Geochemistry Commons^™

Hydrothermal Sediments Associated With A Relict Back-Arc Spreading Center In The Shikoku Basin, Recovered From The Nankai Accretionary Prism, Japan, Jane L. Alexander, Kevin T. Pickering, Elizabeth H. Bailey

Publications and Research

The hemipelagic mudrocks of the Nankai accretionary prism, Japan, contain hydrothermal deposits associated with a relict spreading center in the Shikoku Basin. Initial work on core samples from Ocean Drilling Program Site 808 found several samples with elevated concentrations of calcium, magnesium, iron and manganese, at depths of between 1060 and 1111 m below sea floor. However, the origin of these sediments was uncertain, due to a lack of data. There was no recorded evidence of whether these elevated concentrations were present throughout this interval of core, or if they were present as discrete layers with the background hemipelagic mudrocks …

The Geochronology And Geochemistry Of The Bearhead Rhyolite, Jemez Volcanic Field, New Mexico, Leigh Justet

UNLV Theses, Dissertations, Professional Papers, and Capstones

Around 82% of mapped Bearhead Rhyolite (Main Cluster) and Peralta Tuff appears to have been derived from a relatively long-lived (~680 ka), large, shallow (Earth's surface) magma chamber that did not produce a caldera-forming eruption. Although volatile contents were great enough (~ wt.% H₂O), no large-scale explosive eruptions occurred because magma may have been tectonically vented. The lack of systematic chemical variation within the Main Cluster with time during this ~680 ka interval may imply that erupted magmas were physically separated from each other by fault-formed cupolas in the roof of the magma chamber. These results are significant …

Geochemistry And Petrogenesis Of The Bonanza King Mafic Intrusive Complex, Trinity Terrane Ophiolite, California, Keith R. Willse

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Bonanza King mafic intrusive complex (MIC) (>25 km^2₎ of the Trinity terrane ophiolite, northern California, consists of cogenetic plutonic and dike lithologies. Steep intrusive contacts exist between cumulate pyroxenite, isotropic gabbro, and peridotite country rock. Near vertical east-west trending, bimodal dikes intruded gabbro and are centered within the complex. Geochemical modeling indicates taht accumulation/fractionation of a gabbroic parental magma produced lithologic trends of cumulate pyroxenite and fractionated gabbro and dike lithologies. Similarities between all lithologies suggest cogenetic formation of all the elements of the Bonanza King MIC during the Late Silurian (431 +/- 3).

Parental magma …

The Origin Of Brucite In Hydrothermally Altered Limestone Near Devil Peak, Nevada, Rhonda L. Knupp

UNLV Theses, Dissertations, Professional Papers, and Capstones

Open-space brucite was identified in veins crosscutting hydrothermally altered limestone near the Devil Peak rhyolite plug in southern Nevada. The brucite occurs with serpentine, calcite, chalcedony, hydromagnesite, dolomite, and clinochlore.

Brucite usually forms as a replacement mineral, but textural evidence indicates that the brucite at Devil Peak precipitated in open space. The presence of chalcedony in veins indicates the temperature of the hydrothermal fluid was <180^oC during and after mineral deposition. Thermodynamic modeling shows this temperature is too low for replacement brucite to form, thus the low temperature of alteration may be a factor in this unusual occurrence of …

Effects Of Organic Matter And Iron-Rich Clay On Mobility Of Trace Metals From Flue Dust Contaminated Soil, Scott Ephraim Lewis

OES Theses and Dissertations

The enhanced leaching of trace metals through soil becomes a concern for human health if dissolved trace metals reach groundwater and migrate into a public water system. A serial batch extraction procedure was implemented to determine the effects of Vitagrow © organic matter and Fe-Rich TM clay on the mobility of trace metals (Zn, Pb, and Cd) from a flue dust treated (0, 600, 1200, and 2400 μgig Zn) Appling soil.

The addition of an organic matter (OM) amendment to the Appling soil enhanced Pb mobility and reduced soluble Zn and Cd. In general, average solution concentrations of trace metals …

Analysis Of Lunar Basalt Flows In Oceanus Procellarum Using Clementine Data, Noel William Jackson

OES Theses and Dissertations

Remote sensing analyses of data set taken by Clementine in 1994 permit new observations about mineral distribution on the lunar surface, basalt flow stratigraphy, and thus the geologic evolution of the Moon. The northern section of Oceanus Procellarum contains numerous impact craters which penetrated the basalt and thus can be used as natural probes to estimate the number and thicknesses of flows.

I constructed a mosaic taken in three frequencies ( 415 nm, 750 nm, 950 nm), and a Ratio Image (750/415 = red, 750/950 = green, 415/750 = blue). On such an image, red indicates the iron-poor mature highland …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …

Classification Of Torbanite And Cannel Coal. I. Insights From Petrographic Analysis Of Density Fractions., Zhiwen Han, Michael A. Kruge, John C. Crelling, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Torbanite and cannel coal are considered to be coals because of their low mineral content and overall physical morphology. However, the texture and composition of the organic matter in torbanite and cannel coal are similar to the kerogen occurring in oil shales and lacustrine source rocks. Therefore, understanding the nature and origin of organic components in torbanite and cannel coal is of significance in the study of kerogen and petroleum formation. In this research, a set of torbanites and cannel coals from different locations throughout the world were petrographically characterized and processed using a density gradient centrifugation (DGC) technique. Microscopically, …

A Biogeochemical Comparison Of Fossil (Carboniferous) And Modern Crustose Red Algae, Michael A. Kruge, John E. Utgaard, William Ferry

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The nature of the contribution of the various types of algae to sedimentary organic matter continues to be a topic of research interest. Crustose red algae have however received less attention than other types. The fossil calcareous red algae (Rhodophyta) analyzed in this study are two relatively unrecrystallized specimens of Parachaetetes (Family Solenoporacea) from the lower part of the Ste. Genevieve Formation (Carboniferous, Visean) in Union County, Illinois, USA. They occurred in the patch reef phase of a small carbonate mudmound-patchreef. The three modern specimens (collected and identified by F. Collier) are the crustose algae Lithothamnion, Clathromorphum and Phymatolithon …

Chemistry Of Maceral And Groundmass Density Fractions Of Torbanite And Cannel Coal, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Microscopically, torbanite and cannel coal are composed of coarser macerals set in a fine-grained to amorphous groundmass. It is often assumed that the amorphous groundmass is genetically related to the distinct macerals. The separation of macerals and groundmass from 14 late Paleozoic torbanite, cannel, and humic coals permits the analysis of individual constituents using elemental analysis and flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster and principal component analyses of the Py-GC/MS data further reveal the chemical similarities and differences between the various constituents. Pyrolyzates of Botryococcus-related alginites are characterized by an abundance of normal alkadienes, alkenes, and alkanes. Even their …

Classification Of Torbanite And Cannel Coal. Ii. Insights From Organic Geochemical And Multivariate Statistical Analysis, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Petrographic and megascopic criteria have traditionally been used as the basis for the classification of torbanite and cannel coal. For this study, it was hypothesized that modern analytical organic geochemical and multivariate statistical techniques could provide an alternative approach. Towards this end, the demineralized residues of 14 torbanite (rich in Botryococcus-related alginite) and cannel (essentially, rich in organic groundmass and/or sporinite) coal samples were analyzed by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster analysis performed on the Py-GC/MS data clearly distinguished the torbanite from the cannel coal, demonstrating a consistency between the chemical properties and the petrographic composition. All the torbanite …

Molecular Organic Geochemistry Of New York Bight Sediments. Sources Of Biogenic Organic Matter And Polycyclic Aromatic Hydrocarbons, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

As part of a multidisciplinary evaluation of the environmental impact of waste disposal in the New York Bight, a preliminary effort was undertaken to assess the molecular geochemistry of its sedimentary organic matter (OM). For this initial phase of the study, samples were taken from two New York Bight cores collected outside the area of known dumping [in Sandy Hook Bay, NJ], to establish the environmental context for future work on sediments from within dumpsite zones. The method employed was flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), which is an organic microanalysis technique suitable for solid samples, in this case dried, raw …

New Technique Detects Gas Hydrates, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

As exploration and development moves into deep waters, the possibility of encountering gas hydrates within seafloor sediments becomes increasingly likely. The ability to accurately detect gas hydrates is key to producing deepwater fields, allowing operators to safely design and place offshore drilling and production platforms, subsea production equipment and flow lines, as well as pipelines.

Chemical Weathering Of Volcanic Ash As A Probable Origin Of Chert In The Reid's Mistake Formation Of The Newcastle Coal Measures, Sydney Basin, Australia, Adil M. Wadia

All-Inclusive List of Electronic Theses and Dissertations

Chert is normally considered to be marine biogenic in origin. However, chert lenses and nodules in the volcanic ash horizon of the Reid's Mistake Formation at Swansea Head, Newcastle Coal Measures of the Sydney Basin appear to have formed differently. Their mode of occurrence and their close association with paper-thin clay layers within the same volcanic unit suggest that they formed as a result of chemical weathering of volcanic ash. This hypothesis is supported by the data gathered from thin section petrography and x-ray diffraction analyses. Petrographic studies indicate the precipitation of microcrystalline to cryptocrystalline quartz and the dissolution/replacement/alteration of …

The Geomorphological History Of An Alluvial Fan Complex In Nelson County, Virginia, Melinda Ann Youngblood

OES Theses and Dissertations

An alluvial fan complex blankets a portion of the Rockfish Valley in Nelson County Virginia, located along the eastern slope of the Blue Ridge Mountains. The seven-km² field area contains three mappable relict alluvial surfaces (Qf1, Qf2, and Qf3) and one modern surface (Qa1), each of which is underlain by fluvial deposits dominated by greenstone and charnokite cobbles. The four surfaces were mapped according to topographic position and degree of stream dissection. Alluvial deposits underlying each surface were characterized using a 3-part clast weathering scale based on greenstone clast weathering rinds and using soil development criteria (clay content, Munsell …

Water Quality In The Central Nebraska Basins, Nebraska, 1992-95, S. A. Frenzel, R. B. Swanson, T. L. Huntzinger, J. K. Stamer, P. J. Emmons, Ronald B. Zelt

United States Geological Survey: Publications

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the Central Nebraska Basins Study Unit and to relate these findings to water-quality issues of regional and national concern. The information is primarily intended for those who are involved in waterresource management. Indeed, this report addresses many of the concerns raised by regulators, water-utility managers, industry representatives, and other scientists, engineers, public officials, and members of stakeholder groups who provided advice and input to the USGS during this NAWQA Study-Unit investigation. Yet, the information contained here may also interest those who …

Hydrogeology In The Vicinity Of The Nebraska Management Systems Evaluation Area Site, Centra! Nebraska, Virginia L. Mcguire, John M. Kilpatrick

United States Geological Survey: Publications

From 1991 to 1992, the U.S. Geological Survey participated with the U.S. Department of Agriculture and the University of Nebraska-Lincoln in research activities at the Nebraska Management Systems Evaluation Area (MSEA) site near Shelton, Nebraska. The purpose of the U.S. Geological Survey study was to define the hydrogeologic system in the vicinity of the Nebraska MSEA site to aid the interpretation of ground-water sampling results by other researchers. The primary aquifer in the study area is the High Plains aquifer, which consists of an unconfined part, the shallow aquifer; a silt and clay unit that acts as a confining layer; …

Environmental And Botanical Controls On Peatification - A Comparative Study Of Two New Zealand Restiad Bogs Using Py-Gc/Ms, Petrography And Fungal Analysis, Tomasz K. Kuder, Michael A. Kruge, J C. Shearer, S L. Miller

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study shows that chemical properties of two restiad species, Empodisma minus and Sporadanthus traversii, may contribute to their success as peat-formers in a climate of the North Island of New Zealand which is not conducive to raised mire development. Unlike Sphagnum, the equivalent northern hemisphere peat-former, restiads possess lignin in their tissues. In addition, the presence of non-lignin polyphenols (including tannins and phenolic acids) in restiads may be an important factor in peat formation due to the allelopathic decay retardation. Patterns of degradation of plant biopolymers have been examined and the pathway of degradation of monocotyledons (loss …

A Molecular Evaluation Of Contaminants And Natural Organic Matter In Surface Sediments From Western Lake Ontario, Michael A. Kruge, Prasanta K. Mukhopadhyay, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) analysis of bottom sediment from Lake Ontario was shown to be effective in assessing organic contaminants, especially attractive as it is a rapid technique requiring little sample preparation. Pyrolyzates of samples richer in organic matter (OM) were relatively enriched in aliphatic hydrocarbons and pyrrolic nitrogen compounds, while leaner samples were more aromatic and pyridinic. Alkylbenzene and alkylphenol distributions in the pyrolyzates were most compatible with derivation from aquatic (algal, bacterial) OM. The organonitrogen compounds indicated the presence of degraded proteinaceous material from aquatic sources and/or sewage. Normal and polycyclic aromatic hydrocarbon distributions indicate, at least in …

Petrographic And Chemical Properties Of Carboniferous Resinite From The Herrin No. 6 Coal Seam, John C. Crelling, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Resinite is a naturally occurring substance found in coal and derived from original plant resins. It is ubiquitous in North American coals and comprises 1 to 4% by volume of most Illinois coals. It has been commercially exploited in the western USA for use in adhesives, varnishes and thermal-setting inks. The major objectives of this study were: (1) to separate resinite macerals from the Herrin No. 6 coal seam and to carefully verify, by petrographic and fluorescence microspectrophotometric methods, that the separated material was indeed resinite; (2) to characterize the chemical composition of the separated resinite by Py–GC–MS techniques; and …

A Geochemical Study Of Marine Sediments From The Mac. Robertson Shelf, East Antarctica: Initial Results And Palaeoenvironmental Implications, Peter N. Sedwick, P. T. Harris, L. G. Robertson, G. M. Mcmurtry, M. D. Cremer, P. Robinson

OES Faculty Publications

Sediments from the Antarctic continental margin may provide detailed palaeoenvironmental records for Antarctic shelf waters during the late Quaternary. Here we present results from a palaeoenvironmental study of two sediment cores recovered from the continental shelf off Mac. Robertson Land, East Antarctica. These gravity cores were collected approximately 90 km apart from locations on the inner and outer shelf. Both cores are apparently undisturbed sequences of diatom ooze mixed with fine, quartz-rich sand. Core stratigraphies have been established from radiocarbon analyses of bulk organic carbon. Down-core geochemical determinations include the lithogenic components Al and Fe, biogenic components opal and organic …

Identification Of Past Climate Variability Of The Eastern Pacific Ocean Using Both D13c And D18o Records In Corals From Clipperton Atoll (1994-1906), Lei Ren

Geology Theses and Dissertations

The ENSO (El Nino and the Southern Oscillation) is a fundamental ocean-atmosphere phenomenon that dominates interannual global climate variability. Reconstructing past ENSO events is therefore important for documenting and understanding the past behavior of the global climate system and enabling us to predict future climate change. However, the present understanding of ENSO events has been mainly based on the instrumental record of Pacific climate which provides detailed data only for the past few decades. Recent studies have shown that the stable isotope record in coral skeletons can be used as a valuable indicator of paleoclimatic changes in tropical regions, and …

Effective Elastic Thickness Of The Lithosphere Along The Easter Seamount Chain, Sarah E. Kruse, Zhengro J. Liu, David F. Naar, Robert A. Duncan

Geology Faculty Publications

Bathymetry and gravity data collected during Legs 5, 6, and 7 of the 1993 GLORIA Expedition and the recently released 2-min altimetry-derived global gravity grid are used to determine the effective elastic thickness of the lithosphere along the Easter Seamount Chain (ESC). Forward modeling, admittance, and coherence methods yield consistent results. With the exception of the eastern and western ends of the ESC the effective elastic thickness along the chain is ∼1–4 km. The thin elastic thickness for the majority of the ESC seamounts is compatible with a young seafloor age at the time of loading derived from new radiometric …

Volcanology And Geochemistry Of Pliocene And Quaternary Basalts On Citadel Mountain, Lunar Crater Volcanic Field, Pancake Range, Nevada, Loretta D. Dickson

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali basalts on Citadel Mountain form the southern margin of the Lunar Crater Volcanic Field (LCVF) in the central Great Basin, Nevada. Citadel Mountain comprised of a faulted, north tilted section of Tertiary andesite and ash-flow tuff is capped by Pliocene and Quaternary alkali basalt flows that erupted from six major cinder cones. The basalt flows on Citadel Mountain can be divided into two groups (older and younger) based on age and isotopic signatures. The older basalt group is characterized by higher ⁸⁷ Sr/⁸⁶Sr and lower E_Nd and the younger group has lower ⁸⁷Sr/⁸⁶Sr …

Microanalytical Investigations Of Gold-Bearing Rocks From The An Najadi Region In Saudi Arabia, Nazrul I. Khandaker, M. Ahmed, M. M. Hariri, M. A. Garwan, K. R. Khan, M. M. Al-Ohali

Publications and Research

The Proton Induced X-ray Emission technique with a scanning microbeam (micro-PIXE) and Scanning Electron Microscopy (SEM) were employed to study gold-bearing rocks from the An Najadi and adjacent regions situated within the exposed northeastern part of the Arabian Shield. These microanalytical investigations, together with routine petrological and ore microscopic studies, demonstrated the presence of important partitioning of major minerals and trace elements in several samples. These measurements also revealed microstructural features including brecciation within quartz grains and metal concentrations within these fracture-controlled micro-conduits. Results showed promise in terms of using distinctive geochemical signatures for ore body recognition. Of particular interest …

Estimation Of Groundwater Velocities From Yucca Flat To The Amargosa Desert Using Geochemistry And Environmental Isotopes, Ronald L. Hershey, Steve Y. Acheampong

Publications (WR)

Geochemical modeling techniques were applied to groundwater flowpaths from Yucca Flat on the Nevada Test Site (NTS) to the Amargosa Desert, south of the NTS to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The groundwater flowpaths examined considered flow in the carbonate aquifer beneath Yucca and Frenchman flats mixing with flow from carbonate aquifers east and southeast of the NTS and discharging at wells south of the NTS border. The approach used the computer codes WATEQ4F and NETPATH to calculate chemical speciation, determine the saturation state of mineral phases, and simulate mixing and the …

Geochemistry, Stratigraphy And Provenance Of The Portland Hills Silt In The Tualatin Mountains, Portland, Oregon, John L. Lawes Iii

Dissertations and Theses

Soil morphology and geochemistry of loess were investigated at nine sites in the Tualatin Mountains west of Portland and at additional sites in The Dalles, eastern Washington and Puget Sound. A total of forty samples were examined using Instrumental Neutron Activation Analysis (INAA).

Stratigraphic relationships and soil development suggest that the PHS ages of Lentz (1977) be revised. The age of the Portland Hills Silt (PHS) ranges from 12,000 to at least 960,000 years before present.

The geochemistry of the PHS supports the Lentz (1977) hypothesis of the PHS as a loess of continental origin. Thorium/scandium ratios in the PHS …

Geochemical Characteristics And Correlations Within The Triassic-Jurassic Age Gabbs And Sunrise Formations Of West Central Nevada, Karen Elizabeth Boelling

Dissertations and Theses

Trace and minor element geochemistry was determined using Instrumental Neutron Activation Analysis for ninety-six (96) limestone and calcareous siltstone samples from four stratigraphic sections in the Triassic-Jurassic age Gabbs and Sunrise formations of west central Nevada. Geochemical data support lithologic and faunal interpretations of relative basin positions of the Sunrise Formation stratigraphic sections, as well as basin development (including transgressive­-regressive sequences) during deposition of the Gabbs and Sunrise formations at New York Canyon (Gabbs Valley Range). All sections show characteristics of both oceanic and continental island arc sources. Rare positive Eu anomalies relative to chondrites suggest that the Gabbs Formation …

The Effects Of Organic Matter Rich Topsoil On The Germination Growth And Metal Uptake Of Corn (Zea Mays) Grown In Flue Dust Contaminated Soil, Christopher Allen Impellitteri

OES Theses and Dissertations

The large biomass of corn (Zea mays) and promising results from a previous experiment (Chlopecka and Adriano, 1995) concerning metal uptake by corn indicate that corn may be a good candidate for phytoremediation of trace metal contaminated soil. Appling soil (acid, thermic, typic paleudult) was treated with increasing levels of a metal rich flue dust based on Zn concentration (0, 150, 300, 600, 1200, and 2400 mg/kg). Four replicates at each Zn treatment level were either limed to pH 6.3-6.5 and covered with a two inch thick layer of organic matter rich topsoil (OM), unlimed and covered with …

Biostratigraphic Analysis Of Southern Florida's Plio-Pleistocene Shell Beds, Dalton L. Rasmussen

OES Theses and Dissertations

Four molluscan assemblage zones in southern Florida corresponding to the Pinecrest Sand Member of the Tamiami Formation, and the Caloosahatchee, Bermont and Fort Thompson shell beds were identified following quantitative and qualitative analyses of the fossil molluscan fauna. Twenty-eight bulk sediment samples collected from 16 localities across southern Florida were processed for fossil material, and yielded nearly 60,000 specimens belonging to 311 species. A Q-mode cluster analysis compared sediment samples on the basis of 188 species whose abundances had been converted to binary presence-absence form. The cluster analysis was run four times using the Jaccard and Dice similarity coefficients as …