Transport Phenomena Commons^™

Using Computational Fluid Dynamics And Optical Sensor Technology To Scale Cell Culture Platforms, Mandar Makwana

KGI Theses and Dissertations

Different cell culture vessels ranging from micro scale to laboratory scale to commercial scale play critical role in upstream process development for biologics manufacturing. Based on the mode of operation, cell culture vessels have different hydrodynamic environments, making it challenging to scale. Integrated approaches using computational tools supported by experimental studies can overcome these challenges. Computational Fluid Dynamics (CFD) is one such tool that can simulate hydrodynamics within the cell culture vessels and can provide insights at macro and micro-scale. Accuracy of a CFD model significantly depends on the fluid model and assumptions. Traditionally, simple two-equation fluid models were developed …

Effects Of Confinement On Ionic Liquids And Deep Eutectic Solvents For The Design Of Catalytic Systems, Electrochemical Devices, And Separations, Andrew Drake

Theses and Dissertations--Chemical and Materials Engineering

Confinement of ionic liquids (ILs) and deep eutectic solvents (DESs) within mesoporous materials such as silica helps to control the local environment within the pores for applications such as catalysis, electrochemistry, and absorption. Silica thin films with 2.5 and 8 nm pores and micron-sized silica particles with pore diameters of 5.4 and 9 nm were synthesized to study the effect of nanoconfinement on ILs 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF₆]), 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]), and DESs reline and ethaline (choline chloride and urea or ethylene glycol). Silica thin films with vertically aligned, well ordered, and accessible pores were synthesized via the evaporation-induced …

Attrition Study Of Copper-Supplemented Iron-Based Oxygen Carrier For Chemical Looping Combustion, Neng Huang

Theses and Dissertations--Mechanical and Aerospace Engineering

Chemical looping combustion (CLC) is a promising technology that can mitigate the carbon emissions for power generation. The cost of oxygen carriers (OCs) impedes the scale up of CLC. Compared to synthetic iron-based OCs, red mud (RM), an abundant iron-based solid waste from industry, is a cost-effective choice due to its intrinsic inclusion of both inert and catalytic phases that are crucial for CLC. It was anticipated that the addition of copper oxide to RM using a mechanical mixing method that can be easily scaled up would enhance both reactivity and oxygen transport capacity (OTC), and the heat of reaction …

Impact Of Spallation And Internal Radiation On Fibrous Ablative Materials, Raghava Sai Chaitanya Davuluri

Theses and Dissertations--Mechanical and Aerospace Engineering

Space vehicles are equipped with Thermal Protection Systems (TPS) that encounter high heat rates and protect the payload while entering a planetary atmosphere. For most missions that interest NASA, ablative materials are used as TPS. These materials undergo several mass and energy transfer mechanisms to absorb intense heat. The size and construction of the TPS are based on the composition of the planetary atmosphere and the impact of various ablative mechanisms on the flow field and the material. Therefore, it is essential to quantify the rates of different ablative phenomena to model TPS accurately. In this work, the impact of …

Temperature-Dependent Diffusion In Block Copolymer Organogels, Ridwana Bashar

Master’s Theses

Organogels are often considered for transport-based applications such as transdermal drug delivery vehicles and gel actuators due to their unique properties. Recent consideration of styrenic block copolymer based organogels’ application in transdermal drug delivery requires an extensive investigation of drug diffusion behavior through these gels to assess their applicability. Temperature is a major influencing parameter on diffusion. The goal of this research is to better understand the impact of temperature on diffusion in styrenic triblock copolymer organogels. To accomplish this goal, we focused on three specific objectives: (i) accurately measure the diffusivities of a solute – AOT reverse micelles – …

Hydro Cyclonic Separation Of Polyester Microfibers From Washing Machine Wastewater, Joe Kulkarni

Dissertations, Master's Theses and Master's Reports

Clothing made from synthetic materials shed fibers in washing machines, and these fibers find their way into the effluent water. These fibers can absorb toxic materials in wastewater treatment plants and can then carry these toxins into other aquatic environments.

It’s believed that a hydro cyclone could be scaled down enough to fit into a washing machine and could be used to filter out up to 80% of the microparticles from the effluent water. It’s proposed to investigate if a hydro cyclone can be used for this application. The overall goal was for the hydro cyclone to concentrate the micro …

Techno-Economic Analysis And Optimization Of Hydrogen And Mechanical Energy Storage Systems, Pavitra Senthamilselvan Sengalani

Graduate Theses, Dissertations, and Problem Reports (ETD)

The increasing significance of renewable energy sources is thrusting the load cycling of fossil-fueled power plants (FFPP), designed to operate under nominal-load conditions. Integration of energy storage systems (ESS) with the FFPPs such as hydrogen energy storage (HES) and mechanical energy storage facility such as compressed air energy storage (CAES) shows the potential to minimize the levelized cost of electricity during high demand scenarios and also minimize the negative impacts of off-design FFPP operation. The deployment of energy storage facilities at the FFPP level have considerable potential advantages as they can be exploited within the existing equipment items and facilities …

The Effect Of Different Fracturing Fluids On The Productivity Of Multi-Staged Fractured Marcellus Shale Horizontal Wells, Vida Gyaubea Matey-Korley

Graduate Theses, Dissertations, and Problem Reports (ETD)

While hydraulic fracturing has undeniably improved the production from oil and gas reservoirs, this technology is not without limitations. The primary hurdles lie in the areas of proppant transport, fluid rheology, and stress management. Despite the extensive research conducted in this domain, there remains a considerable amount of work to be done for comprehensive solutions that account for the complex interactions among fracturing fluid, proppant distribution, and geomechanical conditions. Achieving this will then make room for a holistic and efficient hydraulic fracturing strategy.

This study addresses the above-mentioned problem by examining the impact of fluid type on proppant transport and …

Molecular Understanding Of Zwitterions And Quantum Computing For Sustainability, Manh Tien Nguyen

Theses and Dissertations--Chemical and Materials Engineering

The sustainable development of society needs sustainable energy solutions and the mitigation of greenhouse gas emissions. One key subject in this area is the development of safe and efficient ion-based batteries. Moreover, CO₂ capture is a crucial pathway in mitigating emissions from the combustion of fossil fuels. Ongoing efforts are to improve both technologies' safety and efficiency. This thesis presents our efforts to conduct computational research on understanding advanced zwitterionic electrolytes and CO₂ capture. Chapters 2-4 illustrate the computational research to understand ionic solvation in zwitterionic electrolytes. Solid-state electrolytes are essential for safer batteries. While solid polymer electrolytes …

Mechanisms Of Emulsion Destabilization: An Investigation Of Surfactant, Stabilizer, And Detergent Based Formulations Using Diffusing Wave Spectroscopy, Jordan N. Nowaczyk

Theses and Dissertations

Conventional approaches for studying emulsions, such as microscopy and macroscopic phase tracking, present challenges when it comes to establishing detailed mechanistic descriptions of the impact of emulsifier and stabilizer additives. Additionally, while a combination of sizing methods and macroscopic phase tracking can provide insights into droplet size changes and concentration, the use of multiple measurements can be cumbersome and error-prone. It is the focus of this work, to present a new method for studying water in oil (W/O) emulsions that involves using diffusing wave spectroscopy (DWS) to examine the impact of three different surface stabilizing additives at varying concentrations. By …

Scale Modeling Of An Appearance Of Downwash Pattern Of Hot Smoke Ejected From Chimney In The Turbulent Cross Flow, Xangpheuak Inthavideth, Nobumasa Sekishita, Sounthisack Phommachanh, Yuji Nakamura

Progress in Scale Modeling, an International Journal

This study aims to elucidate the scaling law to provide the critical condition on appearance of the downwash pattern of the hot smoke ejected from a chimney in a turbulent cross flow. A specially designed wind tunnel with an active turbulence generator developed by Makita was adopted to offer a quasi-isotropic turbulence field in a lab-scale test facility. A heated jet with smoke is issued into the cross flow from the vertically oriented chimney placed in the test section of the wind tunnel. In this study, the experimental parameters considered are temperature of the heated jet (smoke), jet ejected velocity, …

Method For Routine Density Measurement Of Sublimating Solid Carbon Dioxide (Dry Ice) For Cold-Chain Quality Control, Kimberly Hafner, Bruce A. Welt, William Pelletier

Journal of Applied Packaging Research

With recent development of vaccines and biologics, interest in dry ice for cold chain shipping has increased. However, understanding of how dry ice properties relate to performance is not well understood. This study introduces a simple method for measuring a key property of dry ice that has been shown to correlate to performance. The method involves a variant of the water displacement method for determining volume, where dense solid particles are used in place of water for volume determination. Three particle types (sieved sand, glass beads, and stainless-steel shot) were tested for suitability with the particle displacement method. Items of …

Electric Field Driven Co-Assembly And Transport Of Colloids Using Active-Passive Interaction, Brishty Deb Choudhury

LSU Master's Theses

Over the past few decades, the out-of-equilibrium transport and assembly of colloidal particles have been drawing significant interest due to their myriad applications in biology, engineering, and physics. In the absence of any external force, micro and nanoparticles perform Brownian motion in dispersion and are termed as passive colloids. In contrast, active colloids are a class of particles where a net imbalance of fluid flow around their surface drives their net migration in space when subjected to an external electric field. While several studies have shown the ability to program the dynamics of active colloids using an external electric field, …

Free Convection Heat Transfer From Plates, Alexa Moreno

Chemical Engineering Undergraduate Honors Theses

The purpose of this honors thesis is to create an experiment for the CHEG Lab I course. This report explains the motivation for creating this heat convection experiment, the results of performing the experiment, and provides recommendations for future work on this experiment. Multiple experiments were performed to assess materials and parameters to be investigated. It was determined that a 0.5” plate has smaller percent error and accommodates for the desired timeframe for a Lab I experiment compared to the first plate used (1.5” thickness). Recommendations for expanding on this project include adding experiments using vertical geometry for heat convection …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Diffusion Of A Salt In An Aqueous Media, Aldaly Pineda Hernandez

Chemical Engineering Undergraduate Honors Theses

Diffusion is defined as the net transfer of a molecule from a high concentration region to a low concentration region. The concept of diffusion is used in a very important process called "desalination." Desalination is a separation process used to reduce the salt content dissolved in brackish water to make it suitable for human consumption, irrigation, and industrial use.

In desalination plants, it is important to monitor the constantly changing salt content of water, partly due to the diffusive effect. The main purpose of this experiment was to study the diffusion of NaCl in water at two NaCl concentrations. The …

Structural, Charge Transport, Gas Sensing, Magnetic, Pseudocapacitive, And Electrocatalytic Properties Of Perovskite Oxides., Surendra Bahadur Karki

Electronic Theses and Dissertations

Perovskites are functional materials with the general formula ABO₃ (A = alkali, alkaline earth or lanthanoid cations and B = transition metal or main group cations). These materials are marked by a variety of crystal structures and interesting properties such as colossal magnetoresistance, ferroelectricity, multiferroicity, superconductivity, pseudocapacitance, gas sensing, charge transport, and electrocatalytic properties. The formula of perovskite can be written as AA’BB’O₆, when there is ordering between two cations over A and B-sites. Such compounds are called double perovskite oxides. Some amount of oxygen could be lost from crystal structure without decomposition of the phase. Such …

Development & Validation Of A Piv System For Obtaining Data From A Uasb Reactor, Camila D' Bastiani, Gerald Gallagher, David Kennedy, Anthony Reynolds

Conference Papers

Anaerobic digestion processes can generate energy in the form of biogas while treating organic wastewater. The efficiency of the treatment, and thus the generation of biogas, is closely linked to the type and design of the reactor, and the technology used. Granular anaerobic digestion technology offers advantages such as a higher loading rate and reduction of the space needed. However, the hydrodynamics inside this type of reactor can be complex due to the presence of solids (granules) and gas (biogas) phases along with the liquid phase (wastewater). This is one of the reasons why the study and optimization of reactors …

Tuning Electrochemical Interactions And Polymer Electrolyte Interfaces For Enhanced Organic Acid Separations Using Electrodeionization, Matthew Leo Jordan

LSU Doctoral Dissertations

Chemical separations are critical processes for chemical and industrial plants to purify and isolate products however current separation technologies, such as distillation, rely on energy intensive processes. Electrochemical separation processes, such as electrodialysis and electrodeionization, are an energy efficient alternative that are emerging as an alternative for thermal-based separations. Organic acids are weakly ionizable species and susceptible for purification from process streams using electrochemical processes. Recently the fermentation route has garnered greater attention as a means for producing value-added chemicals, such as organic acids, from a renewable feedstock and aiding the circular economy. Some of the challenges electrodialysis faces for …

Design And Analysis Of Marangoni-Driven Robotic Surfers, Mitchel L. Timm

Dissertations, Master's Theses and Master's Reports

We designed and experimentally studied the dynamics of two robotic systems that surf along the water-air interface. The robots were self-propelled by means of creating and maintaining a surface tension gradient resulting from an asymmetric release of isopropyl alcohol (IPA). The imbalance in the distribution of surface tension surrounding the robots generates a propulsive force commonly referred to as Marangoni propulsion. First, we considered a single surfer, which was custom-made with novel control mechanisms that allow for both forward motion and steering to be remotely adjusted solely through the manipulation of local surface stresses. We analyzed the performance of this …

Development Of Advanced Models For Pre-Ignition Prediction In Gas Engines And Analytical Model For Wallfilm Evaporation, Ankith Ullal

Dissertations, Master's Theses and Master's Reports

Ever-changing regulations aimed at improving efficiency and reducing harmful emissions have resulted in many power-generation device (engine) manufacturers to adopt new strategies. Computer simulation of these new strategies of power generation requires more accurate and higher fidelity modelling tools. In the present study, two such models are developed. The first model deals with pre-ignition phenomena driven by lubricant (lube) oil in natural gas engines and the second model is relevant to prediction of wallfilm evaporation by employing analytical solutions to transport governing equations for boundary layers.

Pre-ignition in engines has been the subject of current research with the advent of …

Fundamentals Of Microgel Flooding And Nanoparticles-Stabilized Foams In Enhanced Oil Recovery, Shuaijun Li

Dissertations and Theses

For centuries oil has remained a critical energy source for human civilization. After years of extraction, many oil fields have reached or are reaching a decline stage of production, even though up to a half of the total crude oil reserves in these fields has not been recovered yet. One reason is due to the structural heterogeneity of the oil reservoirs—reservoirs may consist of regions of higher permeability with larger pore size and regions of lower permeability with smaller pore size. Displacing fluids tend to flow through large permeability zones only without reaching the oil trapped in low permeability region; …

Droplets In An Electric Field: Surface Rheology, Coalescence And Rebound, Yu Han

Dissertations and Theses

Electrocoalescence is the process in which pairs of conducting droplets suspended in a continuous dielectric (nonconducting) liquid phase are drawn together and merge upon the application of an electric field. The electric field polarizes each of the droplets in the field direction. The polarization causes the drops to deform and drives a dipolar attraction which forces them to approach each other and coalesce. Many technologies use electric fields to manipulate fluid dispersions. Electrocoalescence is an essential unit operation for separating water droplets in a crude oil. This water in oil emulsion is stabilized by surfactants, such as asphaltenes, resins and …

Design And Control Of Intensified Membrane Reactor Systems Through Module-Based Design Approach, Brent Bishop

Graduate Theses, Dissertations, and Problem Reports (ETD)

As interest in the modularization and intensification of chemical processes continues to grow, more research must be directed towards the modeling and analysis of intensified process units. Intensified process units such as membrane reactors pose unique challenges pertaining to design and operation that have not been fully addressed in the reported literature. This work aims to address the design and control challenges caused by the integration of phenomena and the loss of degrees of freedom (DOF) that occur in the intensification of modular membrane reactor units.

First, a novel first-principles approach for modeling membrane reactors is developed using the AVEVA …

Advanced Process Modeling And Optimization Of Amine-Based Carbon Capture Process, Paul Jide Terhemba Akula

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the rise of carbondioxide (CO2) concentration in the atmosphere to more than 400 parts per million (ppm), research efforts have been focused on achieving net-zero carbon emission technologies. Post-combustion CO2 capture (PCC) is a key strategy in reducing CO2 emissions. Amine-based CO2 capture is the baseline technology for retrofitting existing power stations. However, the integration of amine-based PCC technology with power plants to reduce greenhouse gas emissions incurs a high energy penalty, decreasing a powerplant’s efficiency by about 23 percentage points. Understanding the capture plant dynamics plays an important role in its technical and economic performance. Rigorous models are …

Numerical Investigation On The Effect Of Spectral Radiative Heat Transfer Within An Ablative Material, Raghava S. C. Davuluri, Rui Fu, Kaveh A. Tagavi, Alexandre Martin

Mechanical Engineering Faculty Publications

The spectral radiative heat flux could impact the material response. In order to evaluate it, a coupling scheme between KATS - MR and P1 approximation model of radiation transfer equation (RTE) is constructed and used. A Band model is developed that divides the spectral domain into small bands of unequal widths. Two verification studies are conducted: one by comparing the simulation computed by the Band model with pure conduction results and the other by comparing with similar models of RTE. The comparative results from the verification studies indicate that the Band model is computationally efficient and can be used to …

Water Recovery From Bioreactor Mixed Liquors Using Forward Osmosis With Polyelectrolyte Draw Solutions, Calen Raulerson

All Theses

The objective of this research was to test the feasibility of using forward osmosis (FO) with polyelectrolyte draw solutions to recover water from bioreactor mixed liquors. When combined with an Anaerobic Osmotic Membrane Bioreactor (AnOMBR), such a system could process fecal and food waste from astronauts aboard the International Space Station (ISS) and reclaim important nutrients and water. This project focused on measuring the obtainable water recovery rates from bioreactor effluent, and the identifying challenges associated with the operation.

AnOMBRs feature several advantages over aerobic bioreactors, and non-osmotic anaerobic membrane bioreactors (AnMBR). Anaerobic bioreactors avoid the significant energy costs of …

Towards Long Term Colloid Suspension In A Vertically Rotated System., Md Mahmudur Rahman

Electronic Theses and Dissertations

Within a colloidal suspension gravity may compromise the observation of governing physical interactions, especially those that are weak and/or take significant time to develop. Conducting the experiment in a long-term microgravity environment is a viable option to negate gravitational effects, though significant resources are required to do so. While it may not be possible to simulate long-term microgravity terrestrially, particles can resist quick sedimentation in a confined suspension system rotating vertically with appropriate rotation speed. The goal of the investigation is to demonstrate the existence of long-term particle suspension regime for a certain colloidal suspension while characterizing colloidal behavior due …

Preliminary Development Of The Dialysis-Membrane-Based Passive Biocide Delivery System For Spacecraft Water Recovery Units, Rogelio Elias Garcia Fernandez

Graduate Theses and Dissertations

The purpose of this investigation is to explore the capabilities of a dialysis-membrane-based system for the in-line dosing of silver ions to treated water in spacecraft water recovery units. The spacecraft environmental control and life support system community (ECLSS) are interested in adopting silver ions as a biocide in future spacecraft water recovery processes since silver ions are effective biocide at concentrations that humans can safely consume. The system has been designed following the configuration of the Water Processor Assembly (WPA) aboard the International Space Station. In this configuration, silver ions have to be added at the last step in …

Cfd Simulations Of Macroscopic And Microscopic Multiphase Fluid Flow And Droplet Interaction, Aaron Harrington

LSU Master's Theses

Multiphase flow is a complex phenomenon which can be modeled on numerous different length scales, both macroscopically and microscopically. The use of a Euler-Euler model for Computation Fluid Dynamics (CFD) simulations of subcooled boiling phenomena is discussed in detail. The CFD conditions have been set up to mimic previous experimental conditions. A cylindrical vessel with subcooled liquid flow is heated along part of the axial wall of the vessel. A constant heat flux is applied to produce subcooled boiling. We discuss the development of the phase change within the vessel as well as the temperature profile, and validate the results …