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The Design And Implementation Of A Modular Tissue Engineering Test Bed To Pursue An Alternate Pathway Of Cell Culture Based Research, Ryley Patrick Griffin 2024 Florida Institute of Technology

The Design And Implementation Of A Modular Tissue Engineering Test Bed To Pursue An Alternate Pathway Of Cell Culture Based Research, Ryley Patrick Griffin

Theses and Dissertations

The development of a Modular Automated Tissue Engineering Test Bed (MATETB) is the next step in the development of cheap and easily available in vitro cell regulatory systems for both academic and industrial purposes. This project outlined the framework and requirements for a device that could automatically regulate and collect data on a cell culture through the manipulation of its liquid environment. From this framework, a prototype was built. The device would fulfill cell culture needs while collecting data automatically and allowing for live viewing and imaging of cells. The device was comprised of a mechanical skeleton (MS), an environmental …


Development And Characterization Of Organic Electrocatalysts For Use In Zinc-Air Batteries, Christopher John Merkel 2024 University of Nebraska-Lincoln

Development And Characterization Of Organic Electrocatalysts For Use In Zinc-Air Batteries, Christopher John Merkel

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

The global deployment of solar photovoltaic and wind power is projected by the International Energy Agency as the primary pathway to reduce dependence on fossil fuels. However, these technologies face a critical bottleneck: their inherently intermittent power generation. For “intermittent renewables” to become the dominant source of electrical energy, efficient energy storage systems are essential. Current storage solutions are not viable on a global scale due to material scarcity, safety concerns, and high capital costs. Among emerging technologies, zinc-air batteries (ZABs) have garnered significant interest. ZABs offer a theoretical energy density five times greater than traditional lithium-ion batteries, utilize safe …


Boosting The Power Performance Of Microbial Fuel Cells By Using Dual Nanomaterial-Modified Carbon Felt Electrodes, Krishna Thapa, Wenyan Liu, Yuwei Zhang, David J. Westenberg, Yishu Zhou, Risheng Wang 2024 Missouri University of Science and Technology

Boosting The Power Performance Of Microbial Fuel Cells By Using Dual Nanomaterial-Modified Carbon Felt Electrodes, Krishna Thapa, Wenyan Liu, Yuwei Zhang, David J. Westenberg, Yishu Zhou, Risheng Wang

Chemistry Faculty Research & Creative Works

Innovative design enhancements to microbial fuel cells (MFCs) are pivotal for improving their viability as renewable energy sources. This study introduces a dual approach to electrode modification, integrating polyaniline (PANI) and gold nanoparticles (AuNPs) on carbon felt (CF) anodes coupled with a unique cathode composed of DNA origami and chitosan. The synergistic effect of PANI and AuNPs significantly increases the hydrophilicity and conductivity of the anode, leading to a considerable surge in power density. Concurrently, the biocompatible DNA origami and chitosan-functionalized cathode facilitates efficient electron transfer without relying on conventional catalysts. Together, these modifications yield a 52.42% increase in the …


Process Development And Techno-Economic Analysis For Combined And Separated Co2 Capture-Electrochemical Utilization, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei 2024 Missouri University of Science and Technology

Process Development And Techno-Economic Analysis For Combined And Separated Co2 Capture-Electrochemical Utilization, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Combining CO2 capture and utilization into a single unit operation offers a feasible solution for converting a sustainable feedstock into marketable commodity chemicals, while reducing energy requirements from separated processes. In this research, we developed a process model and performed a techno-economic analysis (TEA) for point-source CO2 capture and electrochemical-based utilization in light olefins production under both separated and integrated scenarios. CO2 containing flue gas from a 500 MW power plant was utilized as a feed while CO2 utilization involved electrochemical reduction reactions to produce light olefins directly from CO2. A meticulous analysis was …


Biocargos: Capture And Release Gels For Room Temperature Cell Storage., Justin Jacobson 2024 University of Louisville

Biocargos: Capture And Release Gels For Room Temperature Cell Storage., Justin Jacobson

Electronic Theses and Dissertations

Currently, cryovials on dry ice or liquid nitrogen vapor transportation vessels are primary ways utilized to transport mammalian cells from one location to another. Due to the safety concerns of dry ice and liquid nitrogen, associated costly shipping charges, and limitations of proper packaging and labeling of materials, these conventional shipping techniques are unacceptable. It is urgent to develop a safe and environmentally friendly protocol to preserve and ship the biological samples from one place to another. In this research, a method was developed for an ecofriendly and safe protocol to preserve cancer cells. The cell viability of cell line …


Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang 2024 Missouri University of Science and Technology

Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ammonia synthesis has significant implications for global energy and environmental issues, driving the need for highly active catalysts that operate under mild conditions. This study reports the successful deposition of uniform ∼1.0 nm metallic ruthenium (Ru) nanoclusters onto Ba-LaCeOx particles via atomic layer deposition (ALD). The catalytic performance of the ALD-prepared Ru nanoclusters was assessed for ammonia synthesis and compared with two catalysts produced by conventional incipient wetness impregnation. For the ALD-prepared Ru nanoclusters, a pre-reaction H2-reduction step induced partial encapsulation of suboxide species on Ru sites due to strong metal-support interactions, limiting Ru nanocluster sintering and …


Carboxymethyl Cellulose-Based Preformed Particle Gels For Water Management In Oil And Gas Reservoirs, Ahmed Ben Ali, Ahmed Hamza, Abdulaziz A. Almakimi, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai 2024 Missouri University of Science and Technology

Carboxymethyl Cellulose-Based Preformed Particle Gels For Water Management In Oil And Gas Reservoirs, Ahmed Ben Ali, Ahmed Hamza, Abdulaziz A. Almakimi, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Carboxymethyl cellulose (CMC) based materials have been proposed as preformed particle gels (PPGs) for reducing excessive water production in oil and gas reservoirs. Multi-sized dry particles ranging between 100 and 1180 μm have been synthesized using microwave-assisted grafting copolymerization of CMC and acrylamide (AM)/n,n''-methylene-bisacrylamide (MBA). FTIR and SEM confirmed CMC crosslinked polyacrylamide's chemical structure and morphology (CMC/CPAM). Thermo-gravimetric analysis has demonstrated the thermal stability of dry PPGs up to 309 °C. CMC/CPAM showed slightly high absorbency in brine 2 (TDS = 67.3 g/L) compared to brine 1 (TDS = 33.65 g/L), 1% NaCl, and deionized water, with swelling ratios (SR) …


The Effectiveness Of Certain Biological Additives Considered By-Products Of The Food Industry In Baker’S Yeast Activation, Nataliya E. KULIKOVA, Antonina G. CHERNOBROVINA, Natalia N. ROEVA 2024 Russian Biotechnological University (ROSBIOTECH), Russia, Moscow

The Effectiveness Of Certain Biological Additives Considered By-Products Of The Food Industry In Baker’S Yeast Activation, Nataliya E. Kulikova, Antonina G. Chernobrovina, Natalia N. Roeva

CHEMISTRY AND CHEMICAL ENGINEERING

One of the ways to increase the efficiency of the activation process of baking yeast is the use of waste and by-products of the food industry as nutrient media. The goal of the study was to develop ways to activate yeast in a nutrient medium with dietary supplements: potato cell sap, whey and quince pomace powder. We demonstrated the effectiveness of the use of biological additives (potato cell juice, quince pomace powder, whey), which are waste or by-products of the food industry to activate yeast. We have established that incubation in a nutrient medium with dietary supplements has a beneficial …


Glycerol-Free Biodiesel Via Catalytic Interesterification: A Pathway To A Netzero Biodiesel Industry, Nessren Farrag, Omar Youssef Youssef, Esraa Khaled, Omar Aboelazayem 2024 The British University in Egypt

Glycerol-Free Biodiesel Via Catalytic Interesterification: A Pathway To A Netzero Biodiesel Industry, Nessren Farrag, Omar Youssef Youssef, Esraa Khaled, Omar Aboelazayem

Chemical Engineering

Conventional biodiesel manufacturing uses alcohol as an acyl acceptor, resulting in glycerol as a side product. The increased demand for biodiesel has led to the production of a substantial surplus of glycerol, exceeding the market need. Consequently, glycerol is now being regarded as a byproduct, and in some cases, even as waste. The present study aims to suggest an economically viable and ecologically friendly approach for maintaining the viability of the biodiesel sector. This involves generating an alternative byproduct of higher value, rather than glycerol. Triacetin is produced through the interesterification of triglycerides with methyl acetate, and is a beneficial …


Enhancing Ammonium And Bicarbonate Tolerance In Chlorella Sorokiniana Through Ems-Induced Mutagenesis, Wentao Yang 2024 Washington University in St. Louis

Enhancing Ammonium And Bicarbonate Tolerance In Chlorella Sorokiniana Through Ems-Induced Mutagenesis, Wentao Yang

McKelvey School of Engineering Graduate Student Theses & Dissertations

This study explores the enhancement of ammonium and bicarbonate tolerance in Chlorella sorokiniana via EMS-induced mutagenesis, aimed at improving the microalgae's resilience and growth under high-stress conditions of elevated NH4+ and HCO3 concentrations. By mutating C. sorokiniana using EMS, we developed mutant strains capable of thriving in conditions that are inhibitory to the wild type strain. The successful adaptation of these strains demonstrates a significant increase in biomass production and tolerance to environmental stressors, highlighting the potential of EMS mutagenesis in industrial algal applications for sustainable biofuel production and environmental remediation.


A New Air-Assisted Flare Tip Design For Managing Gas Flare Emissions (Cfd Analysis), Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana 2024 Missouri University of Science and Technology

A New Air-Assisted Flare Tip Design For Managing Gas Flare Emissions (Cfd Analysis), Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana

Chemical and Biochemical Engineering Faculty Research & Creative Works

Recently, flares have been considered as a major source of air pollution from the petroleum refining industry. The United Nations has instigated an international effort related to the management of flare emissions to reduce the global warming impact related to flaring. Eliminating or removing the need for gas flares is difficult because these devices are generally used as safety devices to allow the combustion of flammable gases in a controlled fashion which supports safe operation. However, reducing flaring is generally possible using well-designed, efficiently operated flare equipment. In general, flare performance can be enhanced following the API-521 methodology and using …


Antibiotic-Loaded Dendrimer Hydrogels In Periodontal Bone Regeneration: An In Vitro Release Feasibility Study, Nicholas Yesbeck, Da Huang, Caroline Carrico, Parthasarathy Madurantakam, Hu Yang 2024 Missouri University of Science and Technology

Antibiotic-Loaded Dendrimer Hydrogels In Periodontal Bone Regeneration: An In Vitro Release Feasibility Study, Nicholas Yesbeck, Da Huang, Caroline Carrico, Parthasarathy Madurantakam, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The prescription of a course of oral antibiotics following bone grafting procedures is a common practice in clinical periodontics to reduce surgical site infections. The goal of this study is to characterize the release profile of antibiotics via local delivery using dendrimer hydrogels (DH) and to analyze the effect of two different particulate bone allografts on the release of the antibiotics in vitro. DH were synthesized from Poly amidoamine (PAMAM) dendrimer G5 and polyethylene glycol diacrylate, and cefazolin was chosen as the antibiotic. The antibiotic-loaded samples were bathed in PBS and incubated at 37 °C; aliquots were taken (1 h, …


Consistent Intraocular Pressure Reduction By Solid Drug Nanoparticles In Fixed Combinations For Glaucoma Therapy, Da Huang, Pedro Norat, Lin Qi, Anna Chernatynskaya, James D. Cole, Vimalin Jeyalatha Mani, Lei Xu, Xiaorong Liu, Hu Yang 2024 Missouri University of Science and Technology

Consistent Intraocular Pressure Reduction By Solid Drug Nanoparticles In Fixed Combinations For Glaucoma Therapy, Da Huang, Pedro Norat, Lin Qi, Anna Chernatynskaya, James D. Cole, Vimalin Jeyalatha Mani, Lei Xu, Xiaorong Liu, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Efficient topical drug delivery remains a significant challenge in glaucoma management. Although nanoparticle formulations offer considerable promise, their complex preparation processes, co-delivery issues, and batch consistency have hindered their potential. A scalable fabrication strategy is developed here for preparing solid drug nanoparticles (SDNs) with enhanced drug delivery efficiency. Utilizing hydrophobic antiglaucoma drugs brimonidine (BM) and betaxolol (BX), uniform fixed combination BM/BX SDNs are fabricated through a continuous process, improving batch-to-batch consistency for combined glaucoma treatment. With trehalose being used as a lyoprotectant, BM/BX SDNs can be stored as dry powder and easily reconstituted in phosphate buffered saline. Importantly, reconstituted BM/BX …


Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah 2024 University of Dar es salaam

Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah

Tanzania Journal of Engineering and Technology (TJET)

Water quality continues to be the challenge to residents in Dar es Salaam due to various anthropogenic activities in the city. This study was conducted to assess groundwater quality by determining concentrations of heavy metals. Both probability and Nonprobability sampling techniques were used to collect samples from 40 groundwater wells in 24 wards of Temeke municipal and analysed using Microwave Plasma Atomic Emission Spectrometer (Agilent 4210 MP-AES) at the Geochemistry Laboratory of the University of Dar es Salaam. Results indicated varying heavy metal concentrations ranging from 0.71 ± 0.08 to 6.64 ± 0.21 mg/l for As, 0.02 ± 0.01 to …


Genetically-Encoded Optical Barcodes For Single-Cell Analysis, Daniel Pritko 2024 Clemson University

Genetically-Encoded Optical Barcodes For Single-Cell Analysis, Daniel Pritko

All Theses

Cell barcodes are capable of being used to answer many different biological questions. They have been used to track the lineage of cells to identifying the function of a gene. While there are multiple different methods to creating cell barcodes, they are limited in their scalability and application. In a previous publication we propose and computationally prove an optical single-cell barcoding method that bridges fast and scalable readouts with the benefits of genetic encoding. In this approach fluorescent proteins (fps) are combined to form fluorescent barcodes that can then be analyzed using a spectral flow cytometer. Here, we test the …


Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer 2024 Missouri University of Science and Technology

Meteorological Data Mining And Synthesis For Supplementing On-Site Data For Regulatory Compliance, Ben Sonpon, Shoaib Usman, Joseph Smith, Sarah Kovaleski, Jason Wibbenmeyer

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Many regulatory requirements add significant delay in the licensing of new nuclear power stations. One area of particular interest is the environmental impact of potential atmospheric release. The purpose of this research is to demonstrate effectiveness of meteorological data mining and synthesis from offsite locations to reduce need for onsite data, hence allowing rapid licensing. The automated procedures tested for data mining and extraction of meteorological data from multiple offsite sources and the data analytic tool developed for data fusion are presented here. Three important meteorological parameters from regulatory compliance are considered for this analysis: wind velocity, wind direction, and …


Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei 2024 Missouri University of Science and Technology

Design And Development Of Uio-67-Coated Pim-1-Based Composites And Demonstration Of Their Detoxification Performance, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Polymer-supported MOF composites have emerged as versatile candidates for various separation and catalytic applications. In this study, we demonstrate design and development of UiO-67-coated Ce(OH)4@PIM-1 composites via dip-coating, drop-casting, solid-phase coating, and supramolecular assembly, and assess their preparation-structure-performance relations. The catalytic performance of the composites was investigated through hydrolysis of dimethyl 4-nitrophenyl phosphate (DMNP), as a nerve agent simulant. The findings revealed that while dip-coating method was unable to achieve a thick and uniform coverage of the MOF layer on the Ce(OH)4@PIM-1, the supramolecular assembly gave rise to 16 wt.% MOF loading and the composite prepared …


Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan 2024 Missouri University of Science and Technology

Examination And Improvement Of The Taguchi-Based Nanofluids Impact On Co2 Absorption Using Al2o3 Nanoparticles, Safa Waleed Shakir, Saif Saleh Hussein, Shaymaa Hasan Khazaal, Hyder Akram Al-Naseri, Ahmed Mohammed Ahmed, Rana Najah Hachim, Muthanna Hikmat Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, a batch absorption reactor was used to evaluate the nanofluid of a binary aqueous solution of monoethanolamine and 2-amino-2-methyl-1-propanol (MEA/AMP) with nanoparticles of aluminium oxide (Al2O3) as a solvent used to remove carbon dioxide (CO2) from simulated flue gas. Furthermore, the application of the Taguchi experiment design method determined the optimal conditions for the absorption process. This research focuses on the CO2 absorption process and the optimal conditions related to nanoparticle addition. The main effects of using nanofluid were investigated. The concentration of nanoparticles, nanoparticle size, and stirrer speeds were …


Investigating The Detection And Transport Of Low Molecular Weight Species To Better Understand Their Impact On Disease Pathology And Treatment, Haley Michelle Duncan 2024 University of Arkansas, Fayetteville

Investigating The Detection And Transport Of Low Molecular Weight Species To Better Understand Their Impact On Disease Pathology And Treatment, Haley Michelle Duncan

Graduate Theses and Dissertations

Due to the drastic differences in the projects involved, this dissertation will be split into two sections: Alzheimer’s disease and chronic kidney disease. Each chapter will contain an introduction, materials and methods section, results and discussion, conclusions, and works cited section. The Alzheimer’s disease chapter will also have a supplemental figures section containing the polyacrylamide gels that were silver stained and quantified via ImageJ. The presence of elevated levels of amyloid beta oligomeric species in the brain has been related to the pathology of Alzheimer’s disease. As these oligomeric species are transient in nature, their kinetics pose a challenge to …


Fabrication And Characterization Of Lignin–Pva Hydrogels With Tunable Network Structures, Keturah Bethel 2024 Clemson University

Fabrication And Characterization Of Lignin–Pva Hydrogels With Tunable Network Structures, Keturah Bethel

All Dissertations

The ability to directly tune the crosslinked network structure of hydrogels is crucial for their functional applications in various fields, such as water filtration, protein separation, and tissue engineering. By controlling the crosslink density of the hydrogel, one can directly alter the mesh size – i.e., the end-to-end distance between crosslink junctions – and, subsequently, directly alter the hydrogel performance. This work discusses the fabrication and characterization of soft composites containing the biopolymer, lignin, are discussed. Precisely, physically-crosslinked composite lignin–Poly(vinyl alcohol) (PVA) hydrogels were fabricated via the freeze-thaw (F/T) pathway, whereby solutions containing specified amounts of PVA and lignin were …


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