Study Of The Effects Of Thermal Aging Coupled With Shot-Peening Treatment Of Carbonitrided Din 1.6587 Low Alloy Steel On Retained Austenite And Residual Stresses,
2024
Department of Mining and Mineral Processing Engineering, School of Mines and Geosciences, University of Dar es Salaam, P.O. Box 35052, Dar es Salaam, Tanzania
Study Of The Effects Of Thermal Aging Coupled With Shot-Peening Treatment Of Carbonitrided Din 1.6587 Low Alloy Steel On Retained Austenite And Residual Stresses, Richard J. Katemi
Tanzania Journal of Engineering and Technology (TJET)
This work investigated the effects of thermal aging and shot-peening of carbonitrided 1.6587 steel grade on retained austenite and residual stresses. After carbonitriding samples contained maximum of 0.87% carbon, 0.34% nitrogen and 50 mass. -% retained austenite. Thermal aging conditions investigated were -30°C, 90°C and 150°C while the aging period were 14, 96 and 720 hours. After thermal aging, some of the samples were subjected to shot-peening treatment using standard cut wire shots StD – G3 - 0.6 mm VDFI 8001 with intensity in the range of 0.25 to 0.30 mmA and coverage of 1.00 to 1.24 x 98%. It …
Thermogravimetric Analysis And Chemical Kinetics Of Waste Tires,
2024
University of Dar es Salaam
Thermogravimetric Analysis And Chemical Kinetics Of Waste Tires, Mahir Mohammed Said
Tanzania Journal of Engineering and Technology (TJET)
The focus of this paper is to analyse the pyrolysis reaction of waste tires. The pyrolysis was studied experimentally using thermal and chemical kinetics. The tires were pyrolyzed using thermogravimetry at a temperature range of 200 to 600°C, with heating rates of 10, 20, and 50°C/min. The activating energy was observed to increase with increased temperature. The highest activating energy was 101.02 kJ/mol at a heating rate of 50°C/min.
Enhanced Post Deposition Annealing Conditions On The Fabrication Of High Quality Thermochromic Vanadium Dioxide Films,
2024
Department of Physics, University of Dar es Salaam, P.O. Box 35063, Dar es Salaam, Tanzania
Enhanced Post Deposition Annealing Conditions On The Fabrication Of High Quality Thermochromic Vanadium Dioxide Films, Nuru R. Mlyuka
Tanzania Journal of Engineering and Technology (TJET)
Sputter deposition of thermochromic VO2 thin films for smart window applications has been faced with several challenges including the need for high deposition temperature, extremely precise and narrow range of oxygen/argon flow ratio and target poisoning during sputtering. Deposition of VO2 at room temperature without oxygen followed by post-deposition annealing has been cited as one of the potential mitigations to the challenge. In this study, the effects of post-deposition annealing conditions on the structural, electrical and optical properties of VO2 thin films are reported. The films were prepared on soda lime glass substrates using DC magnetron sputtering of metallic vanadium …
Design And Optimization Of An Azeotropic Distillation Pilot Plant For The Production Of Pure Ethanol,
2024
Department of Chemical and Process Engineering, College of Engineering and Technology, University of Dar es Salaam, P.O. Box 35131, Dar es Salaam, Tanzania
Design And Optimization Of An Azeotropic Distillation Pilot Plant For The Production Of Pure Ethanol, Samwel V. Manyele
Tanzania Journal of Engineering and Technology (TJET)
This study aimed to design an azeotropic distillation plant using Aspen Plus® V10 software and determine optimal process conditions for producing pure ethanol greater than 95% from pre-concentrated near-azeotropic ethanol-water solution. The non-random two-liquid Redlich-Kwong thermodynamic model was the base method for property analysis and performance prediction. Modelling and simulation of the converged process were conducted for fixed column variables (R = 5, N = 12 and p = 1 atm). Plant operating parameters were varied in the range of 0 to 1 for the pre-heater vapour fraction, 2 to 10 for the column feed plates (NFP), 2 to 6 …
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant,
2024
Missouri University of Science and Technology
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In recent years, significant attention has been directed toward evaluating the reactivity of diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these polymers, pim-1 has emerged as an exceptional candidate due to its noteworthy attributes including high surface area, excellent solubility, and the capability to fine-tune the nitrile functional groups along its polymeric backbone. In this study, we explored the impact of different functional groups, such as amidoxime (ax), aldoxime (ox), and carboxylate (cooh), on the degradation of dimethyl 4-nitrophenylphosphonate (dmnp) in comparison to pure pim-1 and their respective ce(oh)4-loaded polymer composites. Remarkably, the pim-1-ax analog exhibited …
Lung Cancer Drug Study Using Alc Nanoparticles,
2024
Missouri University of Science and Technology
Lung Cancer Drug Study Using Alc Nanoparticles, Noah Sparks
Undergraduate Research Conference at Missouri S&T
In a previous project it was determined ALC polarized lipid nanoparticles have a high transfection efficiency in some lung cancer cell lines. Building off this information, these ALC particles will now be tested with an actual lung cancer drug. This process will consist of searching articles for promising lung cancer drugs and selecting one for use. The ALC particles will then undergo a comprehensive drug study using multiple lung cancer cell lines with the selected drug. Aspects such as drug release rate, transfection rate, cytotoxicity, etc. will be determined. The goal is to determine whether ALC nanoparticles show real promise …
Biosensors For Antibacterial Medical Applications,
2024
Missouri University of Science and Technology
Biosensors For Antibacterial Medical Applications, Ryan Fagan, Shelby Wallen
Undergraduate Research Conference at Missouri S&T
Healthcare associated infections are significant concern in medicine and as antibiotics are becoming less effective, we need new alternative methods to treat them. We are testing various materials that can be used to prevent infections in healthcare settings and in wound treatments. These materials include bioactive glass and modified hydrogel materials. From these studies we've learned these are effective in killing bacteria and preventing infections. The goal of this project is to determine the mechanism at which these materials kill bacteria. Our approach is to construct biosensor strains that can indicate bacterial stress response to antimicrobial agents. We have used …
Ionizable Lipid Nanoparticles Fabrication For Gene Delivery,
2024
Missouri University of Science and Technology
Ionizable Lipid Nanoparticles Fabrication For Gene Delivery, Noah Sparks, Lei Xu, Hu Yang
Undergraduate Research Conference at Missouri S&T
In this project ionizable lipids were analyzed for their efficacy in delivery of mRNA in multiple metastatic lung cancer cells. Different ionizable lipids with their molar ratio in making the LNPs were analyzed in order to enhance the nucleic acid delivery to cytoplasm. Phospholipids also play a role in targeting efficacy of the LNPs to the lung cells. Different combination of ionizable lipids with multiple phospholipids were studied for physical characterization and in-vitro transcription efficiency. Transcription efficiency was then quantified using flow cytometry and optimal particles for transcription were noted.
Investigating The Role Of Fluid Shear Stress During Metastasis On Enhanced Breast Cancer Extravasation,
2024
Louisiana State University and Agricultural and Mechanical College
Investigating The Role Of Fluid Shear Stress During Metastasis On Enhanced Breast Cancer Extravasation, Alejandra M. Ham
LSU Master's Theses
In 2022, ~288,000 American women were diagnosed with metastatic breast cancer which was the leading cause of patient mortality with ~43,000 American women succumbing to the disease. Women can be diagnosed with four different molecular subtypes of breast cancer: luminal A, luminal B, human epithelial growth receptor type 2 enriched (HER2+), and triple-negative breast cancer (TNBC). TNBC accounts for ~12% of all breast cancers, yet it has the worst outcomes. TNBC is highly invasive, with ~46% of TNBC patients developing metastatic disease. A further understanding of metastatic TNBC is needed to provide a greater understanding of how to treat this …
Mitigation Of Potential Risks In Chemical Laboratories: A Focused Review,
2024
Missouri University of Science and Technology
Mitigation Of Potential Risks In Chemical Laboratories: A Focused Review, Hossein Abedsoltan, Mark B. Shiflett
Chemical and Biochemical Engineering Faculty Research & Creative Works
This review paper presents an analysis of safety practices in chemical laboratories. It encompasses a systematic exploration of various facets including risk assessment, hazard mitigation, and the implementation of safety protocols. Emphasis is placed on the critical role of continuous education and training, advocating a proactive safety culture, and adapting to technological advancements. Additionally, the paper underscores the importance of adhering to regulatory standards, promoting exceeding baseline compliance toward establishing best practices in laboratory safety. This comprehensive approach highlights the dynamic, multifaceted nature of laboratory safety, positioning it as a fundamental aspect of scientific research.
Aphid-Ant Relationships: The Role Of Cuticular Hydrocarbons
And Different Chemical Stimuli In Triggeringmutualistic Behavior,
2024
Humboldt-Universität zu Berlin, University of Agriculture and Life Sciences, Desert Research Center
Aphid-Ant Relationships: The Role Of Cuticular Hydrocarbons And Different Chemical Stimuli In Triggeringmutualistic Behavior, Amged El-Harairy, Ahmed El-Harairy, Alaa Mahfouz
Department of Chemical and Biomolecular Engineering: Faculty Publications
In ant-aphid interactions, various aphid species offer honeydew to the ant partner and increase their density by ant attendance, whilst others never attend ant species, in which case ants tend to treat them as prey. In this regard, ants should have the ability to distinguish myrmecophile aphid species from non-mutualistic species, so that mutualistic aphids will be accepted as partners rather than prey. Although ant-aphid interactions are now the focus of chemical ecology studies, the role of the different chemical stimuli in determining mutualistic interactions has not been completely clarified. Therefore, we have investigated the cuticular hydrocarbon profile of four …
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes,
2024
Missouri University of Science and Technology
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
A global energy transition from fossil-based to renewable-based systems requires advancements in various energy sectors. Current chemical separation processes are quite energy-intensive and require significant advancement to make this transition happen. In the energy transition era, reducing the dependency of separation processes on fossil-based thermal energy seems inevitable for transitioning smoothly and meeting the stringent timelines. In particular, adsorption-based separation processes have the potential to be fully electrified through innovative strategies in developing stimuli-responsive adsorbents and swing processes. In this review, we discuss the recent efforts in electrification of adsorption processes and provide an overview of emerging materials and processes. …
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure,
2024
Missouri University of Science and Technology
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Laboratory Evaluation Of High-Temperature Resistant Lysine-Based Polymer Gel Systems For Leakage Control,
2024
Missouri University of Science and Technology
Laboratory Evaluation Of High-Temperature Resistant Lysine-Based Polymer Gel Systems For Leakage Control, Tao Song, Xuyang Tian, Baojun Bai, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Thomas P. Schuman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
In-situ crosslinking gel known for its cost-effectiveness, has been employed for decades to plug high-permeability features in subsurface environments. However, some commonly used crosslinkers are being phased out due to the increasingly rigorous environmental regulations. As a newly discovered environmentally friendly crosslinker, lysine can crosslink the partially hydrolyzed polyacrylamide through transamidation reaction. The present work aimed to study the effect of polymer composition and concentration on the gelation behavior of lysine and high molecular weight acrylamide-based polymers. Several commercial high molecular weight polymers with different contents of 2-Acrylamido-2-methyl-1-propane sulfonic acid (AMPS) including AN-105/125, SAV-55/37/28, and SAV-10 were deployed in this …
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions,
2024
Missouri University of Science and Technology
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of palladium-modified (Pd-modified) CuO-ZnO-Al2O3 (CZA) catalysts with various Pd loadings (0.3 wt% to 2.4 wt%) were prepared using the wetness impregnation method, on two CZA supports with different structures that are CZA-aged precursor composed of a mixture of zincian-malachite and hydrotalcite-like phases (CZA-zH), and CuO-ZnO-Al2O3 metal oxide nanoparticles (CZA-MO). Enhancement on catalytic activity can be observed on both Pd-modified CZA catalysts in a temperature range of 180–240 °C for methanol synthesis via CO2 hydrogenation. Pd/CZA-zH catalysts exhibited a more efficient and stable production of methanol at a relatively low reaction temperature of 180 °C for 100 hrs. of …
Applications Of Plastics In The Automotive Industry: Current Trends And Future Perspectives,
2024
Missouri University of Science and Technology
Applications Of Plastics In The Automotive Industry: Current Trends And Future Perspectives, Hossein Abedsoltan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Plastics have transformed the automotive industry, contributing substantially to automobile design, weight reduction, fuel efficiency, safety, and sustainability. This review paper examines the applications of plastics in the automotive sector, evaluates the present trends, and describes the future plastic consumption possibilities, emphasizing emerging technology and sustainable practices. The paper delineates how plastics have become an essential component of automotive innovation and illustrates the possibilities for additional breakthroughs in this dynamic industry. Highlights: Advances in plastics, bioplastics, and smart materials in the auto industry. Plastic role in design, safety, and sustainability in the auto industry. Recycling and the circular economy of …
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies,
2024
Missouri University of Science and Technology
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Upgrading heavy oil is a subject of high importance for fossil fuel industry due to the rapid depletion of light oil reservoirs and the consequent increased demand for upgrading heavy oil. In this review, the advancement made in heavy oil upgrading and the proposed sustainable emerging technologies dedicated to heavy oil processing have been discussed in a comprehensive and informative manner with consideration to the encountered associated with properties of heavy oil including its significant content of undesirable large molecular weight hydrocarbons, its high viscosity, and its elevated impurity level. The shortcomings of conventional crude oil upgrading technologies are outlined, …
Influence Of Alkali Metal Cations On The Oxygen Reduction Activity
Of Pt5Y And Pt5Gd Alloys,
2024
Universität München
Influence Of Alkali Metal Cations On The Oxygen Reduction Activity Of Pt5Y And Pt5Gd Alloys, Kun-Ting Song, Alexandra Zagalskaya, Christian M. Schott, Peter M. Schneider, Batyr Garlyyev, Vitaly Alexandrov, Aliaksandr S. Bandarenka
Department of Chemical and Biomolecular Engineering: Faculty Publications
Electrolyte species can significantly influence the electrocatalytic performance. In this work, we investigate the impact of alkali metal cations on the oxygen reduction reaction (ORR) on active Pt5Gd and Pt5Y polycrystalline electrodes. Due to the strain effects, Pt alloys exhibit a higher kinetic current density of ORR than pure Pt electrodes in acidic media. In alkaline solutions, the kinetic current density of ORR for Pt alloys decreases linearly with the decreasing hydration energy in the order of Li+ > Na+ > K+ > Rb+ > Cs+, whereas Pt shows the opposite trend. To gain …
An Overview Of Maternity Healthcare Monitoring In Developing Nations,
2024
Mbeya University of Science and Technology
An Overview Of Maternity Healthcare Monitoring In Developing Nations, Godphrey Kyambille
Tanzania Journal of Engineering and Technology (TJET)
A healthcare monitoring arrangement is essential for frequently monitoring a patient's health status. Specifically, maternal healthcare systems for tracking are utilized to evaluate the clinical status and monitor any abnormal condition changes during all three trimesters. This paper's objective is to conduct an extensive literature review and acknowledge earlier initiatives and studies conducted previously in maternal health care monitoring. This review focuses on accumulating information from earlier work and presents a general overview of previous studies concerning maternal health care monitoring (MHCM). The paper focuses on the maternal healthcare systems in developing countries accessed by pregnant women during the antenatal …
A Review Of Proton Exchange Membrane Degradation Pathways,
Mechanisms, And Mitigation Strategies In A Fuel Cell,
2024
KU Leuven Bruges
A Review Of Proton Exchange Membrane Degradation Pathways, Mechanisms, And Mitigation Strategies In A Fuel Cell, Dharmjeet Madhav, Junru Wang, Rajesh Keloth, Jorben Mus, Frank Buysschaert, Veerle Vandeginste
Department of Chemical and Biomolecular Engineering: Faculty Publications
Proton exchange membrane fuel cells (PEMFCs) have the potential to tackle major challenges associated with fossil fuel-sourced energy consumption. Nafion, a perfluorosulfonic acid (PFSA) membrane that has high proton conductivity and good chemical stability, is a standard proton exchange membrane (PEM) used in PEMFCs. However, PEM degradation is one of the significant issues in the long-term operation of PEMFCs. Membrane degradation can lead to a decrease in the performance and the lifespan of PEMFCs. The membrane can degrade through chemical, mechanical, and thermal pathways. This paper reviews the different causes of all three routes of PFSA degradation, underlying mechanisms, their …
