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Articles 1 - 4 of 4
Full-Text Articles in Transport Phenomena
Sulfonated Ionomer Composite Membranes For Use In Vanadium Redox Flow Batteries, Xueting Wang
Sulfonated Ionomer Composite Membranes For Use In Vanadium Redox Flow Batteries, Xueting Wang
All Dissertations
While vanadium redox flow batteries (VRFBs) have garnered significant attention as a promising scalable energy storage technology, the current membrane material used in this technology, Nafion™, suffers from high cross mixing of vanadium ions in the liquid electrolytes, directly impacting battery performance properties such as the voltage and coulombic efficiencies, as well as resulting in a reduction in the overall battery lifetime. The use of ionomer nancomposites has proven to be one promising route of directly addressing the issue of high ion crossover, though the mechanism by which the nanoparticles act to reduce crossover remains in open question. Herein, the …
A Comparison Of Fiber Mat Thickness Measurement Techniques Using Laser Interferometry And Water Displacement, Ryan Seabeck
A Comparison Of Fiber Mat Thickness Measurement Techniques Using Laser Interferometry And Water Displacement, Ryan Seabeck
Williams Honors College, Honors Research Projects
Polymer fiber mats may often be very thin which leads to complications in measuring thickness. The thickness of fiber mats, however, is crucial in understanding their behavior. Thickness affects how well the mat works as a filter as well as the pressure drop across the mat, and herein lies the need for accurate measurement techniques. Currently two of the available techniques for measuring mat thickness are by laser interferometry[1] and by buoyancy force when submerged in water[2]. Instead of measuring the buoyancy force in this experiment, an enclosure intended to measure the thickness via water displacement was …
A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra
A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra
Articles
Soft condensed matter (SCM) physics has recently gained importance for a large class of engineering materials. The treatment of food materials from a soft matter perspective, however, is only at the surface and is gaining importance for understanding the complex phenomena and structure of foods. In this work, we present a theoretical treatment of navy beans from a SCM perspective to describe the hydration kinetics. We solve the transport equations within a porous matrix and employ the Flory–Huggin’s equation for polymer–solvent mixture to balance the osmotic pressure. The swelling of the legume seed is modelled as a moving boundary with …
Optimizing Polymer Fluorescence For Explosives Detection, Rose K. Cersonsky
Optimizing Polymer Fluorescence For Explosives Detection, Rose K. Cersonsky
Honors Scholar Theses
Pyrene is commonly used for explosives detection, as when mixed with polystyrene, the fluorescence intensity of the resulting film can be used as an indicator of the presence of nitro-aromatic, nitro-ether, or nitro-amine explosives. Previous studieshave tested a three-component system including pyrene, polystyrene, and a salt, tetrabutylammonium hexafluorophosphate (TBAHP). From these previous studies, it has been seen that vapor pressure of the preparation area is a governing factor in the formation of excimers, which are instrumental in achieving and maintaining fluorescence intensity. In this study, three parameters – solution concentration, film thickness, and molecular weight of polystyrene are examined to …