Geochemistry Commons^™

Evaluation Of Practical Methods To Determine If A Karst Creek Is Gaining Or Losing: Case Study Of Leith Creek, Elizabeth Jones

Graduate Theses/Dissertations

Karst landscapes are abundant in Missouri, with features such as caves, springs, and sinkholes that form through the dissolution of limestone. Leith Creek is a small stream in Polk County, Missouri fed by two springs and the shallow unconfined Springfield Plateau aquifer, a highly karstified aquifer which is made up of limestone and minor interbedded shale-mudstone units. To determine if Leith Creek is gaining or losing, stream flow, water chemistry and temperature sensors were monitored. Stream flow results required multiple visits to take measurements while temperature sensors required two visits, one to install the dataloggers and another to remove the …

Utilizing Isotope Tracing To Assess Land Use Implications To Tap And Stream Water Chemistry, Katrina Alexis Mcfadden

Theses and Dissertations--Biosystems and Agricultural Engineering

Water quality is an issue that continues to be worsened by extreme flooding, specifically in Eastern Kentucky. The most recent 2022 flooding event in Eastern Kentucky resulted in loss of human life, over $23.3 billion in damaged infrastructure, and impaired human health. Infrastructure failures, such as leaky pipes, are a growing challenge in these regions as rebuilding has occurred. Therefore, the goal of this project was to evaluate water quality in two of the counties most impacted by the 2022 flood in Kentucky, Breathitt and Perry Counties, using sulfur isotopes as a novel tracer to identify potentially failures in distribution …

Water Quality Of A Karstic Shallow Aquifer In Greene And Lawrence Counties, Missouri, Claudia Patricia Colmenero Chacon

Graduate Theses/Dissertations

A water quality investigation in the Springfield Plateau aquifer of Greene and Lawrence counties, Missouri, was conducted. Water samples from eleven springs were collected at regular intervals during 2023 to determine major water quality parameters: total dissolved solids (TDS), alkalinity, calcium (Ca), magnesium (Mg), sodium (Na), sulfate (SO₄), chloride (Cl) and nitrate-nitrogen (NO₃-N), along with per- and poly-fluorinated alkali substances (PFAS) from spring sediments. Nitrate-nitrogen was analyzed because of the importance for environmental health (e.g. to avoid eutrophication). Springs samples were separated by land use into urban and rural samples. In addition, Springfield Plateau water quality …

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Trends In Water Quality Of Cave Pools At Timpanogos Cave National Monument, July 2008–September 2018, Rebecca Weissinger, Andy Armstrong, Kirsten Bahr, Chris Groves

Crawford Hydrology Laboratory

No abstract provided.

Relating Recharge Mechanisms To Chemical Changes In An Updip Appalachian Coal Mine Discharge: A Case Study From Lambert Run, West Virginia, Matthew Lewis Bell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Impaired drainage from active and abandoned mines degrades the water quality of receiving streams and aquifers. Coal mine drainage (CMD) has been studied for decades in Appalachia, but unknowns and uncertainties are still present, including the influence of mine hydrogeology on the outflow chemistry of above-drainage mines. To evaluate the influence of recharge type on above-drainage mine chemistry, samples were collected every two weeks at a CMD outflow treatment system in Harrison County, West Virginia.

Samples were collected to measure geochemical changes taking place in the mine workings and along the flowpath of the passive treatment system. Samples were divided …

Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber

Theses and Dissertations (Comprehensive)

The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …

Exploring, Exploiting And Evolving Diversity Of Aquatic Ecosystem Models: A Community Perspective, Annette B.G. Janssen, George B. Arhonditsis, Arthur Beusen, Karsten Bolding, Louise Bruce, Jorn Bruggeman, Raoul-Marie Couture, Andrea S. Downing, J. Alex Elliott, Marieke A. Frassl, Gideon Gal, Daan J. Gerla, Matthew R. Hipsey, Fenjuan Hu, Stephen C. Ives, Jan H. Janse, Erik Jeppesen, Klaus D. Jöhnk, David Kneis, Xiangzhen Kong, Jan J. Kuiper, Moritz K. Lehmann, Carsten Lemmen, Deniz Özkundakci, Thomas Petzoldt, Karsten Rinke, Barbara J. Robson, René Sachse, Sebastiaan A. Schep, Martin Schmid, Huub Scholten, Sven Teurlincx, Dennis Trolle, Tineke A. Troost, Anne A. Van Dam, Luuk P.A. Van Gerven, Mariska Weijerman, Scott A. Wells, Wolf M. Mooij

Civil and Environmental Engineering Faculty Publications and Presentations

Here, we present a community perspective on how to explore, exploit and evolve the diversity in aquatic ecosystem models. These models play an important role in understanding the functioning of aquatic ecosystems, filling in observation gaps and developing effective strategies for water quality management. In this spirit, numerous models have been developed since the 1970s. We set off to explore model diversity by making an inventory among 42 aquatic ecosystem modellers, by categorizing the resulting set of models and by analysing them for diversity. We then focus on how to exploit model diversity by comparing and combining different aspects of …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Concentration Of Heavy Metals In The Waters And Surface Sediments Of Wilgreen Lake, Madison County, Kentucky: An Evaluation Of Plausible Sources, Chad Von Gruenigen, Walter S. Borowski

EKU Faculty and Staff Scholarship

Heavy metal pollution remains a problem in natural waters, particularly for localities near plausible anthropogenic sources. We assayed the level of heavy metals in surface waters and within surface sediments of Wilgreen Lake, whose watershed drains industrial, urban, agricultural, and residential areas near Richmond, Kentucky. We sampled both surface (oxic) and deep waters (anoxic) when the lake was stratified over Summer 2010. Water samples were treated according to U.S. Environmental Protection Agency (EPA) protocols and were digested with trace-metal-grade nitric and hydrochloric acids. Sediment samples were collected with a grab sampler and digested using established EPA procedures with trace-metal-grade nitric …

Patterns Of Heavy Metal Concentration In Core Sediments, Wilgreen Lake, Madison County, Clint Mcmaine, Walter S. Borowski

EKU Faculty and Staff Scholarship

Accumulation of heavy metals in ecosystems is a known environmental problem, and several possible industry sources occur within the watershed of Wilgreen Lake, which is fed its two major tributaries, Taylor Fork and Old Town Branch. Elevated levels of cadmium, copper, lead, and nickel were found within the waters of Wilgreen Lake during a preliminary survey in 2007. A possible source of these contaminant occurrences is diffusion from lake sediments, which record past and present activities within their drainage basins.

To obtain a history of anthropogenic practices within the drainage basin, we took 1-meter-long cores of lake sediment in each …

Heavy Metal Concentrations In Water And Surface Sediments Of Wilgreen Lake, Madison County, Kentucky, Chad Von Gruenigen, Walter S. Borowski

EKU Faculty and Staff Scholarship

Heavy metal pollution remains problematic in natural waters, particularly for localities near plausible anthropogenic sources. We assayed the level of heavy metals in surface waters and within surface sediments of Wilgreen Lake, whose watershed drains industrial, urban, agricultural, and residential areas near Richmond, Kentucky. Water samples were treated according to Environmental Protection Agency (EPA) protocols and digested with trace-metal-grade nitric and hydrochloric acids. Sediment samples were collected with a grab sampler and digested using established EPA procedures with hydrogen peroxide and trace-metal-grade nitric acid. Both water samples and sediment samples were sent to Activation Laboratories for analysis, and were measured …

Heavy Metal Concentrations In Water And Surface Sediments Of Wilgreen Lake, Madison County, Kentucky, Chad Von Gruenigen, Walter S. Borowski

EKU Faculty and Staff Scholarship

Heavy metal pollution remains a problem in natural waters, particularly for localities near plausible anthropogenic sources. We assayed the level of heavy metals in surface waters and within surface sediments of Wilgreen Lake, whose watershed drains industrial, urban, and residential areas near Richmond, Kentucky.

Water samples were treated according to Environmental Protection Agency (EPA) protocols and digested with trace-metal-grade nitric and hydrochloric acids. Sediment samples were collected with a grab sampler and digested using established EPA procedures with hydrogen peroxide and trace-metal-grade nitric acid. Both water samples and sediment samples were sent to Activation Laboratories for analysis, and were measured …

Patterns Of Heavy Metal Concentration In Core Sediments, Wilgreen Lake, Madison County, Kentucky, Clint Mcmaine, Walter S. Borowski

EKU Faculty and Staff Scholarship

Elevated levels of cadmium, copper, lead, and nickel were found within the waters of Wilgreen Lake during a preliminary survey in 2007. Accumulation of heavy metals in freshwater systems is a known problem. Heavy metals enter the lake in the dissolved phase or adsorbed onto sediment particles and may be linked to industries within the lake’s watershed. Under certain geochemical conditions such as anoxia, heavy metals may detach from sediment particles and diffuse into overlying lake waters, causing a renewed influx of heavy metals into the ecosystem. We hypothesize that heavy metals should decrease in concentration upcore as a result …

Support For The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This final report details the activities completed for Task 8 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). Task 8, titled "Support for the Nye County Early Warning Drilling Program" provided for a variety of hydrochemical analyses. The requirements of the University and Community College System of Nevada (UCCSN) Quality Assurance (QA) Program were followed for all work performed on this task. The primary activity performed by the Harry Reid Center for Environmental Studies (HRC) for Task 8 was to provide hydrochemical analyses of the groundwater samples collected from …

Preliminary Geochemical Evaluation Of Groundwaters From Wells Of The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

As part of the Yucca Mountain Oversight program, the Nye County Nuclear Waste Repository Project Office (NWRPO) has established a groundwater monitoring program to protect groundwater resources for the residents of Nye County in Amargosa and Pahrump Valleys. This groundwater monitoring program, referred to as the Nye County Early Warning Drilling Program (NCEWDP), involves drilling a series of wells down-gradient from Yucca Mountain for long term groundwater monitoring and also to provide much needed geologic and hydrologic information in this area. A comprehensive database of aquifer parameters in the alluvial, volcanic, and carbonate aquifers down-gradient hydrogeologically of Yucca Mountain is …

Application Of Environmental Organic Petrology And Geochemistry To Fingerprint Organic Pollutants In The Recent Sediments Of Lake Ontario, Prasanta K. Mukhopadhyay, Michael A. Kruge, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Selected surface sediment samples (sediment depth 0-10 cm) collected in the Niagara basin (western Lake Ontario) were chosen for organic matter characterization using organic petrological and geochemical techniques normally reserved for the study of coal, petroleum source rock and crude oil. The study was performed to assess the effectiveness of these techniques in discriminating between natural and anthropogenic organic matter and to determine the extent of organic pollution of the lake sediments. The organic carbon contents of the samples vary from 1.5 to 3.5%, with upper layer (0-5 cm) samples have higher TOC values than those from the lower layer …