Geochemistry Commons^™

Precipitation Dynamics In Kalamazoo, Sw Michigan: A Stable Isotope Perspective, Madhav V. Machavaram

Masters Theses

No abstract provided.

Groundwater Chemistry Analysis Of The Saginaw Formation In Delhi Township, Michigan, Sam L. Kitchin

Masters Theses

Groundwater chemistry and well data provided by the Ingham County (Michigan) Health Department were used to evaluate the distribution of inorganic chemical constituents in the groundwater flow system of the Saginaw Formation, in Delhi Township, Michigan. The data also were used to study the distribution of chemical constituents with respect to different rock types of the Saginaw Formation. The data were analyzed to examine if variations in the concentrations of the chemical constituents and the values of other chemical parameters relate to rock-water interactions, groundwater flow systems, or groundwater contamination.

The results indicate that patterns of increasing or decreasing concentrations …

Geochemistry, Alluvial Facies Distribution, Hydrogeology, And Groundwater Quality Of The Dallas-Monmouth Area, Oregon, Rodney R. Caldwell

Dissertations and Theses

The Dallas-Monmouth area, located in the west-central Willamette Valley, Oregon, consists of Tertiary marine and volcanic bedrock units which are locally overlain by alluvium. The occurrence of groundwater with high salinities has forced many rural residents to use public water supplies. Lithologic descriptions from driller's logs, geochemical (INAA), and x-ray diffraction analyses were used to determine alluvial facies distribution, geochemical and clay mineral distinctions among the units, and possible sediment sources. Driller's log, chemical and isotopic analysis, and specific conductance information from wells and springs were used to study the hydrogeologic characteristics of the aquifers and determine the distribution, characteristics, …

Water-Quality Assessment Of The Central Nebraska Basins: Summary Of Data For Recent Conditions Through 1990, Ronald B. Zelt, P. R. Jordan

United States Geological Survey: Publications

Among the first activities undertaken in each National Water-Quality Assessment (NAWQA) investigation are the compilation, screening, and statistical summary of available data concerning recent water-quality conditions in the study unit. The water-quality conditions of interest in addressing the objectives of the NAWQA program are those that are representative of the general water quality of a given stream reach or area of an aquifer. This report (1) identifies which existing water-quality data are suitable for characterizing general conditions in a nationally consistent manner and (2) describes, to the extent possible, recent, general water-quality conditions in the Central Nebraska Basins. The study …

Considerations Of Variations In Ionospheric Field Effects In Mapping Equatorial Lithospheric Magsat Magnetic Anomalies, Dhananjay Ravat, W. J. Hinze

Earth and Environmental Sciences Faculty Publications

Longitudinal, seasonal, and altitude‐dependent variability of magnetic fields is investigated in equatorial latitudes to determine their effect on the isolation of lithospheric Magsat magnetic anomalies. An estimate of ‘ionospheric effect’ was compiled by averaging the total intensity Magsat anomalies as a function of dip latitudes (called ‘dip‐latitude averages’) from dawn and dusk data sets grouped according to longitudes, time (months), and altitudes. Unanticipated seasonal variations were observed in dusk Magsat data over the Indian sector that may contribute to an improved understanding of the equatorial electrojet. The amplitudes of the dawn dip‐latitude averages are small in comparison to the dusk …

Organic Geochemistry Of Permian Organic-Rich Sediments From The Sudetes Area, Sw Poland, Shareen R. Yawanarajah, Michael A. Kruge, Maria Mastalerz, Wojciech Sliwinski

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Lacustrine and marine sediments from the Permian rift-basins of southwestern Poland were analysed using GC-MS and petrographic techniques. High Pr/Ph ratios, gamma- and beta-carotanes and gammacerane in the lacustrine sediments indicate deposition under elevated water salinities. The primary organic matter is represented by bacterial and algal lipids with variable terrestrial input. Marine algal lipids with minor bacterial and cyanobacterial lipids are the primary source of organic matter in the marine sediments. Extended hopanes, n-alkanes with even-odd predominance and low Ts/Tm ratios are consistent with deposition in a closed, evaporitic basin with substantial carbonate sedimentation.

Correlation Of The Tioga Bentonites Using Rhyolitic Melt Inclusions Found In Quartz Phenocrysts As Geochemical Fingerprints, John W. Waechter

Geology Theses and Dissertations

The Tioga bentonites were first noted by Fettke in 1931 from well cuttings in the Tioga gas fields of Tioga County, Pennsylvania. They have been used by many investigators (Oliver, 1954, 1956; Dennison, 1963; Dennison and Textoris, 1967, 1978; Epstein, 1986; Smith and Way, 1983; Way et al., 1986) as a time-plane to correlate stratigraphic units from eastern Pennsylvania to Illinois and from southern Ontario to Virginia. The Tioga bentonites are recognized as seven major volcanic ash layers labeled Tioga-A - Tioga-G as well as several minor layers labeled Tioga-A1 - Tioga-A3 (Way et al., 1986). They occur within the …

Trace-Element Modelling Of Melting In Spinel Peridotites, Susanne Petra Vogel

Geology Theses and Dissertations

This study addresses three independent topics related to trace element modeling of spinel peridotites that are suggested by the pioneering work of Johnson et al. (1990) on abyssal harzburgites.
First, the fractional non-modal melting equation derived by Johnson and coworkers (1990) is algebraically modified to present a "one-element/two-phase" model. This model suggests a simple test for estimating mantle heterogeneity in the source rock of spinel lherzolites. This model is applied to data from the literature for samples from Dreiser Weiher, Germany; San Luis Potosi, Mexico; and Western Victoria, Australia.
Second, trace elements in clinopyroxenes of abyssal peridotites and continental spinel …

Reconnaissance Data For Selected Herbicides, Two Atrazine Metabolites, And Nitrate In Surface Water Of The Midwestern United States, 1989-90, Elisabeth A. Scribner, E. Michael Thurman, Donald A. Goolsby, Michael T. Meyer, Margaret S. Mills, Michael L. Pomes

United States Geological Survey: Publications

Water-quality data were collected from 147 rivers and streams during 1989-90 to determine the temporal and geographic distribution of selected preemergent herbicides, two atrazine metabolites, and nitrate in 10 Midwestern States. This report includes a description of the sampling design, data-collection techniques, laboratory and analytical methods, and a compilation of constituent concentrations and quality-assurance data. All water samples were collected by depth-integrating techniques at three to five locations across the wetted perimeter of each stream. Sites were sampled three times in 1989~before application of herbicides, during the first major runoff after application of herbicides, and in the fall during a …

Seasonal Hydrology And Geochemistry Of Two Small High Arctic Catchments, Axel Heiberg Island, Northwest Territories, Julia Boike

Theses and Dissertations (Comprehensive)

This study examines hydrological and geochemical processes in a continuous permafrost setting in the Canadian High Arctic on Axel Heiberg Island (79°25 ' N; 90°45 ' W) with the following objective: to identify spatial and seasonal variation in hydrology and geochemistry of the East Inflow (EIF) and West Inflow (WIF) sub basins draining into Colour Lake and relate them to processes operating in the basins. Field work in the catchment was carried out between 20 May to 16 August 1991 and 23 July to 20 August 1992. Surface flow and suprapermafrost groundwater in the active layer were monitored to assess …

Fluid Inclusion Studies Of The Morefield Pegmatite Amelia County, Virginia, John Richard Smerekanicz

OES Theses and Dissertations

The Morefield Pegmatite is a planar, nearly vertical body situated in Grenville age gneisses and schists in the southeast Piedmont of Virginia. It consists of a mineralogically simple albite-quartz outer zone and a texturally and mineralogically complex inner zone of microcline-topaz-quartz, with trace amounts of rare-element minerals. Fluid inclusions in samples of quartz, topaz, beryl, spessartite and albite that span the length, width and depth of both zones can be classified by chemical composition into two main groups: H₂O-rich solutions and CO₂- H₂O -rich fluids. The H₂O -rich inclusions consist of H …

Relation Of Groundwater Fluoride Concentrations To Sediment Mineralogy, Potomac Formation (Cretaceous), Southeastern Virginia, Paul Anthony Maciuika

OES Theses and Dissertations

Thirty-seven Early cretaceous sediment samples of the Potomac Formation were obtained from four cores to determine if fluoride bearing minerals are responsible for elevated fluoride concentrations in Potomac Formation groundwaters of southeastern Virginia. Investigative methods included total sediment fluoride and particle size analysis, semiquantitative mineralogical analysis (achieved by X-Ray Diffraction) and statistical methods (cluster, canonical and regression analysis). The sediments showed wide variation in textures, ranging from clean sands and gravels to silty clays. Sediment mineralogies were dependent on the prevailing size fraction, with quartz and feldspar dominating the sand and silt fractions, muscovite primarily being found in the silt …

Mineralogy, Geochemistry, And Dispersal Of Opaque Oxides On The Continental Shelf Of The Cascadia Margin, Kommajosyula Subramanya Ravi

Dissertations and Theses

Opaque oxide minerals (ilmenite, chromite, and magnetite) in sands from the Oregon continental shelf have been studied to establish the provenance, dispersal, and grade of potential shelf placer deposits. The study area extends southward from offshore of the Columbia River in northern Oregon to the Klamath River in northern California.

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

An Analysis Of Dissolved Organic Compounds And Their Contribution To Iron Complexation In The Shallow Leachate Plume Of The West Kl Landfill Kalamazoo, Michigan, Eric Fahle

Masters Theses

High concentrations of dissolved iron are present in downgradient groundwater samples adjacent to the western border of the West KL Landfill. Analysis by Rudder (1988) of groundwater samples indicates oversaturation of selected iron oxides, iron sulfides and siderite in monitoring wells TW-4 and M3.

Previous research suggests that pyrogallol, gallic acid, tannic acid and similar organic compounds may retard the oxidation of ferrous iron in the shallow leachate plume of the West KL landfill (Rudder, 1988). Present research utilizing solid phase extraction, reverse phase high performance chromatography, Fourier transform IR spectrophotometry, UV/Visible spectrophotometry, and gas chromatography/mass spectroscopy indicate that pyrogallol, …

Sedimentological, Structural, And Organic Geochemical Controls On Natural Gas Occurrence In The Antrim Formation In Otsego County, Michigan, Timothy M. Dellapenna

Masters Theses

The prolific Antrim Formation natural gas reservoir in Otsego County, Michigan, has been examined using core descriptions, X-ray diffraction, petrographic, and geochemical analyses. New stratigraphy nomenclature is proposed for the Antrim and Ellsworth Shales. The Antrim Shale contains two distinctive lithofacies: (1) a fractured, non-bioturbated, silica-rich, organicrich black shale lithofacies; and (2) sparsely fractured, bioturbated, carbonaterich, organic-poor gray-green shale. Gas production comes from the Black shale facies.

Rock-Eval analysis demonstrates that the organic matter is a mixture of types I and II material. Low Tmax (435°C) and vitrinite reflectance (0.41-0.46%) values indicate a submature thermal maturation level. Del 13 carbon …

Chemical Analyses Of Water From Selected Wells And Springs In The Yucca Mountain Area, Nevada And Southeastern California, P. W. Mckinley, M. P. Long, Larry Benson

United States Geological Survey: Publications

Chemical analysis of water samples from 279 wells and springs in the Yucca Mountain area are presented. Where data are available, this report includes: site location expressed as Nevada Central Coordinates and latitude and longitude; source of data; name of analyzing laboratory; geologic unit from which water was obtained; lithology; water use; elevation of well or spring; well depth; depth to water; time pumped before taking the sample; yield; type of filtration; sampling method; date the sample was collected; and anion-cation balance.

Yucca Mountain, Nevada (fig. 1), is being investigated by the U.S. Geological Survey, in cooperation with the U.S. …

Organic Geochemistry And Petrography Of Spanish Oil Shales, Michael A. Kruge, Isabel Suarez-Ruiz

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Four of the principal oil shale units of Spain were examined by organic geochemical and petrographic methods. The samples included three lacustrine shales (Carboniferous from Puertollano, Cretaceous from Llames and Miocene from Rubielos de Mora) and one marine shale (Lower Jurassic from Punta del Cuerno ). The petrographic observations show a dominance of liptodetrinite associated with bitumen-stained mineral matter and alginite, as well as a paucity of structured terrestrial organic matter. Geochemical work shows that the soluble organic matter is a mixture of terrestrially derived and aquatic, with the lacustrine samples having the strongest land plant signatures. Low values of …

Aspects Of Sporinite Chemistry, Michael A. Kruge, John C. Crelling, Edwin J. Hippo, Stephen R. Palmer

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

With the recent advent of the ability to separate coal into maceral concentrates of high purity, the individual constituents of coal can now be analyzed separately, without their mutual interference, giving a much better understanding of the macromolecular structure of coal. The sporinites from two Pennsylvanian age coal samples (Illinois Basin, U.S.A.) were studied, one from a vitrinite-rich high-volatile bituminous coal, the other from a liptinite-rich high-volatile bituminous coal of slightly higher rank. Sporinites were isolated from each coal by density gradient centrifugation. The sporinite of the vitrinite-rich coal was compared chemically and petrographically with the parent coal and with …

Mineral Paragenesis Of The Granulite Facies In The Lake George Area, New York, Boknam Ree

Geology Theses and Dissertations

The Lake George Area belongs to the southeastern part of the Adirondack Highlands. The rocks of this area show variations in mineral assemblages which are caused by differences in bulk chemical composition. This makes it unsuccessful to use a subdivision of the granulite facies which is suggested by de Waard (1965).
The CFM diagram (Abbott, 1982) is used to show the relationship between composition and paragenesis of the Lake George Area. In this study, a different result has been found in the order of partitioning of Fe between coexisting minerals, namely, garnet>hornblende>biotite>orthopyroxene>clinopyroxene. The hornblende granitic gneiss …

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Trace Metals And Pyrite In Sediments Of Chesapeake Bay, Robert S. Kluckhohn

OES Theses and Dissertations

The formation and cycling of iron sulfides within anoxic sediments can affect the cycling of trace metals. The sediments at station CB-27 (near Annapolis, Maryland) in Chesapeake Bay were rich in FeS (39% of TS), low in greigite (3.6% of TS), and has a relatively constant pyrite concentration (50 - 60% of TS) with depth. The percent composition of total metals in pyrite were 25.7% cu, 11.8% Zn, 15.8% Fe, and non-detectable to 2.1% Cd. At Station CB- 28 (near the Choptank River), the sediments were low in FeS (1.7% of TS), richer in greigite (up to 14% of TS), …

Hydrogeology And Hydrogeochemistry Of The Tekonsha Moraine And Adjacent Interlobate Deposits In Charleston Township, Kalamazoo County, Michigan, Victor V. Melbardis

Masters Theses

Hydrogeochemical analyses and hydrogeologic interpretations provide the basis for an understanding of local ground-water flow, in a 12 square mile study area, transected by the Tekonsha Moraine and bound by glaciofluvial deposits. Glacial tills separate an upper and lower aquifer system throughout most of the area.

Degraded and tritiated ground water is present in the lower aquifer system. A negative correlation (-0.62) between tritium concentrations and depth is statistically significant (.04). In this local system, hydrochemical trends are characterized by decreases in sulfate percentages and increases in bicarbonate in the direction of ground-water flow. Statistical evaluation of the hydrochemical data …

Metal Mobilization From A Near-Shore Lake Sediment Under Simulated Acidic Groundwater Inputs, Raveendra V. Ika

OES Theses and Dissertations

Simulation of acidic groundwater passing through lake sediments was conducted under controlled conditions in a laboratory. Three sediment cores collected intact from the near-shore region of an acidic lake were subjected to simulated groundwater inputs of initially identical chemistry for a seven day period. Following this period water being used in the simulation for two of the sediment cores was acidified by hydrochloric acid (HC1) addition to examine the ability of these sediments to neutralize acidic groundwater with varying H⁺ concentration.

Simulated acidic water passing through the sediment cores mobilized significant amounts of metals. The sediment acted as a …

Geochemical Evolution Of Ferruginous Bauxite Deposits In Northwestern Oregon And Southwestern Washington, Joseph Michael Fassio

Dissertations and Theses

Ferruginous bauxite deposits developed from flows of the Columbia River Basalt Group in northwestern Oregon and southwestern Washington. Samples of the iron pisolite and the gibbsite nodular zones from the upper portion of the weathering profile of drill core from Columbia County, Oregon and Cowlitz County, Washington, were analyzed by instrumental neutron activation. The mineralogy was determined using Xray diffraction and Mossbauer spectroscopy.

The gibbsite nodular zone is above the clay-rich saprolite or relic basalt zone. The nodules contain relic vesicles and well preserved relic plagioclase microlites. Gibbsite occurs with poorly crystalline goethite and hematite in the gibbsite nodular zone. …

A Comparison Of Metals In Several Ahermatypic Corals And Surficial Sediments: Mobile Pinnacles And Hoffa Reef, Northcentral Gulf Of Mexico, Kathryn M. Conko

OES Theses and Dissertations

Metal concentrations in marine sediment and carbonate secreting invertebrates are representative of surrounding environmental chemistry. Aluminum, Ba Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, and Zn were measured in carbonate and terrigenous phases of the $<$63 um fraction of sediment samples from two locations in the northcentral Gulf of Mexico. Enrichment factors indicate that Al, Ba, Cu, Cr, Mg, Mn, and Ni are all slightly depleted in these sediments relative to crustal abundances. Discriminant function analyses shows that the concentrations of five elements differ between locations.

Ahermatypic coral (106 specimens) from five genera collected from the study sites were analyzed for Cd, Cu, Cr, Pb, Zn, Mn, Sr, Ba, Fe, Ca and Mg. Eight elements vary between some genera, Al and Ba also vary in concentration in corals between either location. All elements except Sr are significantly depleted in the coral with respect to Ca in the …

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

Biological Markers In Lower Jurassic Synrift Lacustrine Black Shales, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, Jay F. Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The East Berlin Formation (Lower Jurassic, Hartford basin, Connecticut, U.S.A.) is distinctive for its six cyclic units of lacustrine black shale and gray mudstone. separated by playa and fluvial redbeds. The black shales arc each about a meter thick and were deposited in subtropical, thermally stratified, oligomictic lakes, the youngest of which (lakes 3 through 6) were large enough to flood most of the basin and attained depths of several tens of meters.

The saturate fractions of solvent extracts of organic-rich black shales from each of the six lakes, collected at fresh roadcuts near East Berlin, arc dominated by extended …

Characterization Of Organic Sulfur Compounds In Coals And Coal Macerals, Stephen R. Palmer, Edwin J. Hippo, Michael A. Kruge, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Peroxyacetic acid oxidation has been used to investigate the type and distribution of organic sulfur species in samples of vitrinite, sporinite and inertinite, separated from the Herrin No.6 and an Indiana No.5 coal seam. It was established that organic sulfur species were selectively preserved during oxidation and their analysis led to some of the first sulfur-33 NMR spectra obtained for coal. The effects of maceral separation processes on model compounds were also studied. Results from our studies support the following conclusions: 1). Different macerals have different distributions and types of organic sulfur species. 2). Organic sulfur compounds in coal occur …

Organic Geochemistry Of A Lower Jurassic Synrift Lacustrine Sequence, Hartford Basin, Connecticut, U.S.A., Michael A. Kruge, John F. Hubert, David F. Bensley, John C. Crelling, R Jay Akes, Paul E. Meriney

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Synrift terrestrial strata of the Lower Jurassic East Berlin Formation (Hartford basin, Connecticut, U.S.A.) record cyclical expansion and contraction of major lakes, six of which were deep enough to develop anoxic bottom waters. We have studied one representative lacustrine sequence in detail, sampling a new roadcut near the village of East Berlin. The section examined is 4 m thick, with a gray siltstone at the base, deposited in shallow water, overlain by an organic-rich black shale (deep water), succeeded in turn by another gray siltstone, deposited as the lake waters gradually receded. The upper gray siltstone is chemically distinct from …