University of Pennsylvania
Graphical Analysis And Revamping Of Crude Distillation Units Under Variable Operational Scenarios,
2023
Missouri University of Science and Technology
Graphical Analysis And Revamping Of Crude Distillation Units Under Variable Operational Scenarios, Amany G. Abo-Mousa, Dina A. Kamel, Hany A. Elazab, Mamdouh A. Gadalla, Mai K. Fouad
Chemical and Biochemical Engineering Faculty Research & Creative Works
Energy Cost Represents a Significant Part of the Total Operating Costs of Many Processing Units. Crude Distillation is an Energy Intensive Process. Energy Integration is a Typical Solution to Reduce Heating and Cooling Utilities through Maximizing the Target Temperature of Crude Oil Streams Before Entering the Furnace. over the Past Few Decades, Significant Progress Has Been Made in Energy Integration Methods Including Pinch Technology and Mathematical Programming Approaches. Very Recently, Graphical Techniques Have Been Developed for Revamping Studies and Energy Analysis. Such Diagrams Are Valuable in Energy Targeting to Identity Energy Inefficiencies and Are Key to Potential Modifications for Maximum …
Surface Antibody Changes Protein Corona Both In Human And Mouse Serum But Not Final Opsonization And Elimination Of Targeted Polymeric Nanoparticles,
2023
IRCCS Centro Di Riferimento Oncologico Aviano
Surface Antibody Changes Protein Corona Both In Human And Mouse Serum But Not Final Opsonization And Elimination Of Targeted Polymeric Nanoparticles, Sara Capolla, Federico Colombo, Luca De Maso, Prisca Mauro, Paolo Bertoncin, Thilo Kähne, Alexander Engler, Luis Núñez, Gustavo Larsen, Et Al.
Chemical and Biomolecular Engineering: Faculty Publications
Background: Nanoparticles represent one of the most important innovations in the medical field. Among nanocarriers, polymeric nanoparticles (PNPs) attracted much attention due to their biodegradability, biocompatibility, and capacity to increase efficacy and safety of encapsulated drugs. Another important improvement in the use of nanoparticles as delivery systems is the conjugation of a targeting agent that enables the nanoparticles to accumulate in a specific tissue. Despite these advantages, the clinical translation of therapeutic approaches based on nanoparticles is prevented by their interactions with blood proteins. In fact, the so-formed protein corona (PC) drastically alters the biological identity of the particles. Adsorbed …
Optimizing Channel Formation In Peg Maleimide Hydrogels,
2023
University of Massachusetts Amherst
Optimizing Channel Formation In Peg Maleimide Hydrogels, Bakthavachalam Kannadasan
Masters Theses
Blood vessels including the arteries, veins, and capillaries are a critical and indispensable component of various organisms. Some studies estimate that if all the blood vessels present in our body are arranged in line, they would amount to a total length of approximately 60,000 miles. This distance is enough to circle the world two and a half times! In addition to being all pervasive, blood vessels perform certain key functions such as delivery of oxygen and nutrients to various tissues in the body. They also assist in the spread of diseases such as cancer. Therefore, it is important to study …
Computational Modeling Using A Novel Continuum Approach Coupled With Pathway-Informed Neural Networks To Optimize Dynein-Mediated Centrosome Positioning In Polarized Cells,
2023
George Mason University
Computational Modeling Using A Novel Continuum Approach Coupled With Pathway-Informed Neural Networks To Optimize Dynein-Mediated Centrosome Positioning In Polarized Cells, Arkaprovo Ghosal, Padmanabhan Seshaiyar Dr., Adriana Dawes Dr., General Genomics Inc.
Annual Symposium on Biomathematics and Ecology Education and Research
No abstract provided.
New Dual Modality Technique Of Gamma-Ray Densitometry (Grd) And Optical Fiber Probe (Ofp) To Investigate Line-Averaged Diameter Profiles Of Gas, Liquid, And Solid Holdups Along The Height Of A Slurry Bubble Column,
2023
Missouri University of Science and Technology
New Dual Modality Technique Of Gamma-Ray Densitometry (Grd) And Optical Fiber Probe (Ofp) To Investigate Line-Averaged Diameter Profiles Of Gas, Liquid, And Solid Holdups Along The Height Of A Slurry Bubble Column, Omar Farid, Binbin Qi, Sebastián Uribe, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
A new hybrid measurement technique was developed and employed to study line-averaged three-phase holdup distribution in a Slurry Bubble Column Reactor (SBCR) using gamma-ray densitometry (GRD) and point optical fiber probe (OFP) techniques. The OFP technique was used to measure the local gas holdup at 45 nodes in the cross-section area of the SBCR at three different axial levels. Thus, the GRD technique measured the spectrum of the SBCR for two different orientations simultaneously with the OFP technique at the same operating conditions to determine the solid holdup distribution radially and axially. The line-averaged solid holdup for 25% solids loading …
Development Of Eco-Friendly Chitosan-G-Polyacrylamide Preformed Particle Gel For Conformance Control In High-Temperature And High-Salinity Reservoirs,
2023
Missouri University of Science and Technology
Development Of Eco-Friendly Chitosan-G-Polyacrylamide Preformed Particle Gel For Conformance Control In High-Temperature And High-Salinity Reservoirs, Reem Elaf, Ahmed Ben Ali, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Oil and gas extraction has become challenging nowadays due to the accompanying amount of excess produced water that results in poor recoverability of hydrocarbon, besides other environmental and economic isues. A recent and efficient technology for conformance control is the injection of preformed particle gels (PPGs), which results in a more practical production process. Nevertheless, existing treatments fail in high-temperature reservoirs, are extremely sensitive to salinity, and are hazardous. The characteristics of the designed PPG, such as mechanical strength and thermal durability, is mainly depend on their crosslinking method. Polysaccharides-based gels prepared by physical crosslinking are weaker than the ones …
Preparation And Electrocatalytic Performance Of Feni-Cop/Nc Bifunctional Catalyst,
2023
Coellece of Transportation Engineering, Dalian Maritime University, Dalian, Liaoning, 361005, China
Preparation And Electrocatalytic Performance Of Feni-Cop/Nc Bifunctional Catalyst, Si-Miao Liu, Jing-Jiao Zhou, Shi-Jun Ji, Zhong-Sheng Wen
Journal of Electrochemistry
Rechargeable zinc-air batteries have gradually attracted much attention worldwide due to their high capacity, high energy density and low price. Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) correspond to the charging and discharging processes in rechargeable zinc-air battery, respectively. At present, commercial Pt/C and IrO2 catalysts hinder the large-scale application of zinc-air batteries due to low reserves, high prices and poor stability. Therefore, exploring high performance, low cost and high stability with dual functional catalysts is important for the development of rechargeable zinc-Air batteries. The metal-organic frameworks (MOFs) have high specific surface area, structural stability, good catalytic …
Charge-Dependence Of Dissolution/Deposition Energy Barrier On Cu(111) Electrode Surface By Multiscale Simulations,
2023
Materials Genome Institute, Shanghai University, 200444 Shanghai, China
Charge-Dependence Of Dissolution/Deposition Energy Barrier On Cu(111) Electrode Surface By Multiscale Simulations, Hang Qiao, Yong Zhu, Sheng Sun, Tong-Yi Zhang
Journal of Electrochemistry
Behaviors of electrified interface under different applied potentials/charges play the central role in electroplating process and electrochemical corrosion. The mechanism, however, is unclear yet for a surface atom dissolving/depositing from/on an electrode surface under an applied potential. The energy barrier along the reaction path is the key variable. The present work conductes hybrid first-principle/hybrid calculations to study the direct and indirect dissolution/deposition of a Cu atom on perfect/stepped Cu(111) planar electrodes in an electrolyte under different excess charges. Energy profiles present a linear relationship between the energies of the initial/final state and the activation state of different reaction paths under …
Research Progress And Performance Improvement Strategies Of Hard Carbon Anode Materials For Sodium-Ion Batteries,
2023
School of Science, Shanghai University, Shanghai 200444, China
Research Progress And Performance Improvement Strategies Of Hard Carbon Anode Materials For Sodium-Ion Batteries, Xiu-Ping Yin, Yu-Feng Zhao, Jiu-Jun Zhang
Journal of Electrochemistry
This paper systematically summarizes the research progress of hard carbon anode materials in sodium ion batteries(SIBs) and the development of the corresponding sodium storage mechanism in recent years, and reviews the performance improvement strategies of hard carbon materials from the aspects of structural design and electrolyte regulation. The effects of the selection of precursors, carbonization temperature, pretreatment, pore formers, heteroatom doping, material compounding, electrolyte regulation and pre-sodiumization on the sodium storage performance of hard carbon anode materials are briefly described. This paper provides new insights into the design, synthesis and electrolyte
matching of high-performance and low-cost hard carbon materials, and …
Surface Modifications Of Lini0.96Co0.02Mn0.02O2 With Tungsten Oxide And Phosphotungstic Acid,
2023
College of Energy, Xiamen University, Xiamen 361005, Fujian, China
Surface Modifications Of Lini0.96Co0.02Mn0.02O2 With Tungsten Oxide And Phosphotungstic Acid, Gang Zhao, Zheng-Liang Gong, Yi-Xiao Li, Yong Yang
Journal of Electrochemistry
With the rapid development of electric vehicles, enormous demands are made for higher energy density, better cycling performance and lower cost of lithium-ion batteries (LIBs). As an important high capacity cathode material for LIBs, the high nickel layered oxide material LiNi0.8Co0.1Mn0.1O2(NCM811) can reach an energy density of 760 Wh·kg–1. The ultra-high nickel ternary positive electrode material (LiNi1-x-yCoxMnyO2, x ≥ 0.90) has a specific capacity of more than 210 mAh·g–1, and can realize higher energy density. Besides, an ultra-high nickel material …
Enhancing Heat Transfer Performance In Simulated Fischer–Tropsch Fluidized Bed Reactor Through Tubes Ends Modifications,
2023
Missouri University of Science and Technology
Enhancing Heat Transfer Performance In Simulated Fischer–Tropsch Fluidized Bed Reactor Through Tubes Ends Modifications, Laith S. Sabri, Abbas J. Sultan, Jamal M. Ali, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Fluidized bed reactors are essential in a wide range of industrial applications, encompassing processes such as Fischer–Tropsch synthesis and catalytic cracking. The optimization of performance and reduction in energy consumption in these reactors necessitate the use of efficient heat transfer mechanisms. The present work examines the considerable impact of tube end geometries, superficial gas velocity, and radial position on heat transfer coefficients within fluidized bed reactors. It was found that the tapered tube end configurations have been empirically proven to improve energy efficiency in fluidized bed reactors significantly. For example, at a superficial gas velocity of 0.4 m/s, the tapered …
Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries,
2023
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China; University of Chinese Academy of Sciences, Beijing 100049, China
Asymmetric Electrode-Electrolyte Interfaces For High-Performance Rechargeable Lithium-Sulfur Batteries, Jia Chou, Ya-Hui Wang, Wen-Peng Wang, Sen Xin, Yu-Guo Guo
Journal of Electrochemistry
With a high cell-level specific energy and a low cost, lithium-sulfur (Li-S) battery has been intensively studied as one of the most promising candidates for competing the next-generation energy storage campaign. Currently, the practical use of Li-S battery is hindered by the rapidly declined storage performance during battery operation, as caused by irreversible loss of electroactive sulfide species at the cathode, dendrite formation at the anode and parasitic reactions at the electrode-electrolyte interface due to unfavorable cathode-anode crosstalk. In this perspective, we propose to stabilize the Li-S electrochemistry, and improve the storage performance of battery by designing asymmetric electrode-electrolyte interfaces …
Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes,
2023
School of Henan Industry and Trade Vocational College, Zhengzhou, 451191, China;Key Laboratory of Targeting Therapy and Diagnosis for Critical Diseases, Henan Province, Key laboratory of Advanced Drug Preparation Technologies, Ministry of Education, Collaborative Innovation Center of New Drug Research and Safety Evaluation, School of Pharmaceutical Sciences, Zhengzhou University, Zhengzhou, 450001, China
Dependence Of Heat Transfer Model On The Structure Of Electrically Coil-Heated Microelectrodes, Ju Li, Sen Yang, Jian-Jun Sun
Journal of Electrochemistry
Electrically heated microelectrodes have gained much attention in electroanalytical chemistry in recent years. It has been shown that the promotion of mass transport and reaction kinetics at high-temperatures often results in increased current signals. However, there is no study about the heat transfer inner the microelectrodes which is necessary for the design and operation for microsensors. This report introduces a finite element software (COMSOL) to analyze the factors that influence the surface temperature (Ts), which is crucial for the heating ability of micro-disk electrodes with coils. Distances between the electrode surface and the bottom of the heated copper …
Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell,
2023
Hubei Key Laboratory of Electrochemical Power Sources, Department of Chemistry, Wuhan University, Wuhan 430072, China
Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen
Journal of Electrochemistry
Hydrophobicity of the cathode catalyst layers (CCLs) crucially determines the performance of proton exchange membrane fuel cells (PEMFCs) by affecting the transports of oxygen and liquid water. In this regard, polytetrafluoroethylene (PTFE) is usually used as a hydrophobic additive to facilitate the oxygen and water transports in CCLs. So far, there remains lacking systematic effort to optimize the addition methods of PTFE in CCLs and the mechanisms behind. In this work, the effects of the approaches for PTFE addition and the distribution of PTFE on the mass transport of oxygen and the proton conduction in CCLs were studied by using …
Three-Dimensional Two-Phase Cfd Simulation Of Alkaline Electrolyzers,
2023
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China
Three-Dimensional Two-Phase Cfd Simulation Of Alkaline Electrolyzers, Ling-Yu Gao, Lin Yang, Chen-Hui Wang, Gui-Xuan Shan, Xin-Yi Huo, Meng-Fei Zhang, Wei Li, Jin-Li Zhang
Journal of Electrochemistry
The structural and operation parameters of the electrolyzer play important roles in the efficiency of alkaline water electrolysis. In this article, a three-dimensional numerical model coupled with the electric field and the Euler-Eulerian k-ε turbulence flow field was first established to simulate accurately the performance of alkaline electrolyzers, based on a compact assembly structure of the industrial alkaline water electrolyzers, especially at current densities higher than 5000 A·m–2. The simulation results are compared with the experimental data to verify the accuracy of the model. Suitable operating conditions for concentration, flow rate and the optimal design method of the …
Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects,
2023
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, Sichuan, China
Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects, Yue-Hui Zhai, Yi-Xiao Peng, Yan Hong, Yuan-Ming Chen, Guo-Yun Zhou, Wei He, Peng-Ju Wang, Xian-Ming Chen, Chong Wang
Journal of Electrochemistry
Copper interconnects are essential to the functionality, performance, power efficiency, reliability, and fabrication yield of electronic devices. They are widely found in chips, packaging substrates and printed circuit boards, and are often produced by copper electroplating in an acidic aqueous solution. Organic additives play a decisive role in regulating copper deposition to fill microgrooves, and micro-vias to form fine lines and interlayer interconnects. Generally, an additive package consists of three components (brightener, suppressor, and leveler), which have a synergistic effect of super-filling on electroplating copper when the concentration ratio is appropriate. Many works of literature have discussed the mechanism of …
Effect Of Amine Additives On Thermal Runaway Inhibition Of Sic||Ncm811 Batteries,
2023
State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China
Effect Of Amine Additives On Thermal Runaway Inhibition Of Sic||Ncm811 Batteries, Bo-Wen Hou, Long He, Xu-Ning Feng, Wei-Feng Zhang, Li Wang, Xiang-Ming He
Journal of Electrochemistry
The high energy density of NCM batteries with high nickel content is a key advantage in replacing fossil fuels and promoting clean energy development, at the same time, is also a fundamental cause of serious safety hazards in batteries. Primary and secondary amines can lead to ring-opening polymerization of common ethylene carbonate electrolytes, resulting in an isolation layer between the cathode and the anode, and improving the thermal safety of the battery. In this work, the safety of batteries is considered both at the material level and at the cell level, based on the chemical reactions between amines and the …
Pulse Electroplating Of Nanotwinned Copper Using Mps-Peg Two-Additive System For Damascene Via Filling Process,
2023
Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215213, China
Pulse Electroplating Of Nanotwinned Copper Using Mps-Peg Two-Additive System For Damascene Via Filling Process, Yu-Xi Wang, Li-Yin Gao, Yong-Qiang Wan, Zhe Li, Zhi-Quan Liu
Journal of Electrochemistry
High density nanotwinned copper films were pulse electroplated using an optimized electrolyte. In order to find out the influencing factors on the formation of nanotwins, series contents of MPS were added to the electrolyte during the pulse electroplating process. It was found that the copper films electroplated without MPS had large grains but a few nanotwins. And the grain size was about 0.9 μm on average, and the texture components of (110) and (111) crystal orientations were calculated as 49% and 27.8%, respectively. Differently, when 10 ppm MPS was added, the microstructure was changed to columnar grain with high density …
Effects Of Traps On Photo-Induced Interfacial Charge Transfer Of Ag-Tio2: Photoelectrochemical, Electrochemical And Spectroscopic Characterizations,
2023
State Key Laboratory of Physical Chemistry of Solid Surfaces and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
Effects Of Traps On Photo-Induced Interfacial Charge Transfer Of Ag-Tio2: Photoelectrochemical, Electrochemical And Spectroscopic Characterizations, Zhi-Hao Liang, Jia-Zheng Wang, Dan Wang, Jian-Zhang Zhou, De-Yin Wu
Journal of Electrochemistry
In the field of metal-semiconductor composites based plasmon-mediated chemical reactions, a clear and in-depth understanding of charge transfer and recombination mechanisms is crucial for improving plasmonic photocatalytic efficiency. However, the plasmonic photocatalytic reactions at the solid-liquid interface of the electrochemical systems involve complex processes with multiple elementary steps, multiple time scales, and multiple controlling factors. Herein, the combination of photoelectrochemical and electrochemical as well as spectroscopic characterizations has been successfully used to study the effects of traps on the photo-induced interfacial charge transfer of silver-titanium dioxide (Ag-TiO2). The results show that the increase of surface hydroxyl groups may …
Understanding Lignin’S Fast Pyrolysis Through Examination Of The Thermolysis Mechanisms Of Model Oligomers,
2023
University of Tennessee, Knoxville
Understanding Lignin’S Fast Pyrolysis Through Examination Of The Thermolysis Mechanisms Of Model Oligomers, Ross Wesley Houston
Doctoral Dissertations
The lignocellulosic biorefinery is a visionary concept that endeavors to provide an alternative to fossil-based refineries by producing biobased fungible fuels and specialty chemicals almost exclusively derived currently from petroleum refineries. This vision of the lignocellulosic biorefinery can only be realized if all fractions of lignocellulosic biomass are efficiently deconstructed and valorized to generate a diverse portfolio of products to sustain it against market vicissitudes. Of the three main structural constituents of lignocellulosic biomass (i.e., cellulose, hemicellulose, and lignin), lignin is underutilized despite being the most abundant renewable source of aromatic platform chemicals, representing a growing 250 billion dollar market. …
