una mezcla de GOS con otros carbohidratos residuales que reducen su pureza, sus propiedades funcionales y su valor económico. En la actualidad, la separación de GOS mediante procesos de adsorción con carbón activado es uno de los …


Outstanding Advantages, Current Drawbacks, And Significant Recent Developments In Mechanochemistry: A Perspective View, Silvina Pagola 2023 Old Dominion University

Outstanding Advantages, Current Drawbacks, And Significant Recent Developments In Mechanochemistry: A Perspective View, Silvina Pagola

Chemistry & Biochemistry Faculty Publications

Although known since antiquity, mechanochemistry has remained dormant for centuries. Nowadays, mechanochemistry is a flourishing research field at the simultaneous stages of gathering data and (often astonishing) observations, and scientific argumentation toward their analysis, for which the combination of interdisciplinary expertise is necessary. Mechanochemistry’s implementation as a synthetic method is constantly increasing, although it remains far from being fully exploited, or understood on the basis of fundamental principles. This review starts by describing many remarkable advantages of mechanochemical reactions, simplifying and “greening” chemistry in solutions. This description is followed by an overview of the current main weaknesses to be addressed …


Operation And Preliminary Energy Balance Of A Portable Kelp Dryer In Maine, Tuqa Al-Asadi 2022 University of Maine

Operation And Preliminary Energy Balance Of A Portable Kelp Dryer In Maine, Tuqa Al-Asadi

Electronic Theses and Dissertations

Seaweed (macroalgae) is a marine resource that has a high economic value. Seaweeds are important commodities as raw material for food or additives and as a source of biomass. One popular species of seaweed is Sugar kelp (Saccharina latissima) – a brown algae that is native to the Maine coast and also a commonly farmed species. It is a rich source of fibers, vitamins, minerals, and antioxidants. Seaweeds are highly perishable due to their high moisture content and will spoil quickly if not preserved, therefore a common practice is to dry the product to prolong storage life and to minimize …


Generation Of Phase Transitions Boundaries Via Convolutional Neural Networks, Christopher Alexis Ibarra 2022 University of Texas at El Paso

Generation Of Phase Transitions Boundaries Via Convolutional Neural Networks, Christopher Alexis Ibarra

Open Access Theses & Dissertations

Accurate mapping of phase transitions boundaries is crucial in accurately modeling the equation of state of materials. The phase transitions can be structural (solid-solid) driven by temperature or pressure or a phase change like melting which defines the solid-liquid melt line. There exist many computational methods for evaluating the phase diagram at a particular point in temperature (T) and pressure (P). Most of these methods involve evaluation of a single (P,T) point at a time. The present work partially automates the search for phase boundaries lines utilizing a machine learning method based on convolutional neural networks and an efficient search …


Elucidation Of Active Site And Mechanism Of Metal Catalysts Supported In Nu-1000, Hafeera Shabbir 2022 Clemson University

Elucidation Of Active Site And Mechanism Of Metal Catalysts Supported In Nu-1000, Hafeera Shabbir

All Dissertations

Advances in extraction of shale oil and gas has increased the production of geographically stranded natural gas (primarily consisting of methane (C1) and ethane (C2)) that is burned on site. A potential utilization strategy for shale gas is to convert it into fuel range hydrocarbons by catalytic dehydrogenation followed by oligomerization by direct efficient catalysts. This work focuses on understanding metal cation catalysts supported on metal-organic framework (MOF) NU-1000 that will actively and selectively do this transformation under mild reaction conditions, while remaining stable to deactivation (via metal agglomeration or sintering). I built computational models validated by experimental methods to …


Detectability Of Wormholes Through Various Methods, Jonathan W. Keathley 2022 University of North Florida

Detectability Of Wormholes Through Various Methods, Jonathan W. Keathley

PANDION: The Osprey Journal of Research and Ideas

There are three methods that can possibly detect wormholes: Negative Temperature, Hawking/ Phantom Radiation, and iron emission lines. This paper discusses whether or not any of these three methods are useful ways to detect wormholes with today’s technology and if so, which one is the best and which is the worst. As it turns out, all of these methods have their flaws and impracticalities. After looking through all the evidence and comparing it to what capabilities we have currently, there is clearly a best and worst method. The best method to detect possible wormhole candidates is through the detection …


Droplet Dynamics And Heat Transfer During Condensation On Lubricant-Infused Surfaces, Jianxing Sun 2022 Washington University in St. Louis

Droplet Dynamics And Heat Transfer During Condensation On Lubricant-Infused Surfaces, Jianxing Sun

McKelvey School of Engineering Theses & Dissertations

Inspired by pitcher plants, a micro/nano- structured solid surface infused with low-surface-tension lubricant constitutes a novel class of biomimetic surfaces—lubricant-infused surfaces (LISs). Unlike solid hydrophobic and superhydrophobic surfaces, a LIS is “hemi-solid and hemi-liquid”. The thin lubricating film can extraordinarily decrease adhesion and avoid contact line pinning between the working fluid and the underlying solid, displaying many desirable properties, such as excellent liquid repellency, suppression of fouling, and self-healing. Hence, LISs are ideal for applications where liquids or contaminants must be efficiently removed from surfaces in harsh environments. For example, LISs can promote stable dropwise condensation of water or low-surface-tension …


Droplet-Based Two-Phase Thermal Management, Junhui Li 2022 Washington University in St. Louis

Droplet-Based Two-Phase Thermal Management, Junhui Li

McKelvey School of Engineering Theses & Dissertations

The rapid development of electronic systems with ever-higher power densities in a wide range of applications requires new advanced thermal management methods. Droplet-based two-phase thermal management technologies are considered promising solutions to conquer the cooling challenges in the electronic industries. The heat transfer behavior of droplets is based on several important fundamental processes, such as droplet evaporation, droplet impact on heated surfaces, and molten droplet impact. In this dissertation, four research projects are completed to explore the insights of these fundamental processes. For droplet evaporation, I introduce an investigation of diffusion confinement of droplets evaporating on a supported pillar structure. …


Fabrication Of Nb3Sn By Magnetron Sputtering For Superconducting Radiofrequency Application, Md Nizam Sayeed 2022 Old Dominion University

Fabrication Of Nb3Sn By Magnetron Sputtering For Superconducting Radiofrequency Application, Md Nizam Sayeed

Electrical & Computer Engineering Theses & Dissertations

Particle accelerators are considered as an important device that has wide applications in cancer treatment, sterilizing waste, preserving foods, ion implantation in semiconductor industry, and in production of isotopes for medical applications. Superconducting radiofrequency (SRF) cavities are the building blocks of a linear particle accelerator. Current particle accelerators use niobium (Nb) superconductors as the sheet material to fabricate a single SRF cavity for particle acceleration. With better superconducting properties (critical temperature Tc ~ 18.3 K, superheating field Hsh~ 400 mT), Nb3Sn is considered a potential candidate in SRF technology. Magnetron sputtering is a promising deposition …


Study Of Thermoelectric And Lattice Dynamics Properties Of 2d Layered Mx (M = Sn, Pb; X = S, Se, Te) And Zrs2 Compounds Using First-Principles Approach, Abhiyan Pandit 2022 University of Arkansas, Fayetteville

Study Of Thermoelectric And Lattice Dynamics Properties Of 2d Layered Mx (M = Sn, Pb; X = S, Se, Te) And Zrs2 Compounds Using First-Principles Approach, Abhiyan Pandit

Graduate Theses and Dissertations

The aim of this dissertation is the investigation of thermoelectric and lattice dynamics properties of two-dimensional (2D) MX (M = Sn, Pb; X = S, Se, Te) and ZrS2 compounds based on the first-principles density functional theory. The dimensionality reduction (e.g., using 2D structure) of bulk materials is found to have enhanced thermoelectric efficiency. This enhancement is attributed to the increase of the Seebeck coefficient as a result of higher electronic density of states near the Fermi level in low-dimensional materials. In addition, lowering the dimensionality increases phonon scattering near interfaces and surfaces in 2D materials, which leads to a …


Optimization Of Styrene From Ethylbenzene Case Study, Jabria Daria Thompson 2022 University of Mississippi

Optimization Of Styrene From Ethylbenzene Case Study, Jabria Daria Thompson

Honors Theses

The following pages detail the optimization process of styrene from ethylbenzene in the Styrene Production Plant, Unit 500. There were two parts of the assignment, each with slightly different end goals. The goal of the first part of the assignment, was to create a process that would effectively and efficiently increase the negative Net Present Value (NPV) of the production plant. Procedures taken in this process included developing a working kinetic process simulation model and optimizing this model through unit operations and heat integration, as well as developing an accurate economic model that will be used to evaluate the proposed …


Digital Commons powered by bepress