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Articles 241 - 270 of 275

Full-Text Articles in Transport Phenomena

Emulsification And Dispersant Properties Of Sugar Ester Glycolipid In Water In Oil And Oil In Water Emulsion., Azrah Abdul Aziz Jan 2008

Emulsification And Dispersant Properties Of Sugar Ester Glycolipid In Water In Oil And Oil In Water Emulsion., Azrah Abdul Aziz

Student Works (2010-2019)

The influence of different dispersing agent on the rheological behaviors of paraffin oil-water emulsion with addition of TiO2 for uv-protect and moisturizing active ingredient was studied. While making creams with minimal structural defects and longer storage stability, it is important that preparation conditions be optimized. Settle volume properties, Zeta potential, effective diameter and settle volume of TiO2 suspension were studied in the presence of glycolipid (DDM and Carrageenan), nonionic (PEG 10,000 and Brij 35P) as well as anionic surfactants (sodium dodecyl sulfate, SDS). In the experiments, the higher concentration of dispersing agents shows higher settle volume percentage, higher zeta potential …

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Simulation Of The Oxygen Reduction Reaction At An Rde In 0.5 M H2So4 Including An Adsorption Mechanism, Qingbo Dong, Shriram Santhanagopalan, Ralph E. White Jan 2007

Simulation Of The Oxygen Reduction Reaction At An Rde In 0.5 M H2So4 Including An Adsorption Mechanism, Qingbo Dong, Shriram Santhanagopalan, Ralph E. White

Faculty Publications

Oxygen reduction on the surface of a rotating disk electrode (RDE) in 0.5 M H2SO4 is simulated by including mass transfer, adsorption, and charge transfer. A generalized model for the adsorption and reaction of several species is introduced. The oxygen reduction reaction is simulated as a limiting case where oxygen is the only species adsorbed, and oxygen reduction is the only reaction that takes place on the surface of the electrode. The model is based on the Nernst–Planck equations for mass transfer and the Butler–Volmer equation for electrochemical kinetics. The simulated polarization curves capture the change in …

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Short-Time Transient Analysis Of Intercalation Of An Ion Into A Sphere, Sheba Devan, Ralph E. White Jan 2007

Short-Time Transient Analysis Of Intercalation Of An Ion Into A Sphere, Sheba Devan, Ralph E. White

Faculty Publications

A short-time transient analysis is presented for a sinusoidal input potential for a spherical particle. The objective of this work was to extract accurate values of the parameters associated with an intercalation into a spherical particle. These parameters are exchange current density, double-layer capacitance, and diffusion coefficient. The effects of these parameters on the response were examined using a sensitivity analysis, which indicated that optimum frequency values of the input perturbation exist for estimation of these parameters. A procedure is presented to obtain all these parameters using the short-time response. The results show that the short-time analysis is a useful …

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Stability Of Transport And Rate Processes [Review], Yaşar Demirel Jun 2005

Stability Of Transport And Rate Processes [Review], Yaşar Demirel

Papers in Thermal Mechanics

About fifty years ago, the Turing instability demonstrated that even simple reaction-diffusion systems might lead to spatial order and differentiation, while the Rayleigh-Bénard instability showed that the maintenance of nonequilibrium might be the source of order in fluids subjected to a thermodynamic force above a critical value. Therefore, distance from global equilibrium in the form of magnitude of a thermodynamic force emerges as another constraint of stability; some systems may enhance perturbations, and evolve to highly organized states called the dissipative structures after a critical distance on the thermodynamic branch. Although the kinetics and transport coefficients represent short-range interactions, chemical …

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Transport Analysis And Model For The Performance Of An Ultrasonically Enhanced Filtration Process, Michael T. Grossner, Joanne M. Belovich, Donald L. Feke Jun 2005

Transport Analysis And Model For The Performance Of An Ultrasonically Enhanced Filtration Process, Michael T. Grossner, Joanne M. Belovich, Donald L. Feke

Chemical & Biomedical Engineering Faculty Publications

This paper presents an analysis of a filtration technique that uses ultrasound to aid the collection of small particles (tens of microns in diameter) from suspension. In this method, particles are retained within a porous mesh that is subjected to a resonant ultrasonic field, even though the pore size of the mesh is two orders of magnitude greater than the particle diameter. The role of acoustic forces in driving the retention phenomena has previously been studied on a micro-scale, which included modeling and experimental verification of particle motion and trapping near a single element of the mesh. Here, we build …

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Blood Flow Measurements With Magnetic Resonance Phase Velocity Mapping, George P. Chatzimavroudis Apr 2005

Blood Flow Measurements With Magnetic Resonance Phase Velocity Mapping, George P. Chatzimavroudis

Chemical & Biomedical Engineering Faculty Publications

Magnetic resonance (MR) phase velocity mapping (PVM) is a non-invasive technique that can measure the flow velocity in any spatial direction in an imaging slice. This technique has wide application in the clinical field in quantifying blood flow, as well as in non-biomedical areas. This review describes the value and/or potential of MR PVM as a diagnostic/monitoring technique in heart valve regurgitation and in the total cavo-pulmonary connection. A single slice placed in the aortic root can accurately quantify the aortic regurgitant volume. A multi-slice control volume method has high potential for the quantification of the mitral regurgitant volume. …

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Transient Analysis Of A Porous Electrode, Sheba Devan, Venkat R. Subramanian, Ralph E. White Jan 2005

Transient Analysis Of A Porous Electrode, Sheba Devan, Venkat R. Subramanian, Ralph E. White

Faculty Publications

An analytical expression is presented for the voltage response including the transient voltage for a simple (i.e., no concentration gradients) porous electrode model subject to a sinusoidal input current density. The transient voltage response as a function of the frequency, exchange current density, and double layer capacitance is studied independent of the periodic (steady state) voltage response. The change in the voltage response in the transient region is compared to that of the periodic voltage response with respect to the parameters. The physical properties of the porous electrode can be estimated using the voltage response in the transient …

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Fast Measurements Of Flow Through Mitral Regurgitant Orifices With Magnetic Resonance Phase Velocity Mapping, Haosen Zhang, Sandra S. Halliburton, Richard D. White, George P. Chatzimavroudis Dec 2004

Fast Measurements Of Flow Through Mitral Regurgitant Orifices With Magnetic Resonance Phase Velocity Mapping, Haosen Zhang, Sandra S. Halliburton, Richard D. White, George P. Chatzimavroudis

Chemical & Biomedical Engineering Faculty Publications

Magnetic-resonance (MR) phase velocity mapping (PVM) shows promise in measuring the mitral regurgitant volume. However, in its conventional nonsegmented form, MR-PVM is slow and impractical for clinical use. The aim of this study was to evaluate the accuracy of rapid, segmented k-spaceMR-PVM in quantifying the mitral regurgitant flow through a control volume (CV) method. Two segmented MR-PVM schemes, one with seven (seg-7) and one with nine (seg-9) lines per segment, were evaluated in acrylic regurgitant mitral valve models under steady and pulsatile flow. A nonsegmented (nonseg) MR-PVM acquisition was also performed for reference. The segmented acquisitions were …

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Design And Simulation Of An Induction Skull Melting System, Taide Tan May 2004

Design And Simulation Of An Induction Skull Melting System, Taide Tan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Incorporating volatile actinides, mainly americium into a metallic fuel pin (MFP) has been a serious problem due to americium’s high vapor pressure. An Induction Skull Melting (ISM) system was identified by Argonne National Laboratory (ANL) as a potential furnace design to cast MFPs. Through the development of the ISM system, the nuclear waste feedstock can be melted and injected into the mold for fabricating MFPs in the advanced nuclear fuel cycles. The main phenomena in this system include: induction melting process, casting process and mass transfer process of americium. Issues related to ISM system design for casting MFPs are discussed …

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A Rapidly-Converging Alternative To Source Iteration For Solving The Discrete Ordinates Radiation Transport Equations In Slab Geometry, Nicholas J. Wager Mar 2004

A Rapidly-Converging Alternative To Source Iteration For Solving The Discrete Ordinates Radiation Transport Equations In Slab Geometry, Nicholas J. Wager

Theses and Dissertations

I present a numerical technique to solve the time independent Boltzmann Transport Equation for the transport of neutrons and photons. The technique efficiently solves the discrete ordinates equations with a new iteration scheme. I call this new scheme the angle space distribution iteration method because it combines a non-linear, high angular-resolution flux approximation within individual spatial cells with a coarse angular-resolution flux approximation that couples all cells in a spatial mesh. This shown to be an efficient alternative to source iteration. The new method is implemented using the step characteristic and exponential characteristic spatial quadrature schemes. The latter was introduced …

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Teaching Coupled Transport And Rate Processes, Yaşar Demirel Jan 2004

Teaching Coupled Transport And Rate Processes, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: News Releases

Coupling refers to a flux occurring without its primary thermodynamic driving force; for example, mass flux without a concentration gradient called the thermal diffusion is a well-known coupled process. Coupling also refers to a flux occurring in a direction opposite to the direction imposed by its driving force; for example, a mass flux can occur from a low to a high concentration region and is called the active transport or uphill transport, such as potassium and sodium pumps coupled to chemical energy released by the hydrolysis of adenosine triphosphate (ATP) in biological systems. Although the coupled processes seem to be …

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A Steady-State Impedance Model For A Pemfc Cathode, Qingzhi Guo, Ralph E. White Jan 2004

A Steady-State Impedance Model For A Pemfc Cathode, Qingzhi Guo, Ralph E. White

Faculty Publications

A model for the simulation of the steady-state impedance response of a polymer electrolyte membrane fuel cell (PEMFC) cathode is presented. The catalyst layer of the electrode is assumed to consist of many flooded spherical agglomerate particles surrounded by a small volume fraction of gas pores. Stefan-Maxwell equations are used to describe the multicomponent gas-phase transport occurring in both the gas diffusion layer and the catalyst layer of the electrode. Liquid-phase diffusion of O2 is assumed to take place in the flooded agglomerate particles. Newman’s porous electrode theory is applied to determine over-potential distributions. © 2004 The Electrochemical Society. All …

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A Mushy-Zone Rayleigh Number To Describe Interdendritic Convection During Directional Solidification Of Hypoeutectic Pb-Sb And Pb-Sn Alloys, Surendra N. Tewari, R. Tiwari Oct 2003

A Mushy-Zone Rayleigh Number To Describe Interdendritic Convection During Directional Solidification Of Hypoeutectic Pb-Sb And Pb-Sn Alloys, Surendra N. Tewari, R. Tiwari

Chemical & Biomedical Engineering Faculty Publications

Based on measurements of the specific dendrite surface area (S-nu), fraction of interdendritic liquid (phi), and primary dendrite spacing (lambda(1)) on transverse sections in a range of directionally solidified hypoeutectic Pb-Sb and Pb-Sn alloys that were grown at thermal gradients varying from 10 to 197 K cm(-1) and growth speeds ranging from 2 to 157 mum s(-1), it is observed that S-nu = lambda(1)(-1) S*(-0.33) (3.38 - 3.29 phi + 8.85 phi(2)), where S* = D-l G(eff)/V m(1) C-o (k - 1)/k, with D-l being the solutal diffusivity in the melt, G(eff) being the effective thermal gradient, V being the …

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Gibbs Dividing Surface And Helium Adsorption, Sasidhar Gumma, Orhan Talu Mar 2003

Gibbs Dividing Surface And Helium Adsorption, Sasidhar Gumma, Orhan Talu

Chemical & Biomedical Engineering Faculty Publications

All adsorption data is based on the definition of Gibbs dividing surface, which is a purely mathematical transformation. Adsorption measurements in microporous solids necessitate experimental determination of the dividing surface. An international protocol does not exist on how to perform this important measurement. Commonly, helium is assumed not to adsorb and used as a probe molecule for this measurement. Each experimentalist chooses an arbitrary set of conditions, often without even disclosing them, which adds to the confusion in adsorption literature. Here, a self-consistent method for the analysis of helium data is proposed which does not assume non-adsorbing helium …

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The Effect Of Convection On Disorder In Primary Cellular And Dendritic Arrays, R. Trivedi, P. Mazumder, Surendra N. Tewari Dec 2002

The Effect Of Convection On Disorder In Primary Cellular And Dendritic Arrays, R. Trivedi, P. Mazumder, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Directional solidification studies have been carried out to characterize the spatial disorder in the arrays of cells and dendrites. Different factors that cause array disorder are investigated experimentally and analyzed numerically. In addition to the disorder resulting from the fundamental selection of a range of primary spacings under given experimental conditions, a significant variation in primary spacings is shown to occur in bulk samples due to convection effects, especially at low growth velocities. The effect of convection on array disorder is examined through directional solidification studies in two different alloy systems, Pb-Sn and Al-Cu. A detailed analysis of the spacing …

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Accurate Quantification Of Steady And Pulsatile Flow With Segmented K-Space Magnetic Resonance Velocimetry, Haosen Zhang, Sandra S. Halliburton, James R. Moore, Orlando P. Simonetti, Paulo R. Schvartzman, Richard D. White, George P. Chatzimavroudis Sep 2002

Accurate Quantification Of Steady And Pulsatile Flow With Segmented K-Space Magnetic Resonance Velocimetry, Haosen Zhang, Sandra S. Halliburton, James R. Moore, Orlando P. Simonetti, Paulo R. Schvartzman, Richard D. White, George P. Chatzimavroudis

Chemical & Biomedical Engineering Faculty Publications

Conventional non-segmented magnetic resonance phase velocity mapping (MRPVM) is an accurate but relatively slow velocimetric technique. Therefore, the aim of this study was to evaluate the accuracy of the much faster segmented k-space MRPVM in quantifying flow. The axial velocity was measured in four straight tubes (inner diameter: 5.6–26.2 mm), using a segmented MRPVM sequence with seven lines of k-space per segment. The flow rate and flow volume were accurately quantified (errorssteady (r2=0.99) and pulsatile flow (r2=0.98), respectively. The measured velocity profiles and flow rates from the segmented sequence agreed …

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Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Xiaolong Wu Aug 2002

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Xiaolong Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fundamental issues related to the selection of a metallic fuel casting furnace design are presented and discussed including heating mechanisms, casting issues, crucible design, and issues related to the mass transport of americium. The process of evaluating all of these different criteria is undertaken to select a concept that would have the greatest chance of success for casting americium in a metallic fuel rod. Based on this evaluation process, a concept for the casting of metallic fuel pins containing high vapor pressure materials is selected and discussed. The important physics of this concept include mass transport of americium from the …

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Molecular Simulation Of Adsorption: Gibbs Dividing Surface And Comparison With Experiment, Orhan Talu, Alan L. Myers May 2001

Molecular Simulation Of Adsorption: Gibbs Dividing Surface And Comparison With Experiment, Orhan Talu, Alan L. Myers

Chemical & Biomedical Engineering Faculty Publications

At low temperature near the normal boiling point, computer simulations of adsorption of gases can be compared directly with experiment. However, for adsorptive gas separations in which the gas is adsorbed near or above its critical temperature, absolute simulation variables must be converted to excess variables for comparison with experiment. The conversion of absolute to excess variables requires the helium pore volume of the adsorbent. Lennard-Jones potential parameters for helium gas molecules interacting with the oxygen atoms of silicalite are ε/k = 28.0 K and σ = 2.952 Å. The helium pore volume of silicalite is 0.175 cm …

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Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler Mar 2001

Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler

Papers in Thermal Mechanics

Using published experimental data on the thermal conductivity, mutual diffusivity, and heats of transport, the degree of coupling between heat and mass flows has been calculated for binary and ternary nonideal liquid mixtures. The binary mixtures consist of two types: the first is six systems of six-to-eight-carbon straight and branched chain alkanes in chloroform and in carbon tetrachloride; and the second is mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and 11-octane. The ternary mixture considered is toluene-chlorobenzene-bromobenzene. The published data are available at 35°C, 30°C, and 35°C and ambient pressure. Using the linear nonequilibi-ium thermodynainics (LNET) and the …

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Editorial, Orhan Talu, Shivaji Sircar Mar 1999

Editorial, Orhan Talu, Shivaji Sircar

Chemical & Biomedical Engineering Faculty Publications

No abstract provided.

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Diffusivities Of N-Alkanes In Silicalite By Steady-State Single-Crystal Membrane Technique, Orhan Talu, Matthew S. Sun, Dhananjai B. Shah Mar 1998

Diffusivities Of N-Alkanes In Silicalite By Steady-State Single-Crystal Membrane Technique, Orhan Talu, Matthew S. Sun, Dhananjai B. Shah

Chemical & Biomedical Engineering Faculty Publications

A novel experimental technique that measures the diffusive flux through a single-crystal membrane (SCM) was developed and tested. Unlike all other macroscopic techniques that depend on a transient response, SCM is used under steady-state conditions, which results in a wide range of applicability from 10−2 to 10−11 cm2/s. Phenomenological equations for the steady-state data analysis were developed. The variation of driving force over the diffusion path is included in the model. As required by thermodynamics, the micropore concentration is given as a function of surface-excess amount adsorbed and gas density. The membrane configuration measures diffusivity in …

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Dynamic Analysis Of Unidirectional Pressure Infiltration Of Porous Preforms By Pure Metals, Dhiman K. Biswas, Jorge E. Gatica, Surendra N. Tewari Jan 1998

Dynamic Analysis Of Unidirectional Pressure Infiltration Of Porous Preforms By Pure Metals, Dhiman K. Biswas, Jorge E. Gatica, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Unidirectional pressure infiltration of porous preforms by molten metals is investigated numerically. A phenomenological model to describe fluid flow and transport phenomena during infiltration of fibrous preforms by a metal is formulated. The model describes the dynamics of the infiltration process, the temperature distribution, and solid fraction distribution. The numerical results are compared against classical asymptotic analyses and experimental results. This comparison shows that end effects may become important and render asymptotic results unreliable for realistic samples. Fiber volume fraction and initial temperature appear as the factors most strongly influencing infiltration. Metal superheating affects not only the length of the …

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A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White Jan 1998

A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White

Faculty Publications

No abstract provided.

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Governing Equations For Transport In Porous Electrodes, Pauline De Vidts, Ralph E. White Jan 1997

Governing Equations For Transport In Porous Electrodes, Pauline De Vidts, Ralph E. White

Faculty Publications

No abstract provided.

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Droplet Evaporation And Deformations In An Amplitude Modulated Ultrasonic Field, Nihad E. Daidzic, Rene Stadler, Adrian Melling Apr 1996

Droplet Evaporation And Deformations In An Amplitude Modulated Ultrasonic Field, Nihad E. Daidzic, Rene Stadler, Adrian Melling

Aviation Department Publications

The aim of the report presented is the measurements of droplet oscillations.

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Convection During Thermally Unstable Solidification Of Pb-Sn In A Magnetic Field, Hui Song, Surendra N. Tewari, H. C. Degroh Iii Apr 1996

Convection During Thermally Unstable Solidification Of Pb-Sn In A Magnetic Field, Hui Song, Surendra N. Tewari, H. C. Degroh Iii

Chemical & Biomedical Engineering Faculty Publications

Convection and macrosegregation in directionally solidified hypoeutectic Pb-38 wt pct Sn and hypereutectic Pb-64.5 wt pct Sn have been examined during upward and downward growth. Temperature fluctuations are observed along the length of the melt column during downward growth. With increasing Rayleigh number, these fluctuations change from none, to cyclic, to time periodic having multiple harmonics, and finally to random. At the higher convective driving force of 350 K temperature inversion, the transverse magnetic field decreased convective levels, strong random temperature fluctuations (flows) becoming smaller and periodic. The maximum field of 0.45 T was unable to completely eliminate convection. For …

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Time Dependence Of Tip Morphology During Cellular Dendritic Arrayed Growth, Hui Song, Surendra N. Tewari Apr 1996

Time Dependence Of Tip Morphology During Cellular Dendritic Arrayed Growth, Hui Song, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Succinonitrile-1.9 wt pct acetone has been directionally solidified in 0.7 X 0.7-cm-square cross section pyrex ampoules in order to observe the cell/dendrite tip morphologies, not influenced by the ''wall effects,'' which are present during growth in the generally used thin (about 200 mu m) crucibles. The tips do not maintain a steady-state shape, as is generally assumed. Instead, they fluctuate within a shape envelope. The extent of fluctuation increases with decreasing growth speed, as the micro structure changes from the dendritic to cellular. The influence of natural convection has been examined by comparing these morphologies with those grown, without convection, …

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A Multiphase Mathematical Model Of A Nickel/Hydrogen Cell, Pauline De Vidts Jan 1996

A Multiphase Mathematical Model Of A Nickel/Hydrogen Cell, Pauline De Vidts

Faculty Publications

No abstract provided.

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A New Spray Evaporation Model Based On Droplet Interface Phenomena, Nihad E. Daidzic, Gangolf Kohnen, Martin Sommerfeld Apr 1995

A New Spray Evaporation Model Based On Droplet Interface Phenomena, Nihad E. Daidzic, Gangolf Kohnen, Martin Sommerfeld

Aviation Department Publications

In this work the influence of droplet shape oscillations on droplet evaporation is shown. Through nonlinear mode interactions, turbulence and aerodynamic triggering of vibrations cause by vortex shedding, droplets always oscillates in spray flows. Droplet shape oscillation cause higher evaporation rates through several physical phenomena such as an average increase of the superficial surface area, periodic micro-convection and boundary layer destruction, and local saturation pressure changes due to local curvature effects. The inviscid theory of small-amplitude droplet oscillations was used which resulted in better agreement with the measurement data of droplet size distributions in sprays for different axial coordinates.

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Electrostatic Positioning Of Droplets In Turbulent Flows (Lstm 375/Te/93), Nihad E. Daidzic, Adrian Melling Apr 1993

Electrostatic Positioning Of Droplets In Turbulent Flows (Lstm 375/Te/93), Nihad E. Daidzic, Adrian Melling

Aviation Department Publications

Report LSTM 375/TE/93, Lehrstuhl fuer Stroemungsmechanik Universitaet Erlangen-Nuernberg Cauerstr. 4, 8520 Erlangen Germany.

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