Geochemistry Commons^™

Dream Pilot Project: Analysis Of Groundwater Development At Six Villages In Ethiopia, Lindsay K. Gordon

All Graduate Reports and Creative Projects, Fall 2023 to Present

This study presents a hydrogeologic assessment of the Distributed Renewable Energy Agriculture Modalities (DREAM) pilot project, an ongoing groundwater development initiative in rural Ethiopia. This project integrates solar-powered groundwater infrastructure across six villages to improve water access, agricultural productivity, and economic stability.

Fourteen production wells were installed at Murche, four at Dalle, and additional test wells at Murche, Dalle, Chefe Kora, and Huluku. Transmissivity values and the number of wells at Murche suggest that local water needs are currently being met. In contrast, fewer wells were drilled at Dalle. This reflects the high cost of well construction relative to yield, …

Origins And Mechanisms Of Mobility Of Geogenic Arsenic Contamination In Toutle And Silver Lake, Wa, Usa, William A. Hays

All Master's Theses

Arsenic (As), a common contaminant in groundwater, is toxic to human health and has a maximum contaminant level of 10 ppb set by both the World Health Organization and the U.S. Environmental Protection Agency (ATSDR, 2007). In Toutle, WA, USA (30 km west of Mount Saint Helens), a private well, labelled TOU1, was previously identified with ~670 ppb of As and was the impetus of this study. This study targeted private wells in the vicinity of TOU1 to identify the extent of the arsenic contamination, identify the aquifer(s) of concern, and identify the mechanism(s) of mobility.

The wells were screened …

Investigating Controls On Temporal And Spatial Variation Of Dissolved Uranium At Springs In Horn Creek Drainage, Grand Canyon National Park, Arizona, Usa, Collin Davidson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is a critical resource in the Grand Canyon, providing water to local communities, millions of annual visitors, and ecosystems. One major concern for this critical resource is the potential for uranium contamination in conjunction with uranium mining efforts. Upper Horn Bedrock Spring (UHB) in the Horn Creek drainage of the Grand Canyon sits below the oldest uranium mine in the region, Orphan Lode mine. UHB spring contains the highest concentration of dissolved uranium in the region, eclipsing the Maximum Contaminant Level (MCL) set by the USEPA by an order of magnitude on average. This research and recent collaboration with …

Supporting Dataset For The Influence Of Tile-Water On Groundwater Nitrate Concentrations Within A Saturated Riparian Buffer Zone, Aminat Tosin Abdulsalam, Eric Wade Peterson

Faculty Publications - Geography, Geology, and the Environment

In the U.S. Midwest, where fertile soils with high water retention are prevalent, the installation of tile drainage networks have become a common practice to drain excess soil water, which enhances plant growth and increases crop productivity. However, tile drainage networks coupled with the use of inorganic fertilizers have significant implications on water quality, contributing to eutrophication, leading to harmful algal blooms, and resulting in hypoxic conditions in surface water bodies. To mitigate excess nutrient exports to surface water bodies, edge-of-field practices have been introduced. One such practice is the saturated riparian buffer (SRB), which utilizes a diversion system to …

Geoelectrical And Hydrochemical Characterization Of Submarine Groundwater Discharge In Florida Bay, Ifeanyi Emmanuel Eze

College of Graduate Studies: Theses & Dissertations

Florida Bay, situated at the southern tip of Everglades National Park and underlain by the Miami Limestone formation, is an ecosystem of global significance. Over the past century, the bay has faced threats such as droughts, seagrass mortality, and hypersalinity. Despite various studies and management efforts, the dynamics of submarine groundwater discharge (SGD) in the region remain underexplored. Given that SGD plays a significant role in the chemical dynamics of coastal ecosystems, it warrants thorough investigation. This study aims to characterize the spatial and temporal patterns of SGD in Florida Bay by surveying three basins – Rankin, Whipray, and Rabbit …

Study Of Trace Elements In Southern Nevada Spring Waters And Lakes, Hyejeong Lee

UNLV Theses, Dissertations, Professional Papers, and Capstones

Comprehending the natural water resource is imperative for the entire state of Nevada and of particular significance for Southern Nevada, where rapid population growth and climate change are placing significant strain on supplies. This research underscores the significance of water chemistry in identifying potential water source areas through trace elements. For the first time, the study proposed measuring the compositions of the entire suite of metal elements, ranging from Li to U, in over 40 springs in the Moapa Valley and its upper gradient valleys, utilizing the iCAP Qc ICP-MS (Inductively Coupled Plasma Mass Spectrometer) at UNLV. The research evaluated …

Patterns Of Dissolved Methane In Groundwater And Its Contribution To Emissions Inventories, Amanda E. Campbell

Dissertations - ALL

The Marcellus Shale is the largest shale gas play in the U.S. production of natural gas using high-volume hydraulic fracturing (HVHF) and production is prevalent throughout the play except in New York (NY), where it is currently banned. High concentrations of methane, the main component of natural gas, in groundwater, as well as its presence in the atmosphere, can have negative consequences. In this dissertation, three aspects of this issue are explored: 1) how and why naturally-occurring methane concentrations vary through time; 2) how elevated naturally-occurring methane concentrations in domestic water wells can be predicted from commonly observed well characteristics; …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Impact Of Prairie Restoration On Geochemistry And Microbial Communities In Groundwater, Kayla Koenig

Graduate Research Theses & Dissertations

Prairie restoration is important for reversing the loss of biodiversity and repairing ecosystem functions humanity is dependent on diverse ecosystems. This study looks at the impact of the beginning phases of prairie restoration on groundwater geochemistry and microbial communities the relationship between them. This research project studied the geochemistry and microbial communities in five wells before, during, and after the beginning phases of the first year of a prairie restoration on the Northern Illinois University campus. Water samples were collected bimonthly for a year and analyzed on an Ion Chromatograph. Microbial samples were collected monthly and underwent DNA extraction, amplification, …

Quantifying Bedrock Recharge In Two Paired Mountainous Watersheds, Kimberly Bolhuis

Graduate Student Theses, Dissertations, & Professional Papers

This study focuses on 1) estimating the magnitude of bedrock recharge and 2) mean transit time as a function of bedrock permeability in two paired catchments underlain by different lithology. Networks of bedrock wells and stream gauges were installed in two adjacent catchments of approximately the same size in west central Montana. Fracture network properties for both lithologies were characterized from borehole core logging and scan lines on exposed outcrop. Recharge was evaluated using the Water Table Fluctuation (WTF) method on bedrock well hydrographs installed in both catchments. Stable water isotope samples, collected approximately monthly, from precipitation and stream water …

Hardbottom Characterization And Relationship To The Geologic Framework In Long Bay, South Carolina, Cathryn J. Wheaton

Electronic Theses and Dissertations

Hardbottom seafloor is a common element among sediment-starved portions of the inner continental shelf along the U.S. Atlantic margin. These areas are characterized by indurated sediment surfaces that are heavily altered by biological and physical processes. Long Bay, in northeastern South Carolina, offers ideal environmental conditions for hardbottom exposure with only patchy Holocene sand deposits, interspersed with extensive hardbottom areas. Here we use high-resolution multibeam bathymetry, CHIRP subbottom profiling and electrical resistivity data, along with surficial sediment samples, hardbottom thin sections, and water column radioisotope (radon-222) analysis to investigate the origin and geologic framework of a region of hardbottom seafloor …

Using Multiple Environmental Tracers To Investigate The Relative Role Of Soil And Deep Groundwater In Stream Water Generation For A Snow-Dominated Headwater Catchment, Isabellah V. Von Trapp

Graduate Student Theses, Dissertations, & Professional Papers

In this study, seasonal fluctuation of environmental tracers in stream flow, soil water, and deep bedrock groundwater were used to constrain the role of deep bedrock groundwater in streamflow generation for a mountainous headwater catchment. Synoptic measurements of stream discharge, ²²²Rn, specific conductivity and major ion concentrations were measured throughout the water year over a 5 km reach of Cap Wallace Creek in the Lubrecht Experimental Forest, Montana, U.S.A. with the intention of understanding groundwater – surface water interactions across spatial and temporal scales. Stage measurements were continually recorded at seven stilling well locations along the reach. Discharge measurements …

Groundwater And Subsurface Water In A Landscape With Shallow Bedrock: Implications For Agricultural Nutrient Export, Laura Kelley, Hunter R. Evans, Reid E. Buskirk, Jonathan M. Malzone, Walter S. Borowski

EKU Faculty and Staff Scholarship

Controls on nutrient export from agricultural landscapes include regional hydrological and geological conditions. In many central Kentucky basins shallow fractured bedrock produces focused groundwater discharge and flashy runoff events. Eastern Kentucky University’s Meadowbrook Farm is currently experimenting with nutrient sequestration techniques; however the effectiveness of these techniques given the local hydrogeology needs to be quantified. Our objective was to determine the potential pathways for nutrient export by mapping key hydrologic features and using a watershed approach. The key features mapped were springs, tile drains, runoff channels, land use and the underlying geology. We chose a 0.46 km² watershed to …

Diurnal And Seasonal Variation In Groundwater Nitrate -N Concentration In A Saturated Buffer Zone, Joseph Miller

Theses and Dissertations

Surface water pollution by nitrate (NO3-) is identified as a critical problem in agricultural land-use areas. Excess NO3- loading causes eutrophication and hypoxia in near-shore marine waters such as the Gulf of Mexico. Diversion of agricultural runoff into saturated buffer zones reduces NO3- loading. Although the mechanisms responsible for NO3- reduction in saturated buffer zones are well characterized, little is known about how NO3- concentrations vary temporally and what factors control those changes. The objective of this study is to understand NO3- concentration and environmental factor variability in a saturated buffer zone on a diurnal scale within and among the …

Tracking Potential Leakage Of Tailings-Lake Water Into Background Groundwater In Butte, Montana, Using Geochemical And Stable Isotope Tracers, Matthew Berzel

Graduate Theses & Non-Theses

This study was conducted to identify environmental tracers using water chemistry and stable isotopes in the Moulton Road area adjacent to the Yankee Doodle tailings impoundment north of Butte, Montana. The water level of the tailings lake is being raised as tailings slurry is pumped up to the impoundment, and numerous residential wells are located in close proximity. Although it has an alkaline pH (> 9), the water in the tailings lake is much higher in some chemical constituents than the wells and some of these constituents could be used as tracers to determine if lake water is migrating out …

Isotope Investigation Of Nitrate In Soils And Agricultural Drain Waters Of The Lower Yakima Valley, Washington, Dallin Jensen

All Master's Theses

Nitrate in the groundwater of the Lower Yakima Valley, Washington has long been known to frequently exceed the EPA maximum contaminant level standard for potable water (10 mg/L), adversely impacting communities with disadvantaged socio-economic status. In this research, nitrogen and oxygen isotopic signatures were determined for nitrate soil leachates and irrigation return flow collected in the Lower Yakima Valley, Washington and compared to previous isotopic studies of nitrate in Central Washington. δ¹⁵N, δ¹⁸O and Δ¹⁷O values are used to constrain sources of to groundwater. Isotope signatures for nitrate from soil leachate largely overlapped with …

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …

Evaluation Of Groundwater Quality In Paleozoic Aquifers Using Gis Techniques, Central Texas, Garrett R. Harris

Electronic Theses and Dissertations

Lab analyses of groundwater chemistry from monitoring wells completed in the Paleozoic Aquifers surrounding the Llano Uplift of Central Texas has been recorded and made available to the public through the Texas Water Development Board (TWDB). This study evaluated the results of these data dating back to the 1940s to determine changes over time, the dynamics of the hydrologic system, and the locations where hydraulic connectivity is most probable. The initial results established two distinct hydrologic systems that required the separation of the northern from the southern region. The northern sub-region (NSR) contains the largest expanse of continuity of both …

Using Bromide Tracer To Measure Uranium Diffusivity In Ground Water Sediments, Francis Michael Tee, Morris E. Jones, Megan K. Dustin, Sharon Bone, John Bargar

STAR Program Research Presentations

More than 129 million liters of groundwater are contaminated with uranium at Old Rifle, Colorado – a former uranium-processing site that operated until 1958. The original Department of Energy (DOE) strategy for remediation, involving natural flushing of U from the groundwater through mixing with surface water, has not proven successful. Thin pockets of silt-, clay-, and organic-rich sediments referred to as naturally reduced zones (NRZs) act both as sinks and sources of U to the aquifer, contribute to plume persistence, and appear to be diffusion limited controlled.

To better understand how the NRZs are diffusion limited controlled, a bromide tracer …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Noble Gases Identify The Mechanisms Of Fugitive Gas Contamination In Drinking-Water Wells Overlying The Marcellus And Barnett Shales, Thomas H. Darrah, Avner Vengosh, Robert B. Jackson, Nathaniel R. R. Warner, Robert J. Poreda

Dartmouth Scholarship

Horizontal drilling and hydraulic fracturing have enhanced energy production but raised concerns about drinking-water contamination and other environmental impacts. Identifying the sources and mechanisms of contamination can help improve the environmental and economic sustainability of shale-gas extraction. We analyzed 113 and 20 samples from drinking-water wells overlying the Marcellus and Barnett Shales, respectively, examining hydrocarbon abundance and isotopic compositions (e.g., C2H6/CH4, δ13C-CH4) and providing, to our knowledge, the first comprehensive analyses of noble gases and their isotopes (e.g., 4He, 20Ne, 36Ar) in groundwater near shale-gas wells. We addressed two questions. (i) Are elevated levels of hydrocarbon gases in …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Geochemical Modeling Of Solubility And Speciation Of Uranium, Neptunium, And Plutonium, Zhongbo Yu, Yuyu Lin, Karen Johannesson, Amy J. Smiecinski, Klaus J. Stetzenbach

Publications (YM)

The purpose of this study is to model the solubility, speciation, and transport of three actinides: uranium (U), neptunium (Np), and plutonium (Pu) by a geochemical modeling tool under possible repository environmental conditions upon waste package failure. The dissolution concentration of three actinides in the waste package, their aqueous speciation after dissolving in the unsaturated zone (UZ), and transport processes in the saturated zone (SZ) along the groundwater flow path at Yucca Mountain (YM) are simulated by geochemical modeling calculations using PHREEQC. This model report was prepared in fulfillment of Groundwater Characterization at Yucca Mountain, Task II: Surface Complexation and …

Potential Contaminants At A Dredged Spoil Placement Site, Charles City County, Virginia, As Revealed By Sequential Extraction, Jianwu Tang, G. Richard Whittecar, Karen H. Johannesson, W. Lee Daniels

OES Faculty Publications

Backfills of dredged sediments onto a former sand and gravel mine site in Charles City County, VA may have the potential to contaminate local groundwater. To evaluate the mobility of trace elements and to identify the potential contaminants from the dredged sediments, a sequential extraction scheme was used to partition trace elements associated with the sediments from the local aquifer and the dredged sediments into five fractions: exchangeable, acidic, reducible, oxidizable, and residual phases. Sequential extractions indicate that, for most of the trace elements examined, the residual phases account for the largest proportion of the total concentrations, and their total …

Thermochronological Evolution Of Calcite Formation At The Proposed Yucca Mountain Repository Site, Nevada: Part 1, Secondary Mineral Paragenesis And Geochemistry, Jean S. Cline, Amy J. Smiecinski, Robert Bodnar

Publications (YM)

In the near future a decision will be made as to whether or not Yucca Mountain, 90 miles northwest of Las Vegas, Nevada is a suitable site for a permanent, underground, high level nuclear waste repository. A major factor in determining the suitability of Yucca Mountain as a repository is the potential for the site to be flooded by water during the regulatory lifetime. The current study was undertaken to examine the past fluid history at the site, to gain a better understanding of the possibility of flooding in the near geologic future. To estimate the past fluid flux into …

Estimation Of Groundwater Velocities From Yucca Flat To The Amargosa Desert Using Geochemistry And Environmental Isotopes, Ronald L. Hershey, Steve Y. Acheampong

Publications (WR)

Geochemical modeling techniques were applied to groundwater flowpaths from Yucca Flat on the Nevada Test Site (NTS) to the Amargosa Desert, south of the NTS to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The groundwater flowpaths examined considered flow in the carbonate aquifer beneath Yucca and Frenchman flats mixing with flow from carbonate aquifers east and southeast of the NTS and discharging at wells south of the NTS border. The approach used the computer codes WATEQ4F and NETPATH to calculate chemical speciation, determine the saturation state of mineral phases, and simulate mixing and the …

Relation Of Groundwater Fluoride Concentrations To Sediment Mineralogy, Potomac Formation (Cretaceous), Southeastern Virginia, Paul Anthony Maciuika

OES Theses and Dissertations

Thirty-seven Early cretaceous sediment samples of the Potomac Formation were obtained from four cores to determine if fluoride bearing minerals are responsible for elevated fluoride concentrations in Potomac Formation groundwaters of southeastern Virginia. Investigative methods included total sediment fluoride and particle size analysis, semiquantitative mineralogical analysis (achieved by X-Ray Diffraction) and statistical methods (cluster, canonical and regression analysis). The sediments showed wide variation in textures, ranging from clean sands and gravels to silty clays. Sediment mineralogies were dependent on the prevailing size fraction, with quartz and feldspar dominating the sand and silt fractions, muscovite primarily being found in the silt …

Chemistry Of The Spring Waters Of The Ouachita Mountains Excluding Hot Springs, Arkansas, George H. Wagner, Kenneth F. Steele

Arkansas Water Resources Center Technical Reports

This report is based on the chemical analysis of the waters from 93 springs and 9 wells. Springs, when free from metal plumbing, provide an uncontaminated source of the ground water and it was desired to obtain water uncontaminated with metals. A few wells were added to the list, usually because of their unique location in the sampling grid.

Solution Geochemistry Of The Water Of Limestone Terrains, John Thrailkill, David B. Beiter, Michael T. Osolnik, Roger H. Postley, William T. Mitchell, Leonard N. Plummer, James R. Riddell, Richard C. Worley, Robert D. Zwicker

KWRRI Research Reports

Limestone groundwater flows mainly in openings it has solutionally enlarged, thus an understanding of the water's state of saturation relative to calcite (the principal mineral component of limestone) is fundamental to an understanding of the nature and evolution of the limestone aquifer. This study investigated the Mammoth Cave-Sinkhole Plain (MCSP) and Cave Hollow (CH) aquifers in Kentucky, both in Missippian limestones.

Both aquifers were always undersaturated with calcite. Except for completely ventilated vadose flows (usually) and some vadose seepage (occasionally), all recharges sampled (sinking streams, vadose flows, and vadose seepage) were also undersaturated. The lack of saturation in the MCSP …