Geochemistry Commons^™

Bulk Rock Composition And Geochemistry Of Olivine-Hosted Melt Inclusions In The Grey Porri Tuff And Selected Lavas Of The Monte Dei Porri Volcano, Salina, Aeolian Islands, Southern Italy., Angela L. Doherty, Robert J. Bodnar, Benedetto De Vivo, Wendy A. Bohrson, Harvey E. Belkin, Antonia Messina, Robert J. Tracy

All Faculty Scholarship for the College of the Sciences

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical …

Reservoir Potential Of Sands Formed In Glaciomarine Environments: An Analog Study Based On Cenozoic Examples From Mcmurdo Sound, Antarctica, Christopher R. Fielding, Brian A. Blackstone, Tracy D. Frank, Zi Gui

Department of Earth and Atmospheric Sciences: Faculty Publications

This paper provides documentation of unexpectedly high-reservoir-quality glaciomarine sands found in the Cenozoic succession beneath McMurdo Sound, Antarctica, as an analogue study for evaluations of hydrocarbon prospectivity in basins elsewhere. The Oligocene to Lower Miocene succession of the Victoria Land Basin, an extant portion of the West Antarctic Rift System, comprises diamictites, mudrocks, and sandstones with minor conglomerates. These lithologies are arranged in repetitive stacking patterns (cycles), interpreted to record repeated advance and retreat of glaciers into and out of the basin, with attendant eustatic and isostatic effects. Phases of ice retreat within the cycles comprise an array of mudrocks, …

Surficial Redistribution Of Fallout 131iodine In A Small Temperate Catchment, Joshua D. Landis, Nathan T. Hamm, Carl E. Renshaw, W. Brian Dade, Francis J. Magilligan, John D. Gartner

Dartmouth Scholarship

Isotopes of iodine play significant environmental roles, including a limiting micronutrient (¹²⁷I), an acute radiotoxin (¹³¹I), and a geochemical tracer (¹²⁹I). But the cycling of iodine through terrestrial ecosystems is poorly understood, due to its complex environmental chemistry and low natural abundance. To better understand iodine transport and fate in a terrestrial ecosystem, we traced fallout ¹³¹iodine throughout a small temperate catchment following contamination by the 11 March 2011 failure of the Fukushima Daiichi nuclear power facility. We find that radioiodine fallout is actively and efficiently scavenged by the soil system, where it …

Size And Exhumation Rate Of Ultrahigh-Pressure Terranes Linked To Orogenic Stage, Andrew R.C. Kylander-Clark, Bradley R. Hacker, Chris G. Mattinson

All Faculty Scholarship for the College of the Sciences

A growing set of data indicates a stark contrast between the evolution of two types of ultrahigh-pressure (UHP) terranes: large terranes that evolved slowly (over 10–30 Myr), and small terranes that formed and were exhumed on timescales of < 10 Myr. Here we compare the characteristics – area, thickness, formation rate, exhumation rate, age, and tectonic setting – of these two endmember types of UHP terrane worldwide. We suggest that the two UHP terrane types may form during different orogenic stages because of variations in the buoyancy and traction forces due to different proportions of subducting crust and mantle lithosphere or to different rates of subduction. The initial stages of continent collision involve the subduction of thin continental crust or microcontinents, and thus tectonic forces are dominated by the density of the oceanic slab; subduction rates are rapid and subduction angles are initially steep. However, as collision matures, thicker and larger pieces of continental material are subducted, and the positive buoyancy of the down-going slab becomes more prominent; subduction angles become gentle and convergence slows. Assessing the validity of this hypothesis is critical to understanding the physical and chemical evolution of Earth's crust and mantle.

Included here is the post-print copy of this article. The final publication is available via ScienceDirect at http://www.sciencedirect.com/science/article/pii/S0012821X11007564

Geochemical And Strontium Isotope Characterization Of Produced Waters From Marcellus Shale Natural Gas Extraction, Elizabeth C. Chapman, Rosemary C. Capo, Brian W. Stewart, Carl S. Kirby, Richard W. Hammack, Karl T. Schroeder, Harry M. Edenborn

Faculty Journal Articles

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km …

Geochemical Classification Of Placer And Lode Gold Deposits Within The Northern Dome Rock Mountains Of The Quartzsite Mining District, Az, Christina Marie Lopez Velasquez

Theses Digitization Project

In this study the geochemistry and distribution of placer and lode gold deposits of the northern Dome Rock Mountains near Quartzsite, Arizona wre studied. The primary objectives of this study were to geochemically classify the placer and lode gold deposits of the Quartzsite Mining District, Arizona. Additional objectives were to determine estimates of the economic value and quantity of production of placer and lode gold deposits. Addressing the economic geology of placer gold deposits, the ultimate goal for this geochemical study is to determine the source(s) of the placer gold and determining the economic potential.

A Five-Year Analysis Of Carbon Stock Plots In The Gordon Natural Area’S Big Woods, Cathy Spahr, Chad Hudson, Andy Tamez

Forest Carbon Storage Study Documents

No abstract provided.

Geology Of National Parks Modules For The Spreadsheets Across The Curriculum Library, H. L. Vacher, Thomas C. Juster, Judy Mcllrath, Mark Rains

Geology Faculty Publications

No abstract provided.

Evolution With Depth From Detrital To Authigenic Smectites In Sediments From And-2a Drill Core (Mcmurdo Sound, Antarctica), Francesco Iacoviello, Giovanna Giorgetti, Fernando Nieto, Isabella Turbanti Memmi

ANDRILL Research and Publications

We have examined the nature and origin of smectites in glaciomarine sediments of the AND-2A drill core (McMurdo Sound, Antarctica) by means of X-ray diffraction (XRD) analyses on the clay fraction, field emission scanning electron microscopy (FESEM), scanning electron microscopy (SEM) observations and SEM-EDS microanalyses on smectite particles. Relying on the smectite variation throughout the drill core it was possible to split the sequence into three units. Smectites throughout the core are either detrital or authigenic. Detrital smectites are close to montmorillonite-beidellite in composition while newly-formed smectites frequently have higher Fe-Mg contents and intermediate compositions between the saponite and nontronite …

A New Phase Speciation Leaching Procedure For The Determination Of Metals In Oxic And Anoxic Sediments, Brandon R. Gipson

OES Theses and Dissertations

Toxic trace elements such as cadmium, lead, chromium, and arsenic released by human activities can accumulate in marine and estuarine sediments, where these metals are often sequestered until local environmental changes (e.g., redox, salinity, and/or pH) allow these elements to be reintroduced into the food web. In order to assess the extent of toxic trace element contamination in sediment, numerous leaching schemes have been developed that separate sediment-bound trace metals into operationally defined geochemical phases. These "phase speciation" leaching schemes are typically designed with the purpose of being used on either oxic or anoxic sediments. However, natural sediments often contain …

Identifying And Tracking Proteins Through The Marine Water Column: Insights Into The Inputs And Preservation Mechanisms Of Protein In Sediments, Eli K. Moore, Brook L. Nunn, David R. Goodlett, H. Rodger Harvey

OES Faculty Publications

Proteins generated during primary production represent an important fraction of marine organic nitrogen and carbon, and have the potential to provide organism-specific information in the environment. The Bering Sea is a highly productive system dominated by seasonal blooms and was used as a model system for algal proteins to be tracked through the water column and incorporated into detrital sedimentary material. Samples of suspended and sinking particles were collected at multiple depths along with surface sediments on the continental shelf and deeper basin of the Bering Sea. Modified standard proteomic preparations were used in conjunction with high pressure liquid chromatography-tandem …

Assessing Delta Oxygen-18 In The Coral Genus Isopora For Reconstructing Indo-Pacific Regional And Seasonal Climate, Gavin Lemley

Legacy Theses & Dissertations (2009 - 2024)

Paleoclimate reconstructions often utilize coral reefs with very long time spans such as the genus Porites and Diploastrea, because of their potential to provide centuries of continuous climate records via geochemical signatures. Smaller corals, such as the genus Isopora, have been essentially unexplored as climate archives because their small skeletons (<1 m) and short lifespans (years to decades) do not provide such continuous geochemical records. There has not been a practical application for such corals until recently. In early 2010, the Integrated Ocean Drilling Program Leg 325 (IODP-325) cored drowned fossil reefs off the Great Barrier Reef (GBR) with the objectives of reconstructing sea level and surface ocean conditions since the Last Glacial Maximum. Out of 213 massive fossil corals that were recovered, most were massive Isoporan colonies. A 30-specimen subset of these fossils range in age from ~32,000 to ~11,500 years before present with even temporal spacing, based on preliminary U/Th dating of core catcher samples. This age distribution is excellent for meeting IODP-325 objectives, but the suitability of Isopora for paleoclimate analyses remains unknown.

Assessing The Reproducibility Of Coral Oxygen And Carbon Isotope Time Series From Fiji And Tonga And Their Application To The Reconstruction Of South Pacific Convergence Zone Movements Since The Mid-1800s, Emilie Pauline Dassie

Legacy Theses & Dissertations (2009 - 2024)

A major feature affecting the hydrology of the southern hemisphere is the South Pacific Convergence Zone (SPCZ); a band of high rainfall extending southeastward from the Western Pacific Warm Pool (WPWP). It is a key source of atmospheric water vapor and latent heating. While it is clear that the SPCZ plays a fundamental role in Earth's climate, little is known about the patterns and mechanisms responsible for interannual to century-scale changes in its position and how it may respond to global climate change.

Assessment Of Coal Geology, Resources, And Reserves In The Montana Powder River Basin, Jon E. Haacke, David C. Scott, Lee M. Osmonson, James A. Luppens, Paul E. Pierce, Jay A. Gunderson

United States Geological Survey: Publications

The purpose of this report is to summarize geology, coal resources, and coal reserves in the Montana Powder River Basin (MTPRB) assessment area in southeastern Montana. This report represents the fourth assessment area within the Powder River Basin to be evaluated in the continuing U.S. Geological Survey regional coal assessment program.

There are four active coal mines in the MTPRB assessment area: the Spring Creek and Decker Mines, both near Decker; the Rosebud Mine, near Colstrip; and the Absaloka Mine, west of Colstrip. During 2011, coal production from these four mines totaled approximately 36 million short tons (MST). A fifth …

The Evolution Of Grenville Basement In The Eastern Great Smoky Mountains; Constraints From U-Pb Zircon Geochronology, Whole Rock Sm-Nd, And Feldspar Pb Geochemistry, Ryan Joel Quinn

Theses and Dissertations--Earth and Environmental Sciences

Identifying the crustal affinity of Grenville basement rocks in the Dellwood quadrangle, western NC, provides insight into the tectonic evolution of eastern Laurentia during Grenville orogenesis. U-Pb zircon geochronology of orthogneiss, augen gneiss, and mafic xenoliths in orthogneiss reveal magmatic pulses at 1130, 1180, and 1330 Ma and metamorphic episodes at 450 and 1040 Ma. Xenoliths in 1330 Ma orthogneiss are as old as 1382 Ma and represent the oldest component of Blue Ridge basement identified to-date. Feldspar Pb isotope values span a range between juvenile-Laurentian and southern-central Appalachian basement/Amazonia. Most Pb isotope data define an array consistent with crustal …

Isotope Geochemistry And Geochronology Of Lavas From The Line Islands Chain, Central Pacific Basin: Insight Into The Origin Of The Line Islands, Lauren Storm

Open Access Theses & Dissertations

Geochemical compositions of melts produced in the Earth's mantle provide key data for understanding Earth's internal structure. Particularly, the compositions of unusually large outpourings of basaltic lavas in large igneous provinces involve substantial source volumes, thereby contributing to our understanding of mantle structure and dynamics. Although the origin of such lavas remains enigmatic, geochemically they may originate from Earth's oldest and deepest mantle reservoir, transported by a mantle plume or by entrainment in passive upwelling beneath a fast spreading center. The Pacific Ocean basin hosts several large igneous provinces that formed near a triple junction of three oceanic plates, and …

Scientific Drilling Of Speleothems – A Technical Note, Christoph Spötl, David Mattey

International Journal of Speleology

This short article provides detailed descriptions of custom-made and commercially available hand-held drilling gear and options for water-flushing units specifically designed to obtained good-quality core material from speleothems even in remote cave regions. We use small-diameter (6-7 mm) diamond drill bits to obtain aliquots of calcite (as little as a few hundreds of milligram) from the interior of the basal part of in-situ stalagmites. These small cores are used to date the onset of stalagmite growth and occasionally to obtain other compositional information. Larger diameter drill bits produce cores 25-32 mm in diameter and up to 1.3 m in length …

Cora – A Dedicated Device For Carbon Dioxide Monitoring In Cave Environments, Marc Luetscher, Felix Ziegler

International Journal of Speleology

High resolution time-series of cave CO₂ fluctuations are increasingly demanded to quantify calcite precipitation processes. CORA, an energy-efficient NDIR-device, has been specifically developed for the long-term monitoring of carbon dioxide in remote cave environments. To allow comparison between different cave sites, changes in air pressure and temperature are compensated for using dedicated probes. Laboratory experiments demonstrate that CORA’s precision is adapted to the analysis of spatially and temporally variable CO₂ regimes and therefore suitable for a large number of applications. Data obtained with 12 independently calibrated instruments are reproducible within 3% (1σ). The two-point calibration function is validated …

Gypsum-Carbonate Speleothems From Cueva De Las Espadas (Naica Mine, Mexico): Mineralogy And Palaeohydrogeological Implications, Fernando Gázquez, Jose Maria Calaforra, Paolo Forti, Fernando Rull, Jesús Martínez-Frías

International Journal of Speleology

Some of the most outstanding hypogenic gypsum speleothems worldwide have been recently discovered in the Naica mines. The Cueva de las Espadas (Swords Cave), which lies at 120 m depth, hosts a rare type of speleothem called “espada” (“sword”). This study contributes to the understanding of the mineralogical composition of these singular speleothems, by means of their examination using micro-Raman spectroscopy, FT-IR spectroscopy and EDX microprobe. Our data revealed a complex mineralogy comprising a high-purity selenite core covered by several layers of calcite, aragonite and gypsum. Solid inclusions of polymetallic oxides (Mn-Pb-Zn) and graphite were also detected. The position of …

Petrographic And Isotopic Evidence For Late-Stage Processes In Sulfuric Acid Caves Of The Guadalupe Mountains, New Mexico, Usa, Margaret V. Palmer, Arthur N. Palmer

International Journal of Speleology

Caves of the Guadalupe Mountains have experienced many modifications since their final phase of sulfuric acid speleogenesis several million years ago. Petrographic and geochemical data reveal details of the change from H₂SO₄ to CO₂-dominated reactions. The H₂SO₄ dissolution front acquired a coating of replacement gypsum with local pockets of anhydrite and by-products of altered clay, including Fe-Mn oxides. Alteration of bedrock beneath the gypsum produced a white micritized rind with small negative shifts in δ¹³C and δ¹⁸O. Solution basins contain records of the earliest post-speleogenetic processes: corroded bedrock, …

Stable Isotope Analysis Of Busycon Sinistrum To Determine Fort Walton-Period Seasonality At St. Joseph Bay, Northwest Florida, Ryan Michael Harke

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Recent archaeological investigations indicate that coastal Fort Walton cultures in the St. Joseph Bay region of northwest Florida emphasized marine and estuarine foraging. These late prehistoric (A.D. 1000-1500) peoples collected fish, shellfish, and other aquatic resources. At the Richardson's Hammock site (8Gu10), radiocarbon-dated to about A.D. 1300, as at dozens of other shell middens around this salty bay, large gastropods were a major subsistence component. This adaptation is in sharp contrast with that of contemporaneous inland Fort Walton societies, who relied on maize agriculture. It is unknown whether coastal groups represent separate hunter-gatherer-fisher populations or seasonal migrations by inland …

Atr-Ftir Studies On The Kinetics Of Dimethylarsinic Acid (Dma) Surface Complexation With Iron(Oxyhydr)Oxides, Julia Tofan-Lazar Miss

Theses and Dissertations (Comprehensive)

Dimethylarsinic acid (DMA) is an organoarsenical compound that, along with monomethylarsonic acid, poses a health and an environmental risk, and a challenge to the energy industry. Little is known about the surface chemistry of DMA at the molecular level with materials relevant to geochemical environments and industrial sectors. The surface chemistry of phosphorus and arsenic compounds in their organic and inorganic forms is of great interest due to its role in controlling their transport, bioaccessibility and speciation. This thesis reports the first in-situ and surface-sensitive rapid kinetic studies on the adsorption and desorption of DMA to and from Fe-(oxyhydr)oxide films …

Mineralogy And Geochemistry Of Anorogenic Granitic Miarolitic Pegmatites Associated With The White Mountain Intrusive Suite, New Hampshire, Kristen F. Camp

LSU New Orleans Theses and Dissertations

Subvolcanically emplaced granitic, miarolitic pegmatites associated with the White Mountain Igneous Province (WMIP), New Hampshire, were sampled and analyzed using modern analytical techniques including X-ray fluorescence, electron microprobe, scanning electron microscopy, and direct-coupled plasma spectrophotometry. Analytical results suggest that all the sampled miarolitic pegmatites from this study are petrogenetically related to the same intrusive suite, the WMIP. Based on the geochemical data, all the samples formed in an anorogenic tectonic setting and are rift-related. They are classified as NYF-type and plot in the “within plate granite” field on tectonic discrimination diagrams. The majority of the samples are peraluminous, A_{1 …}

Paired Positive Carbonate Carbon Isotope, Organic Carbon Isotope, And Oxygen Isotope Composition Study Across The Lower Mississippian Positive Carbon Isotope Excursion, Southeastern Nevada, Usa, Robert Alan Henry

UNLV Theses, Dissertations, Professional Papers, and Capstones

A prominent positive carbonate carbon isotope (delta13Ccarb) excursion of Early Mississippian age (ca 351 Ma) has been documented by previous studies from numerous sites globally. This delta13Ccarb excursion has been interpreted as resulting from enhanced organic carbon burial that removed 13C-depleted carbon from the ocean and atmosphere. Anticipated outcomes from enhanced organic carbon burial would include a similar positive excursion in organic carbon isotopes (delta13Corg) and a global cooling event resulting from reduced CO2 in the atmosphere and ocean. These predictions, however, were not tested sufficiently in previous studies. This research has tested these predictions through an integrated study of …

Microstructural Characterization Of Kinked Germanate Olivine Grains, Alex Gregory Drue

UNLV Theses, Dissertations, Professional Papers, and Capstones

Olivine is the most common and the weakest mineral in the upper mantle. Thus the strength of olivine controls the rheology of the earth's upper mantle. The rheology of olivine in the upper mantle has important implications for mantle flow, mountain building, and rates of isostatic adjustment. Recent experimental measurements of the flow strength of deformed olivine polycrystals have assumed a homogeneous state of stress. X-ray synchrotron diffraction experiments have implied that this assumption is not always valid. Elastic Plastic Self Consistent (EPSC) modeling offers an approach to estimating the flow strength of olivine that does not assume a homogeneous …

Magma Chamber Processes At Mutnovsky Volcano, Russia, Kelly L. Robertson

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation is composed of two manuscripts about the evolution of Mutnovsky Volcano in Kamchatka, Russia. Mutnovsky has been active for the past approximately 80,000 years, during which there was the formation and subsequent eruption of four major stratocones. These four eruptive centers, named Mutnovsky I, II, III, and IV from oldest to youngest, have a range of erupted product compositions from basalt to dacite. The first major goal of this project was to investigate the melt source for Mutnovsky. Whole rock trace element and Nd, Sr, and Pb isotopic data were used to determine that the melt source was …

Spatial And Temporal Variations In The Air-Sea Carbon Dioxide Fluxes Of Florida Bay, Christopher Michael Dufore

USF Tampa Graduate Theses and Dissertations

The flux of CO2 between the ocean and the atmosphere is an important measure in determining local, global, and regional, as well as short term and long term carbon budgets. In this study, air-sea CO2 fluxes measured using a floating chamber were used to examine the spatial and temporal variability of CO2 fluxes in Florida Bay. Measurements of dissolved inorganic carbon and total alkalinity obtained concurrently with chamber measurements of CO2 flux allowed calculation of ΔpCO2 from flux measurements obtained at zero wind velocity. Floating chamber measurements of ΔpCO2 were subsequently coupled with wind speed data to provide a simple …

Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott

Publications and Research

Test boring associated with the recently accomplished City Water Tunnel # 3 in Manhattan, New York City revealed moderately to highly weathered marble with insoluble silicate residues composed mostly of phlogopite, chlorite, and tremolite. Apparent control on the weatherability of the marble was in response to original mineral constituents dominating this lithology. Encountered marble samples ranged between pure calcitic to mixed dolomitic/siliceous types. Fresh marble samples collected from adjacent boring locations revealed characteristic geochemical data: Lime (25-45%), Silica (4-7%), Alumina (1-3%), MgO (5-20%), and LOI (35-42%); compressive strength of unweathered marble varied between 2000-3000 Kg/cm². Relict foliations with …

Geogram 2011, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Mobile Technology As A Tool For Enhancing Student Learning In Geosciences, Sam Matson

Mobile Learning Symposium

Incorporation of mobile technology into the post-secondary classroom is becoming increasingly common as universities seek to facilitate active, student-centered learning through rapid access to information, connect students with course content through social media, and evaluate digital alternatives to conventional instructor-student interaction. The m-Learning Scholars Program at Boise State University was initiated during the 2010 – 2011 academic year, and provides a venue for exploring the potential of mobile technology to enhance student learning in the geosciences. Through this program, 38 students in an introductory Earth History course for non-geoscience majors each purchased a subsidized handheld device (iPod touch) that they …