Geochemistry Commons^™

Carbon Storage In Headwaters Can Respond Rapidly To Climate Change, Maddie Benello, Carl Renshaw, Joshua Landis

Wetterhahn Science Symposium Posters

Headwater streams play a critical role in the global carbon cycle, serving as significant sites of carbon storage. While there have been recent efforts to quantify carbon storage in headwater streams in the western United States, there remains limited understanding of both the volume and timescale of carbon storage in northeastern forests which often have extensive logging and agricultural histories. Here, we quantify the carbon stock, residence time, and flux of a zero-to-first order headwater stream in Charles Downer State Forest (DF), VT using novel fallout radionuclide (FRN) chronometry. We find DF headwaters have a carbon stock of 66.2 Mg …

Supplemental Bibliographic Details. From 2001 Mars Odyssey To Earth’S Climate Crisis: Integrating Gamma Spectroscopy, Martian Soil Simulants, And Plant Genomes For Agroecology, Anchored In Sri Lanka’S Mars-Context Serpentinites, Suniti Karunatillake, Maheshi Dassanayake, Carlos Gary Bicas

Planetary Science Lab

Bibliographic details follow to supplement hyperlinked citations in the multinational GANGOTRI-supporting project conceived by Karunatillake, Dassanayake, and Gary-Bicas

Effect Of Seasonal Variability In Methane Emissions And Iron Redox Chemistry At Terrestrial-Aquatic Interfaces, Hermes C. Ruiz

Master's Theses

Methane (CH₄) emissions at terrestrial–aquatic interfaces (TAIs) are significant contributors to the global carbon budget, yet the mechanisms driving methanogenesis remain poorly understood. Limited data exist on how seasonal variations and redox processes influence CH₄ fluxes in these dynamic ecosystems. This study addressed two questions: (1) How are CH₄ fluxes in riverine floodplains and adjacent hillslopes impacted by seasonal variations? (2) What roles do metal redox processes (e.g., iron (Fe)) play in regulating methanogenesis?

In-situ CH₄ flux and solid-phase Fe speciation were quantified in East River, CO, under flooded and drained conditions. Groundwater chemistry, gas flux, and soil physical properties …

New Precipitation Is Scarce In Deep Soils: Findings From 47 Forest Plots Spanning Switzerland, Emily I. Burt, Scott T. Allen, Sabine Braun, Simon Tresch, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

As precipitation infiltrates into soils, it can recharge them, displace previously stored waters, or bypass already-filled pores. Using 3,697 δ2H and δ18O measurements of water collected nearly monthly over >3 years in 47 forest plots across Switzerland, we present a systematic investigation of the controls on mobile soil water transport. We quantified the lags and damping of water as it percolates downward using young water fraction analysis (Fyw), and the fractions of soil water composed by precipitation that fell within the previous month (new water fractions, Fnew). The Fnew of water sampled in surface soils ranged …

Are There Neurological Impacts Of Exposure To A Burned Wildfire Site As It Recovers?, Rubye Strickland

Undergraduate Honors Theses

Wildfires are increasing with climate change, making the human health implications of exposure to burned soils an essential area of research. Metals associated with fire-impacted soils can be inhaled or accidentally ingested by surrounding communities, causing health risks. Several studies have evaluated the health impact of wildfires, but few have done so from a neurological perspective. This study explores metal changes in burned soils over time as a site naturally recovers from wildfire and how these changes may impact human neurological health. Soil samples were collected from the burned area 0, 3, 6, 9, and 12 months after the fire. …

Comparison Of Soil Organic Matter Fractions In Non-Grazed And Prescribed Sheep-Grazed Managed Land In Southwest Michigan, Julia M. Shreve, Katelyn Smith, Lauren Burns

Student Summer Scholars Manuscripts

The impact of prescribed sheep grazing on soil organic carbon (SOC) was investigated by comparing a 2-acre grazed and a 2-acre non-grazed (control) portion of redeveloped land previously seeded with pasture mix in Southwest Michigan. This study aimed to measure changes in SOC resulting from prescribed sheep grazing by examining two key soil organic matter (SOM) fractions: particulate organic matter (POM) and mineral-associated organic matter (MAOM) along with soil physical and chemical properties (e.g., bulk density, infiltration rate, moisture content, pH, conductivity). Soil cores were collected from 5 locations within each of the 2-acre plots using a diagonal random sampling …

Investigation Of Temperature, Solution Strength, And Applied Stress Effects On Cation Exchange Processes In Different Geosynthetic Clay Liner Products, Kendra Fuller

Master's Theses

An extensive laboratory test program was conducted to analyze and compare the cation exchange processes in three different varieties of sodium bentonite (Na-B) geosynthetic clay liners (GCLs) over increased conditioning durations up to 32 days and investigate the effects of temperature, solution strength, and applied stress. The goal of this test program was to establish whether the variables of temperature, solution strength, and applied stress improved or degraded the engineering properties of GCLs in laboratory testing and municipal solid waste (MSW) landfill applications. The GCLs were conditioned in liquids of increasing ionic strength, using deionized water and 2, 50, and …

Unearthing The Past: A Comprehensive Study Of Natural And Anthropogenic Changes At An Archaeological Site Through Hydrogeologic Connectivity Utilizing Gis, Mehlich Ii Phosphorus Extractant, And Ph, Dana L. F. Herren

Theses

This thesis aims to thoroughly analyze the Mehlich II Phosphorus Extractant and pH levels at the Bains Gap Village Site in Anniston, AL., while examining the impact of various environmental factors and human activities on them. Phosphorus is often used in archaeology as an indicator of human activity. Soil core samples were collected to analyze anomalies in phosphorus levels.

To establish any relationships, phosphorus and pH levels from soil cores were correlated with findings from past excavation units and features. The potential effects of hydrogeologic connectivity on soil phosphorus and pH levels were investigated. Geospatial technologies were used to manage …

Transport Of Multi-Phase Multi-Component Fluids In The Shallow Subsurface Influenced By Soil And Surface Boundary Conditions: Experimental And Numerical Study With Application To Natural Gas Leakage, Navodi Jayarathne

Civil and Environmental Engineering Theses and Dissertations

With the increased use of Natural Gas (NG) as a source of fuel, underground leak-related events are increasingly reported, and some are fatal. Subsurface migration and development up to flammable limits are highly dependent on leak characteristics, soil, atmospheric variables, and other surface and subsurface structural complexities. Although few studies have characterized the transient behavior of leaked NG in the shallow subsurface, the underlying mechanisms and their interactions are not well understood, which prevents prediction of the impact of environmental and operating conditions on gas migration. The study conducted a series of field scale-controlled release experiments and numerical simulations to …

An Experiment To Determine Mineral-Associated Organic Matter Turnover In A Sandy Clay Loam, Samantha Abel

All Master's Theses

Soil is an important terrestrial carbon sink. Through regenerative land management, which includes minimizing soil disturbance, the carbon content of soil can be raised towards preindustrial levels. This feat requires effectively storing carbon in a natural system that is inclined to cyclicity. The most stable form of soil organic matter is mineral-associated organic matter (MAOM). This carbon labelling experiment was designed to identify short-term CO₂ fluxes within the soil-plant-atmosphere system, particularly those related to MAOM turnover in the rhizosphere. Basil (Ocimum basilicum) was planted on a plot at the campus farm at Central Washington University. Another plot …

Supporting Dataset For The Influence Of Tile-Water On Groundwater Nitrate Concentrations Within A Saturated Riparian Buffer Zone, Aminat Tosin Abdulsalam, Eric Wade Peterson

Faculty Publications - Geography, Geology, and the Environment

In the U.S. Midwest, where fertile soils with high water retention are prevalent, the installation of tile drainage networks have become a common practice to drain excess soil water, which enhances plant growth and increases crop productivity. However, tile drainage networks coupled with the use of inorganic fertilizers have significant implications on water quality, contributing to eutrophication, leading to harmful algal blooms, and resulting in hypoxic conditions in surface water bodies. To mitigate excess nutrient exports to surface water bodies, edge-of-field practices have been introduced. One such practice is the saturated riparian buffer (SRB), which utilizes a diversion system to …

Trace Metal Analysis Of Pond Sediments To Measure Deposition From A Coal-Fired Power Plant In Ackerman Mississippi, Charles Bills

Theses and Dissertations

Trace element sediment pollution due to coal power plants have been reported in many countries. In this study, pond sediment samples collected from locations around a coal fired power plant in Ackerman, MS, were evaluated for their trace element concentration and pollution status. The samples were collected at two depths to study changes in element accumulation over time. The samples were digested and the elements, As, Cd, Cr, Cu, Pb, Hg, and Zn were analyzed using ICP-MS. Results were then compared to known background concentrations as well as sediment quality guidelines and pollution thresholds. The sample locations downwind of the …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

Graduate Theses and Dissertations (2019 - present)

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Climatic Influences On Incipient Alteration In Mars-Relevant Ultramafic Soils, Anthony Feldman

UNLV Theses, Dissertations, Professional Papers, and Capstones

An ongoing debate exists around the nature of the climatic conditions present during the Noachian and early Hesperian periods (~4.1 to 3 Gyr ago) of Mars’ ancient history. The various theories put forward can reasonably be grouped into “warm and wet” vs “cold and icy” camps. Warm and wet approximates an Earth-like system with a relatively clement climate with significant liquid water present including potentially long-lived oceans. Cold and icy theories generally postulate thick ice sheets at high elevations with periodic warming events driving precipitation and the formation of river channels and leading to the formation of chemical alteration products. …

Differentiating Biotic Vs. Abiotic Co2 In The Formation Of Pedogenic Carbonate In Agriculture And Natural Dryland Soils, Valeria Isabel Molina

Open Access Theses & Dissertations

Drylands, characterized by low and sporadic precipitation, require irrigation for crop growth. However, irrigation practices can lead to salt accumulation in soil due to high evaporation rates and reduced leaching. In addition to loading salts to soil, irrigation promotes the accumulation of secondary calcite. In natural systems, the formation of pedogenic carbonate (secondary calcite, CaCO3) is critical, impacting the soil properties hydrologically and biogeochemically, and modifying the global carbon cycle over geological time, albeit at a lower rate. In agricultural sites, irrigation water supplies HCO3- and Ca2+, accelerating the rates of CaCO3 formation and releasing abiotic CO2. This study investigated …

Impacts Of Preferential Flow On Tc-99and Np-237 Vadose Transport In Soils At The Savannah River Site, Josh Parris

All Theses

Since the 1950s, the United States has produced approximately 90,000 metric tons of spent nuclear fuel (SNF) (Office of Nuclear Energy, 2022); however, no long-term storage solutions are available. Technecium-99 and neptunium-237, two fission products found in SNF, readily form highly mobile species in oxidizing conditions (Hu, 2008; Bondietti, 1979) and have respective half-lives of 2.13 x 10⁵ and 2.14 x10⁶ years (Hu, 2010). Considering these characteristics, ⁹⁹Tc and ²³⁷Np are two risk-driving isotopes found in SNF storage. The process of macropore-facilitated preferential flow, transport through cracks within a soil matrix, has been recognized to increase …

Concept Validation: Collecting Composite Samples To Understand The Presence Of Per- And Polyfluoroalkyl Substances (Pfas) In Michigan Forested Areas, Nicole Renee Sanabria

Masters Theses

This research discusses the results of a state-wide study conducted by The Michigan Department of Environment, Great Lakes, and Energy to assess the presence of PFAS in shallow soils of state-owned forested areas in Michigan utilizing a composite sampling method. One sample collected from each of Michigan’s 83 counties reveals the presence of PFAS in all but one sample, with total PFAS concentrations ranging from non-detect to 2.016 μg/kg (dry weight). PFOS is generally detected at the highest concentrations, ranging from non-detect to 0.88 μg/kg, followed by PFBA, with concentrations ranging from non-detect to 0.69 μg/kg, and PFOA, with concentrations …

Organic Matter Content And Grain Size Analysis In Seagrass Sediments, Adriana Amrhein, Rip Hale

College of Sciences Posters

Anthropogenic stresses including increased water temperatures, decreased water quality, sea level rise, ocean acidification and sediment biogeochemical processes have caused a significant loss in seagrass meadow acreage. Seagrass meadows provide coastal protection from storms and recently have been emphasized for their importance in sequestering and storing “Blue Carbon” from the atmosphere and ocean. Seagrass meadows can trap this blue carbon in their sediment as organic carbon, and it can be stored for hundreds to thousands of years. Restoration efforts of seagrass meadows in the Virginia coast started in the 1990s and effects of increasing seagrass density can be observed in …

Determining The Effects Of Elevated Carbon Dioxide On Soil Acidification, Cation Depletion, And Soil Inorganic Carbon And Mapping Soil Carbons Using Artificial Intelligence, Jannatul Ferdush

Theses and Dissertations

Soil carbon is the largest sink and source of the global carbon cycle and is disturbed by several natural, anthropogenic, and environmental factors. The global increase of atmospheric CO₂ affects soil carbon cycling through varied biogeochemical processes. The first chapter is a compilation of current information on potential factors triggering soil acidification and weathering mechanisms under elevated CO₂ and their consequences on soil inorganic carbon (SIC) pool and quality. Soil water content and precipitation were critical factors influencing elevated CO₂ effects on the SIC pool. The second chapter examines a detailed column experiment in which six soils …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding the dynamics of peatland methane (CH₄) emissions and quantifying sources of uncertainty in estimating peatland CH₄ emissions are critical for mitigating climate change. The relative contributions of CH₄ emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH₄ to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH₄ emissions. To improve model simulations …

Evaluating Alternative Ebullition Models For Predicting Peatland Methane Emission And Its Pathways Via Data–Model Fusion, Shuang Ma, Lifen Jiang, Rachel M. Wilson, Jeff P. Chanton, Scott Bridgham, Shuli Niu, Colleen M. Iversen, Avni Malhotra, Jiang Jiang, Xingjie Lu, Yuanyuan Huang, Jason Keller, Xiaofeng Xu, Daniel M. Ricciuto, Paul J. Hanson, Yiqi Luo

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Understanding the dynamics of peatland methane (CH4) emissions and quantifying sources of uncertainty in estimating peatland CH4 emissions are critical for mitigating climate change. The relative contributions of CH4 emission pathways through ebullition, plant-mediated transport, and diffusion, together with their different transport rates and vulnerability to oxidation, determine the quantity of CH4 to be oxidized before leaving the soil. Notwithstanding their importance, the relative contributions of the emission pathways are highly uncertain. In particular, the ebullition process is more uncertain and can lead to large uncertainties in modeled CH4 emissions. To improve model simulations of CH4 emission and its pathways, …

Spatiotemporal Variability Of Soil Water Δ18o And Δ2h Reveals Hydrological Processes In Two Floodplain Soils, Amanda Ceming-Barbato

LSU Master's Theses

The movement of water through soil is preferential and heterogeneous. Subsurface interactions between mobile flows and the soil matrix are not uniform and are therefore difficult to predict through time and space. The use of stable isotopes of hydrogen (²H) and oxygen (¹⁸O) as conservative tracers of water movement is improving understanding of soil hydrological processes, yet field-scale observations of isotopic variability remain scarce despite implications for identifying dominant hydrologic processes. We sampled two adjacent soils at a ridge-swale topography floodplain forest to determine soil water isotopic variability at a 20 cm depth resolution in soils …

Organic-Input Impacts On Soil Carbon Flux, Storage, And Budget In Conservation Agricultural Soils, Central Washington, Usa, Jessica Hartman

All Master's Theses

The increase in global atmospheric CO₂ over the last 200 years has generated an urgent need for strategies for sequestering carbon (C). Soil C, which has been depleted by land use change and agricultural practices, is a prime target for C storage. Land management practices, including no-till, cover cropping and crop rotation, and the application of C amendments such as compost and biochar, are suggested to increase C in the soil. Spoon Full Farm, near Thorp, WA, was a conventional hay farm until 2016, when management practices changed to implement some of these C sequestration strategies. A prior CWU …

Geology, Geochemistry And Petrotectonic Setting Of Idanre Granite Complex, Southwestern Nigeria, Akinola Oluwatoyin Olagoke

Student Works (2020-2029)

During Neoproterozoic, Nigeria like many other Pan-African countries witnessed extensive magmatic activities which resulted in emplacement of granite popularly referred to as Older Granite in Nigeria. The study area is characterized by a large population of this rock type than any other part of Nigeria, so these rocks are investigated in this research. Idanre is underlain by migmatite-gneiss, charnockite and granite. Migmatite form the country rock and are low-lying, charnockite was surrounded by granite, while the granite forms large inselbergs. Three textural types of granite occur in the area, they are coarse-grained granite (undifferentiated) (OGu), porphyritic granite (OGp) and the …

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

Graduate Theses/Dissertations

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …

Phosphorus Variability In The Area Of Influence Of The Mid-Barataria Sediment Diversion, Peter Mates

LSU Master's Theses

Man-made levees along the lower Mississippi River prevent delivery of sediment from building and maintaining Louisiana’s coastal wetlands. The Mid-Barataria sediment diversions is designed to reintroduce Mississippi River water, sediment, and nutrients into the sediment-starved Barataria Basin. Phosphorus (P) is an important macronutrient for regulating primary production in coastal marine ecosystems. Wetlands can serve as a sink or source for phosphorus to the overlying water column through various retention and release processes, dependent on concentration. Louisiana coastal systems can be phosphorus limited due to much higher concentrations of bioavailable Nitrogen in river water. The high soluble molar N:P ( >50:1) …

The Limits Of Lead (Pb) Phytoextraction And Possibilities Of Phytostabilization In Contaminated Soil: A Critical Review, Sara Perl Egendorf, Peter M. Groffman, Gerry Moore, Zhongqi Cheng

Advanced Science Research Center

This review article focuses on lead (Pb), one of the most ubiquitous and harmful toxicants found in soil. Our objective is to address misconceptions regarding the ability of plants to uptake Pb through their roots and translocate it to above-ground tissues, and their ability to act as hyperaccumulators and thereby phytoextract Pb. In accordance with a number of cited definitions, we suggest that species capable of Pb phytoextraction can be rated with the following three criteria: (1) root uptake above a nominal threshold of 1,000 mg Pb/kg, (2) bioconcentration factor (BCF or shoot/soil concentration) >1, and (3) translocation factor (TF …

Evidence Of Variable Climate And Resources During The Late Pleistocene And Holocene At Gona, Ethiopia, Marie White

Steeplechase: An ORCA Student Journal

The African Humid Period (AHP) spanned a period of approximately 15 to 5 thousand years ago (ka) and resulted in Northern and Eastern Africa being wetter than today. This climate change event impacted flora, fauna, and humans to an unknown extent. Much of the work on the AHP across Eastern Africa utilizes lacustrine and marine proxies rather than river-based (fluvial). Gona, located in the Afar region of Ethiopia, is known for its extensive archaeological and fossil records in fluvial deposits. However, the paleoenvironment of the AHP at Gona has not been investigated. This study uses stratigraphy, geochronology, and paleopedology to …

A Terrestrial Reconstruction Of Gona, Ethiopia Before And During The African Humid Period, Marie N. White, Gary E. Stinchcomb

Posters-at-the-Capitol

The African Humid Period (AHP) resulted in more humid conditions across Northern and Eastern Africa from 15 to 5 thousand years ago (ka). This wetter climate affected flora, fauna and the Homo sapiens living in East Africa. The lack of terrestrial paleoenvironmental reconstructions is a problem in East Africa, especially during the AHP, where most are done utilizing lacustrine or marine proxies. In the case of Gona, Ethiopia, terrestrial proxies are desired due to the rich archaeological and fossil concentrations that occur in the area. Paleosols provide more direct, localized reconstructions that provide context for these finds. This study utilizes …