Geochemistry Commons^™

Compound-Specific Isotope Records Of Dust Provenance And Hydroclimate In The North Pacific And Marginal Seas Of East Asia: Integrating N-Alkane Δ13c And Δd With Standardized Analytical Frameworks, Julian W. Traphagan

LSU Doctoral Dissertations

This dissertation presents advancements in compound-specific isotope analysis (CSIA) through methodological innovation and paleoclimate reconstruction in Central and East Asia. Utilizing plant wax n-alkanes from International Ocean Discovery Program (IODP) and Ocean Drilling Program (ODP) sediment cores, this research reconstructs atmospheric circulation shifts responding to tectonic evolution and climate transitions since the Late Miocene.

Chapter 1 investigates hydrogen isotope compositions (δD_wax) from IODP U1430 (Sea of Japan), ODP 886, and ODP 1208 (North Pacific) to trace dust provenance and hydroclimate changes since ~13 Ma. Results reveal persistently segmented source-to-sink systems: the Sea of Japan dominated by westerly …

Applied Depositional Geosystems Of The Coos Bay Basin, Oregon: Organic Geochemistry, Maturation, Paleoenvironmental Reconstruction And Biostratigraphy Of The Coaledo Delta During The Middle Eocene Climatic Optimum (Meco), Allison K. Barbato

LSU Doctoral Dissertations

The Coos Bay Basin on the southwestern coast of Oregon is a forearc basin that contains exceptionally preserved Eocene to Miocene, tidal to wave-dominated, shallow deltaic to deep marine sediments of the Coaledo Delta. Coastal depositional environments are known to host source, reservoir, and seal rocks. Climate, topographic relief, and geographical position all play an important role in regional vegetation development and oceanic setting. This study assesses 84 outcrop and 12 core samples from Coos Bay for their organic geochemical characteristics and microfossil assemblage to provide source rock characterization information, organofacies descriptions, environmental reconstructions, and age control.

Results indicate the …

Palynology And Paleoclimatology Of The Chicxulub Impact Crater In The Early Paleogene, Vann Smith

LSU Doctoral Dissertations

At the end of the Cretaceous Period, a large bolide impacted the Earth and formed the Chicxulub impact crater in the Yucatán Peninsula, Mexico. In 2016, International Ocean Discovery Program (IODP) Expedition 364 Site M0077 drilled into the buried peak ring of the crater, recovering a marine Paleocene to early Eocene post-impact section deposited on top of the impact breccia. Palynological analysis of 195 samples from the post-impact section has yielded the first pre-Holocene vegetational record from inside the Chicxulub impact crater and the first palynological record of the recovery of life following the end-Cretaceous mass extinction from inside the …

Computer Simulations Of Diffusional Isotope Effects And Dynamical Properties Of Silicate Melts, Haiyang Luo

LSU Doctoral Dissertations

Silicate melts have served as transport agents in the chemical and thermal evolution of Earth. Diffusional isotope effect in silicate melts is the key to interpret isotope variations in lots of geological samples. Isotopic mass dependence of diffusion is commonly expressed as (Di/Dj)=(mj/mi)^β, where Di and Dj are diffusion coefficients of two isotopes whose masses are mi and mj. However, how the dimensionless empirical parameter β depends on temperature, pressure, and composition remains poorly constrained. Viscosity and electrical conductivity are two fundamental dynamical properties of silicate melts needed to constrain melt distribution in Earth's interior but remain unclear for most …

Application Of Compound-Specific Stable Isotopes And Molecular Biomarkers To Paleoclimatic And Paleoecological Reconstructions, Mingqiu Hou

LSU Doctoral Dissertations

Compound-specific stable isotope analysis and biomarker-based paleothermometry have been increasingly applied to for paleoclimate and paleoecology studies. The first project aims to reconstruct the paleoclimate in the Qaidam Basin during the last glacial period. Qaidam Basin in the Northern Tibetan Plateau is a critical eolian factory located at a unique geographic location that links the Westerlies and the Asian summer monsoons. However, how the interactions of two climatic systems influence the paleohydrology that in turn impacts the eolian production in the Qaidam Basin has been seldom explored. Our compound-specific hydrogen isotope and U^K ₃₇ temperature data found that the …

Investigating Geochemical Processes Of Fluid-Rock Interactions On Materials Related To Energy And Environment, Zelong Zhang

LSU Doctoral Dissertations

Understanding the potential processes of radionuclides released from nuclear waste forms is essential to the safe disposal and containment of nuclear waste. Iodoapatite, a potential waste form for radioiodine, was chosen as a model system to examine the impact by common aqueous anions on iodine release processes. Four semi-dynamic leaching tests were performed using 0.1 mol/L NaCl, Na₂CO₃, Na₃PO₄, and Na₂SO₄ solutions respectively under 90 °C, 1 bar, fixed S/V ratio 5/m (sample surface area to solution volume), and with 24-hour replacement of the leaching solutions. Solution analysis and …

Element Transport In A River-Lake Continuum Across Forest-Dominated Landscapes: A Case Study In Central Louisiana, Zhen Xu

LSU Doctoral Dissertations

Studying the biogeochemical connectivity between rivers and lakes can help us understand their ecological and environmental impacts within a drainage basin, which is especially true for forest watersheds that play a vital role in provisioning freshwater services to ecosystems and downstream communities. This dissertation research consists of three interconnected studies with the overarching goal of discerning the connectivity of elements in a river-lake continuum across forest-dominated landscapes. These studies utilized water samples and in situ measurements collected from the Little River-Catahoula Lake continuum in the subtropical Louisiana, USA at monthly intervals during 2015-2016 and 1978-2008 historical water quality, hydrological and …

Exploring Planetary Surfaces With Remote Sensing, Donald R. Hood

LSU Doctoral Dissertations

Aside from Earth, Mars is the most well-explored planetary body in our solar system. Much has been learned about its geologic past including a history of volcanism, ice ages, and potentially long-lasting liquid water. Much of this knowledge of Mars comes from remote observations of the surface and atmosphere from Mars-orbiting satellites. Such remote observations remain the only way to examine the entirety of Mars’ surface as rovers and landers can only examine small areas. The chapters of this work cover three projects that explore the surface of Mars through a variety of remote sensing methods.

In chapter 1, Gamma-ray …

Neogene Chemical Weathering And Provenance Records Of The Western Himalaya Preserved In The Arabian Sea, Peng Zhou

LSU Doctoral Dissertations

Some tectonic models for the Himalaya emphasize the importance of surface processes in controlling the structural evolution. To investigate this tectonic–climatic interactions, and the weathering and erosion of the western Himalaya, International Ocean Discovery Program (IODP) Expedition 355 drilled two sites (site U1456 and U1457) in Laxmi Basin, which located in the Eastern Arabian Sea. In my research project, I plan to use a series of geochemical and geochronological methods on the sediment samples from the cores of these two sites, and sediments from an industrial borehole Indus Marine A-1, which near the Indus river mouth, to reconstruct a climatic …

Iron Mediated Organic Preservation In A River Influenced Continental Margin, Neha Ajit Ghaisas

LSU Doctoral Dissertations

Continental margins such as the Mississippi river influenced Louisiana shelf (MIS), are important land-ocean interfaces where excessive water column productivity and rapid burial results in large amounts of organic carbon (OC) being sequestered in the sediments. The preservation of OC in sediments is controlled by a number of processes among which mineral-OC interactions are considered to be more important. Specifically, the interactions between sediment iron (Fe) species and OC have been shown to promote carbon preservation. However, the exact nature of preservation mechanism is not well understood and is based on limited global data, which specifically lacks estimates from large …

A Multi-Proxy Approach To Refining Paleotempestology Records On The Northern Gulf Of Mexico Coast, Marianne Elizabeth Dietz

LSU Doctoral Dissertations

Reconstructing pre-historic hurricane activity is typically accomplished through the analysis of sandy overwash deposits identified in coastal lake settings. This method has been used successfully in many parts of the world and can extend the hurricane record thousands of years into the past. However, this approach also has its limitations. This dissertation addresses some of the limitations associated with geologic proxies used to reconstruct hurricane landfalls in the absence of historic data and tests new proxies for the identification of hurricane-derived overwash deposits. Modern storm deposits from two sites on the northern Gulf of Mexico coast are analyzed in detail …

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'^{18 …}

Signal Propagation, Provenance, And Climate Records In The Indus Submarine Canyon Since The Last Deglacial, Yuting Li

LSU Doctoral Dissertations

The Monsoon is one of the most powerful climatic phenomena on Earth and controls environments in South Asia. Erosion and weathering patterns are influenced by monsoon variations and can be reconstructed through marine sediment records. However, such reconstruction is based on the assumption that such sediments are representative of the onshore basins from which they are sourced. Debate continues regarding the degree to which storage and recycling homogenize short-term variations in sediment compositions. The Indus Submarine Canyon links the river mouth and the deep-water fan of the Indus drainage system. Determining how sediment fluxes through this canyon is important if …

Paleoenvironmental Reconstruction Using Coral Microatolls (Sp. Siderastrea Siderea) From The Gulf Of Gonâve, Haiti, Gilman Reno Ouellette Jr.

LSU Doctoral Dissertations

Natural and anthropogenic climate changes present unique and serious risks to society. In order to plan and implement adaptation and mitigation strategies successfully, regional manifestations of broad-scale climate changes must be understood robustly. The Caribbean region contains part of the Western Hemisphere Warm Pool (WHWP), a major sea surface temperature (SST) feature that plays a key role in North Atlantic climate. Climate variability in the Caribbean is captured poorly by climate models, due in part to a lack of continuous, multidecadal instrumental climate records from the region. I explored three research questions in this dissertation: Does non-systematic bias exist in …

Paleoenvironmental Variation And Provenance Records From Neogene Deep Sea Sediment Of The South China Sea, Chang Liu

LSU Doctoral Dissertations

I employed several paleoenvironmental proxies by utilizing deep sea sediment from the largest marginal basin in east Asia, namely the South China Sea (SCS), to reconstruct the long term paleoenvironmental variation in SE Asia since the Neogene. Sediments deposited within the SCS were mainly delivered by several major fluvial systems whose catchment basins cover several geological blocks in SE Asia. By analyzing the sediment’s geochemical and mineralogical characteristics, several indices which are affected by the source of the sedimentary influx, as well as the weathering state could be built and applied to constrain my paleoenvironmental reconstructions

Two deep sea drilling …

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …