Geochemistry Commons^™

Field Test Of A Calcite Dissolution Rate Law: Fort’S Funnel Cave, Mammoth Cave National Park, J. Scott Slunder

Masters Theses & Specialist Projects

The laboratory-derived calcite dissolution rate law of Plummer et al. (1978) is the most widely used and mechanistically detailed expression currently available for predicting dissolution rates as a function of water chemistry. Such rate expressions are of great use in understanding timescales associated with limestone karst development. Little work has gone into the field testing of the rate law under natural conditions.

This work compared measured dissolution rates measured by a crystal weight loss experiment in Buffalo Creek within Fort’s Funnel Cave, which lies within a pristine, forested catchment of Mammoth Cave National Park. Continuous water chemistry sampling over the …

The Geology Of The Tuff Of Bridge Spring: Southern Nevada And Northwestern Arizona, Shirley Ann Morikawa

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Tuff of Bridge Spring (TBS) is a regionally-widespread, andesite to rhyolite (59.50 to 74.91 wt. %) ash-flow tuff of mid-Miocene age (ca. 15.2 Ma) that is exposed in the northern Colorado River extensional corridor of southern Nevada and northwestern Arizona. Determination of the areal distribution, geochronology, lithology, geochemistry, and internal stratigraphy of the TBS is important for its establishment as a reliable stratigraphic reference horizon for tectonic reconstructions of the extensional corridor during the middle Miocene. Based on reoccurring patterns of major and trace element variation, the TBS is divided into constant Cr/variable SiO₂ and variable Cr/variable SiO …

Anomalous Mesozoic Thermal Regime, Central Appalachian Piedmont: Evidence From Sphene And Zircon Fission-Track Dating, B. P. Kohn, M. E. Wagner, Tim M. Lutz, G. Organist

Earth & Space Sciences Faculty Publications

No abstract provided.

Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna

Chemistry & Biochemistry Theses & Dissertations

Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.

Epa's Map Of Radon Zones, Nebraska, Sharon W. White, Lisa Ratcliff, Kirk Maconaughey, R. Thomas Peake, Dave Rowson, Steve Page, Linda C. S. Gundersen, R. Randall Schumann, James K. Otton, Doug Owen, Russell Dubiel, Kendell Dickinson, Sandra L. Szarzi

United States Environmental Protection Agency: Publications

Sections 307 and 309 of the 1988 Indoor Radon Abatement Act (IRAA) direct EPA to identify areas of the United States that have the potential to produce elevated levels of radon. EPA, the U.S. Geological Survey (USGS), and the Association of, American State Geologists (AASG) have worked closely over the past several years to produce a series of maps and documents which address these directives. The EPA Map of Radon Zones is a compilation of that work and fulfills the requirements of sections 307 and 309 of IRAA. The Map of Radon Zones identifies, on a county-by-county basis, areas of …

Precipitation Dynamics In Kalamazoo, Sw Michigan: A Stable Isotope Perspective, Madhav V. Machavaram

Masters Theses

No abstract provided.

Groundwater Chemistry Analysis Of The Saginaw Formation In Delhi Township, Michigan, Sam L. Kitchin

Masters Theses

Groundwater chemistry and well data provided by the Ingham County (Michigan) Health Department were used to evaluate the distribution of inorganic chemical constituents in the groundwater flow system of the Saginaw Formation, in Delhi Township, Michigan. The data also were used to study the distribution of chemical constituents with respect to different rock types of the Saginaw Formation. The data were analyzed to examine if variations in the concentrations of the chemical constituents and the values of other chemical parameters relate to rock-water interactions, groundwater flow systems, or groundwater contamination.

The results indicate that patterns of increasing or decreasing concentrations …

Geochemistry, Alluvial Facies Distribution, Hydrogeology, And Groundwater Quality Of The Dallas-Monmouth Area, Oregon, Rodney R. Caldwell

Dissertations and Theses

The Dallas-Monmouth area, located in the west-central Willamette Valley, Oregon, consists of Tertiary marine and volcanic bedrock units which are locally overlain by alluvium. The occurrence of groundwater with high salinities has forced many rural residents to use public water supplies. Lithologic descriptions from driller's logs, geochemical (INAA), and x-ray diffraction analyses were used to determine alluvial facies distribution, geochemical and clay mineral distinctions among the units, and possible sediment sources. Driller's log, chemical and isotopic analysis, and specific conductance information from wells and springs were used to study the hydrogeologic characteristics of the aquifers and determine the distribution, characteristics, …

Water-Quality Assessment Of The Central Nebraska Basins: Summary Of Data For Recent Conditions Through 1990, Ronald B. Zelt, P. R. Jordan

United States Geological Survey: Publications

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning recent water-quality conditions in the study unit. The water-quality conditions of interest in addressing the objectives of the NAWQA program are those that are representative of the general water quality of a given stream reach or area of an aquifer. This report (1) identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and (2) describes, to the extent possible, recent, general water-quality conditions in the Central Nebraska Basins. The study …

Considerations Of Variations In Ionospheric Field Effects In Mapping Equatorial Lithospheric Magsat Magnetic Anomalies, Dhananjay Ravat, W. J. Hinze

Earth and Environmental Sciences Faculty Publications

Longitudinal, seasonal, and altitude‐dependent variability of magnetic fields is investigated in equatorial latitudes to determine their effect on the isolation of lithospheric Magsat magnetic anomalies. An estimate of ‘ionospheric effect’ was compiled by averaging the total intensity Magsat anomalies as a function of dip latitudes (called ‘dip‐latitude averages’) from dawn and dusk data sets grouped according to longitudes, time (months), and altitudes. Unanticipated seasonal variations were observed in dusk Magsat data over the Indian sector that may contribute to an improved understanding of the equatorial electrojet. The amplitudes of the dawn dip‐latitude averages are small in comparison to the dusk …

Organic Geochemistry Of Permian Organic-Rich Sediments From The Sudetes Area, Sw Poland, Shareen R. Yawanarajah, Michael A. Kruge, Maria Mastalerz, Wojciech Sliwinski

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Lacustrine and marine sediments from the Permian rift-basins of southwestern Poland were analysed using GC-MS and petrographic techniques. High Pr/Ph ratios, gamma- and beta-carotanes and gammacerane in the lacustrine sediments indicate deposition under elevated water salinities. The primary organic matter is represented by bacterial and algal lipids with variable terrestrial input. Marine algal lipids with minor bacterial and cyanobacterial lipids are the primary source of organic matter in the marine sediments. Extended hopanes, n-alkanes with even-odd predominance and low Ts/Tm ratios are consistent with deposition in a closed, evaporitic basin with substantial carbonate sedimentation.

Correlation Of The Tioga Bentonites Using Rhyolitic Melt Inclusions Found In Quartz Phenocrysts As Geochemical Fingerprints, John W. Waechter

Geology Theses and Dissertations

The Tioga bentonites were first noted by Fettke in 1931 from well cuttings in the Tioga gas fields of Tioga County, Pennsylvania. They have been used by many investigators (Oliver, 1954, 1956; Dennison, 1963; Dennison and Textoris, 1967, 1978; Epstein, 1986; Smith and Way, 1983; Way et al., 1986) as a time-plane to correlate stratigraphic units from eastern Pennsylvania to Illinois and from southern Ontario to Virginia. The Tioga bentonites are recognized as seven major volcanic ash layers labeled Tioga-A - Tioga-G as well as several minor layers labeled Tioga-A1 - Tioga-A3 (Way et al., 1986). They occur within the …

Trace-Element Modelling Of Melting In Spinel Peridotites, Susanne Petra Vogel

Geology Theses and Dissertations

This study addresses three independent topics related to trace element modeling of spinel peridotites that are suggested by the pioneering work of Johnson et al. (1990) on abyssal harzburgites.
First, the fractional non-modal melting equation derived by Johnson and coworkers (1990) is algebraically modified to present a "one-element/two-phase" model. This model suggests a simple test for estimating mantle heterogeneity in the source rock of spinel lherzolites. This model is applied to data from the literature for samples from Dreiser Weiher, Germany; San Luis Potosi, Mexico; and Western Victoria, Australia.
Second, trace elements in clinopyroxenes of abyssal peridotites and continental spinel …

Reconnaissance Data For Selected Herbicides, Two Atrazine Metabolites, And Nitrate In Surface Water Of The Midwestern United States, 1989-90, Elisabeth A. Scribner, E. Michael Thurman, Donald A. Goolsby, Michael T. Meyer, Margaret S. Mills, Michael L. Pomes

United States Geological Survey: Publications

Water-quality data were collected from 147 rivers and streams during 1989-90 to determine the temporal and geographic distribution of selected preemergent herbicides, two atrazine metabolites, and nitrate in 10 Midwestern States. This report includes a description of the sampling design, data-collection techniques, laboratory and analytical methods, and a compilation of constituent concentrations and quality-assurance data. All water samples were collected by depth-integrating techniques at three to five locations across the wetted perimeter of each stream. Sites were sampled three times in 1989~before application of herbicides, during the first major runoff after application of herbicides, and in the fall during a …

Seasonal Hydrology And Geochemistry Of Two Small High Arctic Catchments, Axel Heiberg Island, Northwest Territories, Julia Boike

Theses and Dissertations (Comprehensive)

This study examines hydrological and geochemical processes in a continuous permafrost setting in the Canadian High Arctic on Axel Heiberg Island (79°25 ' N; 90°45 ' W) with the following objective: to identify spatial and seasonal variation in hydrology and geochemistry of the East Inflow (EIF) and West Inflow (WIF) sub basins draining into Colour Lake and relate them to processes operating in the basins. Field work in the catchment was carried out between 20 May to 16 August 1991 and 23 July to 20 August 1992. Surface flow and suprapermafrost groundwater in the active layer were monitored to assess …