Geochemistry Commons^™

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Wonderstone And Its Connection To Liesegang, Microbes, And Beyond, Haden S. Mandery

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

In the western and southwestern United States, the term wonderstone is used to describe volcanic, volcaniclastic, and sedimentary rocks with variegated banding produced by iron oxide mineralization or staining. This iron oxide mineralization is typically described as Liesegang banding. In this paper I will (1) test if the banding in wonderstone follows the spacing and width laws characteristic of Liesegang, (2) identify the source of iron that ultimately precipitated in the bands, and (3) examine the role that microbes played in the formation of the mineralization in these rocks. I conclude that the iron oxide mineralization is not Liesegang banding. …

Preliminary Assessment For Critical Minerals In The Terlingua Quicksilver District, Texas And Tres Marias Mine, Chihuahua, Mexico, Eduardo Lee Zuniga

Open Access Theses & Dissertations

The Terlingua Quicksilver district was discovered around the 1880s and was a mercury producing district from 1900 through 1946. The most productive years were during World War one and two. From 1900-1946 the Terlingua Quicksilver District (TQD) produced 150,000 flasks; 80% came from three mines: the Rainbow-Chisos, Mariposa, and Study Butte mines. The structural controls of the Mercury mineralization within these mines are breccia pipes and fractures, often located near igneous intrusions. This study will assess the potential for Critical Minerals and Rare Earth Elements in the Terlingua Quicksilver District. Fifty-five samples have been collected and analyzed for forty-four different …

Enhancing Our Understanding Of Ancient Oceans Through The Investigation Of Molybdenum Behavior Under Sulfidic Conditions, Rachel Faye Phillips

Open Access Theses & Dissertations

The most abundant trace metal in the ocean today, molybdenum (Mo), exhibits distinct behavior in oxygenated water, where it remains predominantly dissolved, compared to euxinic (i.e., oxygen-free and sulfidic) water, in which it is sequestered into the sediment. This dissimilar behavior allows us to use Mo concentrations and isotopic compositions in sediment to reconstruct marine oxygenation conditions throughout geologic history. However, Mo sequestration mechanisms under euxinic conditions remain unresolved, which limits the accuracy and precision of reconstructions made using Mo signatures in the rock record. For my doctoral research, I experimentally investigated abiotic and biotic Mo sequestration mechanisms under various …

Geochemistry Of Metal-Rich Black Shales And Their Genetic Relationship To Mississippi Valley-Type Pb-Zn Ore Deposits, Midcontinent U.S., Noah S. Morris

Graduate Theses and Dissertations

The formation of Mississippi Valley-type (MVT) lead-zinc (Pb-Zn) ores is complex, involving an interaction of tectonic compression, hydrothermal fluid migration, and geochemical processes within the subsurface. Fundamental questions regarding this interaction remain unclear, including the source(s) of the Pb and Zn ions that make up the ores. A genetic link between black shales and MVT ores has been thought to exist because of (1) the presence of mature hydrocarbon and brine fluid inclusions within many MVT ores, (2) the association of the hydrothermal fluids that are linked to MVT ore formation with organic compounds and oil-like droplets, and (3) the …

Geospatial Analysis Of Weathering And Recession On Architectural Limestone At The 1891 Powerhouse/Icehouse In Eureka Springs, Arkansas, Stuart Bruce Wright

Graduate Theses and Dissertations

The objective of this study of the architectural limestone of the 1891 Powerhouse/Icehouse in Eureka Springs, Arkansas was to analyze the environmental factors that influenced the deterioration and surface recession of this historical stone structure. The focus of this research was to examine and establish a baseline study that may assist in future monitoring and documentation of this historic limestone structure on stone weathering. A replicable methodology was specifically created toward this baseline research in hopes that it represented a solid baseline study. Observations and data analyses revealed the relationship between the architectural limestone building structure and the dominating recession …

New Observations On The Age And Origin Of The Geologist Seamounts, South Hawaiian Seamount Province, Brandon Chester Scott

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigation into seamounts that stem from intraplate volcanism—that is volcanism occurring far from plate boundaries—presents an opportunity to deconvolve processes associated with mantle compositional heterogeneities and melting dynamics. Upwelling and decompression of thermochemically anomalous mantle plumes is the primary mechanism for significant intraplate volcanism; however, many seamounts dotted across the Pacific Plate do not correlate spatially, temporally, or geochemically with mantle plume volcanism. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism are the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present merged multibeam (<100 m) and satellite altimetry bathymetric maps of the Geologist Seamounts region, new ^{40 …}

Quantifying Co2 And Heat Fluxes At Roosevelt Hot Springs, Hydrothermal Area, Samantha R. Wolf

Earth and Planetary Sciences ETDs

Roosevelt Hot Springs is an actively producing hydrothermal system that has been extensively studied by field, geophysical and geochemical techniques since the 1970’s. Roosevelt Hot Springs sits at the western base of the Mineral Mountains in Utah, an area that has formed because of many volcanic, thermal and structural events since the late Oligocene. The work in this manuscript is the first of its kind to incorporate measurements of spring-based CO₂ fluxes with diffuse measurements to quantify the total CO₂ Flux in tons per day of a Basin and Range and Colorado Plateau Transition Zone-hosted hydrothermal system. Using …

Investigating Mobility In The Northern Balkans During The Fifth Millenium Bc Through Strontium Analysis Of Human Tooth Enamel, Aurélien Tafani

USF Tampa Graduate Theses and Dissertations

This research investigates how individual mobility among ancient populations in Romania during the Eneolithic, between 5000 and 4000 BC, may be related to the spread of the material culture known as Kodjadermen-Gumelniţa-Karonovo VI (KGK VI) that extended over most of southern Romania and Bulgaria. This work seeks to combine results on individual mobility with other lines of archaeological evidence to provide a better understanding of the social context and kinship relationships that were in place when these events took place.

Strontium isotopic analyses were performed on 130 individuals from two sites located in the southern Romania: 49 from Sultana and …

Volcanic Diffuse Volatile Emissions Tracked By Plant Responses Detectable From Space, Robert R. Bogue, Peter M. J. Douglas, Joshua B. Fisher, John Stix

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Volcanic volatile emissions provide information about volcanic unrest but are difficult to detect with satellites. Volcanic degassing affects plants by elevating local CO2 and H2O concentrations, which may increase photosynthesis. Satellites can detect plant health, or a reaction to photosynthesis, through a Normalized Difference Vegetation Index (NDVI). This can act as a potential proxy for detecting changes in volcanic volatile emissions from space. We tested this method by analyzing 185 Landsat 5 and 8 images of the Tern Lake thermal area (TLTA) in northeast Yellowstone caldera from 1984 to 2022. We compared the NDVI values of the thermal area with …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Core-Cm Williston Basin Carbon Ore, Rare Earth, And Critical Minerals, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet on the Carbon Ore, Rare Earth and Critical Minerals (CORE-CM) Initiative, an Energy & Environmental Research Center and U.S. Department of Energy project. Includes information on the importance of critical minerals and utilizing lignite from the Williston Basin.

More Than Energy: Coal As A Mineral Resource, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Brochure on Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Initiative, an Energy & Environmental Research Center and U.S. Department of Energy project. Explores the benefits of utilizing lignite coal from the Williston Basin.

A Field, Petrological, And Geochronological Investigation Of The Chief Joseph Dike Swarm, Mary Joyce Mass

Dissertations and Theses

The Columbia River Basalt Group is the youngest continental flood basalt province in the world and covers an aerial extent of 210,000 km² covering Oregon, southern Washington, and eastern Idaho. Eruptions occurred between approximately 17 million and 6 million years ago, with 92% of eruptions occurring within the first million-year interval. Aside from mapping and some bulk compositional data, few studies have focused on the Chief Joseph dike swarm in NE Oregon, the main eruptive center of the Columbia River Basalt Group. Prior to this study there were no published age dates for the Chief Joseph dike swarm.

This …

North Bergen Outcrop Field And Geochemical Data, Jane L. Alexander, Sean T. Thatcher, Jay Tobon, Victoria Rivelli

Publications and Research

This file contains the data collected on an outcrop of the Stockton Formation in North Bergen, NJ. It contains field observations, mineralogy and geochemical data for major, trace and rare earth elements.

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …

Carbon Isotope Chemostratigraphy, Geochemistry, And Biostratigraphy Of The Paleocene–Eocene Thermal Maximum, Deepwater Wilcox Group, Gulf Of Mexico (Usa), Glenn R. Sharman, Eugene Szymanski, Rebecca A. Hackworth, Alicia C.M. Kahn, Lawrence A. Febo, Jordan Oefinger, Gunnar M. Gregory

Geosciences Faculty Publications and Presentations

The Paleocene–Eocene Thermal Maximum (PETM) represents the most pronounced hyperthermal of the Cenozoic era and is hypothesized to have resulted in an intensification of the paleohydrologic cycle, including enhanced seasonality and increased sediment discharge to the coastal ocean. Although the PETM has been widely documented, there are few records from deposits that form the distal, deepwater components of large sediment-routing systems. This study presents new constraints on the stratigraphic placement of the PETM in the deepwater Gulf of Mexico basin through analysis of geochemical, carbon isotopic, and biostratigraphic data within a ∼124 m cored interval of the Wilcox Group. Biostratigraphic …

Trace Metal Analysis Of Pond Sediments To Measure Deposition From A Coal-Fired Power Plant In Ackerman Mississippi, Charles Bills

Theses and Dissertations

Trace element sediment pollution due to coal power plants have been reported in many countries. In this study, pond sediment samples collected from locations around a coal fired power plant in Ackerman, MS, were evaluated for their trace element concentration and pollution status. The samples were collected at two depths to study changes in element accumulation over time. The samples were digested and the elements, As, Cd, Cr, Cu, Pb, Hg, and Zn were analyzed using ICP-MS. Results were then compared to known background concentrations as well as sediment quality guidelines and pollution thresholds. The sample locations downwind of the …

Phase Distribution Of Nickel, Chromium, And Cobalt In Seawater At Olivine-Enriched Beaches: Implications For Carbon Capture By Enhanced Silicate Weathering, Nathaniel J. Padrnos

Master's Theses

The application of olivine to coastal areas is a proposed method of removing carbon dioxide from the atmosphere for climate change mitigation. Olivine is abundant and dissolves relatively fast, but it contains trace amounts of nickel (Ni), chromium (Cr), and cobalt (Co) which may be toxic to marine biota in cases of widespread coastal olivine spreading. Prior studies have suggested that Ni concentrations in marine sediments and/or the overlying water column due to olivine dissolution could be a limiting factor for its carbon capture potential. Therefore, it is critical to understand and model the processes affecting trace metal bioavailability after …

A Hybrid Lateral Flow Sand Filter Wastewater Treatment System: An Evaluation On The Treatment And Disposal Capabilities Of A Modified Sand Filter, Harry Mccaskill Iv

Graduate Theses and Dissertations (2019 - present)

Decentralized wastewater treatment exists primarily in suburban and rural areas where centralized treatment is not an option. Traditional on-site treatment systems usually include the use of a septic tank and a drain field. This orthodox method works well when implemented into environments that are accommodating for the infiltration of effluents, and thus allowing for soil treatment. Unfortunately, there are some circumstances that prevent traditional systems from working such as impermeable soil conditions. The Wastewater Treatment System analyzed in this thesis was created to overcome such inhospitable environments. More specifically, this system is catered towards the rural residences of The Alabama …

Climatic Influences On Incipient Alteration In Mars-Relevant Ultramafic Soils, Anthony Feldman

UNLV Theses, Dissertations, Professional Papers, and Capstones

An ongoing debate exists around the nature of the climatic conditions present during the Noachian and early Hesperian periods (~4.1 to 3 Gyr ago) of Mars’ ancient history. The various theories put forward can reasonably be grouped into “warm and wet” vs “cold and icy” camps. Warm and wet approximates an Earth-like system with a relatively clement climate with significant liquid water present including potentially long-lived oceans. Cold and icy theories generally postulate thick ice sheets at high elevations with periodic warming events driving precipitation and the formation of river channels and leading to the formation of chemical alteration products. …

Magmatic Processes Leading To Compositional Diversity In The Mars Crust, Amanda Marie Ostwald

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ancient Mars crust can yield insights into planet formation and evolution that Earth cannot. Direct investigation of the martian surface is limited to studies on meteorites and rover-obtained analyses. The nakhlites and chassignites, two classes of martian meteorites, are together the largest suite of martian meteorites derived from a single location on the surface. As such, they present a rare opportunity to study the Mars crust in detail using samples bearing a contextual relationship. Rover studies have found a surprising amount of compositional diversity in surface materials, the formation mechanisms of which are not well-constrained. This dissertation leverages meteorites …

Polygonal Faults In The Austin Chalk: Invariance Of Scale From Mud Cracks To Polygons With Implications Of Structural, Geomorphic And Isotopic Data On Polygonal Fault Geometry And Origin., Kun Shang

Earth Sciences Theses and Dissertations

The Cretaceous Austin Chalk contains large numbers of fractures and normal faults whose orientations have been attributed to either regional stresses (e.g., the Balcones fault trend) or, by analogy with the mudrocks, to polygonal faulting resulting from compaction. In this study, we present geomorphic data, field study, and stable isotope data to support that the majority of these faults in North Texas are polygonal. Field-measured fault orientations suggest randomly distributed fault strikes, indicating a polygonal fault structure. Using geomorphologic data (topographic and DEM data) on stream orientations suggests that the polygonal fault patterns are best reflected in the headwater (1st …

Environmental Chemical Analysis Method Optimization And Application To Northwest Cuban Marine Sediment, Thea R. Bartlett

USF Tampa Graduate Theses and Dissertations

A method for gas chromatography tandem mass spectrometry (GC-MS/MS) in selected reaction monitoring (SRM) mode has been optimized to quantify 250 compounds of a variety of compound classes such as polycyclic aromatic hydrocarbons (PAHs), oxidized PAHs, organochlorinated pesticides, polychlorinated biphenyls, biomarkers (hopanes, steranes, tri-aromatic steroids, and fecal sterols), aliphatic hydrocarbons, and plastic additives. This method was validated based on available QA/QC standards using several environmental samples, both sediment and biota, and standard reference materials. This contaminant-focused method can be used as a forensic geochemistry tool to evaluate oil contamination and other contaminant histories in future research studies. When applied to …

Untangling The Nature And Timescales Of Magmatic Processes Driving Eruptions At Quiescent Volcanoes: Examples From Momotombo, Nicaragua, And Cumbre Vieja, Canary Islands, Samantha Tramontano

Dissertations, Theses, and Capstone Projects

Across all scales of human relationships (i.e. person-to-person, country-to-country, etc.), qualms can take the form of long-standing wars, quick and intense bouts, or petty exchanges. While our understanding of human behavior is ever increasing, reactions and behaviors of self and others may still come as a surprise. Expressions of disagreement can occur suddenly or following years to centuries of accumulated grievances. The solid earth is also a system that behaves (like human emotion) predictably at times and unpredictably at other times. Some volcanoes, a tangible surface expression of solid earth processes, exhibit precursory signals prior to eruption (e.g. the bulging …

A Typological And Chemical Analysis Of Roman Oil Lamps From Poggio Del Molino, Brandon Tejo

Dissertations, Theses, and Capstone Projects

Terracotta lamps, known to the Romans as lucernae, are small, handheld, often decorated objects which provided ancient people light. To modern researchers, they serve as tools for dating stratigraphy and iconographic studies. Beyond their immediately apparent aesthetic and symbolic value, the chemical compositions of the clay of these lamps reflect their origin. This study complements archaeological typologies with chemometric analyses to describe 16 Late Republican and Imperial Roman lamps recovered from the villa at Poggio del Molino (PdM), Tuscany. These finds were recovered from the 2021 and 2022 PdM excavations. The combined approach of typology with X-ray Diffraction (XRD) …

Interannual Variation Of Ichthyofaunal Utilization Of A Man-Made Salt Marsh Creek In Mission Bay, California, Maria Angst

Undergraduate Honors Theses

Marsh restoration and creation are increasingly being used to mitigate Southern California’s drastic decline in wetlands due to human activities. This study used minnow traps to resample the ichthyofauna of a created marsh (Crown Point Mitigation Site; CPMS) and an adjacent natural marsh (Kendall Frost) in Mission Bay, California, 26 years following the marsh creation. Data from this study were compared to data collected immediately after marsh creation from 1995-1998, and from 2021. Fishes captured included Fundulus parvipinnis, Gillichthys mirabilis, Acanthagobius flavimanus, Ctenogobius sagittula, and Mugil cephalus. Species richness and dominance measures were higher in the natural relative to the …