Geochemistry Commons^™

Geogram 2004, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Lithium Abundance And Isotope Systematics Of Forearc Serpentinites, Conical Seamount, Mariana Forearc: Insights Into The Mechanics Of Slab-Mantle Exchange During Subduction, Laurie D. Benton, Jeffrey G. Ryan, Ivan P. Savov

Geology Faculty Publications

[1] Variable lithium contents and contrasting Li isotopic signatures are evident in the serpentininite muds and clasts extruded at Conical Seamount in the Mariana forearc. The muds have high Li contents compared to mantle values (3–7 ppm) and a mean δ7Li value of ∼+6‰. The clasts are generally lower in Li, and δ7Li varies from −6‰ to +10‰, with higher δ7Li correlating broadly to higher lithium contents. The diverse δ7Li in the serpentinite clasts suggests Li exchanges between mantle rocks and evolving slab‐derived fluids from different depths, producing a subarc mantle that is zoned in terms of Li abundances and …

Classifying Mollisol Soils Using Hyperspectral Remote Sensing Data, Adil M. Wadia

All-Inclusive List of Electronic Theses and Dissertations

Soil classification is a complex task that involves several factors. Soil classifications that have been published usually need to be updated as soil series definitions and boundaries change over time. Most existing soil classification surveys in the United States, although often very good, lack the required accuracy for selected applications such as precision agriculture. 111 Hyperspectral remote sensing data, with its 100+ bands and very high spectral resolution can help facilitate soil classification detail not achieved through traditional remote sensing methods. The study area selected for research was Wolf Field, near Homer, Champaign County, Illinois, which is a very agriculturally …

Anthropogenic Lead Deposition And Four National Parks In Poland As Determined By Lead Isotope Ratios, Shannon Simcoe

OES Theses and Dissertations

Polluted soils are recognized by having high concentrations of heavy metals, including Pb. Partitioning of metals in geochemical fractions, by sequential chemical extractions, may indicate whether a metal has been recently deposited in the soil. While concentration levels alone cannot distinguish between natural and anthropogenic Pb, studies have demonstrated that anthropogenic pollution is accurately recorded by specific Pb isotope signatures, which differ from natural Pb isotopes. The objective of this project was to use ²⁰⁶Pb/²⁰⁷Pb and ²⁰⁶Pb/²⁰⁴Pb isotope ratios to differentiate between the anthropogenic Pb input and the naturally occurring Pb in four national …

Sulfide Sulfur Concentration And Sulfur Isotopic Composition Of Methane Seep Sediments, V. Lynn Means, Walter S. Borowski

EKU Faculty and Staff Scholarship

No abstract provided.

Isotopic Concentration Of Sulfide Sulfur And Delta-34s From Methane Seeps On The Blake Ridge Diapir And Monterey Canyon, V. Lynn Means, Walter S. Borowski

EKU Faculty and Staff Scholarship

Marine sediments contain pore water with dissolved sulfate. Pore-water sulfate is depleted by two anaerobic chemical reactions tat involves microbes: 1) oxidation of sedimentary organic matter; and 2) anaerobic methane oxidation (AMO; CH₄ + SO₄ → HCO₃^- + HS^- + H₂O). Both sulfate depletion pathways produce dissolved hydrogen sulfide (∑HS^-), which is scavenged by dissolved iron to produce authigenic sulfide minerals. These minerals crystallize in pore spaces or on grain surfaces. Seafloor seeps are where methane moves upward in the sediments to escape into overlying waters. Additional methane supply should fuel …

Relating Water And Otolith Chemistry In Chesapeake Bay, And Their Potential To Identify Essential Seagrass Habitats For Juveniles Of An Estuarine-Dependent Fish, Spotted Seatrout (Cynoscion Nebulosus), Emmanis Dorval

Biological Sciences Theses & Dissertations

A quantitative understanding of habitat use of estuarine-dependent fishes is critical to the conservation of their most essential habitats. Because recruitment and fitness may be influenced by the quality of juvenile habitats, developing methods to quantify habitat-specific survivorship is pivotal to such understanding. An initial step to quantify survivorship is to validate the habitat-specific natural tags contained in otoliths. To this aim I investigated the variability in the chemistry of surface waters and otoliths of juvenile spotted seatrout, Cynoscion nebulosus, in five seagrass habitats of Chesapeake Bay, namely: Potomac, Rappahannock, York, Island, and Eastern Shore. I measured Mg, Ca, …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴ S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the effect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern United States) by extracting total sedimentary sulfide using chromium reduction. We use …

Changes In Sulfur Concentration And Sulfur Isotopic Composition Within Authigenic Sulfide Minerals From Sediments Of Miocene Age To The Present, Odp Site 995, Blake Ridge, Offshore Southeastern United States, Kathryn G. Takacs, Walter S. Borowski

EKU Faculty and Staff Scholarship

The Blake Ridge area (offshore southeastern United States) consists of deep-water continental margin sediments overlying deposits of methane gas hydrate. Authigenic sulfide minerals (elemental sulfur, S˚; iron monosulfides, ~FeS; and pyrite, FeS₂) are actively deposited in these sediments due to sulfate reduction and focused anaerobic methane oxidation (AMO) at the sulfate-methane interface (SMI). Sulfide minerals at the present SMI are enriched in ³⁴S relative to those produced by sulfate reduction of organic matter higher in the sulfate reduction zone. ³⁴S enrichments preserved in the sediment column may identify relatively high amounts of AMO and thus record …

Application Of Pyrolysis-Gc/Ms For Rapid Assessment Of Organic Contamination In Sediments From Barcelona Harbor, Michael A. Kruge, Albert Permanyer

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Pyrolysis-GC/MS is advantageous as a tool for rapid sediment contamination assessment because of the small sample size required, minimal sample preparation, and its ability to detect a wide variety of organic pollutants as well as naturally-occurring biological materials. Py-GC/MS was applied, together with determination of organic carbon, and major and minor element concentrations, to evaluate potentially contaminated sediments in the port of Barcelona (Spain) and the adjacent Llobregat River delta. Detected contaminant markers, most evident in the Old Port (Port Vell) area, included hopanes and alkylated PAHs (petroleum), sterenes (sewage), C₁₆-C₁₉ phenylalkanes (detergents) and parent …

Simulated Changes In Shallow Groundwater And Vegetation Distributions Under Different Reservoir Operations Scenarios, Mark Cable Rains, Jeffery F. Mount, Eric W. Larsen

Geology Faculty Publications

The objectives of this study were to develop and use a linked groundwater and vegetation model to simulate groundwater and vegetation distributions in a riverine and reservoir-fringe system under different reservoir operations scenarios. This study was conducted where Little Stony Creek flows into East Park Reservoir on the east front of the Coast Range, northern California. A numerical groundwater model was used to model mean depth to groundwater during the growing season for water years 1980–1999 for each of five community types identified on the study site. Multiple vegetation models were developed, each of which described the probability that a …

Potential Contaminants At A Dredged Spoil Placement Site, Charles City County, Virginia, As Revealed By Sequential Extraction, Jianwu Tang, G. Richard Whittecar, Karen H. Johannesson, W. Lee Daniels

OES Faculty Publications

Backfills of dredged sediments onto a former sand and gravel mine site in Charles City County, VA may have the potential to contaminate local groundwater. To evaluate the mobility of trace elements and to identify the potential contaminants from the dredged sediments, a sequential extraction scheme was used to partition trace elements associated with the sediments from the local aquifer and the dredged sediments into five fractions: exchangeable, acidic, reducible, oxidizable, and residual phases. Sequential extractions indicate that, for most of the trace elements examined, the residual phases account for the largest proportion of the total concentrations, and their total …

Mute Swans And Their Chesapeake Bay Habitats:Proceedings Of A Symposium, Matthew C. Perry

United States Geological Survey: Publications

The symposium “Mute Swans and their Chesapeake Bay Habitats,” held on June 7, 2001, provided a forum for biologists and managers to share research findings and management ideas concerning the exotic and invasive mute swan (Cygnus olor). This species has been increasing in population size and is considered by many to be a problem in regard to natural food resources in the Bay that are used by native waterfowl during the winter months. Other persons, however, feel that resource managers are attempting to create a problem to justify more killing of waterfowl by hunters. Some persons also believe …

Geochemical And Isotopic Characterization Of Shallow Basinal Brines From The Makgadikgadi Pans Complex, Northeastern Botswana: Determination Of The Sources Of Salinity, Loago N. Molwalefhe

Dissertations

Isotopes and chemical tracers have been used to constrain the sources and causes of salinity in shallow groundwater brine from the Makgadikgadi Basin, northeastern Botswana. The brine is massively rich in chloride and sodium, and moderately rich in carbonates, sulphate and potassium, and is distinctively poor in divalent cationic species. Various models that have been advanced to explain the origin of the brines include evaporative enrichment at the surface and density-induced infiltration, dissolution of evaporites, and trapped connate water.

This study presents the compositional variability and behaviors of ·the stable isotopes of carbon (S¹³C) and oxygen (S^{18 …}

Support For The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

This final report details the activities completed for Task 8 of the University and Community College System of Nevada (UCCSN) Cooperative Agreement with the US Department of Energy (DOE). Task 8, titled "Support for the Nye County Early Warning Drilling Program" provided for a variety of hydrochemical analyses. The requirements of the University and Community College System of Nevada (UCCSN) Quality Assurance (QA) Program were followed for all work performed on this task. The primary activity performed by the Harry Reid Center for Environmental Studies (HRC) for Task 8 was to provide hydrochemical analyses of the groundwater samples collected from …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the affect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern North America) by extracting total sedimentary sulfide using chromium reduction. We use …

Geogram 2003, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Dissolved Humic Substances: Characterization Of Their Sorption Onto Iron Hydroxide Aluminum Hydroxide Kaolinite And Smectite, Sarah E. Diebel

OES Theses and Dissertations

Humic (HA) and fulvic (FA) acids participate in many geochemical processes and the mechanisms of their sorption to colloidal surfaces are numerous, indicating these substances are complex and heterogeneous. The current study focuses on the interactions of the Fe hydroxide (FE), Al hydroxide, Kaolinite (KA) and Smectite (SM) and these naturally occurring organic acids using Fourier Transform Infrared Spectroscopy (FTIR) and DOC analysis at pH 4. FTIR was used for the initial functional group characterization, as well as the comparison of before and after adsorption spectra of the HA and FA. DOC examined the amounts of HA and FA adsorbed …

Exploring Links Between Physical And Probabilistic Models Of Volcanic Eruptions: The Soufriere Hills Volcano, Montserrat, Charles B. Connor, R. S. J. Sparks, R. M. Mason, Costanza Bonadonna, S. R. Young

Geology Faculty Publications

Probabilistic methods play an increasingly important role in volcanic hazards forecasts. Here we show that a probability distribution characterized by competing processes provides an excellent statistical fit (>99% confidence) to repose intervals between 75 vulcanian explosions of Soufrière Hills Volcano, Montserrat in September–October, 1997. The excellent fit is explained by a physical model in which there are competing processes operating in the upper volcano conduit on different time scales: pressurization due to rheological stiffening and gas exsolution, and depressurization due to development of permeability and gas escape. Our experience with the Soufrière Hills Volcano eruption sequence suggests that volcanic …

Hydrogeologic Principles Useful In Predicting The Effects Of Stream Flow Alterations On Shallow Groundwater And Associated Riparian Vegetation, Mark Cable Rains

Geology Faculty Publications

Numerous studies have shown that stream water and shallow groundwater are tightly linked in alluvial settings, and that changes in stream stage are propagated rapidly across alluvial aquifers (Castro and Hornberger 1991, Sophocleous 1991). Thus, many researchers have assumed that stream stages approximate water tables in alluvial aquifers (Auble et al. 1994, Stromberg and Patten 1996). This assumption is valid in some cases but invalid in other cases, particularly in arid basin terrain and more humid mountain terrain. Even when this assumption is valid, this relationship only implies correlation and not causation so the potential effects of stream flow alterations …

Melting Processes And Fluid And Sediment Transport Rates Along The Alaska-Aleutian Arc From An Integrated U-Th-Ra-Be Isotope Study, Rhiannon George, Simon Turner, Chris Hawkesworth, Julie Morris, Chris Nye, Jeffrey G. Ryan, Shu-Hui Zheng

Geology Faculty Publications

A comprehensive data set for young lavas erupted along the Alaska-Aleutian arc is used to examine how fluid and sediment transport rates and melting processes vary in response to systematic changes in subduction rate and dip along the arc and across the ocean-continent boundary. Positive correlations between convergence rate, volcano volume, and ²³⁸U excesses suggest that magmatic output is closely linked to the size of the fluid flux which occurred <10 kyr prior to eruption. Sediment-sensitive tracers like Th/Nb, Ce/Ce*, and ¹⁰Be/⁹Be also increase with convergence rate. However, the inferred ¹⁰Be/⁹Be ratio of this component is low relative to that in the incoming sediments, …

A Geochemical Survey Of The Natural Waters Of Belize, Central America, Anthony D. Marfia

Masters Theses

A geochemical survey of the natural waters in Belize, Central America was carried out to compliment routine water quality analysis and to identify processes affecting water quality. The objective of this research was to provide a geochemical assessment of natural waters throughout Belize by examining select major ions (Ca²⁺, Mg²⁺ , SO₄^2-), and stable isotopes of carbon (¹³C), oxygen (¹⁸O) and hydrogen (²H).

The dominant geology relevant to this investigation comprises a varied landscape of carbonates and elastic sediments in a subtropical rainforest/savannah climate. Stable oxygen and hydrogen …

Enrichments Of 34s In Sulfide Minerals Of Deep-Water Marine Sediments Of The Blake Ridge, Offshore Southeastern United States, Kathryn G. Takacs, Walter S. Borowski

EKU Faculty and Staff Scholarship

Past research shows that active sulfide mineralization occurs at the base of the sulfate reduction zone (SRZ) in modern, deep-water, continental-margin sediments that overlie methane gas hydrate. These sulfide minerals (elemental sulfur, Sº; iron monosulfides, ~FeS; and pyrite, FeS₂) are enriched in ³⁴S because of sulfate reduction and anaerobic methane oxidation (AMO) processes occurring above and near the sulfate-methane interface (SMI).

The data in this study show that 5 discrete zones of sulfide minerals are preserved in a 703.8-meter sediment column associated with methane gas hydrate. These zones of sulfide minerals are also enriched in ³⁴S. …

Energy‐Constrained Open‐System Magmatic Processes Iv: Geochemical, Thermal And Mass Consequences Of Energy‐Constrained Recharge, Assimilation And Fractional Crystallization (Ec‐Rafc), Wendy A. Bohrson, Frank J. Spera

All Faculty Scholarship for the College of the Sciences

A wealth of geochemical and petrological data provide evidence that the processes of fractional crystallization, assimilation, and magma recharge (replenishment) dominate the chemical signatures of many terrestrial igneous rocks. Previous work [Spera and Bohrson, 2001; Bohrson and Spera, 2001] has established the importance of integrating energy, species and mass conservation into simulations of complex magma chamber processes. An extended version of the energy‐constrained formulation, Energy‐Constrained Recharge, Assimilation, Fractional Crystallization (EC‐RAFC), tracks mass and compositional variations of melt, cumulates, and enclaves in a magma body undergoing simultaneous recharge, assimilation, and fractional crystallization [Spera and Bohrson, 2002]. …

Preliminary Investigations Of Seasonal Changes In The Geochemical Evolution Of The Logdson River, Mammoth Cave, Kentucky, Chris Groves, Darlene M. Anthony, Joe Meiman

Earth, Environmental, and Atmospheric Sciences Faculty Publications

Many geochemical studies have been made of karst waters worldwide. Most data that provide the framework for our current understanding of the evolution of karst waters have come from sampling at discrete times and locations, such as springs or wells. Relatively few studies have been made of the geochemical evolution of groundwater as it moves through an open flow system. This paper addresses the seasonal changes in the geochemistry of the Logsdon River conduit as it passes through nearly 10km of the carbonate aquifer of south-central Kentucky . The most important control on the ability of groundwaters to dissolve limestone …

Methods And Models For Estimating Advective Pore Water Exchange In Tidal Flats, Timothy J. Shaw

Faculty Publications

No abstract provided.

Rare-Earth Elements And Nd And Pb Isotopes As Source Indicators For Labrador Sea Clay-Size Sediments During Heinrich Event 2, Larry V. Benson, Don Barber, John T. Andrews, Howard E. Taylor, Paul Lamothe

United States Geological Survey: Staff Publications

Elemental abundances and Nd and Pb isotope ratios were determined on samples from the carbonate-free, clay-size fractions of sediments from intervals above, within, and below Heinrich event 2 (H-2) in core HU87-9 from the Northwest Labrador Sea slope. In HU87-9, rare-earth element (REE) distributions and elemental concentrations within the H-2 event are distinct from those outside this event. ɛ_Nd(0) and ²⁰⁶Pb/²⁰⁴Pb data also indicate different values for sediments deposited within and outside the H-2 event. Comparisons of REE patterns from the H-2 interval with those from bedrock units in Baffin Island, northern Quebec, and Labrador …

Energy‐Constrained Open‐System Magmatic Processes 3. Energy‐Constrained Recharge, Assimilation, And Fractional Crystallization (Ec‐Rafc), Frank J. Spera, Wendy A. Bohrson

All Faculty Scholarship for the College of the Sciences

Geochemical data for igneous rock suites provide conclusive evidence for the occurrence of open‐system processes within thermally and compositionally evolving magma bodies. The most significant processes include magma Recharge (with possible enclave formation and magma mixing), Assimilation of anatectic melt derived from wallrock partial melting and formation of cumulates by Fractional Crystallization (RAFC). In this study, we extend the Energetically Constrained Assimilation and Fractional Crystallization (EC‐AFC) model [Spera and Bohrson, 2001; Bohrson and Spera, 2001] to include the addition of compositionally and thermally distinct recharge melt during simultaneous assimilation and fractional crystallization. Energy‐Constrained Recharge, Assimilation, and Fractional …

Geoelectrical Response Of An Aged Lnapl Plume: Implications For Monitoring Natural Attenuation, Douglas D. Werkema Jr.

Dissertations

The geoelectric stratigraphy at a site impacted with light non-aqueous phase liquids (LNAPLs) is investigated for its link to natural biodegradation, its contribution to the conductive model for aged (i.e. mature) LNAPL contaminated sites, and the relationship to the natural hydrologic regime. The highest conductivities (lowest resistivities) were observed in portions o f soils where LNAPL was in residual and free phase. Corroborating evidence from bacteria enumeration from soil close to the vertical resistivity probe (VRP) installations show orders-of-magnitude increase in both heterotrophic and oil degrading microbes at the depths where the conductivity was at a maximum. The coincidence o …

Preliminary Geochemical Evaluation Of Groundwaters From Wells Of The Nye County Early Warning Drilling Program, Irene Farnham, Klaus J. Stetzenbach, Amy J. Smiecinski

Publications (YM)

As part of the Yucca Mountain Oversight program, the Nye County Nuclear Waste Repository Project Office (NWRPO) has established a groundwater monitoring program to protect groundwater resources for the residents of Nye County in Amargosa and Pahrump Valleys. This groundwater monitoring program, referred to as the Nye County Early Warning Drilling Program (NCEWDP), involves drilling a series of wells down-gradient from Yucca Mountain for long term groundwater monitoring and also to provide much needed geologic and hydrologic information in this area. A comprehensive database of aquifer parameters in the alluvial, volcanic, and carbonate aquifers down-gradient hydrogeologically of Yucca Mountain is …