Geochemistry Commons^™

Understanding The Drivers Of Marine Sediment Diagenesis In Carbonate-Bearing Sediments, Alex Reis

Theses and Dissertations--Earth and Environmental Sciences

Marine sediments serve as an important geochemical record used to study how the Earth’s climate and oceans have changed throughout geologic time. As such, it is critical to understand how these sediments can be altered following deposition on the seafloor. This dissertation targeted two key geochemical archives, carbonate and pyrite, to link changing burial conditions with the resulting marine sediment chemistry. In particular, primary carbonate minerals record several indicators of past ocean chemistry, while pyrite preserves information related to the redox state of the sediment during deposition and burial. Additionally, secondary processes associated with changes in pore fluid chemistry and …

Use Of Stable Isotope Geochemistry To Determine The Paleoenvironment Of The Pond Creek Coal Bed, Pike County, Eastern Kentucky, Vivian A. Edwards

Theses and Dissertations--Earth and Environmental Sciences

Wetlands are both critical habitats and bellwethers of the health of the environment. Coal, being the remains of wetlands, offers the possibility of understanding the evolution of wetlands over large climatic shifts. The paleoenvironment of coals can be determined from palynology, petrology, and geochemistry. Stable isotope ratios within coal, including carbon (δ¹³C), nitrogen (δ¹⁵N), and sulfur (δ³⁴S), are established tools for paleoenvironmental reconstructions. These ratios can be correlated to flora, geochemistry, macerals, and bacterial activity. However, carbon, nitrogen, and sulfur have given conflicting results in some studies and their correlation to known variables is …

Deep Crustal Boundaries As Fluid Conduits: A Geochemical Investigation Of Mvt Mineralization In Kentucky And Beyond, Dairian Boddy M. Boddy

Theses and Dissertations--Earth and Environmental Sciences

Critical minerals are vital to the United States economy and national security, yet their supply chains are at risk. Common minerals in Mississippi Valley-type (MVT) deposits, such as sphalerite, galena, fluorite, and barite, host critical metals such as barium, gallium, germanium, and zinc, which are essential for energy technologies. An investigation of three MVT mineral districts in Kentucky elucidated previously unrecognized systematics, genetic relationships, and sources of ore components using stable and radiogenic isotope geochemistry, particularly from galena, sphalerite, barite, and gangue minerals (e.g., carbonates). The localization and dominant type of mineralization in each district are potentially influenced by deep …

Sedimentary Archives Of Late Quaternary Limnological, Ecological, And Environmental Change In The Eastern Sierra Nevada (California, Usa), Bailee Hodelka

Theses and Dissertations--Earth and Environmental Sciences

The Sierra Nevada essentially serve as the headwaters of California, providing crucial freshwater to the state through seasonal snowmelt. This water supply is threatened by climate change in complex ways that are not fully understood. Geological records provide a valuable source of information on how the hydrology, limnology, and ecology of the Sierra Nevada region has responded to climate changes of the past. This dissertation presents new sedimentary and paleoecological research from Mono Lake and Convict Lake (Mono County, California) and aims to shed light on environmental changes in the eastern Sierra Nevada from ~16 ka to present.

At Mono …

Geochemical And Sedimentological Signals Of Bottom Water Oxygen Dynamics From Lake Tanganyika (Zambia), Njahi Mwangala

Theses and Dissertations--Earth and Environmental Sciences

Lake Tanganyika is a large, ancient freshwater body with exceptional biodiversity that is located in the East African Rift System. Lake Tanganyika’s size and longevity make its sedimentary record useful for understanding environmental changes that cross spatial and temporal boundaries. Lake Tanganyika is known to be susceptible to global warming given its tropical location. Over 12 million people living within Lake Tanganyika’s watershed rely on fishing for their income and nutrition. Changes to limnological function driven by climate could therefore have serious implications for human health and biodiversity conservation. This study focuses on using geochemical properties of modern lake bottom …

Late Holocene Paleolimnology Of Lake Tanganyika (East Africa), Leandro Domingos Luz

Theses and Dissertations--Earth and Environmental Sciences

Understanding the long-term responses of ecosystems to climate variability is crucial for predicting and mitigating future changes in the Afrotropics, a region where a significant portion of the population is highly vulnerable to extreme climatic events. Lake Tanganyika, the largest rift lake in East Africa, offers a unique sedimentary archive that can be used to investigate the limnological changes, hydroclimatic shifts, and vegetation dynamics across various timescales. A multi-proxy approach was employed to assess the landscape responses to hydroclimatic fluctuations in the Late Holocene, integrating paleoenvironmental records from radiocarbon-dated sediment cores. This approach involved sedimentology, mineralogy, geochemistry, phytolith analysis, and …

Geochronologic Constraints On The Meso-Neoproterozoic Tectonic Evolution Of Eastern Laurentia: An Investigation Of Sediment Recycling During And After The Grenvillian Orogeny, John M. Clay Iii

Theses and Dissertations--Earth and Environmental Sciences

The Grenvillian orogeny and Midcontinent Rift shaped the Mesoproterozoic basement of eastern Laurentia. Their convergence beneath Kentucky and Ohio formed a foreland basin, preserved as the Middle Run Formation. Detrital zircon U-Pb geochronology constrains deposition to ~1.0 Ga, reflects Grenville unroofing phases, includes Midcontinent Rift input, and minor Ottawan components. This formation constitutes the most proximal preserved segment of the Grenvillian clastic wedge in Laurentia.

Neoproterozoic-Cambrian rifting followed by Cambrian transgression formed the Great Unconformity in eastern Laurentia. Detrital zircon and basement U-Pb ages from Kentucky and the Appalachians constrain sediment provenance and recycling. Kentucky basement shows Eastern Granite-Rhyolite crust …

Microstructural, Mineralogical, And Chemical Characterization Of The Handys Bend And Flax Creek Meteorites, Kentucky: Relevance For The Iron Meteorite Record, Ethan S.L. Davis

Theses and Dissertations--Earth and Environmental Sciences

Iron meteorites remain the only material view into planetary cores. Despite their scientific relevance, iron meteorites are relatively rare. In June 2021 and March 2022, the Kentucky Geological Survey received requests to identify two metallic specimens discovered in central Kentucky. The specimens were given the provisional names Handys Bend (3175.2 g) and Flax Creek (286.2 g). The goal of this project is to confirm meteoritic origin, characterize their structures and chemistry, assign genetic classifications, and examine potential relations to previous discoveries. Petrography was conducted using scanning electron microscopy. Mineral phases were examined using X-Ray diffraction crystallography. Chemical compositions were determined …

Thermal Alteration Of The Mineralogy Of Calcium Sulfoaluminate Cements: Implications For The Performance Of Rapid Repair Materials, Jillian Cavellier

Theses and Dissertations--Earth and Environmental Sciences

Calcium sulfoaluminate (CSA) was developed in part to lessen the environmental impact of cementitious materials compared to traditional Portland cements. CSA was first put into production in the 1970s and has been undergoing various performance testing to investigate its durability. Yet to be evaluated is CSA’s response to a rapid, high temperature event. In this study, X-ray diffraction, thermogravimetric analysis, Fourier transform infrared spectrometry and scanning electron microscope imaging were used to analyze alterations in the mineralogy due to such an event. As found in previous studies, after ~125°C, ettringite has been completely dehydrated. Ettringite decomposes into bassanite and calcium …

High Resolution Sedimentary Investigations Of Extant Lakes In North America, John Dilworth

Theses and Dissertations--Earth and Environmental Sciences

Investigation of past lake environments forms the discipline of paleolimnology. Paleolimnological studies seek to evaluate geophysical, geochemical, and ecological proxies and indicators contained within lake sediment archives. Using these potential stores of high-resolution environmental information, questions regarding climate, biological, and geochemical changes experienced by a lake and its watershed can be investigated. This dissertation research utilized lake sediment records from two lakes within North America to study different aspects of environmental change. This dissertation consists of three separate studies presented in three chapters.

Chapter Two presents a retrospective environmental assessment of Jackson Lake, Wyoming to investigate the impacts of dam …

Utilizing Isotope Tracing To Assess Land Use Implications To Tap And Stream Water Chemistry, Katrina Alexis Mcfadden

Theses and Dissertations--Biosystems and Agricultural Engineering

Water quality is an issue that continues to be worsened by extreme flooding, specifically in Eastern Kentucky. The most recent 2022 flooding event in Eastern Kentucky resulted in loss of human life, over $23.3 billion in damaged infrastructure, and impaired human health. Infrastructure failures, such as leaky pipes, are a growing challenge in these regions as rebuilding has occurred. Therefore, the goal of this project was to evaluate water quality in two of the counties most impacted by the 2022 flood in Kentucky, Breathitt and Perry Counties, using sulfur isotopes as a novel tracer to identify potentially failures in distribution …

A Source-To-Sink Analysis Of The Pantanal Basin (Brazil): Implications For Weathering, Erosion, And Landscape Evolution In The World's Largest Wetland, Edward L. Lo

Theses and Dissertations--Earth and Environmental Sciences

Large back-bulge retro-arc basins have limited information about the sediment composition, yet they comprise important parts of the stratigraphic rock record. The exorheic Pantanal Basin is the world's largest continental wetland that regulates many valuable ecosystem services (water storage, nutrient cycling, agriculture, ranching, tourism, and transportation). This dissertation is composed of three studies that utilize a suite of tools to examine the most fundamental basin-wide source-to-sink sediment processes and controls that affect the characteristics and distribution of modern sediments.

The first paper consists of a metadata analysis of 76 shallow tropical floodplain lakes in the literature with bathymetric data and …

Distribution Of Particulate Organic Carbon – Fluxes And Inventories – In Growth-Faulted Coastal Wetlands, Samuel Joel Whitehead

Theses and Dissertations--Earth and Environmental Sciences

Coastal wetlands along the Northern Gulf of Mexico (NGOMx) are critically important but threatened environments which provide significant and diverse economic, social, and environmental value. These environments are essential components to the global carbon cycle, serving as one of the most efficient terrestrial carbon sinks. Since onset of the Industrial Revolution increasing rates of coastal wetland loss have been documented due to a variety of anthropogenic activities, neotectonic processes, subsidence, and rising sea-levels. This research utilized an array of methods and sedimentological analyses to test the hypothesis that growth-fault induced changes at Earth’s surface affects the delivery to, and storage …

Timing Of Regional Metamorphism In The Inner Piedmont And Blue Ridge Of North Carolina: Evidence From Monazite U-Pb Geochronology, Nicholas Edwin Powell

Theses and Dissertations--Earth and Environmental Sciences

Channel and escape flow, or lower crustal ductile flow and redirection from orogen-normal to orogen-parallel flow, are among the most impactful concepts introduced to explain shortening accommodation in large, hot orogens. In the Inner Piedmont (IP), southern Appalachians, channel and escape flow were proposed to have occurred during the Neo-Acadian (376–340 Ma) orogeny. However, the polymetamorphic history of the southern Appalachians makes it difficult to isolate thermal and deformational events for process-focused studies necessary to test these ideas in the IP. To address this, we used in situ laser ablation split stream (LASS) monazite U-Pb geochronology alongside new garnet chemical …

Lunar Magnetic Field Models From Lunar Prospector And Selene/Kaguya Along‐Track Magnetic Field Gradients, Dhananjay Ravat, M. E. Purucker, N. Olsen

Earth and Environmental Sciences Faculty Publications

We use L1‐norm model regularization of |Br | component at the surface on magnetic monopoles bases and along‐track magnetic field differences alone (without vector observations) to derive high quality global magnetic field models at the surface of the Moon. The practical advantages to this strategy are the following: monopoles are more stable at closer spacing in comparison to dipoles, improving spatial resolution; L1‐norm model regularization leads to sparse models which may be appropriate for the Moon which has regions of localized magnetic field features; and along‐track differences reduce the need for ad‐hoc external field noise reduction strategies. We examine also …

Crustal Composition And Moho Variations Of The Central And Eastern United States: Improving Resolution And Geologic Interpretation Of Earthscope Usarray Seismic Images Using Gravity, H. L. Zhang, Dhananjay Ravat, A. R. Lowry

Earth and Environmental Sciences Faculty Publications

EarthScope's USArray Transportable Array has shortcomings for the purpose of interpreting geologic features of wavelengths less than the Transportable Array station spacing, but these can be overcome by using higher spatial resolution gravity data. In this study, we exploit USArray receiver functions to reduce nonuniqueness in the interpretation of gravity anomalies. We model gravity anomalies from previously derived density variations of sedimentary basins, crustal V p /V s variation, Moho variation, and upper mantle density variation derived from body wave imaging informed by surface wave tomography to estimate V p/V s. Although average densities and density contrasts for these seismic …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

“The Tale Of 3,000 Zircons”: An Investigation Of Grenville Sedimentation In Amazonia Using U/Pb Detrital Zircon Geochronology, Felicia R. Harris

Theses and Dissertations--Earth and Environmental Sciences

The continental collision between Laurentia and Amazonia that generated Rodinia and the Grenville Orogen is proposed to be one of the largest, hottest and longest-lived orogens in Earth history. Subsequent erosion and weathering led to a mountain range’s worth of sediment recycled into clastic systems across North America, otherwise known as the “Great Grenville Sedimentation Event”. The Sunsas orogeny in Amazonia is correlative to the Grenville in North America and is proposed to be the result of final Rodinian collision at 1200-1000 Ma. Despite the connection between the two ranges and the robust sedimentary record in North America, little work …

A Multi-Method Investigation Of The Modern Sedimentation And Late Holocene Paleolimnology Of June Lake (Mono County, Ca), And A Survey-Based Analysis Of Ninth Graders’ Attitudes Towards Geology, Eva Lyon

Theses and Dissertations--Earth and Environmental Sciences

Three distinct manuscripts comprise this dissertation. The first analyzes the modern sedimentary basin of June Lake, a small glacial lake in the eastern Sierra Nevada of California (USA) using a number of data sets, including bathymetry, surface sediment composition, and seismic stratigraphy. The seismic survey revealed sublacustrine morphological features that suggest the basin originated due to ice scour, as well as four acoustically distinct stratigraphic units that reflect the history of sedimentation following glacial scouring. Corroborating the seismic record, sediment cores from the youngest unit are composed of hemipelagically deposited, organic-rich, laminated diatomaceous oozes alternating with coarse tephra beds. The …

Identification Of The Causes And Extent Of Elevated Methane Concentrations In The Groundwater Of Eastern Kentucky, Cristopher Alvarez Villa

Theses and Dissertations--Earth and Environmental Sciences

Recent development of unconventional oil and gas (UOG) resources has prompted concerns about its potential impact on public health and the quality of water and air resources. Elevated dissolved methane concentrations (> 1 mg/L) have been associated with proximity to UOG development and stray gas, but also with natural microbial activity. Baseline gas data, local hydrogeology and geochemistry context can aid assessment of methane sources and interactions. Methane concentrations in eastern Kentucky groundwater are above the “immediate action” level in some private/domestic water wells, show wide variations over small distances, and have been hypothesized to have different relationships to mining. …

Characterization Of Rare Earth Elements In The Illinois Basin Coals, Alireza Valian

Theses and Dissertations--Mining Engineering

The purpose of this study is to characterize the distribution and occurrence of rare earth elements (REEs) in the coal and coal-related material from the Illinois Basin. For characterizing the distribution of REEs, 17 core samples were investigated from various parts in the basin. Also, several individual samples from coal preparation plants and isolated geological occurrences were included in the study. In result, the average REE concentrations were calculated on a bed-to-bed basis, although the distribution of REEs in the coal beds was found laterally and vertically heterogeneous. A number of trends were found that describe the variations. Most importantly, …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

A Joint Xrf-Δ13CCarb Chemostratigraphic Approach For Characterizing Paleo-Environmental Processes In The Mudstone-Dominated Wolfcamp Formation Of West Texas, Frank Tamakloe

Theses and Dissertations--Earth and Environmental Sciences

The Late Paleozoic Ice Age represents a dynamic period in Earth system history recording a shift from icehouse to greenhouse conditions. Concomitant with this change was a series high-frequency, high-amplitude sea level fluctuations leading to the deposition of “Kansas type” cyclothems in the Mid-Continent, and a similar rhythmic expression of interbedded shales and carbonates in the Midland Basin. Stable isotope geochemistry is a particularly powerful tool when examining these mud-rich successions because changes in organic matter partitioning may be recorded first in δ¹³C_DIC of sea-water and consequently in δ¹³C_carb of marine rocks. The δ …

Temporal And Spatial Variability In Groundwater Flow And Chemistry Along The Cumberland River, Artemus, Kentucky, Amanda Rachelle Sherman

Theses and Dissertations--Earth and Environmental Sciences

Groundwater in the Kentucky Appalachian region is constrained by physiography and lithology. Lithostratigraphy, groundwater flow, and chemistry were delineated in the alluvial aquifer along the Cumberland River at H.L. Disney Training Center. To assess groundwater-river interactions and water quality, 11 monitoring wells were installed and sampled quarterly, plus the river and an existing bedrock well. Analytical results were evaluated for temporal and spatial trends. Collected soil cores were analyzed for bulk chemistry and grain size. Solute speciation and saturation indices were calculated and hydraulic conductivity estimated from grain-size analyses. Pumping and slug tests were performed to estimate hydraulic conductivity and …

The Forestry Reclamation Approach: Measuring Sediment Mass Accumulation Rates In Reclaimed Mine Lands And Naturally Regenerated Logged Forests Of Eastern Kentucky, William E. Bond

Theses and Dissertations--Earth and Environmental Sciences

The spread of surface coal mining has resulted in loss of forests in the Appalachian region. The Forestry Reclamation Approach (FRA) was developed to provide guidance for restoring forests on reclaimed mined land. This study hypothesizes that the FRA will result in larger magnitude of sediment accumulation rates in reclaimed mine sites compared to those reclaimed using grassland reclamation. Three sediment cores and six trenches were sampled within four reclaimed mined and three previously logged sites in eastern Kentucky. Samples were processed for radionuclides, grain-size, stable isotopes (δ¹³C), and POC. LIDAR data were used to identify valley …

Stratigraphy And Organic Geochemistry Reveal Patterns Of Late Quaternary Paleo-Productivity At Mono Lake, California, Bailee Nicole Hodelka

Theses and Dissertations--Earth and Environmental Sciences

Mono Lake (CA) is a hydrologically closed lacustrine basin well-known for its paleo-shorelines, which record fluctuations in water level for the last deglacial and late Holocene. Mono Lake is a sentinel of California’s water supply, situated in the rain shadow of the Sierra Nevada, a mountain range whose snowpack is a vital source of freshwater for urban and agricultural districts to the west and south. Recent droughts, floods, and wildfires show that California is threatened by climate change, but how these changes impact and get recorded by Mono Lake sediments remains poorly known. Here, we use a new radiocarbon-dated deepwater …

A Multi-Indicator Approach To Understanding The Diagenesis Of Carbonates In Pennsylvanian Mudrocks Of The Midland Basin, Alex J. Reis

Theses and Dissertations--Earth and Environmental Sciences

The Late Pennsylvanian was a time of frequent, rapid glacioeustatic sea-level changes. These changes were recorded in the Wolfcamp D Formation of the Midland Basin as a series of cyclothems similar to those studied in the Midcontinent region (e.g., Algeo and Heckel, 2008). This study focuses on identifying the mechanisms and controls on carbonate deposition and diagenesis through the Upper Pennsylvanian Wolfcamp D Formation and evaluating the potential for these layers to be stratigraphically significant. A stepwise progression of diagenetic processes was identified through the use of δ¹³C_carb and δ¹⁸O_carb, bulk geochemical and …

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence …

Zircon As A Proxy For "Taking The Temperature" Of Granites: An Example Using Zircon Thermometry Applied To Grenvillian Mid-Crustal Magmas In The Blue Ridge Province, Virginia, Samantha Rae Burk

Theses and Dissertations--Earth and Environmental Sciences

The Grenville orogeny was a protracted (~200 m.y.) series of “hot” magmatic- metamorphic events that contributed to the growth of the Laurentian margin in the late Mesoproterozoic. The granites contain remarkably high Zr content, lack xenocrysts, and become zircon saturated at high temperatures, which are all unusual for felsic magmas. The “hot Grenville granite” hypothesis is tested and use of high-Zr granitoids as potential zones of crustal magma generation through: U-Pb geochronology and cathodoluminescence imaging to assess inherited zircon components; quantitative modeling of zircon crystallization history using rhyolite-MELTS; and Ti-in-zircon thermometry. U-Pb zircon ages for two samples from the Virginia …

Stratigraphic, Geochemical, And Geochronological Analysis Of The Wolfcamp-D Interval, Midland Basin, Texas, Zachary S. Perlman

Theses and Dissertations--Earth and Environmental Sciences

Subsurface data derived from ~388 ft of drill core from Martin County (TX) were used to understand the depositional setting of the Wolfcamp-D, a petroleum producing interval in the Midland Basin. Elemental geochemistry collected via x-ray fluorescence revealed a highly variable depositional history marked by the deposition of diverse siliciclastic and carbonate lithofacies. Integration of multiple datasets resulted in the interpretation of nine lithofacies, whose deposition appears cyclical. Correlations between molybdenum and total organic carbon indicate slow recharge of bottom waters and anoxic/euxinicconditions within the basin. The presence of phosphatic nodules coinciding with siliceous black mudrocks suggested high levels of …