Chemical Engineering Commons^™

Synthesis Algorithm Of Control System Based On Neural Network For The Gas And Oil Process, Jasur Sevinov, Abdishukurov Maqsudovich Shavkat, A.Z. Shodiyorov

Chemical Technology, Control and Management

Automatic control systems in the oil and gas processing are considered. After extraction of natural gas condensate, management of technological parameters plays an important role in its processing. Among the parameter of regulating algorithms, control based on neural network technology was considered. These control systems are created on the basis of algorithms of neural network technology. There are several structures of neural networks according to their structure. Differences in the process of information processing of these branching structures are considered.

Improving Technology For Producing Complex Fertilizer From Low-Grade Phosphorites Of The Central Kyzylkum, A.Zh. Allamuratova, A.U. Erkaev, A.M. Reimov, Saparbay Kazakhbaev, Dilshodbek Kurbiyazov

Chemical Technology, Control and Management

The methods of nitric acid processing of phosphate raw materials are analyzed. A technology has been developed for the nitric acid processing of phosphate raw materials into nitrogen-phosphorus fertilizer with the implementation of the process in a condensed pulp by adding sulfuric acid. A technology for producing complex fertilizers with a wide range of N:P₂O₅:K₂O ratios with improved physico-chemical parameters due to the introduction of various potassium salts into the process is proposed.

Dynamic Characteristics Of Magnetoelectric Linear Actuators Of Control Systems, Мakhmudjon Muxamedovich Аbdullayev, Rasul Ernazar Ogli Abdiev

Chemical Technology, Control and Management

This paper presents the results of studies carried out on magnetoelectric drives that carry out linear movement, models of drives are built and, on their basis, studies of the main indicators associated with the movement of a linear armature are carried out, such as: speed of movement, acceleration, current values, voltage and traction force of the armature. Also presented are the results of a study of magnetoelectric linear motion drives based on an analysis of graphs of their dynamic characteristics.

Algorithms For Structural Synthesis Of Control Systems For Dynamic Objects Under Conditions Of Unmeasurable Disturbances, Husan Zakirovich Igamberdiev, Uktam Farkhodovich Mamirov, Bunyod Mamurjon Ugli Buronov

Chemical Technology, Control and Management

The paper talks about ways to use inverse dynamic models to structure a control system for moving objects when disturbances are not measured. To solve the main problems that arise when implementing the inverse dynamic model method, methods for synthesizing inverse systems with given dynamic characteristics are used. The solution to this problem is obtained based on the theory that dynamic observers are invariant to unmeasured input influences. We broke down the matrix operator on the right into elementary orthogonal rotation matrices and on the left into permutation matrices to get a stable answer to the equation of the current …

Artificial Neural Network Based Grain Moisture Measuring Device, Erkin Eljaev, Shohrux Nurali O‘G‘Li Narzullayev, Elyor Faxriddinovich Khudoyberdiev

Chemical Technology, Control and Management

To date, the intellectualization of solving technical issues in managing, controlling, and measuring technological processes in all branches of industrial production is considered an urgent task. In this regard, a class of intelligent devices and sensors has emerged. Intelligent devices and sensors differ from their analog counterparts in that they have functions such as automatic adjustment of the measurement range, self-calibration, data processing, and decision-making. The article discusses the development of intelligent measuring instruments based on a capacitive transducer for measuring the moisture content of grain and grain products.

Valorization Of The Polymeric Constituents In Plastic Wastes Through Thermo-Chemical Processes By Using Viable Metal Oxides Additives, Labeeb Ali

Thesis/ Dissertation Defenses

The rapid accumulation of different types of plastic waste necessitates the development of effective and economically viable waste management operations. Such a process should ideally not only mitigate associated environmental burdens but also recycle and recover value-added products. Through incineration or pyrolysis, thermal processing has emerged as a mainstream approach to waste management of the ever-increasing loads of different categorized plastic wastes. Throughout the work of the thesis, we have utilized a multitude of complementary techniques spanning material characterizations, catalysis, kinetic modelling, and density functional theory (DFT) to comprehend the complex chemistry that underpins catalytic chemical recycling of plastic wastes. …

Study Of Kinetics Of Hydrocarbon Gas Purification With Composite Absorbents, Oybek Aripdjanov, Shavkat Nurullaev, Shodiyakhon Azimova

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the work is to improve the process of natural gas purification from acidic components using a composite absorbent. To study the sorption of acidic components in the gas composition, a chromatographic analysis method was used. The kinetics and rate of corrosion of carbon steel grade st.10 when using composite absorbents MDEA +DEA + AVRP have been studied. The results of the study show that the volume of absorption increased from 0.55 mol/mol to 0.65 mol/mol, and the amount of H₂S in the purified gas decreased from 0.022 g/m³ to 0.014 g/m³. Corrosion …

Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …

Modeling And Performance Analysis Of Solid Oxide Fuel Cell, Mariya Pecherskaya, Khakimjan Butanov, Suhrob A. Ibodullaev, Olim Ruzimuradov, Shavkat Mamatkulov

CHEMISTRY AND CHEMICAL ENGINEERING

A three-dimensional numerical model of the system configurations of various types of solid oxide fuel cells (SOFCs) is used and the effect of parameters on SOFC performance is numerically investigated using COMSOL Multiphysics. The effect of parameters such as support layer thickness, operating temperature, and electrode porosity are shown in the polarization and power curves for each model. The results of the study showed the advantages of the anode-supported SOFC compared to cathode- and electrolyte-supported SOFC.

Theoretical calculations demonstrate the highest output power density in the anode-supported SOFC at 900 ℃, and reach a value of 0.585 W cm^{-2 …}

Alkynylation Of Benzaldehyde And Its R-Substituted Derivatives Based On Lithium Phenylacetylenide, Sanat B. Samatov, Odiljon E. Ziyadullayev, Abduvakhab Ikramov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research work is for the first time the synthesis of the corresponding acetylene alcohols based on the alkynylation reaction of isolated benzaldehyde and its R-substituted derivatives in the BuLi/TGF system. The study proposed the reaction stages for the synthesis of acetylene alcohols in the selected BuLi/TGF system, the influence of factors influencing the process, including temperature, reaction duration and nature selected solvents. The structure of the synthesized acetylene alcohols was confirmed by modern methods of physicochemical analysis (¹H NMR, ¹³C NMR). In addition, the effect of substituents in benzaldehyde and its R-substituted derivatives …

A Tilted Broad Plume Underneath The Greenland Cratonic Keels, Dan Wang, Stephen S. Gao, Yangyang Liao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To advance our comprehension of the complex geological history and mantle dynamics in the north atlantic region, we employ all available broadband seismic data recorded in greenland to reveal an abnormal mantle transition zone (mtz) structure. Central and eastern greenland exhibits depressed 410 and 660 km discontinuities (d410 and d660, respectively) bordering the mtz, indicative of a substantial thermal anomaly associated with an underlying plume, surpassing the 1,800°c threshold for post-garnet phase transitions at the d660. Variations in mtz thickness across greenland stem from differing temperature anomalies at the d410 and d660, possibly linked to a tilted plume within the …

Electrocatalytic Cyclopropanation Of Active Methylene Compounds, Liang-Hua Jie, Hai-Chao Xu

Journal of Electrochemistry

The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.

Electrochemical Syntheses Of Aryl-Substituted Benzothiophenes And Phenanthrenes Using Benzenediazonium Salts As The Aryl Radical Precursors, Li-Yuan Lan, Yang-Ye Jiang, Raymond Daniel Little, Cheng-Chu Zeng

Journal of Electrochemistry

Aryl-substituted benzothiophene and phenanthrene are important structural units in medicinal chemistry and materials science. Although extensive effort has been devoted to prepare these compounds and a variety of approaches have been developed to construct the 2-substituted benzothiophene core structure, environmental-friendly and efficient synthetic means are still desired. Based on our previous electrochemical Minisci-type arylation reaction with aryl diazonium salt as the aryl precursor, as well as the work from König’s group, herein, we described the use of paired electrolysis to achieve 2-aryl benzothiophenes and 9-aryl phenanthrenes employing benzenediazonium salts as the aryl radical precursors. Initially, 2-methylthiobenzendiazonium salt 1a and 4-methylbenzene …

Electrochemical Advanced Treatment Of Desulfurization Wastewater From Coal-Fired Power Plants, Ju-Cai Wei, Juan Yi, Xu Wu

Journal of Electrochemistry

Zero-emission of desulfurization wastewater is one of the main demands for coal-fired power plants. As typical high salinity wastewater, it is hard to purify the desulfurization wastewater from coal-fired power plants through traditional physicochemical treatment or biochemical treatment, e.g., COD and Cl^–. A high concentration of Cl^– ion in desulfurization wastewater restricts wastewater reuse and zero-emission. Electrochemical technology is an attractive method for high salinity wastewater zero-emission, which provides a versatile, efficient, cost-effective, easily automatable, and clean industrial process. For advanced treatment of effluent after triple box process treatment in power plants, this paper reports an electrochemical …

Transforming Fermentation Residues From Date Fruit Pomace For The Synthesis Of Bioadsorbent Material In An Integrated Biorefinery Framework, Sabeera Haris

Thesis/ Dissertation Defenses

In the pursuit of enhanced waste management solutions, this comprehensive research delves into the untapped potential of date fruit pomace (DFP), an abundant byproduct from the date syrup industry that is currently underutilized, leading to environmental concerns. The study emphasizes the need for proper waste management and valorization strategies to mitigate the environmental impact of DFP and promote sustainability within the date processing industry. The initial phase involves characterizing DFP from Emirati varieties, highlighting its compositional and functional properties. The analysis reveals that DFP is rich in total dietary fiber (45.5%), residual sugars (35.3%), protein (10.6%), ash (4.1%), and fat …

A Synergistic Approach To Outreach And Teaching: Combining Service Learning At The College Level With A Summer Hands-On Outreach Program In Chemical And Biomolecular Engineering For High School Girls, Geeta Verma, Sogol Asaei, Jacob D. Hostert, Rebecca Ahn, Julie N. Renner

Faculty Scholarship

A synergetic approach to combine service learning at the university level with a high school outreach program is described. A holistic view is presented by discussing the importance of outreach and service learning, survey results, and outcomes. Overall, it was found that the unique program increased the self-efficacy (belief about one’s abilities) of students ranging from high school to graduate level, and positively impacted the social responsibility attitudes of university student participants.

Research Of The Influence Of Physical And Chemical Properties Of Coal On The Gasification Process Using The Example Of Angren Brown Coal, Murodjon Mamitbekovich Kavkatbekov, Rakhimzhan Pachekhanovich Babakhodzhaev

Technical science and innovation

The influence of the properties of Angren brown on the process of layered gasification was studied. The dependence of the calorific value of the resulting gas on the quality characteristics of coal when using air as a gasifying agent has been established. Methods are shown for increasing the calorific value of gas obtained during the gasification process when using coal with different moisture content and different fractional composition. The features of technological processes in the reaction zones of a laboratory gas generator have been studied. Based on generally accepted methods, the volume fractions of flammable components, as well as the …

Acoustothermal Transfection For Cell Therapy, Xiufang Liu, Ning Rong, Zhenhua Tian, Joseph Rich, Lili Niu, Pengqi Li, Laixin Huang, Yandai Dong, Wei Zhou, Pengfei Zhang, Yizhao Chen, Congzhi Wang, Long Meng, Tony Jun Huang, Hairong Zheng

Faculty Publications

Transfected stem cells and T cells are promising in personalized cell therapy and immunotherapy against various diseases. However, existing transfection techniques face a fundamental trade-off between transfection efficiency and cell viability; achieving both simultaneously remains a substantial challenge. This study presents an acoustothermal transfection method that leverages acoustic and thermal effects on cells to enhance the permeability of both the cell membrane and nuclear envelope to achieve safe, efficient, and high-throughput transfection of primary T cells and stem cells. With this method, two types of plasmids were simultaneously delivered into the nuclei of mesenchymal stem cells (MSCs) with efficiencies of …

Production Of Mrna Vaccine For Influenza, Christina Miller

Honors Theses

The objective of this project is to design a process to produce an mRNA influenza vaccine that serves as an alternative to conventional influenza vaccines, replacing current options with innovative mRNA technologies. Given that older populations are most likely to follow up on immunizations consistently, and the increasing average age worldwide, the market for this project appears to be expanding in the next 80 years. Additionally, experts predict more frequent mutations and outbreaks of viral disease from a variety of factors including globalization and global temperature trends. Rapid response to these viral outbreaks will continue to be as, or even …

Electrodeposition Of Gadolinium Metal Thin Films For Neutron Phase Contrast Imaging, Mary Louise Gucik

Chemical and Biological Engineering ETDs

A rare earth metal, gadolinium has unique magnetic properties and the largest neutron absorption cross section making it highly sought after in emerging technology. However, unlike most metals, it is difficult to work with and lacks a damascene process. When incorporated into alloys, gadolinium’s properties are muted and the film thickness must increase to account for the low concentration. Gadolinium metal films have been deposited successfully through sputter coating, but these films have density deficiencies and are limited to line-of-sight substrates. In this work, the deposition of gadolinium metal thin films was investigated for use on complex geometries via electrophoretic …