Geochemistry Commons^™

Characterizing The Unique Chemical Imprint Of On-Axis, Lower-Temperature Hydrothermal Flow To The Deep Ocean (Southern East Pacific Rise, 16.5°-18.0°S), Laura E. Moore, Randelle M. Bundy, Joseph A. Resing, Scott White, Tamara Baumberger, Peter N. Sedwick, Nathaniel J. Buck, Anson M. Antriasian, Isaac Keohane, Bettina M. Sohst, Sharon L. Walker, Christopher R. German

OES Faculty Publications

In addition to high-temperature vents, lower-temperature flow (LTF) (< 300°C) is abundant along mid-ocean ridges and contributes globally-important fluxes of heat and water along with largely-unconstrained geochemical influences on the ocean. We examined the impact of on-axis LTF on the chemical composition of the overlying water column (< 40 m above seafloor) along the 16.5°-18.0°S sector of the ultrafast-spreading southern East Pacific Rise using autonomous underwater vehicle Sentry surveys and conductivity-temperature-depth rosette casts. LTF sites were typically spatially isolated from high-temperature systems and imparted unique chemical signatures to the overlying ocean. Water column samples impacted by LTF exhibited low particulate iron:sulfur ratios and high methane: total-dissolvable manganese ratios, whereas samples influenced by high-temperature venting exhibited opposite trends. We confirmed that LTF imparts a distinct and measurable chemical signature to the water column, independent from high-temperature vents. Isolated, on-axis LTF will be important to consider when assessing hydrothermal circulation impacts upon ocean biogeochemistry.

The Effects Of A Microplate On Plume-Ridge Interactions: Constraints From Comparing Easter And Juan Fernandez Microplates In The Eastern Pacific Ocean, Katherine Ames, Jennifer Georgen

OES Faculty Publications

This study investigates the nature of plume-ridge interactions near a tectonic microplate using mantle Bouguer anomaly (MBA) gravity calculations. The focus of this investigation is a comparison of the Easter and Juan Fernandez microplates, which are located in the eastern Pacific Ocean along the Pacific, Nazca, and Antarctic plate boundaries. The microplates have several similar characteristics, including general size, time of formation, and clockwise rotation within the larger bounding mid-ocean ridge systems. Unlike the Juan Fernandez microplate, however, the Easter microplate is located near a mantle plume (Easter/Salas y Gomez). Previously published geochemical data suggest that material from this plume …

Terrestrial And Lacustrine Organic Matter Biomolecular Transformations Via Thermal Maturation And Oxidative Degradation, Louis Connor Bondurant

Chemistry & Biochemistry Theses & Dissertations

The most abundant source of fossil fuel-forming kerogen on Earth is classified as Type II kerogen, believed to originate from marine biomass. However, a significant amount of lacustrine and terrigenous carbon is transported to the ocean through fluvial discharge. Less than half of the exported organic carbon is observed in coastal regions and the open ocean. There is a great need for an explanation of what is happening to this organic carbon during transport and deposition. Traditionally, the marine organic matter in coastal regions accumulates to eventually be buried and transformed into petroleum over millions of years due to its …

Evidence For Distal Bolide Impact And Tsunami Deposits In The Upper Atlantic Coastal Plain Of Moore County (North Carolina, Usa) Generated By The Eocene Chesapeake Bay Bolide Impact, G. Robert Ganis, Ralph H. Willoughby, David J. Cicimurri, G. Richard Whittecar, Steven J. Hageman

OES Faculty Publications

Beds interpreted as Eocene bolide-generated impact and tsunami deposits occur at Paint Hill in the Upper Atlantic Coastal Plain of Moore County, North Carolina, USA. These strata, herein named the Mount Helicon Formation, consist of four distinct beds comprising about one meter of total section. Bed 1 (the basal bed) is approximately 43 cm thick and consists of sandy carbonaceous clay with carbon glass and rock fragments and contains 14-18 parts per billion (ppb) iridium (interpreted as bolide impact ejecta). Bed 2 is approximately 9 cm thick and consists of non-cohesive silt-size particles and loosely bound sand-size accretionary lapilli-like masses …

08 - Blue Carbon Sequestration And Sediment Storage In Seagrass Meadows Of South Bay, Luke C. Clements, Adriana Amrhein, Richard P. Hale

Undergraduate Research Symposium

Blue carbon is stored in coastal and marine ecosystems like seagrass meadows and salt marshes, which helps combat climate change by preventing greenhouse gas emissions. This study examines the role of seagrass in carbon storage by comparing sediment cores from a mud channel and a seagrass meadow in South Bay.

We collected a 100 cm core from the mud channel and a 55 cm core from the seagrass area, taking samples every 10 cm to analyze grain size and organic carbon content. Using a wet sieving method, we separated sand from mud and measured organic carbon through loss on ignition. …

Core-Top Constraints On The Ecology And Paleothermometry Of Planktic Foraminifera In The Indian Ocean, Ryan H. Glaubke, Elisabeth L. Sikes, Natalie E. Umling, Katherine A. Allen, Matthew W. Schmidt

OES Faculty Publications

The magnesium-to‑calcium ratio (Mg/Ca) of fossil foraminifera is a widely used geochemical proxy for reconstructing past ocean temperatures. Culturing experiments have shown that, for some species, nonthermal influences like salinity and carbonate chemistry play a non-trivial role in the incorporation of Mg into foraminiferal calcite. Inclusion of these variables into Mg/Ca calibrations have provided a better fit to core top and sediment trap data in some recent studies, but the widespread covariation of potential control variables in the open ocean and the lack of multivariate calibrations for some species warrants additional work. Here, we assess Mg/Ca calibrations for four common …

Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The Amazon rainforest is the largest tropical rainforest in the world. Amazonian Podzol soils, characteristic of this region, are known to store substantial amounts of organic carbon in both their surface and deep horizons. Despite decades of research, the molecular-level composition of these soils remains uncharacterized. This study addresses this knowledge gap by employing ultrahigh resolution mass spectrometry, namely, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), to determine the molecular composition of humic acid (HA) and fulvic acid (FA) fractions from two Amazonian Podzol profiles of varying levels of groundwater exposure (waterlogged vs well-drained). In the waterlogged soil compounds containing nitrogen, …

Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The export of terrestrial organic matter (TOM) to the ocean has been traditionally viewed to be minimal or only of significance in near-coastal continental margins. The broadly accepted explanation for the widespread loss of terrestrial lignin biomarkers and apparent disappearance of the <-25‰ stable carbon isotopic signature (δ¹³C) of TOM is that TOM is almost fully degraded before reaching the open ocean. Oceanic carbon (δ¹³C value ≥ -22‰) is therefore thought to be derived primarily from algae. However, an alternative explanation for the different molecular and δ¹³C signatures in terrestrial and marine environments may be that oxidative processing transforms TOM to appear marine-like. To test this hypothesis, we subjected eight TOM samples to a strong oxidation gradient. At carbon losses typical of TOM degradation during transport and sedimentation (above 60%), the differentiators of provenance disappeared, leaving a residue that was marine-like both chemically (aliphatic- and nitrogen-rich) and isotopically (δ¹³C enrichment of 4 to 9‰). This challenges the validity of conventional two-endmember mixing models, suggesting that a much larger fraction than previously estimated of the organic matter found in the ocean may originate from terrestrial sources, impacting global models of carbon cycling and sequestration.

Global Subterranean Estuaries Modify Groundwater Nutrient Loading To The Ocean, Stephanie J. Wilson, Amy Moody, Tristan Mckenzie, M. Bayani Cardenas, Elco Luijendijk, Audrey H. Sawyer, Alicia Wilson, Holly A. Michael, Bochao Xu, Karen L. Knee, Hyung-Mi Cho, Yishai Weinstein, Adina Paytan, Nils Moosdorf, Chen-Tung Aurthur Chen, Melanie Beck, Cody Lopez, Dorina Murgulet, Guebuem Kim, Mathew A. Charette, Hannelore Waska, J. Severino P. Ibánhez, Gwénaëlle Chaillou, Till Oehler, Shin-Ichi Onodera, Mitsuyo Saito, Valenti Rodellas, Natasha Dimova, Daniel Montiel, Henrietta Dulai, Christina Richardson, Jinzhou Du, Eric Petermann, Xiaogang Chen, Kay L. Davis, Sebastien Lamontagne, Ryo Sugimoto, Guizhi Wang, Hailong Li, Américo I. Torres, Cansu Demir, Emily Bristol, Craig T. Connolly, James W. Mcclelland, Brenno J. Silva, Douglas Tait, Bsk Kumar, R. Viswanadham, Vvss Sarma, Emmanoel Silva-Filho, Alan Shiller, Alanna Lecher, Joseph Tamborski, Henry Bokuniewicz, Carlos Rocha, Anja Reckhardt, Michael Ernst Böttcher, Shan Jiang, Laura M. Hernández-Terrones, Suresh Babu, Beata Szmczycha, Mahmood Sadat-Noori, Felipe Niencheski, Kimberly Null, Craig Tobias, Bongkeun Song, Iris C. Anderson, Isaac R. Santos

OES Faculty Publications

Terrestrial groundwater travels through subterranean estuaries before reaching the sea. Groundwater-derived nutrients drive coastal water quality, primary production, and eutrophication. We determined how dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and dissolved organic nitrogen (DON) are transformed within subterranean estuaries and estimated submarine groundwater discharge (SGD) nutrient loads compiling > 10,000 groundwater samples from 216 sites worldwide. Nutrients exhibited complex, nonconservative behavior in subterranean estuaries. Fresh groundwater DIN and DIP are usually produced, and DON is consumed during transport. Median total SGD (saline and fresh) fluxes globally were 5.4, 2.6, and 0.18 Tmol yr⁻¹ for DIN, DON, and DIP, …

Submarine Groundwater Discharge As A Major Nutrient Source In River-Fed Vs. Tidally Dominated Estuaries, Stephanie J. Wilson, Joseph J. Tamborski, Bongkeun Song, Peter Bernhardt, Margaret R. Mulholland

OES Faculty Publications

The tidal tributaries of the lower Chesapeake Bay experience seasonally recurring harmful algal blooms and the significance of submarine groundwater discharge (SGD) as a nutrient vector is largely unknown. Here, we determined seasonal SGD nutrient loads in two tributaries with contrasting hydrodynamic conditions, river-fed (York River) vs. tidally dominated (Lafayette River). Radon surveys were performed in each river to quantify SGD at the embayment-scale during spring and fall 2021. Total SGD was determined from a ²²²Rn mass balance and Monte Carlo simulations. Submarine groundwater discharge rates differed by a factor of two during spring (Lafayette = 11 ± 17 cm …

Potentially Massive And Global Non-Pyrogenic Production Of Condensed "Black" Carbon Through Biomass Oxidation, Aleksandar I. Goranov, Hongmei Chen, Jianshu Duan, Satish C. B. Myneni, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

With the increased occurrences of wildfires worldwide, there has been an increase in scientific interest surrounding the chemistry of fire-derived "black" carbon (BC). Traditionally, wildfire research has assumed that condensed aromatic carbon (ConAC) is exclusively produced via combustion, and thus, ConAC is equated to BC. However, the lack of correlations between ConAC in soils or rivers and wildfire history suggests that ConAC may be produced non-pyrogenically. Here, we show quantitative evidence that this occurs during the oxidation of biomass with environmentally ubiquitous hydroxyl radicals. Pine wood boards exposed to iron nails and natural weather conditions for 12 years yielded a …

Organic Matter Content And Grain Size Analysis In Seagrass Sediments, Adriana Amrhein, Rip Hale

College of Sciences Posters

Anthropogenic stresses including increased water temperatures, decreased water quality, sea level rise, ocean acidification and sediment biogeochemical processes have caused a significant loss in seagrass meadow acreage. Seagrass meadows provide coastal protection from storms and recently have been emphasized for their importance in sequestering and storing “Blue Carbon” from the atmosphere and ocean. Seagrass meadows can trap this blue carbon in their sediment as organic carbon, and it can be stored for hundreds to thousands of years. Restoration efforts of seagrass meadows in the Virginia coast started in the 1990s and effects of increasing seagrass density can be observed in …

Dust Deposition To The Bermuda Region: A Comparison Of Estimates Using Seasonally-Resolved Measurements Of Aluminum In Water-Column, Aerosol, And Rain Samples, Tara Williams, Peter Sedwick, Bettina Sohst, Joe Resing, Kristen Buck, Salvatore Caprara, Rod Johnson, Dan Ohnemus, Ben Twining, Alessandro Tagliabue

College of Sciences Posters

Dust deposition is a major source of bioactive trace elements to the surface ocean, yet this flux remains difficult to constrain. Previously, time-averaged dust flux has been estimated using surface ocean dissolved aluminum (DAl) concentrations, assumed values for aerosol aluminum solubility (%Al_S), and the residence time of DAl in the surface mixed layer (SML). We apply this method to estimate dust deposition in the Bermuda Atlantic Time-series Study (BATS) region using water-column DAl data from cruises in 2019, which is compared with direct flux estimates from contemporaneous measurements of aluminum in aerosols and rain collected on Bermuda. Seasonal …

Revisiting 228Th As A Tool For Determining Sedimentation And Mass Accumulation Rates, Joseph J. Tamborski, Pinghe Cai, Meagan Eagle, Paul Henderson, Matthew A. Charette

OES Faculty Publications

The use of ²²⁸Th has seen limited application for determining sedimentation and mass accumulation rates in coastal and marine environments. Recent analytical advances have enabled rapid, precise measurements of particle-bound ²²⁸Th using a radium delayed coincidence counting system (RaDeCC). Herein we review the ²²⁸Th cycle in the marine environment and revisit the historical use of ²²⁸Th as a tracer for determining sediment vertical accretion and mass accumulation rates in light of new measurement techniques. Case studies comparing accumulation rates from ²²⁸Th and ²¹⁰Pb are presented for a micro-tidal salt marsh and a marginal sea …

Reconstructing Surface Water Carbonate Ion Concentration Changes In The Eastern Equatorial Pacific Across Glacial Transitions, Lenzie Gail Ward

OES Theses and Dissertations

Today, the eastern equatorial Pacific (EEP) plays a critical role in the global CO₂ budget as a major source of CO₂ to the atmosphere, but recent studies suggest the region may shift to a sink for atmospheric CO₂ under different climate states. Here, I focus on two transitional periods, the last deglaciation (25 kyr to present) and last glaciation (the Marine Isotope Stage (MIS) 5a-4 transition, 96 to 60 kyr), to investigate how the carbon system in the EEP responds to major climate changes. I measured B/Ca ratios in the planktic foraminifera Globigerina bulloides from core MV1014-17JC …

Sodium-Calcium Ratios In The Planktic Foraminifera Trilobatus Sacculifer As A Proxy For Sea Surface Salinity, Colton Steele Watkins

OES Theses and Dissertations

Recent culture and field studies have found a significant positive correlation between seawater salinity and the incorporation of sodium into foraminiferal calcite, suggesting a potential new proxy for reconstructing past changes in sea surface salinity (SSS) (Mezger et al., 2016 and Bertlich et al., 2018). In order to test the applicability of this new proxy in an open-ocean setting, Na/Ca ratios in the planktic foraminifera Trilobatus sacculifer (T. sacculifer Na/Ca) were measured from a suite of sediment core tops spanning a natural salinity gradient from the North Atlantic subtropical gyre to the South Atlantic subtropical gyre. Initial results from …

Structural Characterization Of Organic Matter In Oil Shales Using Multiple Nuclear Magnetic Resonance Spectroscopic Techniques, Wenying Chu

Chemistry & Biochemistry Theses & Dissertations

Oil shale is a promising source of hydrocarbon fuel that is distributed throughout the world. The petroleum generating potential of oil shale is related to the molecular structure of the organic matter in source rock. The major fraction of organic matter of oil shale is termed kerogen, and due to its insolubility in organic solvents, ¹³C solid-state nuclear magnetic resonance (NMR) spectroscopy is one of the best ways to directly measure the insoluble organic matter without changing its chemical structures. This dissertation investigated oil shale samples using advanced solid-state ¹³C NMR spectroscopy techniques and high resolution magic angle …

An Introduction To “Microbial Biogeochemistry: A Special Issue Of Aquatic Geochemistry Honoring Mark Hines”, W. Berry Lyons, David J. Burdige

OES Faculty Publications

(First paragraph) This issue of Aquatic Geochemistry is dedicated to the memory of Dr. Mark E. Hines (Fig. 1) and his contributions to the fields of microbial biogeochemistry and aquatic geochemistry. Mark passed away in March of 2018, and through his career as a researcher, teacher, mentor, colleague, and university administrator, he greatly influenced the lives of all around him. We hope that this volume will serve not only as a memory of Mark, but also as a way to recognize his significant influences and major contributions in the fields of carbon, sulfur, and trace element biogeochemistry.

Marine Carbonyl Sulfide (Ocs) And Carbon Disulfide (Cs2): A Compilation Of Measurements In Seawater And The Marine Boundary Layer, Sinikka T. Lennartz, Christa A. Marandino, Marc Von Hobe, Meinrat O. Andreae, Kazushi Aranami, Elliot Atlas, Max Berkelhammer, Heinz Bingemer, Dennis Booge, Gregory A. Cutter, Pau Cortes, Stefanie Kremser, Cliff S. Law, Andrew Marriner, Rafel Simó, Birgit Quack, Günther Uher, Huixiang Xie, Xiaobin Xu

OES Faculty Publications

Carbonyl sulfide (OCS) and carbon disulfide (CS₂) are volatile sulfur gases that are naturally formed in seawater and exchanged with the atmosphere. OCS is the most abundant sulfur gas in the atmosphere, and CS₂ is its most important precursor. They have attracted increased interest due to their direct (OCS) or indirect (CS₂ via oxidation to OCS) contribution to the stratospheric sulfate aerosol layer. Furthermore, OCS serves as a proxy to constrain terrestrial CO₂uptake by vegetation. Oceanic emissions of both gases contribute a major part to their atmospheric concentration. Here we present a database of …

Abiotic Formation Of Dissolved Organic Sulfur In Anoxic Sediments Of Santa Barbara Basin, Hussain A. Abdulla, David J. Burdige, Tomoko Komada

OES Faculty Publications

Sulfurization has been found to enhance organic matter preservation and petroleum formation in marine sediments. However, we do not yet have a comprehensive understanding of sulfurization mechanisms. In this study, we investigated several possible mechanisms of dissolved organic sulfur (DOS) formation in the top 4.5 m of anoxic sediments of Santa Barbara Basin (SBB), California Borderland. Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS), we identified chemical formulas of potential dissolved organic matter (DOM) precursors to these DOS compounds. We also examined how the formulas of abiotically formed DOS changed as a function of depth across a major redox …

Temporal And Spatial Scales Of Correlation In Marine Phytoplankton Communities, A. M. Kuhn, S. Dutkiewicz, O. Jahn, Sophie Clayton, T. A. Rynearson, M. R. Mazloff, A. D. Barton

OES Faculty Publications

Ocean circulation shapes marine phytoplankton communities by setting environmental conditions and dispersing organisms. In addition, processes acting on the water column (e.g., heat fluxes and mixing) affect the community structure by modulating environmental variables that determine in situ growth and loss rates. Understanding the scales over which phytoplankton communities vary in time and space is key to elucidate the relative contributions of local processes and ocean circulation on phytoplankton distributions. Using a global ocean ecosystem model, we quantify temporal and spatial correlation scales for phytoplankton phenotypes with diverse functional traits and cell sizes. Through this analysis, we address these questions: …

Biogeochemical Controls Of Surface Ocean Phosphate, Adam C. Martiny, Michael W. Lomas, Weiwei Fu, Philip W. Boyd, Yuh-Ling L. Chen, Gregory A. Cutter, Michael J. Ellwood, Ken Furuya, Fuminori Hasshihama, Jota Kanda, David M. Karl, Taketoshi Kodama, Qian P. Li, Jian Ma, Thierry Moutin, E. Malcolm S. Woodward, J. Keith Moore

OES Faculty Publications

Surface ocean phosphate is commonly below the standard analytical detection limits, leading to an incomplete picture of the global variation and biogeochemical role of phosphate. A global compilation of phosphate measured using high-sensitivity methods revealed several previously unrecognized low-phosphate areas and clear regional differences. Both observational climatologies and Earth system models (ESMs) systematically overestimated surface phosphate. Furthermore, ESMs misrepresented the relationships between phosphate, phytoplankton biomass, and primary productivity. Atmospheric iron input and nitrogen fixation are known important controls on surface phosphate, but model simulations showed that differences in the iron-to-macronutrient ratio in the vertical nutrient supply and surface lateral transport …

The Evolution Of The El Niño-Southern Oscillation And Tropical Pacific Climate Across The Last Deglaciation, Ryan Hunter Glaubke

OES Theses and Dissertations

The El Niño – Southern Oscillation (ENSO) is the largest interannual component of Earth’s climate system, capable of exerting significant influence over global climate patterns that affect communities around the globe. Nevertheless, a comprehensive understanding of the ENSO system and its relationship to tropical Pacific climate dynamics remains unclear. Although new paleoceanographic proxies have shown promise in in their ability to constrain past ENSO change, little is known about how ENSO varied in response to millennial-scale climate events over the last 25,000 years. Here, I present new records of tropical Pacific mean state and ENSO variability over the last 25,000 …

Formation Of Water-Soluble Organic Matter Through Fungal Degradation Of Lignin, Seyyedhadi Khatami, Ying Deng, Ming Tien, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Lignin is a major component of decaying terrestrial vegetation in soils and has been reported to contribute substantially to the formation of soil carbon humus and associated water extracts of soil. To better understand this process of humification, lignin from brown-rot degraded wood is subjected to a white-rot fungus (Phanerochaete chrysosporium)whose enzymes are particularly effective in lignin degradation. This enzymatic attack was monitored by ultrahigh resolution mass spectrometry of water soluble extracts of the fungal cultures. The ensuing molecular level characterizations showed that the P. chrysosporium fungi induced aromatic ring oxidations followed by ring opening as expected. However, …

The Geotraces Intermediate Data Product 2017, Reiner Schlitzer, Robert F. Anderson, Elena Masferrer Dodas, Maeve Lohan, Walter Geibert, Alessandro Tagliabue, Andrew Bowie, Gregory A. Cutter, Peter N. Sedwick, Bettina Sohst

OES Faculty Publications

The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and …

Advances In Amino Acid Analysis For Marine Related Matrices And Its Application To Coastal Shelf Settings In The Canadian Arctic, Rachel M. Mcmahon

OES Theses and Dissertations

Amino acids comprise up to 50% of organic matter in cellular material and are a major fraction of oceanic organic carbon. Amino acids are also considered highly labile during organic matter recycling, making them useful proxies for organic carbon cycling. Nevertheless, analysis of individual amino acids has been burdened by lengthy derivatization and complex analysis since the 1950s. In this thesis, I describe the modification of advanced analytical techniques, developed in the biomedical field, for analysis of marine matrices which allow the determination of at least 40 amino acids without the need for lengthy sample preparation and derivatization, twice the …

Production And Composition Of Pyrogenic Dissolved Organic Matter From A Logical Series Of Laboratory-Generated Chars, Kyle W. Bostick, Andrew R. Zimmerman, Andrew S. Wozniak, Siddhartha Mitra, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Though pyrogenic carbon (pyC) has been assumed to be predominantly stable, degradation and transfers of pyC between various pools have been found to influence its cycling and longevity in the environment. Dissolution via leaching may be the main control on loss processes such as microbial or abiotic oxidation, mineral sorption, or export to aquatic systems. Yet, little is known about the controls on pyrogenic dissolved organic matter (pyDOM) generation or composition. Here, the yield and composition of pyDOM generated through batch leaching of a thermal series of oak and grass biochars, as well as several non-pyrogenic reference materials, was compared …

Evidence For Ephemeral Middle Eocene To Early Oligocene Greenland Glacial Ice And Pan-Arctic Sea Ice, Aradhna Tripati, Dennis Darby

OES Faculty Publications

Earth's modern climate is defined by the presence of ice at both poles, but that ice is now disappearing. Therefore understanding the origin and causes of polar ice stability is more critical than ever. Here we provide novel geochemical data that constrain past dynamics of glacial ice on Greenland and Arctic sea ice. Based on accurate source determinations of individual ice-rafted Fe-oxide grains, we find evidence for episodic glaciation of distinct source regions on Greenland as far-ranging as ~68°N and ~80°N synchronous with ice-rafting from circum-Arctic sources, beginning in the middle Eocene. Glacial intervals broadly coincide with reduced CO_{2 …}

A Near-Global Atmospheric Distribution Of N2o Isotopologues, Peter F. Bernath, Mahdi Yousefi, Eric Buzan, Chris D. Boone

Chemistry & Biochemistry Faculty Publications

The distributions of the four most abundant isotopologues and isotopomers (N₂O, ¹⁵NNO, N¹⁵NO, and NN¹⁸O of nitrous oxide have been measured in the Earth's stratosphere by infrared remote sensing with the Atmospheric Chemistry Experiment (ACE) Fourier transform spectrometer. These satellite observations have provided a near-global picture of N₂O isotopic fractionation. The relative abundances of the heavier species increase with altitude and with latitude in the stratosphere as the air becomes older. The heavy isotopologues are enriched by 20-30% in the upper stratosphere and even more over the poles. These observations are …

Selenium Distribution And Cycling In The Eastern Equatorial Pacific Ocean, Zoe Wambaugh

OES Theses and Dissertations

Oxygen minimum zones in oceanic waters have become increasingly important to the marine environment and society. Low oxygen waters affect not only the distribution and abundance of marine organisms, but also impact the solubility and transport of trace elements that are of biological importance, with the chemical speciation and solubility depending on the actual redox poise of the waters. One redox sensitive trace element of interest is selenium, which can be both toxic and essential for organisms, depending on its chemical speciation. In 2013, the US GEOTRACES program completed the GP16 transect from Peru to Tahiti, going through the oxygen …