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Articles 1 - 30 of 193

Full-Text Articles in Geochemistry

Career: New Insights Into The Ancient Carbon Cycle From Siliceous Deep-Sea Sediments, Donald Penman Jul 2026

Career: New Insights Into The Ancient Carbon Cycle From Siliceous Deep-Sea Sediments, Donald Penman

Funded Research Records

No abstract provided.


Characterizing The Unique Chemical Imprint Of On-Axis, Lower-Temperature Hydrothermal Flow To The Deep Ocean (Southern East Pacific Rise, 16.5°-18.0°S), Laura E. Moore, Randelle M. Bundy, Joseph A. Resing, Scott White, Tamara Baumberger, Peter N. Sedwick, Nathaniel J. Buck, Anson M. Antriasian, Isaac Keohane, Bettina M. Sohst, Sharon L. Walker, Christopher R. German Jan 2026

Characterizing The Unique Chemical Imprint Of On-Axis, Lower-Temperature Hydrothermal Flow To The Deep Ocean (Southern East Pacific Rise, 16.5°-18.0°S), Laura E. Moore, Randelle M. Bundy, Joseph A. Resing, Scott White, Tamara Baumberger, Peter N. Sedwick, Nathaniel J. Buck, Anson M. Antriasian, Isaac Keohane, Bettina M. Sohst, Sharon L. Walker, Christopher R. German

OES Faculty Publications

In addition to high-temperature vents, lower-temperature flow (LTF) (< 300°C) is abundant along mid-ocean ridges and contributes globally-important fluxes of heat and water along with largely-unconstrained geochemical influences on the ocean. We examined the impact of on-axis LTF on the chemical composition of the overlying water column (< 40 m above seafloor) along the 16.5°-18.0°S sector of the ultrafast-spreading southern East Pacific Rise using autonomous underwater vehicle Sentry surveys and conductivity-temperature-depth rosette casts. LTF sites were typically spatially isolated from high-temperature systems and imparted unique chemical signatures to the overlying ocean. Water column samples impacted by LTF exhibited low particulate iron:sulfur ratios and high methane: total-dissolvable manganese ratios, whereas samples influenced by high-temperature venting exhibited opposite trends. We confirmed that LTF imparts a distinct and measurable chemical signature to the water column, independent from high-temperature vents. Isolated, on-axis LTF will be important to consider when assessing hydrothermal circulation impacts upon ocean biogeochemistry.


The Effects Of A Microplate On Plume-Ridge Interactions: Constraints From Comparing Easter And Juan Fernandez Microplates In The Eastern Pacific Ocean, Katherine Ames, Jennifer Georgen Jan 2026

The Effects Of A Microplate On Plume-Ridge Interactions: Constraints From Comparing Easter And Juan Fernandez Microplates In The Eastern Pacific Ocean, Katherine Ames, Jennifer Georgen

OES Faculty Publications

This study investigates the nature of plume-ridge interactions near a tectonic microplate using mantle Bouguer anomaly (MBA) gravity calculations. The focus of this investigation is a comparison of the Easter and Juan Fernandez microplates, which are located in the eastern Pacific Ocean along the Pacific, Nazca, and Antarctic plate boundaries. The microplates have several similar characteristics, including general size, time of formation, and clockwise rotation within the larger bounding mid-ocean ridge systems. Unlike the Juan Fernandez microplate, however, the Easter microplate is located near a mantle plume (Easter/Salas y Gomez). Previously published geochemical data suggest that material from this plume …


Sedimentological And Geochemical Investigation Of The Origin Of Upper Pennsylvanian Black Shales, East-Central Appalachian Basin, Tyler Hickey Jan 2026

Sedimentological And Geochemical Investigation Of The Origin Of Upper Pennsylvanian Black Shales, East-Central Appalachian Basin, Tyler Hickey

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the east-central Allegheny foreland basin, laminated black shales overlying Upper Pennsylvanian Glenshaw Fm. coal seams record paleoenvironmental conditions associated with the termination of peat swamp deposition before, during, and after the Carboniferous Coal Forest Collapse (CCFC), a major paleobotanical evolutionary event during the Late Paleozoic Ice Age (LPIA) that contributed to extinction of lepidodendrons near the Desmoinesian-Missourian boundary (~306 Ma). Previous investigations of the CCFC commonly implicate an episode of aridification during intensification of LPIA glaciation that stressed the lepidodendrons beyond their ecological tipping point; however, the cause of this aridification is unclear. An investigation of Glenshaw Fm. black …


Reconstructing Central American Hydroclimate Changes Across Time From Isotopic Signatures In Modern And Paleo-Rainfall Records, Giuseppe Lucia Dec 2025

Reconstructing Central American Hydroclimate Changes Across Time From Isotopic Signatures In Modern And Paleo-Rainfall Records, Giuseppe Lucia

UNLV Theses, Dissertations, Professional Papers, and Capstones

Tropical monsoon rainfall is a key component of Earth’s climate system and supports the livelihood and economy of billions of people. Yet, projections of future monsoons remain highly uncertain, particularly in regions with distinct physiography and complex land-ocean-atmosphere interactions like Central America, where long and continuous high-resolution paleoclimate data to test climate model simulations are still limited. This series of studies aims to reconstruct monsoon dynamics and underlying forcing controls in Central America on multiple timescales by the analysis and integration of stable isotope data in modern and paleo-rainfall records from Guatemala.

In Chapter 2, I present a daily-resolution, two-year-long …


An Investigation Of Paleoclimate Through A Sedimentological Lens In The Gulf Of Mexico And Western North Pacific, Sarah Monica Dec 2025

An Investigation Of Paleoclimate Through A Sedimentological Lens In The Gulf Of Mexico And Western North Pacific, Sarah Monica

Dissertations

This dissertation explores the use of sediment cores as proxy data for the reconstruction of paleoclimatic and environmental conditions. Human-caused climate change is leading to dramatic shifts in the global climate. As the instrumental record of climate is relatively short compared to the amount of time Earth has experienced weather, this work aims to extend our knowledge of climate beyond the instrumental record, thereby improving our holistic understanding of the climate system. In Chapter one, sediment cores from the central Texas inner shelf are used to produce a record of intense tropical cyclone (TC) activity over a ~4500-year period. X-Ray …


Pre-Calibration Of Δ18O For Paleoclimatic Interpretations Using Stalagmites In Cueva Ensueño, Puerto Rico, Gabriel Enrique López Borobia, Ny Riavo G. Voarintsoa, Ricardo Sánchez-Murillo, Pablo Antonio Llerandi Román Oct 2025

Pre-Calibration Of Δ18O For Paleoclimatic Interpretations Using Stalagmites In Cueva Ensueño, Puerto Rico, Gabriel Enrique López Borobia, Ny Riavo G. Voarintsoa, Ricardo Sánchez-Murillo, Pablo Antonio Llerandi Román

International Journal of Speleology

Stalagmites are invaluable archivers of past climate conditions, as their oxygen isotopic composition (δ¹⁸Oc) closely mirrors the isotopic signature of the drip water (δ¹⁸Ow) from which they precipitate. This isotopic relationship is governed by the fractionation factor (1000ln¹⁸α), which is temperature dependent. In this research, we studied 1000ln¹⁸α within Cueva Ensueño, a cave situated in Puerto Rico’s northern karst region, as a step toward calibrating δ¹⁸Oc for paleoclimate interpretations using stalagmites. We collected drip waters, measured their temperature in situ, and sampled carbonates from ten selected stations within the cave. Sampling was conducted in December …


Effect Of Seasonal Variability In Methane Emissions And Iron Redox Chemistry At Terrestrial-Aquatic Interfaces, Hermes C. Ruiz Aug 2025

Effect Of Seasonal Variability In Methane Emissions And Iron Redox Chemistry At Terrestrial-Aquatic Interfaces, Hermes C. Ruiz

Master's Theses

Methane (CH₄) emissions at terrestrial–aquatic interfaces (TAIs) are significant contributors to the global carbon budget, yet the mechanisms driving methanogenesis remain poorly understood. Limited data exist on how seasonal variations and redox processes influence CH₄ fluxes in these dynamic ecosystems. This study addressed two questions: (1) How are CH₄ fluxes in riverine floodplains and adjacent hillslopes impacted by seasonal variations? (2) What roles do metal redox processes (e.g., iron (Fe)) play in regulating methanogenesis?

In-situ CH₄ flux and solid-phase Fe speciation were quantified in East River, CO, under flooded and drained conditions. Groundwater chemistry, gas flux, and soil physical properties …


New Precipitation Is Scarce In Deep Soils: Findings From 47 Forest Plots Spanning Switzerland, Emily I. Burt, Scott T. Allen, Sabine Braun, Simon Tresch, James W. Kirchner, Gregory R. Goldsmith Aug 2025

New Precipitation Is Scarce In Deep Soils: Findings From 47 Forest Plots Spanning Switzerland, Emily I. Burt, Scott T. Allen, Sabine Braun, Simon Tresch, James W. Kirchner, Gregory R. Goldsmith

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

As precipitation infiltrates into soils, it can recharge them, displace previously stored waters, or bypass already-filled pores. Using 3,697 δ2H and δ18O measurements of water collected nearly monthly over >3 years in 47 forest plots across Switzerland, we present a systematic investigation of the controls on mobile soil water transport. We quantified the lags and damping of water as it percolates downward using young water fraction analysis (Fyw), and the fractions of soil water composed by precipitation that fell within the previous month (new water fractions, Fnew). The Fnew of water sampled in surface soils ranged …


Mechanisms Of Gold Enrichment In Seafloor Massive Sulfide Deposits: A Study On The Higashi-Aogashima Hydrothermal Field, Claudia Martinez Aug 2025

Mechanisms Of Gold Enrichment In Seafloor Massive Sulfide Deposits: A Study On The Higashi-Aogashima Hydrothermal Field, Claudia Martinez

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of Seafloor Massive Sulfides (SMS) deposit formation is vital for assessing both the economic potential and environmental risks posed by future marine mining projects. Metal-rich SMS deposits form in hydrothermal vent systems within tectonically active regions, such as back-arc basins, where faults enhance crustal permeability, enabling fluid migration driven by magmatic heat sources at depth in the crust. Currently our understanding of SMS formation processes is based on bulk-rock geochemical and isotopic data, lacking the necessary spatial and temporal resolution to understand ore forming processes. As a result, critical gaps remain in understanding the exact mechanisms responsible for …


Development And Evaluation Of Supported Ionic Liquid Membrane And Porphyrin Frameworks For Carbon Capture Separation, Sarang Ismail Aug 2025

Development And Evaluation Of Supported Ionic Liquid Membrane And Porphyrin Frameworks For Carbon Capture Separation, Sarang Ismail

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

The global urgency to mitigate anthropogenic CO₂ emissions has intensified the pursuit of energy-efficient separation technologies. Supported Ionic Liquid Membranes (SILMs) have emerged as promising candidates for CO₂ capture due to their tunable solubility-selectivity and low energy requirements. However, challenges such as mechanical instability, limited scalability, and trade-offs in transport performance have impeded their widespread adoption.

This thesis explores a systematic approach to designing and optimizing SILMs for enhanced CO₂ separation by tailoring polymer–ionic liquid interactions, processing conditions, and material architectures. A comprehensive set of studies were conducted using poly(vinylidene fluoride) (PVDF) with varying molecular weights, different grades of PEBAX®, …


Optimizing Nitrogen Management: Assessing Nitrate Transport In The Deep Vadose Zone And Its Impact On Groundwater Quality In East-Central Nebraska, Muili O. Lawal May 2025

Optimizing Nitrogen Management: Assessing Nitrate Transport In The Deep Vadose Zone And Its Impact On Groundwater Quality In East-Central Nebraska, Muili O. Lawal

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Groundwater contamination by nitrate (NO₃-N) is a growing environmental and public health concern driven largely by intensive agricultural fertilizer applications. The vadose zone plays an important role in NO₃-N transport, influencing groundwater quality and agricultural sustainability. This study investigated NO₃-N leaching dynamics in the deep vadose zone of Water Quality Sub-Area 30 (WQA30) within the Lower Loup Natural Resources District (LLNRD), northeast of Columbus, Nebraska (mean groundwater NO₃-N: 20.3 mg/L), using soil cores from 16 shallow (to 6.1 m) and four deep (down to 25.9 m) across four zones, two with inorganic fertilizer (Zones 1 and 4) and two with …


The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski May 2025

The Petm: A Window Into Earth's Future Climate, Jacalyn M. Wittmer Malinowski

Climate Change and the Individual, 2025-26

The Paleocene-Eocene Thermal Maximum (PETM) is not just an event that occurred in Earth’s distant past (~55 million years ago) but is a crucial lesson for today’s meteoric climate change. The PETM offers a historical parallel of rapid flux of greenhouse gases into the atmosphere that caused global warming, ocean acidification, dramatic changes in weather, and extinctions. This global warming event was the result of 20,000 years of “rapid” warming (in geological terms) however, we are experiencing rates of warming that are 5-10x higher than PETM levels. We are not experiencing rapid warming today, in comparison to the past, we …


08 - Blue Carbon Sequestration And Sediment Storage In Seagrass Meadows Of South Bay, Luke C. Clements, Adriana Amrhein, Richard P. Hale Apr 2025

08 - Blue Carbon Sequestration And Sediment Storage In Seagrass Meadows Of South Bay, Luke C. Clements, Adriana Amrhein, Richard P. Hale

Undergraduate Research Symposium

Blue carbon is stored in coastal and marine ecosystems like seagrass meadows and salt marshes, which helps combat climate change by preventing greenhouse gas emissions. This study examines the role of seagrass in carbon storage by comparing sediment cores from a mud channel and a seagrass meadow in South Bay.

We collected a 100 cm core from the mud channel and a 55 cm core from the seagrass area, taking samples every 10 cm to analyze grain size and organic carbon content. Using a wet sieving method, we separated sand from mud and measured organic carbon through loss on ignition. …


Glacial Isostatic Adjustments And Their Impact On Sea-Level Predictions, Dayne M. Williams, Jeanne Sumrall Mar 2025

Glacial Isostatic Adjustments And Their Impact On Sea-Level Predictions, Dayne M. Williams, Jeanne Sumrall

SACAD: Scholarly Activities

Relative sea level adjustments and their effects directly contribute to modern day climate change and ocean knowledge. This is shown through Glacial isostatic adjustment models which depend on ice thickness, time period, and core analyzations within a local region. These models demonstrate a direct correlation between RSL, era of retreat, and ice thickness even with comparison of other similar models, with some minor discrepancies. These discoveries led to several new advancements within the field of glaciology regionally and nationally. Generally concluding that the research done isn’t sufficient and more data regionally is needed to study its impacts more detailed.


Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones Jan 2025

Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones

Graduate Theses/Dissertations

Karst landscapes are abundant in Missouri, with features such as caves, springs, and sinkholes that form through the dissolution of limestone. Leith Creek is a small stream in Polk County, Missouri fed by two springs and the shallow unconfined Springfield Plateau aquifer, a highly karstified aquifer which is made up of limestone and minor interbedded shale-mudstone units. To determine if Leith Creek is gaining or losing, stream flow, water chemistry and temperature sensors were monitored. Stream flow results required multiple visits to take measurements while temperature sensors required two visits, one to install the dataloggers and another to remove the …


Core-Top Constraints On The Ecology And Paleothermometry Of Planktic Foraminifera In The Indian Ocean, Ryan H. Glaubke, Elisabeth L. Sikes, Natalie E. Umling, Katherine A. Allen, Matthew W. Schmidt Jan 2025

Core-Top Constraints On The Ecology And Paleothermometry Of Planktic Foraminifera In The Indian Ocean, Ryan H. Glaubke, Elisabeth L. Sikes, Natalie E. Umling, Katherine A. Allen, Matthew W. Schmidt

OES Faculty Publications

The magnesium-to‑calcium ratio (Mg/Ca) of fossil foraminifera is a widely used geochemical proxy for reconstructing past ocean temperatures. Culturing experiments have shown that, for some species, nonthermal influences like salinity and carbonate chemistry play a non-trivial role in the incorporation of Mg into foraminiferal calcite. Inclusion of these variables into Mg/Ca calibrations have provided a better fit to core top and sediment trap data in some recent studies, but the widespread covariation of potential control variables in the open ocean and the lack of multivariate calibrations for some species warrants additional work. Here, we assess Mg/Ca calibrations for four common …


Resolving Antarctic Margin Paleoceanography For Two Different Timescales And Archives, Theresa M. King Jun 2024

Resolving Antarctic Margin Paleoceanography For Two Different Timescales And Archives, Theresa M. King

USF Tampa Graduate Theses and Dissertations

Recent decades have seen increased rates of ice mass loss from Antarctic ice sheets, through thinning of many ice shelves around the periphery of the continent. The most vulnerable are the glacial systems that are marine-terminating and grounded below sea level, a characteristic that exposes these systems to sea level rise and warming oceans. Enhanced basal melting under the influence of warm ocean water masses can lead to thinning and retreat of glaciers, and ultimately to the acceleration of grounded ice loss. To contextualize current ice mass loss and contribute to accurate model projections for future retreat scenarios, it is …


Antarctic Atmosphere-Ocean-Ice Interactions During Past Warm Climates: An Ice-Proximal Perspective, Imogen Mireille Browne Jun 2024

Antarctic Atmosphere-Ocean-Ice Interactions During Past Warm Climates: An Ice-Proximal Perspective, Imogen Mireille Browne

USF Tampa Graduate Theses and Dissertations

Antarctica’s ice sheets contain 58 m of sea level equivalent ice and thus exert a fundamental control on global sea level on decadal to million-year timescales. Interactions between Antarctica’s ice sheets, regional atmospheric circulation, and the Southern Ocean influence ice sheet mass balance, sea ice formation, and deep water production, which regulate Earth’s climate. At present, Antarctica’s fringing ice shelves and outlet glaciers, particularly in West Antarctica, are losing mass as warm ocean waters move landward across the continental shelves, melting the underside of ice shelves and eroding glacial grounding lines. In East Antarctica, net ice mass gain is occurring …


Applied Depositional Geosystems Of The Coos Bay Basin, Oregon: Organic Geochemistry, Maturation, Paleoenvironmental Reconstruction And Biostratigraphy Of The Coaledo Delta During The Middle Eocene Climatic Optimum (Meco), Allison K. Barbato Apr 2024

Applied Depositional Geosystems Of The Coos Bay Basin, Oregon: Organic Geochemistry, Maturation, Paleoenvironmental Reconstruction And Biostratigraphy Of The Coaledo Delta During The Middle Eocene Climatic Optimum (Meco), Allison K. Barbato

LSU Doctoral Dissertations

The Coos Bay Basin on the southwestern coast of Oregon is a forearc basin that contains exceptionally preserved Eocene to Miocene, tidal to wave-dominated, shallow deltaic to deep marine sediments of the Coaledo Delta. Coastal depositional environments are known to host source, reservoir, and seal rocks. Climate, topographic relief, and geographical position all play an important role in regional vegetation development and oceanic setting. This study assesses 84 outcrop and 12 core samples from Coos Bay for their organic geochemical characteristics and microfossil assemblage to provide source rock characterization information, organofacies descriptions, environmental reconstructions, and age control.

Results indicate the …


Global Subterranean Estuaries Modify Groundwater Nutrient Loading To The Ocean, Stephanie J. Wilson, Amy Moody, Tristan Mckenzie, M. Bayani Cardenas, Elco Luijendijk, Audrey H. Sawyer, Alicia Wilson, Holly A. Michael, Bochao Xu, Karen L. Knee, Hyung-Mi Cho, Yishai Weinstein, Adina Paytan, Nils Moosdorf, Chen-Tung Aurthur Chen, Melanie Beck, Cody Lopez, Dorina Murgulet, Guebuem Kim, Mathew A. Charette, Hannelore Waska, J. Severino P. Ibánhez, Gwénaëlle Chaillou, Till Oehler, Shin-Ichi Onodera, Mitsuyo Saito, Valenti Rodellas, Natasha Dimova, Daniel Montiel, Henrietta Dulai, Christina Richardson, Jinzhou Du, Eric Petermann, Xiaogang Chen, Kay L. Davis, Sebastien Lamontagne, Ryo Sugimoto, Guizhi Wang, Hailong Li, Américo I. Torres, Cansu Demir, Emily Bristol, Craig T. Connolly, James W. Mcclelland, Brenno J. Silva, Douglas Tait, Bsk Kumar, R. Viswanadham, Vvss Sarma, Emmanoel Silva-Filho, Alan Shiller, Alanna Lecher, Joseph Tamborski, Henry Bokuniewicz, Carlos Rocha, Anja Reckhardt, Michael Ernst Böttcher, Shan Jiang, Laura M. Hernández-Terrones, Suresh Babu, Beata Szmczycha, Mahmood Sadat-Noori, Felipe Niencheski, Kimberly Null, Craig Tobias, Bongkeun Song, Iris C. Anderson, Isaac R. Santos Jan 2024

Global Subterranean Estuaries Modify Groundwater Nutrient Loading To The Ocean, Stephanie J. Wilson, Amy Moody, Tristan Mckenzie, M. Bayani Cardenas, Elco Luijendijk, Audrey H. Sawyer, Alicia Wilson, Holly A. Michael, Bochao Xu, Karen L. Knee, Hyung-Mi Cho, Yishai Weinstein, Adina Paytan, Nils Moosdorf, Chen-Tung Aurthur Chen, Melanie Beck, Cody Lopez, Dorina Murgulet, Guebuem Kim, Mathew A. Charette, Hannelore Waska, J. Severino P. Ibánhez, Gwénaëlle Chaillou, Till Oehler, Shin-Ichi Onodera, Mitsuyo Saito, Valenti Rodellas, Natasha Dimova, Daniel Montiel, Henrietta Dulai, Christina Richardson, Jinzhou Du, Eric Petermann, Xiaogang Chen, Kay L. Davis, Sebastien Lamontagne, Ryo Sugimoto, Guizhi Wang, Hailong Li, Américo I. Torres, Cansu Demir, Emily Bristol, Craig T. Connolly, James W. Mcclelland, Brenno J. Silva, Douglas Tait, Bsk Kumar, R. Viswanadham, Vvss Sarma, Emmanoel Silva-Filho, Alan Shiller, Alanna Lecher, Joseph Tamborski, Henry Bokuniewicz, Carlos Rocha, Anja Reckhardt, Michael Ernst Böttcher, Shan Jiang, Laura M. Hernández-Terrones, Suresh Babu, Beata Szmczycha, Mahmood Sadat-Noori, Felipe Niencheski, Kimberly Null, Craig Tobias, Bongkeun Song, Iris C. Anderson, Isaac R. Santos

OES Faculty Publications

Terrestrial groundwater travels through subterranean estuaries before reaching the sea. Groundwater-derived nutrients drive coastal water quality, primary production, and eutrophication. We determined how dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and dissolved organic nitrogen (DON) are transformed within subterranean estuaries and estimated submarine groundwater discharge (SGD) nutrient loads compiling > 10,000 groundwater samples from 216 sites worldwide. Nutrients exhibited complex, nonconservative behavior in subterranean estuaries. Fresh groundwater DIN and DIP are usually produced, and DON is consumed during transport. Median total SGD (saline and fresh) fluxes globally were 5.4, 2.6, and 0.18 Tmol yr−1 for DIN, DON, and DIP, …


Diatom Productivity And Nutrient Dynamics In The Ross Sea, Antarctica During Warm Events In The Neogene, Marialena Christopoulou Jan 2024

Diatom Productivity And Nutrient Dynamics In The Ross Sea, Antarctica During Warm Events In The Neogene, Marialena Christopoulou

Graduate Research Theses & Dissertations

Increased melting of the Antarctic Ice Sheet (AIS) in recent decades, has had a significant impact on many aspects of the global ocean. Models indicate that by the end of the 21st century atmospheric carbon dioxide (CO2) concentrations may exceed 500 ppm, and the average global temperature will likely warm by more than 2°C. However, data that provide model constraints on potential feedbacks in ice-ocean-atmosphere system are limited by short-timescales (e.g., decadal- to centennial-scale) and incomplete spatial coverage. In particular, little is known about the impacts of future warming and widespread melting of AIS on marine biological productivity, silicate weathering …


Submarine Groundwater Discharge As A Major Nutrient Source In River-Fed Vs. Tidally Dominated Estuaries, Stephanie J. Wilson, Joseph J. Tamborski, Bongkeun Song, Peter Bernhardt, Margaret R. Mulholland Jan 2024

Submarine Groundwater Discharge As A Major Nutrient Source In River-Fed Vs. Tidally Dominated Estuaries, Stephanie J. Wilson, Joseph J. Tamborski, Bongkeun Song, Peter Bernhardt, Margaret R. Mulholland

OES Faculty Publications

The tidal tributaries of the lower Chesapeake Bay experience seasonally recurring harmful algal blooms and the significance of submarine groundwater discharge (SGD) as a nutrient vector is largely unknown. Here, we determined seasonal SGD nutrient loads in two tributaries with contrasting hydrodynamic conditions, river-fed (York River) vs. tidally dominated (Lafayette River). Radon surveys were performed in each river to quantify SGD at the embayment-scale during spring and fall 2021. Total SGD was determined from a ²²²Rn mass balance and Monte Carlo simulations. Submarine groundwater discharge rates differed by a factor of two during spring (Lafayette = 11 ± 17 cm …


Geoelectrical And Hydrochemical Characterization Of Submarine Groundwater Discharge In Florida Bay, Ifeanyi Emmanuel Eze Jan 2024

Geoelectrical And Hydrochemical Characterization Of Submarine Groundwater Discharge In Florida Bay, Ifeanyi Emmanuel Eze

College of Graduate Studies: Theses & Dissertations

Florida Bay, situated at the southern tip of Everglades National Park and underlain by the Miami Limestone formation, is an ecosystem of global significance. Over the past century, the bay has faced threats such as droughts, seagrass mortality, and hypersalinity. Despite various studies and management efforts, the dynamics of submarine groundwater discharge (SGD) in the region remain underexplored. Given that SGD plays a significant role in the chemical dynamics of coastal ecosystems, it warrants thorough investigation. This study aims to characterize the spatial and temporal patterns of SGD in Florida Bay by surveying three basins – Rankin, Whipray, and Rabbit …


Wonderstone And Its Connection To Liesegang, Microbes, And Beyond, Haden S. Mandery Dec 2023

Wonderstone And Its Connection To Liesegang, Microbes, And Beyond, Haden S. Mandery

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

In the western and southwestern United States, the term wonderstone is used to describe volcanic, volcaniclastic, and sedimentary rocks with variegated banding produced by iron oxide mineralization or staining. This iron oxide mineralization is typically described as Liesegang banding. In this paper I will (1) test if the banding in wonderstone follows the spacing and width laws characteristic of Liesegang, (2) identify the source of iron that ultimately precipitated in the bands, and (3) examine the role that microbes played in the formation of the mineralization in these rocks. I conclude that the iron oxide mineralization is not Liesegang banding. …


New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott Dec 2023

New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigation into seamounts that stem from intraplate volcanism—that is volcanism occurring far from plate boundaries—presents an opportunity to deconvolve processes associated with mantle compositional heterogeneities and melting dynamics. Upwelling and decompression of thermochemically anomalous mantle plumes is the primary mechanism for significant intraplate volcanism; however, many seamounts dotted across the Pacific Plate do not correlate spatially, temporally, or geochemically with mantle plume volcanism. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism are the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present merged multibeam (<100 m) and satellite altimetry bathymetric maps of the Geologist Seamounts region, new 40 …


Enhancing Our Understanding Of Ancient Oceans Through The Investigation Of Molybdenum Behavior Under Sulfidic Conditions, Rachel Faye Phillips Dec 2023

Enhancing Our Understanding Of Ancient Oceans Through The Investigation Of Molybdenum Behavior Under Sulfidic Conditions, Rachel Faye Phillips

Open Access Theses & Dissertations

The most abundant trace metal in the ocean today, molybdenum (Mo), exhibits distinct behavior in oxygenated water, where it remains predominantly dissolved, compared to euxinic (i.e., oxygen-free and sulfidic) water, in which it is sequestered into the sediment. This dissimilar behavior allows us to use Mo concentrations and isotopic compositions in sediment to reconstruct marine oxygenation conditions throughout geologic history. However, Mo sequestration mechanisms under euxinic conditions remain unresolved, which limits the accuracy and precision of reconstructions made using Mo signatures in the rock record. For my doctoral research, I experimentally investigated abiotic and biotic Mo sequestration mechanisms under various …


Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford Oct 2023

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …


Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett Jun 2023

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …


Evaluating Fungal Population Response To The Miocene Climatic Optimum: High-Resolution Palynological Insights From The South China Sea And Mcmurdo Sound, Antarctica, Mallory Pilie Apr 2023

Evaluating Fungal Population Response To The Miocene Climatic Optimum: High-Resolution Palynological Insights From The South China Sea And Mcmurdo Sound, Antarctica, Mallory Pilie

LSU Master's Theses

Fungi play key and specific roles in ecosystems, specifically as many have restricted geographic distributions, known host/substrate preferences, and are important local environmental indicators due to their short dispersal distances. This study of fossil fungi from a time interval of pronounced global warming, the Miocene Climatic Optimum (MCO), allows analysis of fungal response to an analogue for future climate change scenarios. The research presented herein is part of a larger project, Fungi in a Warmer World (FiaWW), which is using globally-distributed sediment samples to provide foundational information on fungal community distribution patterns and will provide the first fungi-based climatological reconstructions …