Geochemistry Commons^™

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO₂ inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …

A Precambrian History Of Cratonic North American Crust Beneath The Snake River Plain, Idaho, Emerald Kirke Shirley

Boise State University Theses and Dissertations

Granulite xenoliths erupted in Neogene basalts, and a rare outcrop of Precambrian basement along the northern margin of the Snake River Plain (SRP), can be used as windows into the origin and stabilization of the lower crust of southern Idaho. Previous work to determine the nature of the lower crust beneath the Snake River Plain was conducted on a suite of xenoliths exposed in Southern Idaho at Square Mountain (SM), Craters of the Moon National Monument and Preserve (CRMO), and the Spencer-Kilgore (SK) area (Leeman, 1979; Leeman et al., 1985; Matty, 1984; Wolf et al., 2005), as well as on …

Hydrochemical Investigation Of A Transient Parafluvial Zone Under Drought Conditions, Platte River, Nebraska, Audrey R. Boerner

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Shallow groundwater (0.5 m -1.2 m deep) beneath a vegetated and non-vegetated fluvial island was observed in the lower Platte River, Nebraska, USA during exceptional summer drought. Over the course of three months, sub-hourly measurements of hydraulic head, and weekly measurements of redox indicators, δ²H, δ¹⁸O, and dissolved gases were analyzed together with nitrogen and carbon species from an array of shallow piezometers in the river bed and islands. These data were compared with the same parameters collected from a 15 m-deep riparian borehole. Vertical hydraulic gradients in the island piezometers indicated the vertical component to …

Hydrogeology And Chemical Characterization Of Hydrocarbon In Domestic Water Wells, Rancho Villa Subdivision, Rogers, Arkansas, Janelle Renee Sherman

Graduate Theses and Dissertations

This project is centered on the Rancho Villa community in Rogers, Arkansas where several residents have had hydrocarbon contamination in their domestic water wells. The goal of this project was to understand the hydrogeology in the study area, characterize the contaminant chemically, and determine the source of the contaminant. The hydrogeology of the area was determined from previous theses. Seventeen samples were taken from the wells in the Rancho Villa community; each sample was analyzed for geochemical parameters and by Gas Chromatography/Mass Spectrometry (GC/MS) for organic compounds analysis. Four of the 17 samples had a visible non-aqueous layer of hydrocarbon …

A Detailed Seabed Signature From Hurricane Sandy Revealed In Bedforms And Scour, Arthur Trembanis, Carter Duval, Jonathan Beaudoin, Val E. Schmidt, Doug Miller, Larry A. Mayer

Center for Coastal and Ocean Mapping

On 30 October 2012, Hurricane Sandy made landfall near Brigantine New Jersey bringing widespread erosion and damage to the coastline. We have obtained a unique set of high-resolution before and after storm measurements of seabed morphology and in situhydrodynamic conditions (waves and currents) capturing the impact of the storm at an inner continental shelf field site known as the “Redbird reef”. Understanding the signature of this storm event is important for identifying the impacts of such events and for understanding the role that such events have in the transport of sediment and marine debris on the inner continental shelf. …

Geogram 2013, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Molecular Characteristics Of The Water Soluable Organic Matter In Size Resolved Aerosols Collected Over The North Atlantic Ocean, Sarah Catherine Gurganus

Chemistry & Biochemistry Theses & Dissertations

Aerosol particulate matter is acknowledged to have effects on health and the environment and further investigation into the molecular characteristics of aerosols is necessary in order to fully understand the potential links between the molecular characteristics and the impacts that these particles have on health and the environment. Aerosols are often discussed with reference to their size because particles of different sizes can often be associated with different primary sources. This study presents a molecular-level chemical characterization of the water soluble organic matter fraction of 17 aerosol impactor samples representing 3 air mass influences (North American, North African, and marine) …

The Mechanism And Timescales Of Soil Formation In The Hyper-Arid Atacama Desert, Chile, Fan Wang

Open Access Dissertations

The planetary surfaces that evolve in the near absence of water are strikingly different from surfaces where water is abundant, but their formation is poorly documented. This research is an in-depth exemplary work in the Atacama Desert in northern Chile to understand the soil formation in hyper-arid environments, as an analog for planetary surfaces such as the Mars. In detail, the basic mechanism regarding the source material, timescale, paleo-climatic settings and the role of crypto-biotic crusts have been investigated to constrain the Atacama soil development.

The geochemical, isotopic and mineralogical composition of atmospheric dust deposited along a West-East transect in …

Unusual Polygenetic Void And Cave Development In Dolomitized Miocene Chalks On Barbados, West Indies, Jonathan B. Sumrall, John E. Mylroie, Hans G. Machel

International Journal of Speleology

Barbados provides an unusual case of polygenetic cave development within dolomitized chalks and marls of the Miocene Oceanics Group. These diagenetic processes are driven by a succession and interplay of tectonic uplift, fracturing, hypogene fluid injection, overprinting by mixing zone diagenesis, and mechanical and biological erosion in the current littoral zone. The significance of the voids and caves within the chalks on Barbados are: 1) these appear to be the first dissolution caves documented in dolomitized chalk, and 2) these features show a polygenetic origin documenting the diagenetic changes in lithology that allowed the development and preservation of these cave …

Origin And Provenance Of Spherules And Magnetic Grains At The Younger Dryas Boundary, Yingzhe Wu, Mukul Sharma, Malcom A. Lecompte, Mark N. Demitroff, Joshua D. Landis

Dartmouth Scholarship

One or more bolide impacts are hypothesized to have triggered the Younger Dryas cooling at ∼12.9 ka. In support of this hypothesis, varying peak abundances of magnetic grains with iridium and magnetic microspherules have been reported at the Younger Dryas boundary (YDB). We show that bulk sediment and/or magnetic grains/microspherules collected from the YDB sites in Arizona, Michigan, New Mexico, New Jersey, and Ohio have (187)Os/(188)Os ratios ≥1.0, similar to average upper continental crust (= 1.3), indicating a terrestrial origin of osmium (Os) in these samples. In contrast, bulk sediments from YDB sites in Belgium and Pennsylvania exhibit (187)Os/(188)Os ratios <<1.0 and at face value suggest mixing with extraterrestrial Os with (187)Os/(188)Os of ∼0.13. However, the Os concentration in bulk sample and magnetic grains from Belgium is 2.8 pg/g and 15 pg/g, respectively, much lower than that in average upper continental crust (=31 pg/g), indicating no meteoritic contribution. The YDB site in Pennsylvania is remarkable in yielding 2- to 5-mm diameter spherules containing minerals such as suessite (Fe-Ni silicide) that form at temperatures in excess of 2000 °C. Gross texture, mineralogy, and age of the spherules appear consistent with their formation as ejecta from an impact 12.9 ka ago. The (187)Os/(188)Os ratios of the spherules and their leachates are often low, but Os in these objects is likely terrestrially derived. The rare earth element patterns and Sr and Nd isotopes of the spherules indicate that their source lies in 1.5-Ga Quebecia terrain in the Grenville Province of northeastern North America.

Assessing The Reliability Of Stable Isotopes In Fossil Bone: A Unique Case Study Of Prehistoric Lung Pathology., Kathleen Bundy, Samuel D. Matson

Student Research Initiative

Mammals at Ashfall Fossil Beds State Historical Park (NE Nebraska) offer a unique opportunity to test for the preservation of primary isotopic signatures in fossilized materials. At this site, large herbivores such as rhinoceroses, horses and camels are buried in volcanic ash sourced from an eruption of the Bruneau-Jarbridge caldera (Idaho/Nevada) ca. 11.8 million years ago. Most fossils from Ashfall display pathologic bone symptomatic of a lung disease (hypertrophic osteopathy or HPOA) likely related to inhalation of volcanic ash. In this study, we compare the stable oxygen isotopic composition (δ¹⁸O) of pathologic bone with that of normal cortical …

Spectroscopic Study Of Uranium (Vi) Reduction By Plant Biomass, Margaret C. Murphy, John Bargar, Noémie Janot

STAR Program Research Presentations

Uranium is a common and problematic groundwater contaminant at Department of Energy legacy sites. At the former uranium ore processing plant at Rifle, Colorado, sediments rich in decayed plant biomass contain large concentrations of uranium that are slowly being released back to the aquifer. To simulate the reaction that occurs in organic rich sediments of the Rifle aquifer, biomass was incubated in U (VI) bearing groundwater. Carbon X-ray absorption spectroscopy (XAS) was then used to measure if uranium was bound to the biomass. When uranium binds to biomass the peaks in the C XAS spectra will change shape. Uranium L …

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …

Tectonosedimentologic Significance Of The Upper Cretaceous Foreland Basin Siliciclastics: Western Interior, Usa, Nazrul I. Khandaker

Publications and Research

The Upper Cretaceous Frontier Formation exposed along the western margin of the western interior foreland basin is composed of clastic sediments that were deposited during the initial late Cretaceous transgressive-regressive phases of the Western Interior Seaway across Wyoming (Figure 1). Current study is aimed at providing attendees with the best practices associated with tectonic, lithofacies and sedimentologic interpretation of foreland basin sequences and emphasizing the need for utilizing field, structural, geochemical, and compositional data for reconstructing a viable scenario connected with foreland basin sedimentary packages. An attempt will be made to compare documented sedimentological findings with foreland basins located in …

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …

Cyclic Distributional Model Of The Late Moscovian Fusulinids In The Donets Basin (Ukraine) In Response To Eustatic Sea Level Fluctuations And Its Application In Biostratigraphy And Correlation, Rimma Khodjanyazova

Boise State University Theses and Dissertations

The continuous Pennsylvanian shallow-marine, paralic, siliciclastic succession in the Donets Basin is pivotal for correlation of marine and continental strata in northern Pangaea with coeval shallow-marine mainly carbonate strata in the Moscow Basin, a historical type area of Moscovian Horizons. The details of the history of establishment, lithostratigraphy and current biostratigraphy of Podolskian and Myachkovian Horizons in the Moscow Basin that are not readily available in Western literature are reviewed.

A model of cyclic recurrence (~0.6 —1myr) of three main fusulinid assemblages in the Pennsylvanian siliciclastic-carbonate succession in the Donets Basin is proposed. A Hemifusulina-association (A) indicates the onset …

Activated Carbon Preconditioning To Reduce Contaminant Leaching In Cement-Based Stabilization Of Soils, Renee Elizabeth Crane

Masters Theses

Powdered activated carbon (PAC) is often added with cement to enhance the stabilization and solidification (S/S) of materials contaminated with organic compounds. Adsorption of organic contaminants onto PAC can reduce leaching of organic contaminants. Simultaneous addition of PAC and cement reduces soil handling costs, but cement hydration reactions coat PAC with Ca(OH)2 before contaminants can be adsorbed onto PAC. Laboratory studies were done on four aged, contaminated soils from manufactured gas plant sites to compare the performance of S/S treatment with simultaneous addition of PAC and cement vs. cement addition after preconditioning with PAC to enhance contaminant adsorption. Performance was …

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …

Water Track Modification Of Soil Ecosystems In The Lake Hoare Basin, Taylor Valley, Antarctica, Joseph S. Levy, Andrew G. Fountain, Michael N. Gooseff, John E. Barrett, Robert Vantreese, Kathleen A. Welch, W. Berry Lyons, Uffe N. Nielsen, Diana H. Wall

Geology Faculty Publications and Presentations

Water tracks are zones of high soil moisture that route shallow groundwater down-slope, through the active layer and above the ice table. A water track in Taylor Valley, McMurdo Dry Valleys, was analysed for surface hydrogeological, geochemical, and biological characteristics in order to test the hypothesis that water tracks provide spatial structure to Antarctic soil ecosystems by changing the physical conditions in the soil environment within the water tracks from those outside the water tracks. The presence of the water track significantly affected the distribution of biotic and abiotic ecosystem parameters: increasing soil moisture, soil salinity, and soil organic matter …

Oil-Source Rock Correlation In The Late Paleozoic, Denver Basin, Nebraska: The Search For A Negative Δ¹³C Anomaly In Pennsylvanian–Permian Cyclothems, John P. Still

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Late Paleozoic sedimentation in the Denver basin occurred in two environmentally distinct depocenters. The northern-most Alliance Basin has been interpreted to have a restricted character: anhydrite-bearing mudstones are present in cyclothems comprising wackestone, packstone and mudstone. The source of petroleum produced from these intervals is considered to be organic-rich units within these cyclothems. Oil recovered from late Paleozoic reservoirs has δ13C values that range from -30.8‰ to -28.8‰: values that are lower than those reported previously for prospective source rocks from this interval. Cores from seven wells that penetrate upper Pennsylvanian to lower Permian rocks have been chosen for analysis. …

Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour

Graduate Theses and Dissertations

The main objectives of this thesis are to estimate Mg isotopic compositions of the Moon and achondrites, to understand the behavior of Mg isotopes during magmatic differentiation processes in different planetary bodies, and to evaluate the extent of Mg isotopic heterogeneity in the solar system. In order to achieve these goals, Mg isotopes have been measured for 47 well-characterized lunar samples and 22 differentiated meteorites by MC-ICPMS. The limited Mg isotopic variations among mare and highland regolith, mare breccias, and highland impact-melt rocks reflect negligible Mg isotope fractionation during lunar surface processes (e.g. solar wind, cosmic rays, micrometeorite bombardments, meteorite …

Dissolution Rates Of Amorphous Al- And Fe-Phosphates And Their Relevance To Phosphate Mobility On Mars, Valerie Tu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Phosphate is an essential element for life on Earth, and therefore if life exists or ever existed on Mars it may have required phosphate. Amorphous Al- and Fe-phosphates rapidly precipitate from acidic solutions and amorphous Al-phosphates likely control phosphate concentrations in some natural waters on Earth. Amorphous phases may be even more important on Mars than on Earth, and amorphous phosphates are therefore likely important in the phosphate cycle on Mars. Despite this importance, however, few dissolution rates exist for amorphous Al- and Fe- phosphates. In this study, dissolution rates of amorphous Al- and Fe-phosphates were measured in flow-through reactors …

Paleoecology Of Nebraska’S Ungulates During The Eocene–Oligocene Climate Transition, Grant S. Boardman

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The White River Group (WRG) preserves the Eocene-Oligocene climate transition (EOCT), an interval of global cooling and drying during the onset of Antarctic glaciation. In the Great Plains, a shift from forested conditions to drier woodland-savanna biomes is hypothesized to have occurred at this time. I test this hypothesis through the analyses of several paleoenvironmental proxies on the teeth of 12 WRG ungulate species: stable carbon and oxygen isotopes from tooth enamel, and mesowear and microwear texture. The EOCT shift toward more open habitats and lower vegetation density under drying climates should have resulted in an increase in mean carbon …

Adsorption Of Hexavalent Chromium On Hydrous Manganese Oxide, Andrew K. Macleod

Masters Theses

Hexavalent chromium is a very common contaminant most often associated with industrial processes, it is quite mobile in the subsurface and a better understanding of its mobility and interactions with soil constituents will help ongoing remediation efforts.

Hydrous manganese oxides (HMO) are a very common soil constituent and thus would be likely to interact with Cr(VI) in contaminated shallow subsurface environments. The goal of this study is to develop a working model that can improve predictions of Cr(VI) mobility in natural systems. A diffuse double layer surface complexation model (DLM) was developed by deriving reaction stoichiometries and stability constants for …

Epistemology And Synthesis: Instrumental Neutron Activation Analysis And The Caddo Tradition, Robert Z. Selden Jr.

CRHR: Archaeology

The statistical groupings illustrated herein represent the current iteration of Caddo INAA compositional groups based upon the chemical composition of archaeologically-recovered ceramics. For some time, a number of Caddo archaeologists have thought these results to be lacking. This poster symbolizes the first step toward a new interpretation of chemical composition groups, and the initial instancce within which GIS has been employed as an analytical tool.

Consilience: Radiocarbon, Instrumental Neutron Activation Analysis, And Litigation In The Ancestral Caddo Region, Robert Z. Selden Jr.

CRHR: Archaeology

Through the creation and analysis of databases for radiocarbon, instrumental neutron activation analysis (INAA), and law, macro-level trends are exposed that form the framework of a broader research program aimed at advancing ideas of craft specialization and archaeological theory in the ancestral Caddo region of Southwest Arkansas, Northwest Louisiana, Northeast Texas, and Southeast Oklahoma. The findings of this investigation illustrate the research potential that remains buried within the context of cultural resource management (CRM) reports and legal databases (Westlaw and LexisNexis) that is awaiting consumption within regional research designs aimed at exploring the nuances and trends that appear through synthetic …

Stable Isotope Record Of Archean And Cambrian Serpentinizing Fluid Composition From Stichtite (Mg-Cr Carbonate Hydroxide), Amanda Lopez

Theses Digitization Project

This study will focus on stichtite from two locations that contain the most abundant deposits of stichtite. The first location in Tasmania, Australia includes the Stichtite Hill locality (the type locality for stichtite) and the Tunnel Hill locality. The second location is at the New Amianthus Mine, Barberton District, South Africa. The broad geographical distribution of stichtite in deposits ranging from the Archean tho the early Cambrian, provides a window into the history and chemistry of serpentinizing environments on Earth through time.

Assessment Of Coal Geology, Resources, And Reserve Base In The Powder River Basin, Wyoming And Montana, James A. Luppens, David C. Scott, Lee M. Osmonson, Jon E. Haacke, Paul E. Pierce

United States Geological Survey: Publications

Using a geology-based assessment methodology, the U.S. Geological Survey estimated in-place resources of 1.07 trillion short tons of coal in the Powder River Basin, Wyoming and Montana. Of that total, with a maximum stripping ratio of 10:1, recoverable coal was 162 billion tons. The estimate of economically recoverable resources was 25 billion tons.

Five Year Carbon Storage Analysis In The Gordon Natural Area, Joy Fritschle, Chad Hudson, Catherine Spahr, Andy Tamez

Forest Carbon Storage Study Documents

The Gordon Natural Area (GNA) serves as a natural laboratory for a range of class research projects. In a Geography Field Methods course led by Dr. Fritschle, students established five permanent carbon-study plots in 2008. Since then, students have returned to these plots to measure the carbon stock of standing trees in five plots located along a topographic gradient: floodplain, ridge-top, lower mid-slope, mid-slope and upper mid-slope. Using U.S. Forest Service established guidelines, all trees greater than 5 cm and up to 73 cm in diameter at breast height (DBH) were measured and identified within each 40 m circular plot. …

Oil Pollution In Water Bodies Of Restricted Circulation, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Coastal lagoons and embayments near urban centers around the world share many common characteristics and problems. Physical impediments to free water circulation (spits, barrier islands, internal islands, tombolos, submerged sills) often lead to water stagnation and, in the presence of excess nutrients, eutrophication. Urban and industrial activities provoke (usually accidental) spills of hazardous materials into these confined water bodies, such as crude petroleum and refined petroleum products, leading to difficulties for resident biota and potential hazards for human health. The sluggish turnover of these water bodies (or low-energy zones within them) may retard the natural attenuation of the spilled contaminants. …