Geochemistry Commons^™

New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigation into seamounts that stem from intraplate volcanism—that is volcanism occurring far from plate boundaries—presents an opportunity to deconvolve processes associated with mantle compositional heterogeneities and melting dynamics. Upwelling and decompression of thermochemically anomalous mantle plumes is the primary mechanism for significant intraplate volcanism; however, many seamounts dotted across the Pacific Plate do not correlate spatially, temporally, or geochemically with mantle plume volcanism. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism are the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present merged multibeam (<100 m) and satellite altimetry bathymetric maps of the Geologist Seamounts region, new ^{40 …}

Quantifying Co2 And Heat Fluxes At Roosevelt Hot Springs, Hydrothermal Area, Samantha R. Wolf

Earth and Planetary Sciences ETDs

Roosevelt Hot Springs is an actively producing hydrothermal system that has been extensively studied by field, geophysical and geochemical techniques since the 1970’s. Roosevelt Hot Springs sits at the western base of the Mineral Mountains in Utah, an area that has formed because of many volcanic, thermal and structural events since the late Oligocene. The work in this manuscript is the first of its kind to incorporate measurements of spring-based CO₂ fluxes with diffuse measurements to quantify the total CO₂ Flux in tons per day of a Basin and Range and Colorado Plateau Transition Zone-hosted hydrothermal system. Using …

Investigating Mobility In The Northern Balkans During The Fifth Millenium Bc Through Strontium Analysis Of Human Tooth Enamel, Aurélien Tafani

USF Tampa Graduate Theses and Dissertations

This research investigates how individual mobility among ancient populations in Romania during the Eneolithic, between 5000 and 4000 BC, may be related to the spread of the material culture known as Kodjadermen-Gumelniţa-Karonovo VI (KGK VI) that extended over most of southern Romania and Bulgaria. This work seeks to combine results on individual mobility with other lines of archaeological evidence to provide a better understanding of the social context and kinship relationships that were in place when these events took place.

Strontium isotopic analyses were performed on 130 individuals from two sites located in the southern Romania: 49 from Sultana and …

Volcanic Diffuse Volatile Emissions Tracked By Plant Responses Detectable From Space, Robert R. Bogue, Peter M. J. Douglas, Joshua B. Fisher, John Stix

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Volcanic volatile emissions provide information about volcanic unrest but are difficult to detect with satellites. Volcanic degassing affects plants by elevating local CO2 and H2O concentrations, which may increase photosynthesis. Satellites can detect plant health, or a reaction to photosynthesis, through a Normalized Difference Vegetation Index (NDVI). This can act as a potential proxy for detecting changes in volcanic volatile emissions from space. We tested this method by analyzing 185 Landsat 5 and 8 images of the Tern Lake thermal area (TLTA) in northeast Yellowstone caldera from 1984 to 2022. We compared the NDVI values of the thermal area with …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Core-Cm Williston Basin Carbon Ore, Rare Earth, And Critical Minerals, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet on the Carbon Ore, Rare Earth and Critical Minerals (CORE-CM) Initiative, an Energy & Environmental Research Center and U.S. Department of Energy project. Includes information on the importance of critical minerals and utilizing lignite from the Williston Basin.

More Than Energy: Coal As A Mineral Resource, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Brochure on Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Initiative, an Energy & Environmental Research Center and U.S. Department of Energy project. Explores the benefits of utilizing lignite coal from the Williston Basin.

A Field, Petrological, And Geochronological Investigation Of The Chief Joseph Dike Swarm, Mary Joyce Mass

Dissertations and Theses

The Columbia River Basalt Group is the youngest continental flood basalt province in the world and covers an aerial extent of 210,000 km² covering Oregon, southern Washington, and eastern Idaho. Eruptions occurred between approximately 17 million and 6 million years ago, with 92% of eruptions occurring within the first million-year interval. Aside from mapping and some bulk compositional data, few studies have focused on the Chief Joseph dike swarm in NE Oregon, the main eruptive center of the Columbia River Basalt Group. Prior to this study there were no published age dates for the Chief Joseph dike swarm.

This …

North Bergen Outcrop Field And Geochemical Data, Jane L. Alexander, Sean T. Thatcher, Jay Tobon, Victoria Rivelli

Publications and Research

This file contains the data collected on an outcrop of the Stockton Formation in North Bergen, NJ. It contains field observations, mineralogy and geochemical data for major, trace and rare earth elements.

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Carbon Isotope Chemostratigraphy, Geochemistry, And Biostratigraphy Of The Paleocene–Eocene Thermal Maximum, Deepwater Wilcox Group, Gulf Of Mexico (Usa), Glenn R. Sharman, Eugene Szymanski, Rebecca A. Hackworth, Alicia C.M. Kahn, Lawrence A. Febo, Jordan Oefinger, Gunnar M. Gregory

Geosciences Faculty Publications and Presentations

The Paleocene–Eocene Thermal Maximum (PETM) represents the most pronounced hyperthermal of the Cenozoic era and is hypothesized to have resulted in an intensification of the paleohydrologic cycle, including enhanced seasonality and increased sediment discharge to the coastal ocean. Although the PETM has been widely documented, there are few records from deposits that form the distal, deepwater components of large sediment-routing systems. This study presents new constraints on the stratigraphic placement of the PETM in the deepwater Gulf of Mexico basin through analysis of geochemical, carbon isotopic, and biostratigraphic data within a ∼124 m cored interval of the Wilcox Group. Biostratigraphic …

Trace Metal Analysis Of Pond Sediments To Measure Deposition From A Coal-Fired Power Plant In Ackerman Mississippi, Charles Bills

Theses and Dissertations

Trace element sediment pollution due to coal power plants have been reported in many countries. In this study, pond sediment samples collected from locations around a coal fired power plant in Ackerman, MS, were evaluated for their trace element concentration and pollution status. The samples were collected at two depths to study changes in element accumulation over time. The samples were digested and the elements, As, Cd, Cr, Cu, Pb, Hg, and Zn were analyzed using ICP-MS. Results were then compared to known background concentrations as well as sediment quality guidelines and pollution thresholds. The sample locations downwind of the …

Phase Distribution Of Nickel, Chromium, And Cobalt In Seawater At Olivine-Enriched Beaches: Implications For Carbon Capture By Enhanced Silicate Weathering, Nathaniel J. Padrnos

Master's Theses

The application of olivine to coastal areas is a proposed method of removing carbon dioxide from the atmosphere for climate change mitigation. Olivine is abundant and dissolves relatively fast, but it contains trace amounts of nickel (Ni), chromium (Cr), and cobalt (Co) which may be toxic to marine biota in cases of widespread coastal olivine spreading. Prior studies have suggested that Ni concentrations in marine sediments and/or the overlying water column due to olivine dissolution could be a limiting factor for its carbon capture potential. Therefore, it is critical to understand and model the processes affecting trace metal bioavailability after …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

Graduate Theses and Dissertations (2019 - present)

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Climatic Influences On Incipient Alteration In Mars-Relevant Ultramafic Soils, Anthony Feldman

UNLV Theses, Dissertations, Professional Papers, and Capstones

An ongoing debate exists around the nature of the climatic conditions present during the Noachian and early Hesperian periods (~4.1 to 3 Gyr ago) of Mars’ ancient history. The various theories put forward can reasonably be grouped into “warm and wet” vs “cold and icy” camps. Warm and wet approximates an Earth-like system with a relatively clement climate with significant liquid water present including potentially long-lived oceans. Cold and icy theories generally postulate thick ice sheets at high elevations with periodic warming events driving precipitation and the formation of river channels and leading to the formation of chemical alteration products. …

Magmatic Processes Leading To Compositional Diversity In The Mars Crust, Amanda Marie Ostwald

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ancient Mars crust can yield insights into planet formation and evolution that Earth cannot. Direct investigation of the martian surface is limited to studies on meteorites and rover-obtained analyses. The nakhlites and chassignites, two classes of martian meteorites, are together the largest suite of martian meteorites derived from a single location on the surface. As such, they present a rare opportunity to study the Mars crust in detail using samples bearing a contextual relationship. Rover studies have found a surprising amount of compositional diversity in surface materials, the formation mechanisms of which are not well-constrained. This dissertation leverages meteorites …

Polygonal Faults In The Austin Chalk: Invariance Of Scale From Mud Cracks To Polygons With Implications Of Structural, Geomorphic And Isotopic Data On Polygonal Fault Geometry And Origin., Kun Shang

Earth Sciences Theses and Dissertations

The Cretaceous Austin Chalk contains large numbers of fractures and normal faults whose orientations have been attributed to either regional stresses (e.g., the Balcones fault trend) or, by analogy with the mudrocks, to polygonal faulting resulting from compaction. In this study, we present geomorphic data, field study, and stable isotope data to support that the majority of these faults in North Texas are polygonal. Field-measured fault orientations suggest randomly distributed fault strikes, indicating a polygonal fault structure. Using geomorphologic data (topographic and DEM data) on stream orientations suggests that the polygonal fault patterns are best reflected in the headwater (1st …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Untangling The Nature And Timescales Of Magmatic Processes Driving Eruptions At Quiescent Volcanoes: Examples From Momotombo, Nicaragua, And Cumbre Vieja, Canary Islands, Samantha Tramontano

Dissertations, Theses, and Capstone Projects

Across all scales of human relationships (i.e. person-to-person, country-to-country, etc.), qualms can take the form of long-standing wars, quick and intense bouts, or petty exchanges. While our understanding of human behavior is ever increasing, reactions and behaviors of self and others may still come as a surprise. Expressions of disagreement can occur suddenly or following years to centuries of accumulated grievances. The solid earth is also a system that behaves (like human emotion) predictably at times and unpredictably at other times. Some volcanoes, a tangible surface expression of solid earth processes, exhibit precursory signals prior to eruption (e.g. the bulging …

A Typological And Chemical Analysis Of Roman Oil Lamps From Poggio Del Molino, Brandon Tejo

Dissertations, Theses, and Capstone Projects

Terracotta lamps, known to the Romans as lucernae, are small, handheld, often decorated objects which provided ancient people light. To modern researchers, they serve as tools for dating stratigraphy and iconographic studies. Beyond their immediately apparent aesthetic and symbolic value, the chemical compositions of the clay of these lamps reflect their origin. This study complements archaeological typologies with chemometric analyses to describe 16 Late Republican and Imperial Roman lamps recovered from the villa at Poggio del Molino (PdM), Tuscany. These finds were recovered from the 2021 and 2022 PdM excavations. The combined approach of typology with X-ray Diffraction (XRD) …

Interannual Variation Of Ichthyofaunal Utilization Of A Man-Made Salt Marsh Creek In Mission Bay, California, Maria Angst

Undergraduate Honors Theses

Marsh restoration and creation are increasingly being used to mitigate Southern California’s drastic decline in wetlands due to human activities. This study used minnow traps to resample the ichthyofauna of a created marsh (Crown Point Mitigation Site; CPMS) and an adjacent natural marsh (Kendall Frost) in Mission Bay, California, 26 years following the marsh creation. Data from this study were compared to data collected immediately after marsh creation from 1995-1998, and from 2021. Fishes captured included Fundulus parvipinnis, Gillichthys mirabilis, Acanthagobius flavimanus, Ctenogobius sagittula, and Mugil cephalus. Species richness and dominance measures were higher in the natural relative to the …

Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama

Undergraduate Honors Theses

The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …

Structural Relationships Across The Sevier Gravity Slide Of Southwest Utah And Implications For Catastrophic Translation And Emplacement Processes Of Long Runout Landslides, Michael J. Braunagel, William Ashley Griffith, Robert F. Biek, David B. Hacker, Peter D. Rowley, David H. Malone, Danika Mayback, Tiffany A. Rivera, Zachary Loffer, Zachary D. Smith

Faculty Publications - Geography, Geology, and the Environment

The physical processes that facilitate long-distance translation of large-volume gravity slides remain poorly understood. To better understand these processes and the controls on runout distance, we conducted an outcrop and microstructural characterization of the Sevier gravity slide across the former land surface and summarize findings of four key sites. The Sevier gravity slide is the oldest of three mega-scale (>1,000 km2) collapse events of the Marysvale volcanic field (Utah, USA). Field observations of intense deformation, clastic dikes, pseudotachylyte, and consistency of kinematic indicators support the interpretation of rapid emplacement during a single event. Furthermore, clastic dikes and characteristics of …

Investigation Of The Sheep Creek Carbonatites, Ravalli County, Montana, Sarah Risedorf

Graduate Theses & Non-Theses

Carbonatite-related REE-Nb mineralization in southern Ravalli County, Montana was first discovered in the late 1950s and early 1960s. Over 30 discontinuous carbonatite bodies occur in a ~ 10 km² area centered on Sheep Creek, a tributary to the headwaters of the West Fork of the Bitterroot River (WFBR). The deposits are contained in a belt that extends to the southeast into the Mineral Hill district of Lemhi County, Idaho. Country rocks include a deformed and metamorphosed bimodal igneous suite of diabase and A-type granite, both dated to 1.37 Ga by previous workers. These rocks are locally metamorphosed to amphibolite …

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …

Differentiating Biotic Vs. Abiotic Co2 In The Formation Of Pedogenic Carbonate In Agriculture And Natural Dryland Soils, Valeria Isabel Molina

Open Access Theses & Dissertations

Drylands, characterized by low and sporadic precipitation, require irrigation for crop growth. However, irrigation practices can lead to salt accumulation in soil due to high evaporation rates and reduced leaching. In addition to loading salts to soil, irrigation promotes the accumulation of secondary calcite. In natural systems, the formation of pedogenic carbonate (secondary calcite, CaCO3) is critical, impacting the soil properties hydrologically and biogeochemically, and modifying the global carbon cycle over geological time, albeit at a lower rate. In agricultural sites, irrigation water supplies HCO3- and Ca2+, accelerating the rates of CaCO3 formation and releasing abiotic CO2. This study investigated …

Investigating The Petrogenesis Of The Naifeh And Plumeria Seamounts: Insights Into The Geochemical Diversity Of Seamounts Adjacent To The Hawaiian Seamount Chain, Geoffrey Montour

Boise State University Theses and Dissertations

The Naifeh and Plumeria seamount clusters, which consist of 10 submarine volcanoes located ~220km north of the Northwest Hawaiian Ridge, were mapped and sampled by the E/V Nautilus expedition NA101 in 2018. The origin of these seamounts is unknown, but their unique orientation and location imply several possible mechanisms of formation. Four possible mechanisms of formation include: 1) off-axis upwelling of the Hawaiian mantle plume, 2) ancient arch volcanism, 3) intraplate extension and deformation, 4) hotspot volcanism. Investigating the origin of these seamount clusters will better constrain the composition of the underlying mantle, as well as the depth and extent …

The Impact Of Glacial Proximity On The Elemental Composition Of Leachate Derived From Sediment Weathering, Karoline Ford

Theses/Capstones/Creative Projects

This study assesses chemical weathering trends as they relate to glacial retreat. The chemical environment of surfaces exposed to the atmosphere differs significantly from beneath a glacier. As a glacier melts, changes to the biogeochemical processes generate environmental gradients. This study analyzed chemical weathering signals at different distances from a glacial front by comparing the elemental composition of leachate derived from sediments in southeastern Greenland. Samples from proglacial, nonglacial, and moraine locations were weathered in a laboratory setting, and ion chromatography was used to determine the elemental composition of the products. Divergent trends in leachate composition were observed as distance …

Modeled Uranium Series Disequilibria In A Heterogeneous Mantle Underlying Iceland, Dana Andersen

Honors Program: Senior Projects (Public)

Regional lithologic heterogeneities in Earth’s mantle may significantly contribute to variations in magma productivity and crustal generation. Such heterogeneities may be a key factor in the anomalously high rates of magmatism and thickened crust of Iceland, which are not fully explained by the presence of a mantle plume. However, the exact lithologic composition of the mantle underlying Iceland is largely unknown. Recent trace element modeling has suggested a two-component melt source beneath Iceland, consisting of a typical upper mantle peridotite mixing with one of several compositions of pyroxenitic material. This study further investigates these potential melt sources by calculating U-series …

Isotopic Insights Into Water Of Condensation, Cross-Formation Water Flow, And Natural Hydrocarbon Migration In Sedimentary Basins, Lisa J. Molofsky

Open Access Theses & Dissertations

This dissertation applies geochemical tools to track the movement, transformation, and behavior of water and gases in hydrocarbon-bearing sedimentary basins. During petroleum exploration and production, hydrocarbons are generated at the surface along with other fluids naturally present in the formation, such as formation water. In addition, where hydraulic fracturing is used to stimulate shale gas and oil production, a percentage of the injected fracturing fluid also returns to the surface. Understanding the origin and movement of these water sources, as well as targeted and non-targeted hydrocarbon gases is critical to evaluating reservoir performance and properly managing fluids at the surface. …