Geochemistry Commons^™

A Method For Determining Creosote Contamination Of Sediment From The Elizabeth River, Norfolk, Va, Elizabeth G. Merrill

OES Theses and Dissertations

Hydrocarbon input sources to the Elizabeth River were investigated. Carbonized coal products (creosote, coal tar, and roof tar), petroleum products (Kuwait Crude Oil, No. 2 Fuel Oil, and a fuel oil spill sample) and soot (woodstove and diesel engine) have unique hydrocarbon distributions. Elizabeth River sediment hydrocarbon distributions indicate that they are contaminated with both carbonized coal and petroleum products. Using a simple two member mixing model, greater than 65 percent of Elizabeth River sediments' resolved aromatic compounds were determined to originate from carbonized coal products. These aromatic hydrocarbons include the EPA priority pollutant polynuclear aromatic hydrocarbons which are known …

Peat Resources Of Maine - Volume 4: Southern And Western Maine, Cornelia C. Cameron, Michael K. Mullen, Carolyn A. Lepage

Maine Collection

Peat Resources of Maine - Volume 4: Southern and Western Maine

by Cornelia C. Cameron, Michael K. Mullen, Carolyn A. Lepage & Walter A. Anderson

Bulletin 31 - Maine Geological Survey, Department of Conservation, Augusta, Maine (1984).

Preparation of this report was supported by funds furnished by the U.S. Department of Energy, Grant No. DE-FG18-79ET14690, the Maine Office of Energy Resources, the Maine Geological Survey, and the U.S. Geological Survey.

Contents: Introduction / The Maine Peat Resource Evaluation Program / Geologic Setting of Maine Peat Deposits / Formation of Peat Deposits in Maine / Methods of Investigation / Identification of …

Trace-Elements In Ilmenite - A Way To Discriminate Provenance Or Age In Coastal Sands, Dennis A. Darby

OES Faculty Publications

Trace elements and Ti percentage in ilmenite grains magnetically separated from modern and late Pleistocene coastal sands of southeastern Virginia and northwestern North Carolina were used to distinguish different deposits. Multivariate analysis of ilmenite composition (Ti, Mn, Mg, Cr, V, Ni, and Cu) from coastal deposits and potential source rivers enabled the identification of dominant source rivers. Using the trace element content of one mineral instead of heavy-mineral suites eliminated most of the hydraulic sorting, selective weathering, and intrastratal solution problems that often obscure heavy-mineral provenance determinations. Most ilmenite grains lacked exsolution or twinning, which are common to ilmenite; however, …

Hydrochemical Data For The Truckee River Drainage System, California And Nevada, Larry V. Benson

United States Geological Survey: Staff Publications

Abstract

Surface-water samples were collected from the Truckee River drainage system during 1975, 1976, and 1981. Data resulting from chemical analyses of these samples, as well as certain other previously unpublished data, are tabulated in this report. The report contains the following hydrochemical data:

1. Chemical composition of 21 tributaries to Lake Tahoe and the Truckee River upstream from Farad, California (May and October 1971, and June 1972).

2. Chemical composition of the Truckee River at Tahoe City (January 1968-January 1975) and at Farad, California (January 1968-June 1980), and of the Little Truckee River upstream from Stampede Reservoir, California (January …

The Effect Of Polynuclear Aromatic Hydrocarbons On The Fecundity Of Acartia Tonsa (Calanoid Copepoda), Juanita Y. Grabarczyk

OES Theses and Dissertations

The concentrations of polynuclear aromatic hydrocarbons (PNAHs) were determined for several stations in the Elizabeth River. Thirteen PNAHs of the sixteen EPA priority pollutant PNAHs were present in the particulate fraction. The concentrations ranged from 10.0 ng/1 to 1000 ng/1. Ten of the sixteen EPA priority pollutant PNAH were present in the dissolved phase. Concentrations ranged from 2.0 ng/1 to 100 ng/1.

The environmental PNAHs concentrations were used to determine test concentrations. Bioassays were conducted to determine the effects of indigenous concentrations of seven predominant PNAHs (0.01 mg/1 to 2.4 mg/1 concentrations) on the fecundity of Acartia tonsa (calanoid Copepoda). …

Input And Distribution Of Sewage Derived Sedimentary Material Adjacent To Chesapeake-Elizabeth Sewage Outfall, Virginia Beach, Virginia, Robert Carroll Brown

OES Theses and Dissertations

The concentrations of coprostanol and hydrocarbons were measured in the effluent from the Chesapeake-Elizabeth sewage treatment plant and surface sediments from the area surrounding the effluent discharge site. Most of the coprostanol (>84%) and hydrocarbons (>91%) were associated with particulates in the effluent. Some of these particles were incorporated into the sedimentary column within the study area, while some may have escaped from the area.

The study area is found to be a dynamic area where changes in the percentage and distribution of fine-grained sediments occur over periods of months. The movement of fine-grained sediments is an important …

Diagenesis Of Miocene Biogenic Sediments In Lost Hills Oil Field, San Joaquin Basin, California, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Major portions of the Miocene Monterey formation of California were deposited under low oxygen conditions, with restricted clastic influx, beneath waters with high phytoplankton productivity. The resulting diatomaceous and organic-rich sediments underwent diagenetic modification as they were buried.

A suite of core samples was collected from eight wells in the Lost Hills oil field ranging in present depth of burial between 535 and 2285 meters. In one well, the entire Monterey section was sampled. Cores taken from the remaining wells sampled the Reef Ridge and Antelope Members of the Monterey Formation at various burial depths.

Silica mineralogy was studied using …

Chemical Composition Of Ground Water And The Locations Of Permeable Zones In The Yucca Mountain Area, Nevada, Larry Benson, J. H. Robison, R. K. Blankennagel, A. E. Ogard

United States Geological Survey: Publications

Ten wells in the Yucca Mountain area of southern Nevada have been sampled for chemical analysis. Samples were obtained during pumping of water from the entire well bore (composite sample) and in one instance by pumping water from a single isolated interval in well UE-25b#1. Sodium is the most abundant cation and bicarbonate the most abundant anion in all water samples. Although the general chemical compositions of individual samples are similar, there are significant differences in uncorrected carbon-14 age and in inorganic and stable-isotope composition. Flow surveys of seven wells performed using iodine-131 as a tracer indicate that ground-water production …

Some Effects Of The Polychaete Nereis Succinea Frey And Leukart 1847 On The Distribution Of Copper Cadmium And Zinc In Sediments And Water, Gabriela Kitzig August

OES Theses and Dissertations

Two laboratory experiments, each lasting 216 hours, were conducted in order to determine the effects of a burrowing polychaete, Nereis succinea Frey and Leukart, 1847, on the distribution of copper, cadmium, and zinc in sediments and water in environmentally controlled microcosms. Dissolved metal concentrations in microcosms containing worms (experimental) decreased more rapidly than in microcosms without worms (controls). From 72 hours to 216 hours, suspended metal concentrations in experimental microcosms increased while concentrations in controls remained relatively constant. Sediment cadmium concentrations in experimental microcosms increased more over time than in controls. Polychaetes accumulated significant amounts of all three metals. These …

An Ecological Analysis Of Relic Diatoms In Sediments Of Las Vegas Bay, Lake Mead, David Ross Hetzel

Publications (WR)

Relic diatoms in sediments of the inner Las Vegas Bay, near the Las Vegas Wash sewage inflow, were examined in order to assess historic trophic conditions in this area of Lake Mead. Diatom sedimentation rates and ratios of Araphidineae/Centrales (A/C) diatom groups were determined from sediment cores collected in the old wash channel 1.5 km from the sewage inflow (station 2), in a small cove 1.5 km further downstream (station 3) and in an adjacent embayment off Gypsum Wash (station 4). Diatom sedimentation rates generally increased from the bottom to the top of each core, but pronounced minima existed at …

A Geochemical Study Of The Rhododendron And Dalles Formations In The Area Of Mount Hood, Oregon, Marshall W. Gannett

Dissertations and Theses

The Miocene Rhododendron and Dalles Formations in the Mount Hood area are accumulations of chiefly pyroclastic andesitic material, largely confined to the Dalles-Mount Hood syncline. These very similar units are geographically separated by overlying andesites including the present Mount Hood cone, and past workers have suspected that they may share a common source. Prior to this study, few geochemical data were available for the Rhododendron and the Dalles Formations, compared to the well studied Columbia River basalts underlying them and the overlying Pliocene andesites. This geochemical study was designed to investigate certain aspects of the Rhododendron and Dalles Formations such …

Structure And Influence Of The Tillamook Uplift On The Stratigraphy Of The Mist Area, Oregon, Moinoddin Murtuzamiya Kadri

Dissertations and Theses

Fifty three sedimentary samples were analyzed for their minor and trace element concentrations utilizing instrumental neutron activation analysis. Concentrations of Na, K, La, Sm and Sc, and their ratios appear to establish significant trends. The data suggest a major break from a granitic-metamorphic provenance and a volcanic component dominated provenance between the Cowlitz and Keasey Formations respectively. The provenance of the Astoria Formation indicates the presence of flood basalts.

Lithologic And Structural Controls On Karst Landforms Of The Mitchell Plain, Indiana, And Pennyroyal Plateau, Kentucky, Frederick Jennings Woodson

All-Inclusive List of Electronic Theses and Dissertations

Karst features in Harrison County, Indiana, and the Mammoth Cave region, Kentucky, are profoundly influenced by lithology and structure. In the Sinkhole Plain two classes of sinkholes, shallow solutional and deeper subsidence, differ in morphology, origin, age, distribution, and density. Distributions of the two kinds of sinkholes reflect the outcrop pattern of specific lithostratigraphic units. Broad shallow dolines (Ste. Genevieve-type sinks) develop on the Horse Cave Member of the St. Louis Limestone and on the Ste. Genevieve, Girkin, and Paoli Limestones. Innumerable steeper-sided subsidence and collapse depressions (St. Louis-type sinkholes) form on the Corydon Chert Member, lower St. Louis Limestone, …

A Geochemical Study Of The Sudbury Breccia, Kevin M. Prochaska

Masters Theses

The origin of the Sudbury Breccia surrounding the Sudbury Basin of Ontario, Canada has long been debated. The breccia has been described both as an igneous injection and as an abraded country rock formed by attrition in place.

A geochemical analysis of selected elements in matrix and clast samples from the breccia revealed distinct differences between the two sample groups. Matrix samples were lower in silicon and higher in heavy elements than the clasts. Matrix and clasts were comparable in light elements.

The results of the analysis favor an igneous process. Petrographic observations and structural evidence support this idea. The …

A Stratigraphic And Geochemical Investigation Of Ferruginous Bauxite Deposits In The Salem Hills, Marion County, Oregon, Charles William Hoffman

Dissertations and Theses

Pacific Northwest ferruginous bauxite deposits have formed in four main areas of northwestern Oregon and southwestern Washington by laterization of flows of the Columbia River Basalt Group (CRBG). The deposits, averaging 36.3% Al₂O₃ , 31.8% Fe₂O₃ , and 5.9% Sio₂, generally occur near the surface of hilltops in gently rolling areas. Two very different views have been advanced regarding the setting in which the deposits have formed. The first hypothesis calls for a blanket-type laterization by erosion of much of the original deposit upon uplift and dissection of the area.

Geochemical Results From A Rock Geochemical Survey In The Mount Belknap Caldera Vicinity, Utah, Robert E. Tucker, William R. Miller, J. N. Motooka, U.S. Geological Survey

All U.S. Government Documents (Utah Regional Depository)

Rock, stream-sediment, and hydrogeochemical surveys were conducted in the Mount Belknap caldera area, south-central Utah, during the summer of 1979. The presence of leucocratic rocks and relatively high concentrations of the elements Nb, Be, Ga, Y, Pb, Sn, Mo, and F with corresponding low concentrations of the elements Ba, Mg, Ca, Fe, Sr, and Cu suggests that late phase highly differentiated felsic magmas were intruded and (or) erupted in the caldera vicinity. The presence of Mo and Sn in the rocks and F in the water samples suggest that the ore elements were concentrated, first in residual fluids in the …

Some Chemical And Mineralogical Aspects Of Plutonic Rocks From The North Arm Mountain Massif, Bay Of Islands Ophiolite, Newfoundland, Jerry W. Sullivan

Geology Theses and Dissertations

Whole-rock major and trace element compositions of one basalt, one diabase, and 21 rocks from the magmatic-plutonic units of the North Arm Mountain massif, Bay of Islands ophiolite, Newfoundland, were determined. Mineral compositions of a subset of the plutonic rocks were also determined.
The major and trace element compositions of the basalt and diabase are similar to abyssal tholeiites, and this is consistent with the REE data of Malpas (1978) and Suen, et. al. (1979) that suggest the lavas and dikes formed from a depleted or slightly enriched abyssal tholeiitic magma. The alkaline nature of the magma proposed by several …

Geophysical And Geochemical Analyses Of Selected Miocene Coastal Basalt Features, Clatsop County, Oregon, Virginia Josette Pfaff

Dissertations and Theses

The proximity of Miocene Columbia River basalts to the "locally-erupted" coastal Miocene basalts in northwestern Oregon, and the compelling similarities between the two groups, suggest that the coastal basalts, rather than being locally erupted, may be the westward extension of plateau basalts derived from eastern Oregon and Washington.

The local-origin hypothesis is based largely on the interpretation of coastal dikes and sills as representing vent areas; however, a complex mechanism, as yet unsatisfactorily defined, would be required to cause the eruption of virtually identical magmas simultaneously from source areas 500 km apart.

This study, therefore, has investigated the coastal basalt …

The Distribution Of Cesium-137, Copper, Lead And Zinc In Various Sedimentary Environments Of The James River Estuary, Virginia, Colin Stevenson Moy

OES Theses and Dissertations

Ten grab samples and eight cores were obtained within a short stretch of the James River estuary. The distribution of CU, Pb, Zn, Cs-137, organic carbon (TOC) and fine-grained sediments in various depositional environments were examined. Within the past quarter of a century, these measured parameters have been accumulating preferentially in the low energy environment (Burwell Bay). The inventory of Cs-137 in the cores was linearly related to the inventory of heavy metals and TOC. The concentrations of Cs-137 in the surface sediments vary linearly to those of the other parameters suggesting that Cs-137 may be used as a tracer …

The Effects Of Elevated Calcium Chloride And Magnesium Chloride Levels On Larval Growth And Survival Of Macrobrachium Rosenbergii (De Man) (Decapoda Palaemonidae) Reared In The Laboratory, James Thomas Michaels Ii

OES Theses and Dissertations

The effects of elevated CaCl₂ , MgCl₂ , combination CaCl₂ and MgCl₂ concentrations and their associated ionic strengths on larval growth and survival of the freshwater prawn, Macrobrachium rosenbergii were investigated in the laboratory. Larvae were reared in diluted seawater of 15 parts per thousand salinity with elevated calcium concentrations of 330 parts per million and elevated magnesium concentrations of 1275 parts per million. Control larvae were also reared with elevated NaCl concentrations to duplicate the ionic strength increases of the combination CaCl₂ - MgCl₂ test solution which had the highest ionic strength. A …

Tourmaline - A Prospecting Guide For Massive Base-Metal Sulfide Deposits In The Penobscot Bay Area, Maine, John F. Slack

Maine Collection

Tourmaline - A Prospecting Guide for Massive Base-Metal Sulfide Deposits in the Penobscot Bay Area, Maine

by John F. Slack, U.S. Geological Survey

Special Economic Studies Series No.8

Maine Geological Survey, Department of Conservation, Augusta, Maine (June, 1980).

Contents: Abstract / Introduction / Geologic Setting / Massive Sulfide Deposits / Tourmaline Occurrences / Tourmaline: A Guide to Ore / Acknowledgements / References Cited

Influence Of Las Vegas Wash Density Current On Nutrient Availability And Phytoplankton Growth In Lake Mead, John R. Baker, Larry J. Paulson

Publications (WR)

Density currents are commonly formed in reservoirs because of temperature or salinity induced density differences between inflowing and receiving waters. Anderson and Pritchard (1951) were among the first to demonstrate this in their investigations of density currents in Lake Mead. They found that the Colorado River formed an underflow in Lake Mead during the winter, an overflow in the spring and an interflow in the summer and fall. Wunderlich and Elder (1973) have since described the hydromechanics of these types of flow patterns, and density currents have been reported for several other large reservoirs (Carmack et al. 1979, Johnson and …

Chemistry Of The Spring Waters Of The Ouachita Mountains Excluding Hot Springs, Arkansas, George H. Wagner, Kenneth F. Steele

Arkansas Water Resources Center Technical Reports

This report is based on the chemical analysis of the waters from 93 springs and 9 wells. Springs, when free from metal plumbing, provide an uncontaminated source of the ground water and it was desired to obtain water uncontaminated with metals. A few wells were added to the list, usually because of their unique location in the sampling grid.

A Statistical Analysis Of The Quality Of Surface Water In Nebraska, R. A. Engberg

United States Geological Survey: Publications

This report provides descriptive statistics for 29 chemical or biological constituents for 109 stream sites in Nebraska sampled by the U.S. Geological Survey beginning in 1946. Also provided for each site are regression equations relating specific conductance to each of 12 chemical constituents and a regression equation relating specific conductance to stream discharge. The descriptive statistics are presented by river basins. Water leaving these basins that has the lowest mean specific conductance (266 umho/cm) is from the Niobrara River at Verdel, and water that has the highest (1,890 umho/cm) is from the South Platte River at Roscoe. Statewide, the principal …

Saratoga: The Bubbles Of Reputation And Their Implications For An Embryonic Rift System In The Upper Hudson River Valley, James R. Young

Geology Theses and Dissertations

Carbonated, alkaline, saline waters occur over a wide area in the upper Hudson River Valley approaching 1,000 square miles. Through the sampling (spring and fall) of 39 locations, half of which were hitherto unsampled, the waters are shown to be a complexly mixed system with at least five major components.
They are:
1) a gaseous phase consisting primarily of CO2;
2) a fluid (containing the dissolved CO2) possibly analogous to a metamorphic brine whose major chemistry is HCO3>Na>Cl;
3) formational waters of variably low salinities which may be the end products of progressive dilution of Paleozoic connate brines …

"Energy Resources", Harrison Scott Brown

Special Collections: Oregon Public Speakers

With: Salter, C. L. The urban enigma.

The Geology And Geochemistry Of The North Fork Stock, Northeastern Oregon, David Joseph Matty

Dissertations and Theses

The North Fork stock is a composite intrusive body of Late Jurassic-Early Cretaceous age which outcrops in the Blue Mountains of northeastern Oregon. The upper 600 m of the intrusion are exposed over an area of approximately 36 km² along the canyon walls of the North Fork of the John Day River in Grant and Umatilla counties. The stock intrudes metasediments, metavolcanics, and metagabbros associated with the Permian-Triassic Elkhorn Ridge Argillite. Contact metamorphism of the Elkhorn Ridge Argillite is developed to the hornblende-hornfels facies throughout most of the exposed area of this unit in the study area. The contact …

Alkalinity And Ph In The Southern Chesapeake Bay And The James River Estuary, George T. F. Wong

OES Faculty Publications

The ranges of alkalinity and pH in the southern Chesapeake Bay and the James River estuary were 2.25 meq·liter⁻¹ at 32‰ to

Petrology And Mineral Chemistry Of Some Jan Mayen Volcanics, Carla A. White

Geology Theses and Dissertations

The island of Jan Mayen is the northernmost active volcano on the Mid-Atlantic Ridge. The rocks of Jan Mayen belong to the potassic series of the alkaline rocks and appear to belong to the straddle type association. The ankaramites and alkali olivine basalts are characterized by the presence of large xenocrysts of rimmed chromium diopside, titaniferous salite, olivine (Fo83 to Fo88), magnetite and sometimes plagioclase (bytownite rimmed by labradorite). Phenocrysts of olivine (Fo74) and plagioclase (andesine) are present in several rocks. These and phenocrysts lie in a matrix composed of` titaniferous salite, olivine (Fo58), plagioclase (andesine), magnetite, biotite and sometimes …

The Distribution Of Several Metals And Cation Exchange Capacity In Sediment Fractions From An Artificial And Natural Marsh, James River, Virginia, William Nivens

OES Theses and Dissertations

In order to examine the mechanisms by which Fe, Mn, Ca, Zn, Cu, Ni and Pb are bound in sediments, a sequential selective extraction procedure was employed on sediment samples collected at an experimental dredge disposal marsh and a neighboring natural marsh located near Windmill Point, James River, Va. The metal concentrations were determined in six phases, interstitial water, exchangeable, easily reducible (oxides of Mn), organic, moderately, reducible (oxides of Fe), and residual fractions. In addition, the cation exchange capacity (CEC) of the sediments was determined as well as the actual role of organics and colloidal iron coatings as they …