Geochemistry Commons^™

Geochemical Modeling Of Solubility And Speciation Of Uranium, Neptunium, And Plutonium, Zhongbo Yu, Yuyu Lin, Karen Johannesson, Amy J. Smiecinski, Klaus J. Stetzenbach

Publications (YM)

The purpose of this study is to model the solubility, speciation, and transport of three actinides: uranium (U), neptunium (Np), and plutonium (Pu) by a geochemical modeling tool under possible repository environmental conditions upon waste package failure. The dissolution concentration of three actinides in the waste package, their aqueous speciation after dissolving in the unsaturated zone (UZ), and transport processes in the saturated zone (SZ) along the groundwater flow path at Yucca Mountain (YM) are simulated by geochemical modeling calculations using PHREEQC. This model report was prepared in fulfillment of Groundwater Characterization at Yucca Mountain, Task II: Surface Complexation and …

Seagrass-Mediated Carbonate Dissolution And Early Diagenesis In Bahamas Bank Sediments, Xinping Hu

OES Theses and Dissertations

This dissertation presents the results of studies examining the role that seagrasses play in carbonate dissolution and early diagenesis of Bahamas Bank sediments. Three aspects of this problem are addressed: (1) stable carbon isotopes as an indicator of early diagenesis of carbonates, using results of a field study; (2) carbonate dissolution stoichiometry and carbonate reprecipitation, using the results from closed-system sediment incubation studies; (3) carbonate dissolution and reprecipitation across the broader Bahamas Bank. In Chapter II, I examined δ¹³C in the dissolved inorganic carbon (DIC) of sediments with various degrees of seagrass densities. In low seagrass density and …

Sulfur Geochemistry And Diagenesis In A Gas Hydrate Terrane, Cascadia Margin, Offshore Oregon: Role Of Anaerobic Methane Oxidation, David Deigert, Walter S. Borowski

EKU Faculty and Staff Scholarship

We present sulfide mineral data from south Hydrate Ridge located in a gas hydrate terrane, offshore Oregon. Sulfide sulfur concentration and the isotopic composition of sulfur (d³⁴S) in authigenic sulfide minerals are analyzed from sediment samples collected on Ocean Drilling Project (ODP) Leg 204. Shallow sediment samples (<25 >mbsf) assess the relative importance of anaerobic methane oxidation (AMO) as a biogeochemical process, both here and at the Blake Ridge, another well known gas hydrate terrane offshore southeastern United States. Deep samples (>25 mbsf) are used to evaluate sulfur diagenesis and its controls from early Pleistocene to the …

High Crystallinity Si-Ferrihydrite: An Insight Into Its Neel Temperature And Size Dependence Of Magnetic Properties, Thelma S. Berquo, Subir K. Banerjee, Robert G. Ford, R. Lee Penn, Thomas Pichler

Geology Faculty Publications

Ferrihydrite, an antiferromagnetic iron oxyhydroxide with resulting magnetization due to uncompensated spins, is of great importance for the cycling of many trace metals in the environment. Four ferrihydrite samples prepared with 1.3 to 3.5 wt% of Si at different synthesis temperatures (7.5°C, 22°C, 50°C, and 75°C) were studied by temperature-dependent hysteresis loops, ZFC/FC susceptibility curves, ac susceptibility and Mössbauer spectroscopy. The incorporation of Si into the ferrihydrite during synthesis changed the properties of this mineral. Interestingly, seven sharp lines were observed in the X-ray diffraction pattern of the ferrihydrite samples prepared at 50°C and 75°C. In general, both XRD and …

Impact Of Anthropogenic Combustion Emissions On The Fractional Solubility Of Aeroosol Iron: Evidence From The Sargasso Sea, Peter N. Sedwick, Edward R. Sholkovitz, Thomas M. Church

OES Faculty Publications

We report empirical estimates of the fractional solubility of aerosol iron over the Sargasso Sea during periods characterized by high concentrations of Saharan dust (summer 2003) and by low concentrations of aerosols in North American/maritime North Atlantic air masses (spring 2004 and early summer 2004). We observed a strong inverse relationship between the operational solubility of aerosol iron (defined using a flow-through deionized-water leaching protocol) and the total concentration of aerosol iron, whereby the operational solubility of aerosol iron was elevated when total aerosol iron loadings were low. This relationship is consistent with source-dependent differences in the solubility characteristics of …

Interdecadal-Decadal Climate Variability From Multi-Coral Oxygen Isotope Records In The South Pacific Convergence Zone Region Since 1650ad, Peipei Zhang

Geology Theses and Dissertations

Annual average oxygen isotope (δ18O) time series from five coral cores collected from Fiji and Tonga are used to construct a Fiji-Tonga Interdecadal-Decadal Pacific Oscillation (F-TIDPO) index of low frequency (>9yr and <55yr) climate variability in this area back to 1650 A.D. Presently, both Fiji and Tonga are located in the South Pacific Convergence Zone (SPCZ) salinity front region where the Interdecadal Pacific Oscillation (IPO) variation is most pronounced. We first demonstrate the consistency between this F-T IDPO index and a MSL pressure-based SPCZ Position Index (SPI) (1891-2000), thus verifying the ability of coral δ18O to record past interdecadal-decadal climatic variations in this region back to 1891. The F-T IDPO index is then shown to be synchronous with the IPO index (1856-2000), suggesting that this coral-based index effectively represents the interdecadal-decadal scale climate variance back to 1650. The consistently anti-phase spectrums of the F-T five-coral composite and the interdecadal-decadal components in equatorial Pacific coral δ18O series from Maiana [Urban et al., 2000] and Palmyra [Cobb et al., 2001] suggest that the simultaneous eastern expansion (western contraction) of the eastern salinity front of Western Pacific Warm Pool (WPWP) occurs at the same time as the northeast (southwest) movement of the SPCZ during a positive IPO (negative IPO) phase.

Outcrop Analog For Lower Paleozoic Hydrothermal Dolomite Reservoirs, Mohawk Valley, Ny, Brian E. Slater

Geology Theses and Dissertations

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that they have undergone significant fault-related hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally an early Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A 3D ground penetrating radar survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or “sags” flanked by anticlines. The dolomite structures …

Concentrations Of Metals In Aquatic Invertebrates From The Ozark National Scenic Riverways, Missouri, Christopher J. Schmitt, William G. Brumbaugh, John M. Besser, Thomas W. May

United States Geological Survey: Publications

This report summarizes the findings of a study conducted as a pilot for part of a park-wide monitoring program being developed for the Ozark National Scenic Riverways (ONSR) of southeastern Missouri. The objective was to evaluate using crayfish (Orconectes spp.) and Asian clam (Corbicula fluminea) for monitoring concentrations of metals associated with lead-zinc mining. Lead-zinc mining presently (2007) occurs near the ONSR and additional mining has been proposed. Three composite samples of each type (crayfish and Asian clam), each comprising ten animals of approximately the same size, were collected during late summer and early fall of 2005 …

Late Cretaceous To Paleocene Metamorphism And Magmatism In The Funeral Mountains Metamorphic Core Complex, Death Valley, California, Chris G. Mattinson, Joseph P. Colgan, James R. Metcalf, Elizabeth L. Miller, Joseph L. Wooden

All Faculty Scholarship for the College of the Sciences

Amphibolite-facies Proterozoic metasedimentary rocks below the low-angle Cenozoic Boundary Canyon Detachment record deep crustal processes related to Mesozoic crustal thickening and subsequent extension. A 91.5 ± 1.4 Ma Th-Pb SHRIMP-RG (sensitive high-resolution ion microprobe–reverse geometry) monazite age from garnet-kyanite-staurolite schist constrains the age of prograde metamorphism in the lower plate. Between the Boundary Canyon Detachment and the structurally deeper, subparallel Monarch Spring fault, prograde metamorphic fabrics are overprinted by a pervasive greenschist-facies retrogression, high-strain subhorizontal mylonitic foliation, and a prominent WNW-ESE stretching lineation parallel to corrugations on the Boundary Canyon Detachment. Granitic pegmatite dikes are deformed, rotated into parallelism, and …

High- And Ultrahigh-Pressure Metamorphism In The North Qaidam And South Altyn Terranes, Western China, Chris G. Mattinson, C. A. Menold, Jian-Xin Zhang, D. K. Bird

All Faculty Scholarship for the College of the Sciences

The North Qaidam and South Altyn terranes extend approximately 1000 km across the northern Tibetan Plateau, and five localities preserve evidence of Early Paleozoic high-pressure (HP) or ultrahigh-pressure (UHP) metamorphism, including the presence of coesite, coesite pseudomorphs, and diamond. A review of the geology, petrology, and geochronology collected over the past 10 years since these localities were discovered supports a correlation of the North Qaidam and South Altyn terranes, offset 350-400 km across the Altyn Tagh fault. Geochronology interpreted to reflect eclogite-facies metamorphism yields ages between 500 and 420 Ma; detailed geochronology from one locality supports a protracted (tens of …

A Preliminary Study Of Sulfide Mineral Formation In Methane-Rich, Marine Sediments Associated With Anaerobic Methane Oxidation, Cascadia Continental Margin, Offshore Oregon, David Deigert, Walter S. Borowski

EKU Faculty and Staff Scholarship

Within gas hydrate settings, sulfide mineralization in marine sediments is likely controlled by two microbially-mediated, sulfate-depleting processes: anaerobic methane oxidation (AMO) and sulfate reduction. If large amounts of methane are delivered to the sulfate-methane interface (SMI), predominantly by diffusion, larger amounts of solid sulfide sulfur should occur there as dissolved sulfide combines with iron, forming an authigenic precipitate. We measure the amount of diagenetic sulfide sulfur at three locations in the Hydrate Ridge vicinity by extracting the bulk sedimentary sulfide-phase minerals (S^o, FeS, and FeS₂) through chromium reduction, precipitating sulfide sulfur as silver sulfide, and gravimetrically …

Geogram 2006, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Significance Of Polycyclic Aromatic Hydrocarbons (Pahs) And Petroleum Biomarker Compounds In Contaminated Passaic River Sediments, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lower Passaic River (northeastern New Jersey) flows through one of the most densely populated regions of the United States. The area’s long history of industrial activity is reflected in the complex and variable hydrocarbon composition of the river sediments. Sediments from river bottom grab samples at Newark and a 30 cm deep core at Kearny were subjected to thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). This technique offers a practical alternative for rapid, inexpensive analysis, simply employing milligram quantities of dry, disaggregated sediment, avoiding the use of hazardous organic solvents. For each sample, a total of 181 hydrocarbons and organosulfur compounds …

Data Report: Dissolved Sulfide Concentration And Sulfur Isotopic Composition Of Sulfide And Sulfate In Pore Waters, Odp Leg 204, Hydrate Ridge And Vicinity, Cascadia Margin, Offshore Oregon, Walter S. Borowski

EKU Faculty and Staff Scholarship

We report dissolved sulfide sulfur concentrations and the sulfur isotopic composition of dissolved sulfate and sulfide in pore waters from sediments collected during Ocean Drilling Program Leg 204. Porewater sulfate is depleted rapidly as the depth to the sulfate/methane interface (SMI) occurs between 4.5 and 11 meters below seafloor at flank and basin locations. Dissolved sulfide concentration reaches values as high as 11.3 mM in Hole 1251E. Otherwise, peak sulfide concentrations lie between 3.2 and 6.1 mM and occur immediately above the SMI. The sulfur isotopic composition of interstitial sulfate generally becomes enriched in 34 S with increasing sediment depth. …

Sinkhole Structure Imaging In Covered Karst Terrain, Sarah E. Kruse, M. Grasmueck, Matthew Weiss, D. Viggiano

Geology Faculty Publications

Ground penetrating radar (GPR) and resistivity techniques have been widely used to map the locations of sinkholes in covered karst terrain. To determine whether a sinkhole is a likely preferential conduit for groundwater flow, however, requires higher-resolution imaging than that used in conventional sinkhole mapping surveys. Field observations combined with simulated surveys for a 15-m diameter 3-m deep sinkhole in west-central Florida are used to assess the resolution of GPR and resistivity surveys targeting the semiconfining unit that floors the sinkhole depression. 2D resistivity surveys clearly show the central depression as well as resistivity contrasts between the cover sediments within …

The Impact Of Acid Mine Drainage On West Little Sugar Creek, Vigo Co., In, Jodie L. Gibson

All-Inclusive List of Electronic Theses and Dissertations

This study evaluates the degree and extent of contamination in West Little Sugar Creek by analyzing water chemistry in the stream during low and moderate flow conditions. West Little Sugar Creek is located in Vigo County, Indiana and has been severely impacted by AMD discharging from the abandoned Green Valley Mine site. Stream water is commonly acidic (as low as pH 2.4) with elevated concentrations of Fe and Al and elevated trace elements including Ni, Zn, Cu, Cd, Cr, Co, and others, many of which exceed local and/or national surface water quality standards. Amorphous Fe and Al precipitates also form …

Geochemistry Of Benthic Foraminifera As An Environmental Indicator: A Study From Multiple Hydrographic Regimes, Chandranath Basak

All-Inclusive List of Electronic Theses and Dissertations

The geochemistry (stable isotopes and Lracc clements) or living (sLaincd) calcareous benthic foraminifera was compared with ambient botlom water stable isotope values to provide modern analog conditions and calibrations for environmental and paleoenvironmental assessments. Stable isotope values of live (stained) bcnthic foraminifera were investigated from push core and multicorer samples from the North Pacific (on the Aleutian margin, water depth 1988m) and the South Australian Bight (water depth 2476m and 1634m). Living benthic foraminifera specimens collected from contaminated sites in the Venice Lagoon were analyzed for trace elements. Both the isotopic and the trace element study involved interpretation of modern …

A Preliminary Comparison Of The Sulfur Geochemistry Between Two Gas Hydrate Terranes, Michael D. Spicer, Walter S. Borowski

EKU Faculty and Staff Scholarship

We compare the authigenic sulfide mineral geochemistry of two, different gas hydrate terranes: the accretionary wedge of the Cascadia continental margin (offshore Oregon) and the passive margin of the Blake Ridge region (offshore southeastern US). We expect diagenetic processes effecting sulfide mineral formation (elemental sulfur, iron monosulfides, and pyrite) within these sediments to respond to differing geologic conditions at each setting. In both settings, methane diffuses upward from gas hydrates to the methane-sulfate interface (SMI), where it is consumed by reaction with sulfate during anaerobic methane oxidation (AMO). This microbially-mediated, diagenetic process produces an interstitial environment conducive to authigenic sulfide …

Results Of Chemical Analyses For Alcove 8/ Niche 3 Tracer Studies, Jeanette Daniels, Amy J. Smiecinski

Publications (YM)

This is the final report detailing the analyses performed under ORD-FY04-011 "Chemical Analyses for Alcove 8/Niche 3 Tracer Studies," The work was performed under The University and Community College System of Nevada (UCCSN) and the Department of Energy (DOE) Cooperative Agreement DE-FC28-04RW12232, This task provided method development and analytical support for the Alcove 8/Niche 3 Tracer Studies in the Exploratory Studies Facility (ESF). Concentrations of tracers as well as major anions and cations were reported for samples provided by Lawrence Berkeley National Laboratory (LBNL) and the US Geological Survey (USGS). Samples were analyzed using High Performance Liquid Chromatography (HPLC) and …

Guide To Participation For The Andrill Mcmurdo Ice Shelf Project, Andrill Science Management Office, Mcmurdo-Andrill Science Implementation Committee

ANDRILL Project Information

Purpose of This Document

This document is a guide to participation for science team members involved in the McMurdo Ice Shelf (MIS) Project of the ANDRILL Program. The document provides the following information: 1) An overview of the ANtarctic geologic DRILLing (ANDRILL) Program; 2) An overview of expected individual involvement in and commitment to the MIS Project; and 3) Logistical information most relevant to on-ice participants. Information provided in this document will be supplemented by the publication of the MIS Science and Logistics Implementation Plan (SLIP).The SLIP will be available to all MIS ANDRILL participants prior to commencement of drilling. …

Scientific Logistics Implementation Plan For The Andrill Mcmurdo Ice Shelf Project, Timothy R. Naish, Richard H. Levy, Ross D. Powell, Mis Science And Operations Team Members

ANDRILL Project Information

Summary

Response of Antarctic ice sheets to projected greenhouse warming of up to 5.8°C by the end of the century is unknown. Models on which predictions are based need to be constrained by geological proxy data from the ancient ice sheets during times when Earth is known to have been warmer than today. The marine-based West Antarctic Ice Sheet (WAIS) and its fringing ice shelves are hypothesized (Clark et al., 2002; Weaver et al., 2003; Stocker, 2003) and documented (Scherer et al., 1998) to have collapsed during past “super-interglacial” warm extremes when global sea-level was more than 5m higher than …

Origin Of Gabbroic Xenoliths Within The Lone Mountain Dacite Intrusion, Big Sky, Montana: A Field And Petrographic Analysis, Emily Clement

Undergraduate Review

No abstract provided.

The Sparrow Surface Water-Quality Model: Theory, Application And User Documentation, G. E. Schwarz, A. B. Hoos, R. B. Alexander, R. A. Smith

United States Geological Survey: Publications

SPARROW (SPAtially Referenced Regressions On Watershed attributes) is a watershed modeling technique for relating water-quality measurements made at a network of monitoring stations to attributes of the watersheds containing the stations. The core of the model consists of a nonlinear regression equation describing the non-conservative transport of contaminants from point and diffuse sources on land to rivers and through the stream and river network. The model predicts contaminant flux, concentration, and yield in streams and has been used to evaluate alternative hypotheses about the important contaminant sources and watershed properties that control transport over large spatial scales.

This report provides …

Field, Petrographic, And Geochemical Characteristics Of Price Creek, Russ Mccormack

Undergraduate Review

No abstract provided.

Western Caribbean Sea Surface Temperatures During The Late Quaternary, Matthew W. Schmidt, Maryline J. Vautravers, Howard J. Spero

OES Faculty Publications

[1] Mg/Ca ratios in the planktonic foraminifera Globigerinoides ruber from Colombian Basin core ODP 999A suggest that Caribbean sea surface temperatures ( SSTs) were from 2.1 to 2.7°C colder than the present during the last three glacial maximums. In comparison, faunal derived SSTs ( SIMMAX method) show that August SSTs in the Caribbean varied < 2° over the past 360 kyr, whereas February SSTs varied between 21.0°C and 26.5°C. Changes in the Mg/Ca-SST record contain a strong 23 kyr periodicity, suggesting the Mg/Ca-SST record reflects a warm season weighted SST average rather than an annual mean SST. Combining several dissolution indices, we identify brief periods of decreased carbonate preservation in our record and show that MIS 11 stands out as the most intensive dissolution cycle in the Caribbean over the last 460 kyr. Comparison of Caribbean SST change with a similar estimate of tropical SST variability in the western Pacific over the past 360 kyr reveals shifts in the east-west tropical SST gradient that are coeval with glacial-interglacial climate change and consistent both with a southward migration of the glacial ITCZ and with a glacial El Niño-like mode of tropical circulation.

Thermochronology And Provenance Of The Yakutat Terrane, Southern Alaska Based On Fission-Track And U/Pb Analysis Of Detrital Zircon, Stephanie Ellen Perry

Geology Theses and Dissertations

Northward transport of the Yakutat terrane along the Transition and Queen Charlotte-Fairweather transform faults led to Neogene collision of the Yakutat terrane with the southern continental Alaska margin. Northward translation resulted in a stratigraphy that records the erosion of thermotectonic terranes along its path. The strata of the Yakutat terrane includes the Lower Oligocene to Lower Eocene Kulthieth Formation, the Upper Eocene to Lower Miocene Poul Creek Formation and the Miocene-Pleistocene Yakataga Formation. Detrital zircon fission-track (DZFT) ages from stratigraphically coordinated samples collected in the Northern Robinson Mountains yield provenance information of the units that can shed light on their …

Assessing The Paleoceanographic Potential Of The Coral Montipora Venosa At Fanning Atoll, Central Equatorial Pacific, Alexa Stolorow

Geology Theses and Dissertations

As interest in global climate change increases, so does the need for better and more extensive climate proxies. The central equatorial Pacific has been established as the region with the largest ENSO-related sea surface temperature (SST) and precipitation (PPT) anomalies, which are known to impact global interannual climate variability. To date, the coral genus Porites has been most commonly utilized for coral-based paleo-reconstructions of ENSO and lower frequency phenomena. However, due to questions of biological artifacts in coral, to more fully understand coral-based reconstruction, different coral genera need to be analyzed.
In this study, oxygen (δ18O) and carbon (δ13C) isotopic …

The Effects Of Land Use Changes On Soil Carbon In The Russian Steppe, Andrew M. Ratigliano

Geology Theses and Dissertations

Increasing atmospheric CO2 levels within the past few centuries have led to many studies about the global carbon cycle. An important aspect in balancing the modern global carbon budget revolves around a missing sink of carbon. It is thought that the carbon accumulation in soil may be a significant component in this loss. As changes in land use under natural conditions have increased over the years, it is not well understood how these changes may affect the soil carbon. A useful technique in determining these changes are with the use of archived samples. Within a Russian steppe preserve that has …

Geochronology And Tectonic Significance Of Middle Proterozoic Granitic Orthogneiss, North Qaidam Hp/Uhp Terrane, Western China, Chris G. Mattinson, Joseph L. Wooden, Juhn G. Liou, D. K. Bird, C. L. Wu

All Faculty Scholarship for the College of the Sciences

Amphibolite-facies para- and orthogneisses near Dulan, in the southeast part of the North Qaidam terrane, enclose minor ultra-high pressure (UHP) eclogite and peridotite. Field relations and coesite inclusions in zircons from paragneiss suggest that felsic, mafic, and ultramafic rocks all experienced UHP metamorphism and a common amphibolite-facies retrogression. Ion microprobe U–Pb and REE analyses of zircons from two granitic orthogneisses indicate magmatic crystallization at 927 ± Ma and 921 ± 7 Ma. Zircon rims in one of these samples yield younger ages (397–618 Ma) compatible with partial zircon recrystallization during in-situ Ordovician-Silurian eclogite-facies metamorphism previously determined from eclogite and paragneiss …

The Earth All Around Us: Selected Building Stone In Lincoln, Nebraska. A Walking Tour, William J. Wayne

Department of Earth and Atmospheric Sciences: Faculty Publications

Stone has been a primary building material for millennia. Cities, therefore, are treasure troves of earth materials. A wide variety of stones from many places are used for walls, as foundations to support entire buildings, as trim, and more recently as cladding (facing, an overlay). The Earth science teacher can find, in the limited space of an urban environment, a superb collection of stones with which to introduce students to these materials. The surfaces of stones on the outsides of buildings illustrate the durability and the vulnerability of each kind of stone to the local climate. And the history of …