Geochemistry Commons^™

A Stable Isotope Comparison Of The Biogenic Carbonate Of Mammalian Tooth Enamel From The Modern Ohio River Valley And Fort Ancient Buffalo Sites, Sara Elizabeth Slack

Theses, Dissertations and Capstones

δ¹⁸O and δ¹³C values change in response to anthropogenic factors (Ghosh & Brand, 2003). Little is known about the effects of anthropogenic climate and land use change on the ecology of the Ohio River Valley. The goal of this research was to quantify the effects of European colonization on the native ecology of the region. The specific questions of this research were: (1) How have mammalian tooth enamel δ¹⁸O and δ¹³C compositions shifted over time within the Ohio River Valley in response to anthropogenic climate change and vegetation? (2) Are there differences …

Chemical And Morphological Characterization Of Airborne Particulate Matter At The Jackpile-Paguate Mine, Pueblo Of Laguna, New Mexico: Implications For Potential Metals Exposure, Andreanna C. Roros

Earth and Planetary Sciences ETDs

The inhalation of windblown particulate matter (PM) derived from abandoned uranium mines (AUMs) is a potential environmental health risk to Native American communities that live in proximity to these sites. However, the aeolian transport of metal-bearing PM from AUMs, as a potential exposure pathway, has not been investigated in any detail. In this study, we sampled airborne particulate matter within the Jackpile Mine located on the lands of the Pueblo of Laguna, New Mexico using passive sampling methods to understand the characteristics of dust within the mine site. The objective was to determine the elemental concentrations, mineralogy, and morphology of …

Unearthing The Past: A Comprehensive Study Of Natural And Anthropogenic Changes At An Archaeological Site Through Hydrogeologic Connectivity Utilizing Gis, Mehlich Ii Phosphorus Extractant, And Ph, Dana L. F. Herren

Theses

This thesis aims to thoroughly analyze the Mehlich II Phosphorus Extractant and pH levels at the Bains Gap Village Site in Anniston, AL., while examining the impact of various environmental factors and human activities on them. Phosphorus is often used in archaeology as an indicator of human activity. Soil core samples were collected to analyze anomalies in phosphorus levels.

To establish any relationships, phosphorus and pH levels from soil cores were correlated with findings from past excavation units and features. The potential effects of hydrogeologic connectivity on soil phosphorus and pH levels were investigated. Geospatial technologies were used to manage …

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …

Assessing Ecosystem Health Through Contaminants In The Tijuana River National Estuarine Research Reserve, Nancy Torres

Theses

Although the Tijuana River Estuary (TRE) remains the largest, most-intact coastal wetland in Southern California, it has a history of major changes, much of this related to its location immediately north of the US / Mexico Border. One of the primary challenges is cross-border flows from the rapidly growing city of Tijuana, Baja California, Mexico, and the delivery of wastewater, debris, and sediment to sensitive coastal wetland ecosystems. There is a need to more fully investigate these environmental changes to assess the ecosystem health of the Tijuana River Estuary over time, especially related to pollution impacts. This can inform an …

Acid Mine Drainage In The Shamokin Creek Watershed: A Spatial Analysis Of Economic And Environmental Consequences Of Coal Mining, Ben Shimer

Student Project Reports

No abstract provided.

Monitoring Sars-Cov-2 Risk With Co2. The Importance Of Ventilation, Masks, And Vaccinations., Preston Betz

Earth Sciences Theses and Dissertations

To assess airborne pathogen infection risk, concentrations of interior carbon dioxide and changes in relative humidity serve as proxies for human respiration products. Yanes and Yapp, 2010, demonstrated that interior air carbon dioxide concentrations and ¹³C/¹²C ratios display a two-component mixing relationship between respiration carbon dioxide which is highly concentrated (>100x atmospheric) in respiration air CO₂ at >40,000 ppm compared with ambient air (~410 ppm). In the absence of combustion carbon dioxide, the concentration of carbon dioxide, in an interior space, depends on the rate of respiration CO₂ addition relative to the amount of …

Impact Of Prairie Restoration On Geochemistry And Microbial Communities In Groundwater, Kayla Koenig

Graduate Research Theses & Dissertations

Prairie restoration is important for reversing the loss of biodiversity and repairing ecosystem functions humanity is dependent on diverse ecosystems. This study looks at the impact of the beginning phases of prairie restoration on groundwater geochemistry and microbial communities the relationship between them. This research project studied the geochemistry and microbial communities in five wells before, during, and after the beginning phases of the first year of a prairie restoration on the Northern Illinois University campus. Water samples were collected bimonthly for a year and analyzed on an Ion Chromatograph. Microbial samples were collected monthly and underwent DNA extraction, amplification, …

Chemical Mapping To Evaluate Post-Depositional Diagenesis Among The Earliest Ceramics In The Teotihuacan Valley, Mexico, Wesley D. Stoner, Barry J. Shaulis

Anthropology Faculty Publications and Presentations

Chemical and mineral sourcing techniques are commonly employed in archaeology to reconstruct patterns of ceramic exchange and raw material procurement practices for the past, but the effects of post-depositional diagenesis are still often ignored despite a number of key studies warning that the composition of ceramics from archaeological deposits often diverges greatly from their original composition at the time of production. This current study on diagenesis derives from a large chemical and petrographic analysis of some of the earliest ceramics (1500-100 cal Before Common Era [BCE]) in the Basin of Mexico at a time when the development of ceramic trade …

Mexican Obsidian On Maui: Hawaiian Connection, Harmonic Convergence, Or Hokum?, Matthew Boulanger

Anthropology Research

In 2014, the television show America Unearthed (A & E Networks) featured an episode discussing evidence for pre-Columbian contact between Polynesia and continental North and South America. Included in this “evidence” was a large spearpoint, allegedly found on the island of Maui. The show’s host argues that the spearpoint is made on obsidian from central Mexico, and therefore represents evidence for direct contact between Polynesian and Maya peoples prior to the sixteenth century CE. A detailed analysis of the spearpoint, including geochemical sourcing, reveals that it is indeed made of so-called Pachuca obsidian from central Mexico; however, the size, shape, …

An Isotopic Assessment Of Late Prehistoric Interregional Warfare In The Southcentral Us, John R. Samuelsen

Graduate Theses and Dissertations

Skull burials are found all over the world. The cause of such ancient Native Americans deposits often lead to disagreement among scholars torn between warfare and ancestor veneration. One skull-and-mandible deposit, representing at least 352 people (A.D. 1253-1399), was uncovered at the Crenshaw site, a multiple-mound Caddo ceremonial center in southwest Arkansas. Most previous research suggested they were victims of interregional warfare from the Southern Plains or Mississippi Valley. One previous study hypothesized that this was a Caddo burial practice which expanded during the Middle Caddo period (A.D. 1200-1500) due to the adoption of maize as a staple and a …

Archaeological Feature Identification Through Geochemical Analysis Of Arctic Sediments From The Cape Krusenstern National Monument, Northwest Alaska, Patrick William Reed

Dissertations and Theses

Identification and interpretation of archaeological phenomena is typically based on visual cues and the physical presence of "something archaeological," such as a diagnostic artifact, landscape modification, or structural element. Yet many archaeological features, i.e. the discrete archaeological deposits related to past human behavior, lack clear indicators of human activity that provides clues to the feature's origin. At the Cape Krusenstern beach ridge complex, located in northwest Alaska, ambiguous features, that could be natural or anthropogenic (vegetation anomalies), or are of unknown cultural function (indeterminate), comprise 60% of the identified features at the complex. These ambiguous features represent a large gap …

Fort Ancient And Woodland Pottery From The Hahn Site, Hamilton County, Ohio: A Petrographic Analysis Of Chronological Changes In Ceramic Temper, Shelby C. Lutz 20

Honor Scholar Theses

Thousands of pottery sherds have been excavated by the Cincinnati Museum Center from the Hahn Site (Ohio Archaeological Site #33HA10), located near Newtown, Ohio. These potsherds, created by Native Americans, show a variety of temper materials, including fragments of limestone, shell, grog, and rock debris from glacial outwash. To better understand changes in the pottery-making technique, transitions and advancements in temper material, and possible economic and trade indicators, ceramic petrography and geochemical analyses were used to determine temper variability. A single archaeological feature from the site was chosen as a case study, Feature 146. This feature is a depression that …

Recovering Lost Information From Avocational Projectile Point Collections, Mackenzie Hughes

All Master's Theses

Human prehistory in North America has sparked the interest of private citizens for decades, sometimes leading to an accumulation of avocational artifact collections that lack site-level provenience. The Wild/Clymer artifacts (n = 1,371) are one such collection where precise site provenience was lost. The analysis aims to recover regional provenience by using morphology, raw material sourcing, and typology to create a data set. The avocational collection data set was analyzed by comparing it to the professionally recorded archaeological data sets from within 100 miles of Frenchglen, Oregon. A paradigmatic classification approach identified 606 typeable points in the avocational collection, in …

Oldowan Tool Behaviors Through Time On The Homa Peninsula, Kenya, Emma M. Finestone

Dissertations, Theses, and Capstone Projects

The adaptive significance of tool use to genus Homo is a central theme in human origins. However, what we know from the early Oldowan sites suggests that persistent technology may have begun as an opportunistic behavior with minimal investment, rather than a habitual and widespread adaptive revolution. This dissertation seeks to investigate investment in Oldowan tool production on the Homa Peninsula, Kenya, considering raw material selection, transport, and lithic production at two newly discovered Oldowan localities: Nyayanga (ca. 2.6 Ma) and Sare River (ca. 1.7 Ma).

The first section of this dissertation outlines a method that enables the comparison of …

Stable Isotope And Geochemical Characterization Of Nutrient Sources In The Big Creek Watershed Of Northwest Arkansas, Kelly Robin Sokolosky

Graduate Theses and Dissertations

The establishment of a concentrated animal-feeding operation (CAFO) in Newton County, Arkansas near Big Creek, a tributary of the Buffalo National River, has raised concern over potential degradation of water-quality in the watershed. In this study, isotopic tools were combined with standard geochemical approaches to characterize nutrient sources and dynamics in Big Creek. An isotopic and geochemical reference library of potential nutrient sources in the Big Creek watershed was established by direct sampling of representative potential sources, including septic-system effluent, poultry litter, swine and cattle manure, and CAFO waste lagoons. Representative nutrient sources and Big Creek stream samples were analyzed …

Protocol Implementation Plan For Cave Water Quality Monitoring In The Northern Great Plains Network, Narrative Version 1.0, Isabel W. Ashton, Justin S. Mills, Marc Ohms, Daniel Austin, Michael Wiles, Kara Paintner-Green

United States National Park Service: Publications

Executive Summary

The Northern Great Plains Inventory and Monitoring Network includes thirteen park units located in five northern Great Plains states across six ecoregions. Two park units, Jewel Cave National Monument (JECA) and Wind Cave National Park (WICA), protect significant cave resources. These two caves are among the longest caves in the world and have an assortment of underground water resources ranging from drip sites to cave lakes. Subsurface water quantity and quality in the caves is a concern due to groundwater depletion and groundwater contamination from pesticides (aboveground applications), hydrocarbons (vehicle use and related activities), and wastewater effluent (sewage …

Multivariate Analysis Of Hydrochemical Data For Jewel Cave, Wind Cave, And Surrounding Areas, Andrew J. Long, James B. Paces, William G. Eldridge

United States National Park Service: Publications

Abstract

Jewel Cave National Monument and Wind Cave National Park in South Dakota contain two of the six longest caves worldwide. These caves contain subterranean lakes that are important points of intersection between the water table of the Madison aquifer and the caves. During 2015 to 2017, several subterranean lakes were discovered in Jewel Cave, which previously was thought to be above the regional water table. The objectives of this study were to better understand the hydrology of the recently discovered subterranean lakes in Jewel Cave and to evaluate their relation or possible connection to similar lakes in Wind Cave. …

High-Precision Lead Isotope Analysis On Modern Populations To Determine Geolocation Reliability, Gennifer M. Goad

USF Tampa Graduate Theses and Dissertations

Forensic anthropologists increasingly use chemical isotope analysis in the investigation of unidentified human remains, as biochemical georeferencing continually improves with the development of modern reference data of known origins. Isotope variations in trace elements such as strontium (Sr) and lead (Pb) in human teeth are some of the most useful indicators of past domicile in archaeological research and thus have high potential for modern, forensic applications. In this study, high-precision lead isotope analysis was conducted on 63 modern human teeth, which were previously analyzed for strontium isotopes. The results present new lead isotope data for the following countries: United States …

Relating Cyanobacteria And Physicochemical Water-Quality Properties In Willow Creek Lake, Nebraska, 2012–14, David L. Rus, Brent M. Hall, Steven A. Thomas

United States Geological Survey: Water Reports and Publications

Document abstract

Cyanobacteria (also referred to as blue-green algae) are naturally present members of phytoplankton assemblages that may detract from beneficial uses of water because some strains produce cyanotoxins that pose health hazards to people and animals. Cyanobacteria populations observed in Willow Creek Lake during 2012 through 2014 were compared to external nutrient loading from the Willow Creek drainage basin and several other physicochemical properties within the lake, including internal nutrient loading. This report is part of a cooperative study between the United States Geological Survey, the Lower Elkhorn Natural Resources District, the Nebraska Department of Environmental Quality, the Nebraska …

An Assessment Of Atmospheric And Meteorological Factors Regulating Red Sea Phytoplankton Growth, Wenzhao Li, Hesham El-Askary, Mohamed A. Qurban, Emmanouil Proestakis, Michael J. Garay, Olga V. Kalishnikova, Vassilis Amiridis, Antonis Gkikas, Eleni Marinou, Thomas Piechota, K. P. Manikandan

Mathematics, Physics, and Computer Science Faculty Articles and Research

This study considers the various factors that regulate nutrients supply in the Red Sea. Multi-sensor observation and reanalysis datasets are used to examine the relationships among dust deposition, sea surface temperature (SST), and wind speed, as they may contribute to anomalous phytoplankton blooms, through time-series and correlation analyses. A positive correlation was found at 0–3 months lag between chlorophyll-a (Chl-a) anomalies and dust anomalies over the Red Sea regions. Dust deposition process was further examined with dust aerosols’ vertical distribution using satellite lidar data. Conversely, a negative correlation was found at 0–3 months lag between SST anomalies …

The Origin Of Dark Mats At The Sunrise Ridge Borrow Pit Site (45pi408) Mount Rainier National Park, Washington, Sean Stcherbinine

All Master's Theses

The Sunrise Ridge Borrow Pit Site is a precontact archaeological site located in the upland forest soils of Mount Rainier National Park. Site stratigraphy is complicated, consisting of tephra deposits from mostly known origins that are intercalated with dark sediments of unknown origin, referred to here as dark mats. Precontact occupation has been split previously into two components based on the ambiguous depositional history of the dark mats, notably their unknown parent material, depositional environment, and relationship with adjacent tephra strata. Stratigraphic samples from excavation units, features, and one off-site excavation unit was used to investigate these data gaps. Grain …

Occupational Seasonality And Paleoenvironmental Reconstruction At Quebrada Jaguay 280, Stephanie Melissa Gruver

Graduate Research Theses & Dissertations

Quebrada Jaguay 280 (QJ-280) is one of the oldest maritime archaeological sites in the New World. Previous excavations of the southern Peruvian coastal site have dated occupation from ~13,000-8,000 cal yr BP. These excavations also determined that the occupants of the site used preferential maritime resource procurement strategies and had an interzonal connection to the highlands. In 2017 a new excavation was conducted at QJ-280 and the remains of the marine mollusk Mesodesma donacium were recovered. Geochemical examinations on the shell remains informed on the occupational seasonality of the site and reconstructed sea surface temperatures experienced off the coast of …

Paleoenvironmental Reconstruction Using Coral Microatolls (Sp. Siderastrea Siderea) From The Gulf Of Gonâve, Haiti, Gilman Reno Ouellette Jr.

LSU Doctoral Dissertations

Natural and anthropogenic climate changes present unique and serious risks to society. In order to plan and implement adaptation and mitigation strategies successfully, regional manifestations of broad-scale climate changes must be understood robustly. The Caribbean region contains part of the Western Hemisphere Warm Pool (WHWP), a major sea surface temperature (SST) feature that plays a key role in North Atlantic climate. Climate variability in the Caribbean is captured poorly by climate models, due in part to a lack of continuous, multidecadal instrumental climate records from the region. I explored three research questions in this dissertation: Does non-systematic bias exist in …

Inventory And Analysis Of Some Obsidian Artifacts In The James M. Collins Collection, Matthew Boulanger, Alexis Graves

Anthropology Research

An inventory and analysis of four lots of Native American artifacts within the James M. Collins Collection curated at Southern Methodist University reveals the research value of archaeological materials with less than perfect provenience information. All that is known about the origins of these artifacts is that they appear to have come from Oregon. Elemental analysis by energy dispersive X-ray fluorescence identifies the most likely geochemical source for all of the obsidian artifacts in these lots. Source profiles identified from the 75 artifacts represent major sources located in southwestern Idaho. Similarly, the morphology of the artifacts is consistent with material …

Climate, Ecology, And Human Evolution During The Plio-Pleistocene, Scott Adam Blumenthal

Dissertations, Theses, and Capstone Projects

A major goal of paleoanthropology is to identify the selective pressures associated with hominin biological and behavioral evolution, yet establishing cause-effect relationships between climate, ecology, and human evolution remains problematic. This dissertation seeks to investigate hominin paleoecology in eastern Africa by reconstructing aspects of climate and ecology using stable isotope analysis.

The first part of this dissertation is focused on the ecology of primates and hominins. Modern tropical African ecosystems provide a useful model for understanding the ecological correlates of isotopic variation in the fossil record, and living primates provide a useful model for understanding the ecological significance of isotopic …

Middle Preclassic Period Maya Greenstone "Triangulates": Forms, Contexts, And Geology Of A Unique Mesoamerican Groundstone Artifact Type, Terry G. Powis, Sherman Horn Iii, Gyles Iannone, Paul F. Healy, James F. Garber, Jaime J. Awe, Sheldon Skaggs, Linda A. Howie

Publications and Research

Over the past twenty years our understanding of the Middle Preclassic (900–300 BCE) period has become much clearer through archaeological investigations at a number of sites located in the Upper Belize River Valley region of the eastern Maya Lowlands. While the picture of Middle Preclassic Maya life, including their material culture, has sharpened, there are aspects that remain uninvestigated. One artifact type, identified as greenstone triangulates, has been found at several Belize Valley sites and in a variety of contexts. Although a number of these multifaceted, polished groundstone items have been recovered, little research has focused on their distribution and …

Predictive Modeling Of Terrestrial Radiation Exposure From Geologic Materials, Daniel A. Haber

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys are an important tool for national security, scientific, and industrial interests in determining locations of both anthropogenic and natural sources of radioactivity. There is a relationship between radioactivity and geology and in the past this relationship has been used to predict geology from an aerial survey. The purpose of this project

is to develop a method to predict the radiologic exposure rate of the geologic materials in an area by creating a model using geologic data, images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), geochemical data, and pre-existing low spatial resolution aerial surveys …

Solubility And Detectability Of Hydrocarbons On The Surface Of Titan, Sandeep Singh

Graduate Theses and Dissertations

Titan’s thick atmosphere is enriched with organic compounds and its surface holds reservoirs of hydrocarbons. This makes Titan the only other candidate in our solar system (apart from Earth) to have stable liquid at the surface. The stability and characteristics of liquid and ices on the surface of Titan are of high importance in understanding its surface-atmosphere interactions. Titan’s hydrological cycle is similar to what we see on Earth, with the exception of methane (CH4) and ethane (C2H6) taking the place of water. The smoggy atmosphere veils the surface of Titan from the view of Cassini spacecraft, except at seven …

Using Kriging, Cokriging, And Gis To Visualize Fe And Mn In Groundwater, Crystal Johnson

Electronic Theses and Dissertations

For aesthetic, economic, and health-related reasons, allowable concentrations of iron (Fe) and manganese (Mn) found present in drinking water are 0.3 mg/L and 0.05 mg/L, respectively. Water samples taken from private drinking wells in the rural communities within Buncombe County, North Carolina contain amounts of these metals in concentrations higher than the suggested limits. This study focused on bedrock geology, elevation, saprolite thickness, and well depth to determine factors affecting Fe and Mn. Using ArcGIS 10.2, spatial trends in Fe and Mn concentrations ranges were visualized, and estimates of the metal concentrations were interpolated to unmonitored areas. Results from this …