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Continuous Synthesis And Condition Exploration Of Precursor Ni1/3Co1/3Mn1/3(Oh)2 Ternary Cathode Material, Zhi-jun JIANG, Ya-li ZHANG, Qian WANG, Hui ZHANG 2016 Zibo Guoli New Power Source Technology Co., Ltd., Zibo, Shandong 255086, China; Zibo Engineering Technology Research Center of Asymmetric Large Power Capacitor Battery, Zibo, Shandong 255086, China;

Continuous Synthesis And Condition Exploration Of Precursor Ni1/3Co1/3Mn1/3(Oh)2 Ternary Cathode Material, Zhi-Jun Jiang, Ya-Li Zhang, Qian Wang, Hui Zhang

Journal of Electrochemistry

Commercial LiNi1/3Co1/3Mn1/3(OH)2 ternary material is generally prepared by a combination of co-precipitation and solid state reaction method. The particle size distribution and morphology of Ni1/3Co1/3Mn1/3(OH)2 precursor have a great impact on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2. In this work, the precursor Ni1/3Co1/3Mn1/3(OH)2 ternary cathode material was prepared by co-precipitation method with MnSO4, NiSO4, and CoSO4 as raw materials, NaOH as a precipitating agent and NH3 …


Template-Assisted Hydrothermal Synthesis Of Nio@Co3O4 Hollow Spheres With Hierarchical Porous Surfaces For Supercapacitor Applications, Wen ZHOU, Xue-feng LU, Ming-mei WU, Gao-ren LI 2016 MOE Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China;

Template-Assisted Hydrothermal Synthesis Of Nio@Co3O4 Hollow Spheres With Hierarchical Porous Surfaces For Supercapacitor Applications, Wen Zhou, Xue-Feng Lu, Ming-Mei Wu, Gao-Ren Li

Journal of Electrochemistry

Hollow structures have shown great potentials in a variety of important applications, such as energy conversion and storage. In order to further enhance the performance, the rational design of hollow structures with higher complexity in terms of composition and structure is highly desirable and still remains a great challenge. In this work, an efficient strategy was established for the fabrication of novel NiO@Co3O4 hollow spheres (HSs) with hierarchical porous surfaces by silica spheres template-assisted hydrothermal synthesis. The as-fabricated NiO@Co3O4 HSs showed high specific surface area of 219.68 m2·g-1, and significant …


Electrochemical Performance Of Crystalline Li12Si7 As Anode Material For Lithium Ion Battery, Ya-xiong YANG, Rui-jun MA, Ming-xia GAO, Hong-ge PAN, Yong-feng LIU 2016 State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;

Electrochemical Performance Of Crystalline Li12Si7 As Anode Material For Lithium Ion Battery, Ya-Xiong Yang, Rui-Jun Ma, Ming-Xia Gao, Hong-Ge Pan, Yong-Feng Liu

Journal of Electrochemistry

Crystalline Li12Si7 is successfully synthesized by heating the mixture of LiH and Si with a molar ratio of 12:7, which avoids the huge difference of the melting points between Li and Si. The electrochemical performance and lithium storage mechanism of the as-prepared Li12Si7 are studied in this work. It is found that only a change in cell volume takes place without a phase change during the lithiation/delithiation of Li12Si7 at a voltage range of 0.02 ~ 0.6 V, exhibiting a solid-solution lithium storage mechanism. Such a lithium storage process effectively retards the volume effect …


Design And Implementation Of Ccny Dc Microgrid Testbed, Mahmoud Saleh, Yusef Esa, Yassine Mhandi, Werner Brandauer, Ahmed Mohamed 2016 CUNY City College

Design And Implementation Of Ccny Dc Microgrid Testbed, Mahmoud Saleh, Yusef Esa, Yassine Mhandi, Werner Brandauer, Ahmed Mohamed

Publications and Research

This paper presents the design, control, energy management, and implementation of the City College of New York (CCNY) direct current (DC) microgrid laboratory testbed. This facility was custom designed and implemented by researchers at CCNY with minimal off-the-shelf components to enable significant flexibility and reconfiguration capability. The microgrid consists of renewable energy resources, energy storage system and controllable loads, and can operate in either a grid-connected or an islanded mode. The design steps, requirements, and results of the developed testbed were discussed. Moreover, several operational scenarios were tested. The experimental results verify the applicability and flexibility of the developed microgrid …


Plasticized Polymer Coatings For Sh-Saw Sensors For High Sensitivity And Long-Term Monitoring Of Btex Analytes In Liquid Phase, Pintu Adhikari 2016 Marquette University

Plasticized Polymer Coatings For Sh-Saw Sensors For High Sensitivity And Long-Term Monitoring Of Btex Analytes In Liquid Phase, Pintu Adhikari

Master's Theses (2009 -)

BTEX compounds (benzene, toluene, ethylbenzene, and xylene) are constituents of crude oil and hazardous to human health. Among them, benzene has the lowest maximum contaminant level for drinking water because of its carcinogenicity. Spills or leakage from underground storage tanks or hazardous waste sites can contaminate nearby groundwater with these volatile organic compounds. Therefore, it is very important to detect the presence of BTEX contamination as early as possible in order to start the remediation process and maintain a healthy environment. To develop an in-situ continuous monitoring sensor system, shear horizontal surface acoustic wave (SH-SAW) sensor devices are being investigated …


Configuring The Urban Smart Grid: Transitions, Experimentation, And Governance, Anthony Michael Levenda 2016 Portland State University

Configuring The Urban Smart Grid: Transitions, Experimentation, And Governance, Anthony Michael Levenda

Dissertations and Theses

In the face of challenges of energy security, decarbonization, resilience, and the replacement of aging infrastructure systems, federal, state, and local actors are facilitating the development of smart electricity networks to transition towards a more sustainable electricity system. In the United States, development of "smart grids" is being pursued as a national policy mandate and goal, promising that the deployment of smart grid technologies -- referring in general to digital information and communication technologies that sense, monitor, control and manage the electric grid -- will make electricity systems more environmentally sustainable and reliable, and at the same time, provide opportunities …


Energy Managment Of Photovoltaic Charging Station (Pv-Cs) For Green University Campus Transportation, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah McCormack 2016 Technological University Dublin

Energy Managment Of Photovoltaic Charging Station (Pv-Cs) For Green University Campus Transportation, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah Mccormack

Conference Papers

Battery Electric Vehicles (BEVs) have been recognised as the ideal solution for lowering the CO2 emissions in the transport sector and helping to achieve a sustainable future. When BEV technology is leveraged with a solar energy source such as a Photovoltaic Charging Station (PV-CS), the CO2 saving potential is extended to both generation and consumption points. Due to the intermittent nature of our solar resource, once the PV-CS is combined with a storage unit, energy production is achieved without risking the disruption to power supply reliability and quality. Technological University Dublin (DIT) has recognised the viability of this …


On The Feasibility Of Carbon Nanotube Windings For Electrical Machines — Case Study For A Coreless Axial Flux Motor, Vandana Rallabandi, Narges Taran, Dan M. Ionel, John F. Eastham 2016 University of Kentucky

On The Feasibility Of Carbon Nanotube Windings For Electrical Machines — Case Study For A Coreless Axial Flux Motor, Vandana Rallabandi, Narges Taran, Dan M. Ionel, John F. Eastham

Power and Energy Institute of Kentucky Faculty Publications

The latest developments in carbon nanotube (CNT) wires and yarns attract great interest for potential application to electromagnetic devices, such as electrical machines and transformers. The CNT material properties are largely different from copper and aluminum in terms of electrical conductivity, mass density, and thermal transfer, creating a new design paradigm for which the traditional rules and device topologies no longer apply. This paper proposes a brushless permanent magnet multidisc axial flux construction with coreless stator and special windings and minimal rotor back iron, as a suitable topology for CNT winding application. Specific analytical closed-form sizing equations, as a function …


Capture And Recycle Of Industrial Co2 Emissions Using Mircoalgae, Michael H. Wilson, Daniel T. Mohler, John G. Groppo, Thomas E. Grubbs, Stephanie Kesner, E. Molly Frazar, Aubrey Shea, Czarena L. Crofcheck, Mark Crocker 2016 University of Kentucky

Capture And Recycle Of Industrial Co2 Emissions Using Mircoalgae, Michael H. Wilson, Daniel T. Mohler, John G. Groppo, Thomas E. Grubbs, Stephanie Kesner, E. Molly Frazar, Aubrey Shea, Czarena L. Crofcheck, Mark Crocker

Center for Applied Energy Research Faculty and Staff Publications

A novel cyclic flow photobioreactor (PBR) for the capture and recycle of CO2 using microalgae was designed and deployed at a coal-fired power plant (Duke Energy’s East Bend Station). The PBR was operated continuously during the period May–September 2015, during which algae productivity of typically 0.1–0.2 g/(L day) was obtained. Maximum CO2 capture efficiency was achieved during peak sunlight hours, the largest recorded CO2 emission reduction corresponding to a value of 81 % (using a sparge time of 5 s/min). On average, CO2 capture efficiency during daylight hours was 44 %. The PBR at East Bend …


Technological Assessment Of Different Solar-Biomass Systems For Hybrid Power Generation In Europe, CM Iftekhar Hussain, Brian Norton, Aidan Duffy 2016 Technological University Dublin

Technological Assessment Of Different Solar-Biomass Systems For Hybrid Power Generation In Europe, Cm Iftekhar Hussain, Brian Norton, Aidan Duffy

Articles

Solar Tower thermal (ST), Parabolic Trough thermal (PT), Linear Fresnel thermal (LF) and Solar PV are discussed in the context of suitability for hybridization with biomass in Europe. Technical, economical and climate data have been compared to identify the key drivers of technology selection in setting up large scale solar-biomass hybrid power plants. The sole solar-biomass hybrid power plant is currently in operation in Spain uses PT technology due to its performance characteristics, comparatively easy installation process compared to ST and relatively higher heat and optical gain than LF. The climate condition in the EU shows that the region within …


Special Issue: Photoelectrochemistry And New Types Of Solar Cells, Chang-jian LIN, Yong-fang LI 2016 State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University;

Special Issue: Photoelectrochemistry And New Types Of Solar Cells, Chang-Jian Lin, Yong-Fang Li

Journal of Electrochemistry

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Cathode Buffer Layer For Improving Photovoltaic Performance Of Planar P-I-N Perovskite Solar Cells, Xiao-dong LIU, Yong-fang LI 2016 Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, China;

Cathode Buffer Layer For Improving Photovoltaic Performance Of Planar P-I-N Perovskite Solar Cells, Xiao-Dong Liu, Yong-Fang Li

Journal of Electrochemistry

Organic/inorganic hybrid metal halide perovskite semiconductor materials have drawn great attention for the application in solar cells in recent years because of their combined superior photoelectrical properties of inorganic semiconductors (with high dielectric constant and high charge carriers mobility) and organic semiconductors (with good solution processability and high absorbance). The power conversion efficiency (PCE) of the organometal halide perovskite solar cells (pero-SCs) based on CH3NH3PbI3 has been increased dramatically in a few years from 3.8% to a certified 22.1%, primarily owing to the development of new interfacial materials, careful optimization of morphology, and perovskite crystallization …


Application Of Metal-Organic Frameworks In Dye-Sensitized Solar Cells, Ya-feng Li, Qing-qing Sun, Ming-deng Wei 2016 Institute of Advanced Energy Materials, Fuzhou University, Fuzhou 350002, China;

Application Of Metal-Organic Frameworks In Dye-Sensitized Solar Cells, Ya-Feng Li, Qing-Qing Sun, Ming-Deng Wei

Journal of Electrochemistry

To assemble dye-sensitized solar cells (DSSCs) with high efficiencies, their photoanodes should have large specific surface area to establish a large adsorption amount of dyes and good light-harvesting ability. From this point of view, it will be an interesting topic to explore the application of metal-organic frameworks (MOFs) in the field of DSSCs due to their huge specific surface area. This paper introduces the application of MOFs in photovoltaic devices briefly, and then summaries our approaches in using MOFs in the study of DSSCs, including the pre-treatment and the post-treatment of photoanode, the preparation of photoanode materials and the light …


Photoelectrochemical Water Splitting Cells: Methods For Improving Performance Of Electrodes And Recent Progress On Photocathodes, Kai-jian ZHU, Wen-jun LUO, Zhong-jie GUAN, Xin WEN, Zhi-gang ZOU, Wei HUANG 2016 Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, P. R. China.;

Photoelectrochemical Water Splitting Cells: Methods For Improving Performance Of Electrodes And Recent Progress On Photocathodes, Kai-Jian Zhu, Wen-Jun Luo, Zhong-Jie Guan, Xin Wen, Zhi-Gang Zou, Wei Huang

Journal of Electrochemistry

Photoelectrochemical water splitting can convert solar energy into hydrogen which is an ideal way to utilize and store solar energy. A p-n tandem cell is considered as the most promising solar water splitting cell due to its high theory conversion efficiency, low cost and photoelectrode material flexibility. However, solar conversion efficiency of a tandem cell is still low in the experiment because of poor performance in a single photoelectrode. In this review, we have introduced some effective approaches to improve the performances of photoelectrodes by reducing recombination of photogenerated carriers in the bulk or on the surface, and suppressing back …


Theoretical Study Of Photoelectrochemical Reactions And Ec-Sers On Spr Metallic Electrodes Of Silver And Gold, Yuan-fei WU, Ran PANG, Meng ZHANG, Jian-zhang ZHOU, Bin REN, Zhong-qun TIAN, De-yin WU 2016 Department of Chemistry, College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian, China;

Theoretical Study Of Photoelectrochemical Reactions And Ec-Sers On Spr Metallic Electrodes Of Silver And Gold, Yuan-Fei Wu, Ran Pang, Meng Zhang, Jian-Zhang Zhou, Bin Ren, Zhong-Qun Tian, De-Yin Wu

Journal of Electrochemistry

At present photoelectrochemistry has received much concern back to nanostructures of noble metals from semiconductor electrodes. This is due to the surface plasmon resonance (SPR) effect of metallic nanostructures, which can effectively convert the far-field light to the near-field light and concentrate the photonic energy to the local surface area with high energy density. Thus, the different enhancement mechanisms, such as the local optical field enhancement, the formation of light generated hot carriers (hot electron-hole pairs), or the photothermal effect, have been proposed in literatures. On the basis of the SPR enhancement effect, the surface-enhanced Raman spectroscopy (SERS) can be …


Prospects Of D-Π-A Structured Porphyrins And Their Photoelectrochemical Application, Shuang-shuang LIU, Jian-feng LU, Ming-kui WANG 2016 Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan , 430074,Hubei,China;

Prospects Of D-Π-A Structured Porphyrins And Their Photoelectrochemical Application, Shuang-Shuang Liu, Jian-Feng Lu, Ming-Kui Wang

Journal of Electrochemistry

Porphyrins and their metalloderivatives are a class of compounds exhibiting a wide variety of interesting and highly useful properties, such as chlorophyll. Porphyrins are particularly interesting in photoelectrochemical applications due to their structural similarity to chlorophylls in natural photosynthetic systems, as well as their strong and tunable absorption properties. Recently, various porphyrins have been extensively studied for their applications in solar cells, photocatalytic hydrogen production, optical information storage and others. This review will focus on the unique physical and chemical properties of D-π-A structured porphyrins, and their photovoltaic performances in dye-sensitized solar cells. A brief discussion in the future development …


Preparations And Photoelectrochemical Properties Of Phosphate Modified Rgo-Biobr Nanocomposites, Shuang-ying CHEN, Zhi-jun LI, Xu-liang ZHANG, Kang HU, Rui YAN, Li-qiang JING 2016 Key Laboratory of Functional Inorganic Materials Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, P. R. China;

Preparations And Photoelectrochemical Properties Of Phosphate Modified Rgo-Biobr Nanocomposites, Shuang-Ying Chen, Zhi-Jun Li, Xu-Liang Zhang, Kang Hu, Rui Yan, Li-Qiang Jing

Journal of Electrochemistry

The RGO-BiOBr nanocomposites have been successfully synthesized by a hydrothermal process, and then modified with phosphorous acids. The photoelectrochemical properties of the fabricated RGO-BiOBr nanocomposite films were studied. The results indicate that the photocurrent densities of RGO-BiOBr were much larger compared with those of the bare BiOBr, and interestingly, the photocurrent densities were further improved after phosphate modification. Based on the analyses of the produced hydroxyl radical amounts, the enhanced photocurrent densities could be attributed to the introduction of RGO and to the formed negative fields of modified phosphate groups, which are favorable for electrons to be transferred and for …


Activation Effect Of Nano-Carbon Derived From Co2 On Lead Electrode In Sulfuric Aqueous Solution, Yu-qiao SONG, Hua ZHU, Guang-jin ZHAO, Wen-long WU, Shou-bin ZHOU, Di-hua WANG 2016 School of Resource and Environmental Sciences, Wuhan University, Wuhan 430072, Hubei, China;

Activation Effect Of Nano-Carbon Derived From Co2 On Lead Electrode In Sulfuric Aqueous Solution, Yu-Qiao Song, Hua Zhu, Guang-Jin Zhao, Wen-Long Wu, Shou-Bin Zhou, Di-Hua Wang

Journal of Electrochemistry

Serious sulfation of the negative plate is one of the most popular reasons of the early failure of lead-acid battery. Addition of nano-carbon was proved to be effective for recovering the sulfated electrode and the property of the carbon material always plays an important role. In this work, a new kind of nano-carbon material with high electrical conductivity and good adsorption capability for heavy metal cations, which is electrochemically prepared from CO2 in molten carbonates, was tested as activation additive for the sulfated lead electrode by cyclic voltammetry and SEM measurements. The results showed that the as-prepared carbon can …


Hydrothermal One-Step Synthesis Of Layered Nickel/Cobalt Double Hydroxide With Using Shape-Directing Agent And Homogeneous Precipitating Agent, Li-wei ZHU, Yun-hai YAN, Hui JIA, Run-fen LIANG 2016 College of Chemistry and Chemieal Engineering, Uniersity ofSouth China, Hlengyang, Hunan 421001, China

Hydrothermal One-Step Synthesis Of Layered Nickel/Cobalt Double Hydroxide With Using Shape-Directing Agent And Homogeneous Precipitating Agent, Li-Wei Zhu, Yun-Hai Yan, Hui Jia, Run-Fen Liang

Journal of Electrochemistry

Nickel/cobalt double hydroxide (Ni/Co-DH) has been prepared by facile hydrothermal one-step synthesis method using hexamethylene tetramine (HMT) as a homogeneous precipitating agent and cetyltrimethylammonium bromide (CTAB) as a shape-directing agent. With the hydrolysis of HMT and the use of CTAB, the Ni/Co-DH could be synthesized without additional alkali source, and in the meantime, the Ni/Co-DH exhibited a controlled mesopore size of 13.4 nm and a large BET surface area of 93.6 m2 •g-1 . The X-ray diffraction (XRD) pattern displays that the Ni/Co-DH existed as a mixture of α-Ni(OH)2-β-Co(OH)2. The scanning electron microscope (SEM) …


Large Scale Monolithic Solar Panel Simulation - A Study On Partial Shading Degradation, Suhas V. Baddela, Xingshu Sun, Muhammad A. Alam 2016 Purdue University

Large Scale Monolithic Solar Panel Simulation - A Study On Partial Shading Degradation, Suhas V. Baddela, Xingshu Sun, Muhammad A. Alam

The Summer Undergraduate Research Fellowship (SURF) Symposium

Shadow-induced degradation is a major concern for both power output and long-term reliability in solar cells. Apart from the obvious fact that shading reduces the amount of solar irradiance available to solar panels, it may lead to formation of hot spots, where solar cells are forced to reverse breakdown with localized heating, and potentially, permanent damage. To get a better understanding of shadow-induced degradation, we develop an electro-thermal coupled simulator that can self-consistently solve the electrical and thermal distributions of solar panel under arbitrary shading conditions. The simulation framework consists of two part: a) compact models that can describe the …


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