Geochemistry Commons^™

Orphan Basalts: Understanding The Origins Of Unassigned Eastern Oregon Basalts, Angela Rae Stetson

Dissertations and Theses

For more than a century, scientists have studied the geologic stratigraphy of eastern Oregon, which chronicles a rich history of volcanic activity spanning millions of years. Recent and ongoing geologic mapping of the northeastern Harney Basin -- along a corridor east of Highway 395 between the towns of Burns and John Day -- provides a more detailed understanding of an area originally mapped only in reconnaissance during the 1960s. At that time, geologic units were poorly delineated, often with entire quadrangles mapped as a single unit. For example, over 90% of the Calamity Butte quadrangle was previously mapped as 'Tba' …

Geochemistry And Geochronology Of The Steens And Monument Dike Swarm: Implications And Relationships To Magmatic Storage And To Lava Flows Of The Picture Gorge And Steens Basalt, Rachel Anne Sweeten

Dissertations and Theses

The Columbia River Basalt Group (CRBG) is the youngest and best-preserved example of a continental flood basalt province. Vents and dikes for the four main eruptive units (Steens, Imnaha, Grande Ronde, and Picture Gorge Basalt) are the Monument, Steens and Chief Joseph Dike Swarms located in eastern Oregon, southeastern Washington, and northern Nevada.

Here we report on the compositions and timing of the dikes and sills of the Monument Dike Swarm (MDS), as well as their relationship to the subaerial lava flows of the Picture Gorge Basalt (PGB) with implications for crustal storage of these magmas. We evaluate data from …

A Field, Petrological, And Geochronological Investigation Of The Chief Joseph Dike Swarm, Mary Joyce Mass

Dissertations and Theses

The Columbia River Basalt Group is the youngest continental flood basalt province in the world and covers an aerial extent of 210,000 km² covering Oregon, southern Washington, and eastern Idaho. Eruptions occurred between approximately 17 million and 6 million years ago, with 92% of eruptions occurring within the first million-year interval. Aside from mapping and some bulk compositional data, few studies have focused on the Chief Joseph dike swarm in NE Oregon, the main eruptive center of the Columbia River Basalt Group. Prior to this study there were no published age dates for the Chief Joseph dike swarm.

This …

Cementation And Groundwater Chemistry In Pleistocene Paleodune Deposits Of The Central Oregon Coast, Adrienne Lynn Stephens

Dissertations and Theses

Pleistocene paleodune deposits occur along the Oregon coast, underlying coastal towns, roadways, and associated power and water infrastructure(s). Secondary cementation within these deposits provides some stability, allowing for near-vertical sea cliffs and roadcut outcrops. Yet, slope instability is a prevalent hazard observed within the paleodune deposits. Weakening of cementing agents via changes to groundwater conditions due to altered vegetation, climate change, or contamination, for example, could promote slope instability, threatening lives and infrastructure. This study aims to investigate the variability in the type and degree of cementation and to determine how they are affected by changes in groundwater conditions.

To …

Analysis Of Chemical Elements In Basalts Using Mislabeled Data, A Machine Learning Approach, Jenifer Vivar

Dissertations and Theses

Scientists use basalt chemistry to discriminate among different tectonic settings. There are well-known chemical elements used to classify tectonic settings. An exploration of new features is done using Logistic Regression and Random Forest to discover any new elements of interest. The models were used with other tools, such as recursive feature elimination and permutations, to increase reliability. Among the scarcely explored chemical elements are Terbium (Tb), Holmium (Ho), Samarium (Sm), and Erbium (Er). The data used for the exploration contained many outliers. Therefore, an ensemble model was created to explore the location and composition of such outliers. The ensemble was …

Shallow Water Coral Distribution And Its Response To Climate Change, Amaury De Jesus

Dissertations and Theses

Shallow water corals are one of the main reef-building organisms that secrete carbonates as their skeletons, and therefore, are one of the major sinks of CO2 in the ocean. These reef builders are also very crucial to marine environments and human society. As the global energy demand continues rising, fossil fuel burning increases at a faster pace despite the increase in energy supply using clean and renewable energy. The increase of CO2 in the atmosphere has been shown to exacerbate global warming and may cause ocean acidification, threatening the habitat of shallow-water corals. Many recent observations show alarming signs of …

Investigation Of Basal Imnaha Basalt Flows And Their Relationship To The Picture Gorge Basalt Of The Columbia River Basalt Group, Luke James Fredenberg

Dissertations and Theses

The lower American Bar flows (AB 1 and 2) of the Imnaha Basalt have previously been observed as being chemically similar to those of the Picture Gorge Basalt (PGB). Previous age data separate eruption of the Imnaha and Picture Gorge Basalts by approximately 1.5 Ma, precluding the possibility of a genetic link between the two basalt units. New age data for the Picture Gorge Basalt has expanded the eruptive timeframe and the earliest flows coincide with the eruption of the Imnaha Basalt, making it possible that the lower American Bar flows of the Imnaha Basalt and the Picture Gorge Basalt …

Geochronological And Geochemical Investigation Into Rhyolite Volcanism Of The High Lava Plains And Columbia River Basalt Group Provinces Of Eastern Oregon, Usa, Vanessa Marie Swenton

Dissertations and Theses

Voluminous and widespread bimodal volcanism has significantly impacted the Pacific Northwest, USA, throughout the Miocene to present day. The two primary volcanic provinces of eastern Oregon include the Columbia River Basalt Group (CRBG) province and the High Lava Plains (HLP) trend. The magmatic and tectonic processes responsible for generating bimodal volcanism, and particularly rhyolites of the ~17-15 Ma CRBG and 12-0 Ma HLP provinces has recently been a popular topic of debate. Rhyolite volcanism of the HLP province has been ascribed to either buoyancy-driven westward plume spreading or to slab rollback and mantle convection spanning from southeast Oregon to Newberry …

Stratigraphic And Geochemical Evaluation Of Distal Flows Of The Columbia River Flood Basalts In The Greater Vale Area, Southeastern Oregon, Lena Marie Fox

Dissertations and Theses

Exposures of Columbia River Basalt Group (CRBG) in southeastern Oregon are dominated by the four main phase CRBG units: Steens Basalt, Imnaha Basalt, Grande Ronde Basalt (GRB), and Picture Gorge Basalt (PGB). These units are best seen in stratigraphic sequence along the Malheur Gorge corridor of southeastern Oregon, between the towns of Vale and Juntura, with flows of Steens Basalt from the south overlain by flows of Imnaha and GRB from the north. Recently, PGB flows were found to be part of the eastern Malheur Gorge stratigraphy as well.

In Malheur Gorge, local units of Birch and Hunter Creek Basalt …

New Perspectives On Prolific And Voluminous Rhyolite Volcanism Of The Mahogany Mountain--Three Fingers Rhyolite Field, Eastern Oregon, Robert Andrew Jackson

Dissertations and Theses

Voluminous silicic volcanism of the Mahogany Mountain--Three Fingers rhyolite field (MM--TFrf) is spatially and temporally associated with mid-Miocene flood basalts of the Columbia River Basalt province. Early studies of the area advocated for a two-caldera model consisting of the Mahogany Mountain and the slightly younger Three Fingers caldera with pre- and post-caldera effusive rhyolite eruptions. Although close in time, the calderas were thought to be spatially offset producing the tuff of Leslie Gulch and the tuff of Spring Creek. Finding that the tuff of Spring Creek, that is exposed in Leslie Gulch, is an altered product of the tuff of …

Reassessing Hydrothermal Heat Discharge And The Relationship Of Hot Springs In The North Oregon Cascades, Aaron Alexander Orr

Dissertations and Theses

Reservoir temperatures of hydrothermal systems in the Pacific Northwest reflect the feasibility of geothermal energy production and the tectonic framework of the region. Multicomponent geothermometry techniques were applied to new and historic water chemistry data in the north-central Oregon Western Cascades and the lower Wind River Valley in southern Washington in order to recalculate reservoir temperatures. Revised reservoir temperatures, water chemistry, and isotope data were used to determine relationships between hot springs in the north-central Oregon Cascades. Geothermal reservoir temperatures were estimated for the lower Wind River Valley (98.44 ± 0.96°C) and for Austin and Bagby Hot Springs (100.10 ± …

Distribution, Geochronology, And Petrogenesis Of The Picture Gorge Basalt With Special Focus On Petrological Relationships To The Main Columbia River Basalt Group, Emily Bogdan Cahoon

Dissertations and Theses

The Columbia River Basalt Group (CRBG) is the youngest and volumetrically smallest continental flood basalt exposed across the Pacific Northwest, USA. Similar to other large igneous provinces, the majority of material erupted during the initial 1 million years of activity, these lavas are subdivided into four main-phase units. The Picture Gorge Basalt (PGB) is the only main-phase unit of the CRBG whose age is not precisely known and understanding of PGB petrogenesis is largely based on a limited number of samples when compared with other main-phase units. It is suggested that a time gap of over 0.5 myr existed between …

Archaeological Feature Identification Through Geochemical Analysis Of Arctic Sediments From The Cape Krusenstern National Monument, Northwest Alaska, Patrick William Reed

Dissertations and Theses

Identification and interpretation of archaeological phenomena is typically based on visual cues and the physical presence of "something archaeological," such as a diagnostic artifact, landscape modification, or structural element. Yet many archaeological features, i.e. the discrete archaeological deposits related to past human behavior, lack clear indicators of human activity that provides clues to the feature's origin. At the Cape Krusenstern beach ridge complex, located in northwest Alaska, ambiguous features, that could be natural or anthropogenic (vegetation anomalies), or are of unknown cultural function (indeterminate), comprise 60% of the identified features at the complex. These ambiguous features represent a large gap …

Geochemical Response To Thermal Energy Storage In The Columbia River Basalt Aquifer System Beneath The Portland Basin, Oregon, Ellen Elizabeth Svadlenak

Dissertations and Theses

Deep direct use thermal energy storage (TES) is a low carbon emission method of geothermal energy storage and supply for large-scale residential, commercial, and manufacturing heating and cooling. The process entails repeated cycles of hot- or cold-water injection, storage, and extraction from slow groundwater flow zones within the deeper layers of an aquifer system. Though a promising technology, TES cycles may increase mineral dissolution and precipitation reactions, particularly at elevated temperatures. The ensuing mass transfer can form scale in heat exchange systems and alter aquifer porosity and permeability, processes that can reduce the operational efficiency of a TES system.

Within …

Geothermometry Of H6 And L6 Chondrites And The Relationship Between Impact Processing And Retrograde Metamorphism, Michael Tyler Ream

Dissertations and Theses

Ordinary chondrites are the most common type of meteorite to fall to Earth and are composed of lithified primitive nebular materials which have experienced variable extents of thermal metamorphism and shock processing. They were subjected to radiogenic heating by incorporation of unstable short lived radionuclides such as ²⁶Al in the early solar system.

The relationship between metamorphism and impact processing in ordinary chondrites is not fully understood. An unresolved issue in the study of ordinary chondrites is whether their original parent bodies were fragmented by impacts into rubble-pile bodies while they were still hot, or whether they retained their …

Distribution And Origin Of Carbide In Ordinary Chondrites, Karla Rae Farley

Dissertations and Theses

To understand the occurrence and distribution of carbide minerals in ordinary chondrites, thirty meteorites were examined, twenty-eight ordinary chondrites and two iron meteorites. The occurrence of carbide, textures, and chemical compositions were examined in the 7 carbide-bearing meteorites. Two formation methods for carbide have been presented in previous research. These are aqueous alteration and shock heating, and they are examined for validity in this thesis. Additionally, one other formation method for carbide formation through impact and brecciation is put forth and examined. Textural differences between the carbide-magnetite assemblages (CMAs) observed by Krot et al., (1997) and those seen in this …

Carbonatites As A Record Of The Carbon Isotope Composition Of Large Igneous Province Outgassing, Ellen Gales

Dissertations and Theses

Large igneous province (LIP) eruptions have been linked in some cases to major perturbations of Earth’s carbon cycle. However, few observations directly constrain the isotopic composition of carbon released by LIP magmas because carbon isotopes fractionate during degassing, which hampers understanding of the relative roles of mantle versus crustal carbon reservoirs. Carbonatite magmatism associated with LIPs provides a unique window into the isotopic systematics of LIP carbon because the majority of carbon in carbonatites crystalizes rather than degassing. Here, we present new δ¹³C data for the Guli carbonatites in the Siberian Traps. In addition, we compile ~260 published …

Volcanic Glass As A Paleoenvironmental Proxy: Comparing Preparation Methods On Ashes From The Lee Of The Cascade Range In Oregon, Usa, Tessa Boe Carlson

Dissertations and Theses

Deuterium ratios (δD) of hydrated volcanic glass have been used to reconstruct paleoenvironments, although the reliability and proper sample preparation protocol have been debated. In this study, hydrated volcanic ash samples from the lee of the Cascades were prepared using two separate methods. Method 1 involves sonicating and rinsing samples with hydrochloric acid (HCl) followed by hand-selection of glass shards (125-212µm). Method 2 requires hydrochloric acid (HCl) and hydrofluoric acid (HF) abrasion as well as heavy liquid separation of shards (70-150µm). Method 2 produced more consistent results with decreased intra-replicate variability in both water content (-0.92 wt. %) and deuterium …

Mineral Evidence For Generating Compositionally Zoned Rhyolites Of The Devine Canyon Tuff, High Lava Plains, Oregon, Erik Paul Shafer

Dissertations and Theses

Large-volume silicic eruptions are often evacuated from magma reservoirs which display gradients in composition, temperature, crystallinity, and volatile content. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon represents such an eruption, with >300 km³ of compositionally zoned pyroclastic material deposited as a variably-welded ignimbrite. The ignimbrite displays homogenous bulk tuff major element compositions with a wide range of trace element compositions, allowing for the investigation of how these magmas were generated, stored, and modified in the magma reservoir by studying pumices which represent the primary magmas composing the DCT. Five pumices ranging from dacite to rhyolite bulk compositions …

Geothermometry Of Two Cascade Geothermal Systems, Donnel Alexander Malkemus

Dissertations and Theses

For this thesis I applied classical and multi-component geothermometry techniques to new water chemistry data from Breitenbush Hot Springs, Oregon and the Wind River Valley, Washington. A total of 20 well, spring, and stream samples from Breitenbush Hot Springs and 4 spring samples from the Wind River Valley were collected and analyzed for major, minor, and select trace anions and cations, as well as stable oxygen and hydrogen isotopes. I used two computer programs, GeoT and RTEst, to conduct multi-component geothermometry reservoir condition estimation on each water sample. Water chemistry data from Breitenbush Hot Springs indicates a range of thermal, …

Geochemistry, Stratigraphy And Provenance Of The Portland Hills Silt In The Tualatin Mountains, Portland, Oregon, John L. Lawes Iii

Dissertations and Theses

Soil morphology and geochemistry of loess were investigated at nine sites in the Tualatin Mountains west of Portland and at additional sites in The Dalles, eastern Washington and Puget Sound. A total of forty samples were examined using Instrumental Neutron Activation Analysis (INAA).

Stratigraphic relationships and soil development suggest that the PHS ages of Lentz (1977) be revised. The age of the Portland Hills Silt (PHS) ranges from 12,000 to at least 960,000 years before present.

The geochemistry of the PHS supports the Lentz (1977) hypothesis of the PHS as a loess of continental origin. Thorium/scandium ratios in the PHS …

Geochemical Characteristics And Correlations Within The Triassic-Jurassic Age Gabbs And Sunrise Formations Of West Central Nevada, Karen Elizabeth Boelling

Dissertations and Theses

Trace and minor element geochemistry was determined using Instrumental Neutron Activation Analysis for ninety-six (96) limestone and calcareous siltstone samples from four stratigraphic sections in the Triassic-Jurassic age Gabbs and Sunrise formations of west central Nevada. Geochemical data support lithologic and faunal interpretations of relative basin positions of the Sunrise Formation stratigraphic sections, as well as basin development (including transgressive­-regressive sequences) during deposition of the Gabbs and Sunrise formations at New York Canyon (Gabbs Valley Range). All sections show characteristics of both oceanic and continental island arc sources. Rare positive Eu anomalies relative to chondrites suggest that the Gabbs Formation …

Geochemistry, Alluvial Facies Distribution, Hydrogeology, And Groundwater Quality Of The Dallas-Monmouth Area, Oregon, Rodney R. Caldwell

Dissertations and Theses

The Dallas-Monmouth area, located in the west-central Willamette Valley, Oregon, consists of Tertiary marine and volcanic bedrock units which are locally overlain by alluvium. The occurrence of groundwater with high salinities has forced many rural residents to use public water supplies. Lithologic descriptions from driller's logs, geochemical (INAA), and x-ray diffraction analyses were used to determine alluvial facies distribution, geochemical and clay mineral distinctions among the units, and possible sediment sources. Driller's log, chemical and isotopic analysis, and specific conductance information from wells and springs were used to study the hydrogeologic characteristics of the aquifers and determine the distribution, characteristics, …

Mineralogy, Geochemistry, And Dispersal Of Opaque Oxides On The Continental Shelf Of The Cascadia Margin, Kommajosyula Subramanya Ravi

Dissertations and Theses

Opaque oxide minerals (ilmenite, chromite, and magnetite) in sands from the Oregon continental shelf have been studied to establish the provenance, dispersal, and grade of potential shelf placer deposits. The study area extends southward from offshore of the Columbia River in northern Oregon to the Klamath River in northern California.

Geochemical Evolution Of Ferruginous Bauxite Deposits In Northwestern Oregon And Southwestern Washington, Joseph Michael Fassio

Dissertations and Theses

Ferruginous bauxite deposits developed from flows of the Columbia River Basalt Group in northwestern Oregon and southwestern Washington. Samples of the iron pisolite and the gibbsite nodular zones from the upper portion of the weathering profile of drill core from Columbia County, Oregon and Cowlitz County, Washington, were analyzed by instrumental neutron activation. The mineralogy was determined using Xray diffraction and Mossbauer spectroscopy.

The gibbsite nodular zone is above the clay-rich saprolite or relic basalt zone. The nodules contain relic vesicles and well preserved relic plagioclase microlites. Gibbsite occurs with poorly crystalline goethite and hematite in the gibbsite nodular zone. …

A Geochemical Study Of The Eagle Creek Formation In The Columbia River Gorge, Oregon, Rachel Ann Carlin

Dissertations and Theses

The Early Miocene Eagle Creek Formation, a series of volcanic mudflows and debris flows, is exposed in the Columbia River Gorge about 64 kilometers east of Portland, Oregon. Eighty-seven samples were analyzed using instrumental neutron activation analysis for trace element concentrations. Eleven samples were analyzed by Dr. Peter Hooper at Washington State University using X-ray Fluorescence for major element chemistry. These data were used to determine that the Eagle Creek Formation compositionally ranges from andesite to dacite.

Geochemical Stratigraphy Of The Dooley Rhyolite Breccia And Tertiary Basalts In The Dooley Mountain Quadrangle, Oregon, David Neale Whitson

Dissertations and Theses

The Dooley Rhyolite Breccia in northeast Oregon was erupted between 12 and 16 million years ago, from central vents and linear feeder dikes within the Dooley Mountain quadrangle. The peraluminous, high-silica rhyolites of the formation were erupted over an irregular highland of eroded pre-Tertiary metamorphic rocks locally overlain by intracanyon, Eocene Clarno-type basalt flow(s). The Dooley Rhyolite Braccia is exposed in a tectonically disrupted, north-south trending graben across the Elkhorn Range. The formation is variable in thickness with maximum thickness exceeding 660 meters in the south and 600 meters in the north half of the quadrangle. Volumetrically the formation is …

A Stratigraphic-Geochemical Study Of The Troutdale Formation And Sandy River Mudstone In The Portland Basin And Lower Columbia River Gorge, Rodney Duane Swanson

Dissertations and Theses

Hyaloclastic sediment forms an identifiable stratigraphic interval within the Troutdale Formation that can be traced from the Bridal Veil channel to the Portland basin. Hyaloclastic sediment composed chiefly vitric sands is found interbedded with muds, sandy muds and gravels penetrated by wells in northeast Portland are correlated with the upper member of the Troutdale Formation. These beds are characteristic of the informal upper member of the Troutdale Formation in the Bridal Veil channel of the ancestral Columbia River (Tolan and Beeson, 1984) and the type area of the Troutdale Formation exposed along the Sandy River (Trimble, 1963). Fluvially deposited hyaloclastic …

The Geology, Geochemistry, And Alteration Of Red Butte, Oregon: A Precious Metal-Bearing Paleo Hot Spring System, Carol Susan Evans

Dissertations and Theses

Red Butte is located 60 km south of Vale, Oregon, about 20 km west of the Oregon/Idaho border. The butte is within the Owyhee Upland physiographic province of eastern Oregon which lies at the intersection of the Western Snake River Plain, the High Lava Plains, and the Northern Basin and Range provinces.

The butte is composed of Miocene to Pliocene lacustrine and fluvial volcaniclastic sediments. The topography of the butte is controlled by silicification of the sandstones and mudstones which cap it. Silicification and hydrothermal alteration are both structurally and stratigraphically controlled. North-trending normal faults dominate the area, and show …

Geochemistry Of Alteration And Mineralization Of The Wind River Gold Prospect, Skamania County, Washington, Krista I. Mcgowan

Dissertations and Theses

The Wind River gold prospect is located in TSN, R7E of Skamania County, Washington, and is an epithermal gold-quartz vein system hosted in volcanic rocks of the Ohanapecosh Formation, a late Eocene to middle Oligocene unit of calcalkaline chemical composition. Andesitic pyroclastic rocks of the Ohanapecosh Formation are the host of mineralization in the study area, and form the lowest of several stratigraphic subunits. These pyroclastic rocks are overlain by two sequences of lava flows which cap the ridges and are folded by an anticlinal warp over the length of Paradise Ridge, plunging gently to the southeast. Toward the west, …