Chemical Engineering Commons^™

Spatial And Temporal Variations Of Seismic Azimuthal Anisotropy Following The 2019 Ridgecrest Earthquake Sequence In Southern California, Yan Jia, Stephen S. Gao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate the spatial and temporal variations of seismic azimuthal anisotropy in the vicinity of the conjugate fault network activated by the 4 July 2019 (UTC) M6.4 foreshock and the 6 July 2019 M7.1 mainshock in Ridgecrest, California, a total of 1,470 shear wave splitting measurements were obtained from local events recorded by five seismic stations over the period of July 2019 to January 2020. The results suggest a strong asymmetry in anisotropy forming mechanisms across the NW-SE striking Eastern Little Lake Fault, which is the main fault of the area. In the area located to the northeast of the …

Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ammonia synthesis has significant implications for global energy and environmental issues, driving the need for highly active catalysts that operate under mild conditions. This study reports the successful deposition of uniform ∼1.0 nm metallic ruthenium (Ru) nanoclusters onto Ba-LaCeO_x particles via atomic layer deposition (ALD). The catalytic performance of the ALD-prepared Ru nanoclusters was assessed for ammonia synthesis and compared with two catalysts produced by conventional incipient wetness impregnation. For the ALD-prepared Ru nanoclusters, a pre-reaction H_2-reduction step induced partial encapsulation of suboxide species on Ru sites due to strong metal-support interactions, limiting Ru nanocluster sintering and …

Ir Spectral Analysis Of Broussonetia Papyrefera Plant, Umid Hamroyevich Alamov, Zaytuna Ali Qizi Qurbonaliyeva, Dostonbek Qurbonsho Ugli Shomurodov, Elmurod Abduqodirovich Egamberdiev

Technical science and innovation

in this study, a method for determining the concentration of lignin, cellulose and hemicellulose in plant materials using Fourier-transform IR spectroscopy of Broussonetia papyrefera was developed and tested. The procedure is based on the use of calibration functions that reflect the dependence of the intensity of analytical absorption lines on the concentration of lignin (1512 cm-1) and cellulose (1450 cm-1) in standard samples; indirect correlation was used for hemicellulose. The model samples were ternary mixtures composed of lignin, bacterial cellulose and hemicellulose in different proportions. The proposed method was tested on a wide range of plant biomass samples.

Study Of Technological Parameters On Catalytic Hydroisomerisation Of Aromatic Hydrocarbons Into Alkyl Naphthenic Hydrocarbons, Habibullaeva Mirzaxmatovna Ra'no, Nodira Turobjonovna Torayeva, Temurbek Z. Daminov, Murod Azimovich Eshmukhamedov

Technical science and innovation

The article presents experimental results of the catalytic hydroisomerization of aromatic hydrocarbons into alkyl naphthenic hydrocarbons. Aluminum col-molybdenum with silicon oxides has been studied as a catalytic system, which imparts acidic properties to the catalytic system and stimulates isomerization.

The dehydrogenation reaction of cyclohexane has been studied, which occurs on the active surface of one of the metal oxides to cyclohexene, then the resulting cycloolefin diffuses to the acidic active center - aluminosilicate, where skeletal isomerization occurs and then the isomerized cycloolefin again returns to the active center of the surface of the catalytic system, where it is hydrogenated to …

Nanoparticles In Drilling Fluids: A Review Of Types, Mechanisms, Applications, And Future Prospects, Vasanth Gokapai, Prasad Pothana, Kegang Ling

Petroleum Engineering Student Publications

Nanofluids have gained significant attention as a promising solution to several challenges in drilling operations. Nanoparticles, due to their exclusive properties such as high specific surface area, strong adsorption potential, and excellent thermal conductivity, offer significant potential to improve the efficiency and performance of drilling processes. Regardless of the advancements in drilling fluids and techniques that have improved borehole stability, hole cleaning, and extreme operational condition (HTHP) management, limitations still persist. This review discusses a detailed summary of existing research on the application of nanofluids in drilling, exploring their types, properties, and specific uses in areas such as fluid loss …

Hydrogen Underground Storage For Grid Electricity Storage: An Optimization Study On Techno-Economic Analysis, Yunzhi Chen, Daniel Hill, Blake Billings, John Hedengren, Kody Powell

Faculty Publications

This study performs a techno-economic analysis of hydrogen underground storage systems for grid electricity storage, evaluating their economic viability at the plant scale using dynamic optimization. It explores the feasibility of various system configurations and revenue models in the context of volatile electricity prices and the necessity for multiple revenue streams. The hypothesis tested is that large-scale hydrogen storage, despite its low round-trip efficiency, can be economically viable with the right mix of revenue streams. This study uses scenario-based analysis to assess the impacts of different system configurations, including engaging in time-shifting arbitrage, ancillary service markets and blending hydrogen with …

Efficient Phosphate Removal From Water Using Ductile Cast Iron Waste: A Response Surface Methodology Approach, Mai Hassan Dr., Nada Alkhashab Eng., Ahmed Osman Dr., Dalia A. Ali Eng

Chemical Engineering

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design …

Efficient Phosphate Removal From Water Using Ductile Cast Iron Waste: A Response Surface Methodology Approach, Mai Hassan Roushdy Dr., Nada Amr El-Khashab Eng,, Ahmed Ibrahim Osman Dr., Dalia Amer Ali Dr.

Chemical Engineering

Water scarcity is a critical issue worldwide. This study explores a novel method for addressing this issue by using ductile cast iron (DCI) solid waste as an adsorbent for phosphate ions, supporting the circular economy in water remediation. The solid waste was characterized using XRD, XRF, FTIR, and particle size distribution. Wastewater samples of different phosphate ion concentrations are prepared, and the solid waste is used as an adsorbent to adsorb phosphate ions using different adsorbent doses and process time. The removal percentage is attained through spectrophotometer analysis and experimental results are optimized to get the optimum conditions using Design …

Kinetic Modeling Of Dust Grain Dynamics In Electrostatic Sieving, Aaron Berkhoff, Easton Ingram, Fateme Rezaei, Jeffrey Smith, David Bayless, William Schonberg, Daoru Han

Chemical and Biochemical Engineering Faculty Research & Creative Works

A new kinetic particle modeling framework was developed to investigate electrostatic transport of lunar regolith dust particles with applications to the concept of electrostatic sieving. the new approach is based on kinetic particle dynamics and includes major modules of sampling the particle size distribution, solving electric fields, and tracking motion of charged dust grains. a case study for a concept of electrostatic sieving was chosen to validate the new model. the simulation achieved similar performance of particle size classification as reported in the literature. the new model is computationally efficient (takes a few minutes on a PC-type laptop computer) so …

Delivery Of Tgfβ3 From Magnetically Responsive Coaxial Fibers Reduces Spinal Cord Astrocyte Reactivity In Vitro, Jessica L. Funnell, Jasper Fougere, Diana Zahn, Silvio Dutz, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

A spinal cord injury (SCI) compresses the spinal cord, killing neurons and glia at the injury site and resulting in prolonged inflammation and scarring that prevents regeneration. Astrocytes, the main glia in the spinal cord, become reactive following SCI and contribute to adverse outcomes. The anti-inflammatory cytokine transforming growth factor beta 3 (TGFβ3) has been shown to mitigate astrocyte reactivity; however, the effects of prolonged TGFβ3 exposure on reactive astrocyte phenotype have not yet been explored. This study investigates whether magnetic core-shell electro spun fibers can be used to alter the release rate of TGFβ3 using externally applied magnetic fields, …

The Undergraduate Engineering Mental Health Help-Seeking Instrument (Ue-Mh-Hsi): Development And Validity Evidence, Joseph H. Hammer, Courtney J. Wright, Melanie E. Miller, Sarah A. Wilson

Chemical and Materials Engineering Faculty Publications

Background: Undergraduate engineering students experiencing distress are less likely than peers to ask for professional help. A population-specific instrument to facilitate the identification of factors that influence mental healthcare utilization could guide development and testing of interventions to increase help seeking.

Purpose: We used mixed methods guided by the Integrated Behavioral Model (IBM) to develop and evaluate the Undergraduate Engineering Mental Health Help-Seeking Instrument (UE-MH-HSI).

Method: First, we adapted existing measures of mental health help-seeking intention and mechanisms (i.e., attitudes, perceived norm: injunctive, perceived norm: descriptive, personal agency: autonomy, personal agency: capacity). Second, we coded qualitative interviews (N = 33) …

Solubility Characterization Of Organic Molecules For Aqueous Organic Redox Flow Batteries, Anthony W. Ferrell, Harkeerith K. Vij, Seamus D. Jones

College of Engineering Summer Undergraduate Research Program

The major obstacle to renewable energy sources is a lack of long-term energy storage capabilities. Energy produced during the day dissipates, leaving insufficient electricity for at night. The goal of the project is to design an Aqueous Organic Redox Flow Battery (AORFB) to act as long-term energy storage. Work has been done using machine learning to identify suitable compounds for the batteries. In this work there was no indication as to the aqueous solubility of the molecules; this controls the device’s energy storage capabilities. We used a machine learning model to determine the aqueous solubility of slightly more than 3000 …

Carboxymethyl Cellulose-Based Preformed Particle Gels For Water Management In Oil And Gas Reservoirs, Ahmed Ben Ali, Ahmed Hamza, Abdulaziz A. Almakimi, Mohammed Saad, Ibnelwaleed A. Hussein, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Carboxymethyl cellulose (CMC) based materials have been proposed as preformed particle gels (PPGs) for reducing excessive water production in oil and gas reservoirs. Multi-sized dry particles ranging between 100 and 1180 μm have been synthesized using microwave-assisted grafting copolymerization of CMC and acrylamide (AM)/n,n''-methylene-bisacrylamide (MBA). FTIR and SEM confirmed CMC crosslinked polyacrylamide's chemical structure and morphology (CMC/CPAM). Thermo-gravimetric analysis has demonstrated the thermal stability of dry PPGs up to 309 °C. CMC/CPAM showed slightly high absorbency in brine 2 (TDS = 67.3 g/L) compared to brine 1 (TDS = 33.65 g/L), 1% NaCl, and deionized water, with swelling ratios (SR) …

Carbon Fiber And Carbon Fiber Composites—Creating Defects For Superior Material Properties, Ashis Sutradhar Nitai, Tonny Chowdhury, Md Nafis Inam, Md Saifur Rahman, Md Ibrahim H. Mondal, M. A.H. Johir, Volker Hessel, Islam Md Rizwanul Fattah, Md Abul Kalam, Wafa Ali Suwaileh, John L. Zhou, Masoumeh Zargar, Mohammad Boshir Ahmed

Research outputs 2022 to 2026

Recent years have seen a rise in the use of carbon fiber (CF) and its composite applications in several high-tech industries, such as the design of biomedical sensor components, 3D virtual process networks in automotive and aerospace parts, and artificial materials or electrodes for energy storage batteries. Since pristine CF have limited properties, their properties are often modified through a range of technologies, such as laser surface treatment, electron-beam irradiation grafting, plasma or chemical treatments, electrophoretic deposition, carbonization, spinning-solution or melt, electrospinning, and sol–gel, to greatly improve their properties and performance. These procedures cause faulty structures to emerge in CF. …

Operational And Design Factors In Air Staging And Their Effects On Fouling From Biomass Combustion, Akram Elsebaie, Mingming Zhu, Yasir M. Al-Abdeli

Research outputs 2022 to 2026

The global transition towards a carbon-neutral economy highlights the potential of biomass as a renewable fuel source. However, the sustainability of biomass energy systems is challenged by its complex fouling behaviours during combustion. This study investigates the impact of air staging on mitigating fouling in biomass combustion. By optimising the secondary-to-total air flowrate ratio (Qs/Qt) and the positioning of secondary air, this research investigates the impact of operational and design parameters on fouling deposits in biomass combustion. A fixed-bed combustor was used for the experiments, with hardwood pellets as fuel. This study employed TGA and SEM to analyse the fouling …

An Overview Of Additively Manufactured Metal Matrix Composites: Preparation, Performance, And Challenge, Liang Yu Chen, Peng Qin, Lina Zhang, Lai Chang Zhang

Research outputs 2022 to 2026

Highlight Recent progresses in additive manufacturing on metal matrix composites are reviewed. Additive manufacturing technologies for metal matrix composites are summarized. The characteristics of feedstocks and reinforcements are introduced. Mechanical property of additively manufactured metal matrix composites is reviewed. Challenges of additively manufactured metal matrix composites are discussed.

Harnessing The Power Of Hollow Zein Nanoparticles For Enhanced Antifouling And Heavy Metal Removal Of Polyethersulfone Membranes, Farzan Esmali, Mohadeseh Najafi Arani, Elsie Betmoushoul, Masoumeh Zargar, Khalil Farhadi, Vahid Javan Kouzegaran, Rahim Molaei, Yaghoub Mansourpanah

Research outputs 2022 to 2026

This study explores the physicochemical characteristics of an innovative mixed matrix membrane made from polyethersulfone (PES) and hollow Zein nanoparticles (HZNs), which are derived from the corn storage protein, Zein. HZNs, with a mean diameter of 40 nm, were applied to address the challenges associated with metal and inorganic nanoparticles, such as their tendency to accumulate unevenly on the membrane surface. The membranes were fabricated by incorporating varying concentrations of HZNs into the PES casting solution through the nonsolvent phase separation method. The addition of HZNs enhanced the hydrophilicity and pure water flux of the membranes. It also modified the …

Production Of Lioh·H2o From Lithium Chloride By Electrodialysis And Crystallisation, Kwang Loon Ang, Maryam Barmi, Yasaman Boroumand, Amir Razmjou, Aleksandar N. Nikoloski

Research outputs 2022 to 2026

Laboratory bench scale experiments were performed to develop a process for electrodialysis (ED) of LiCl liquor from spodumene leaching and purification to produce LiOH solution, for subsequent conversion by evaporative crystallisation to LiOH·H2O crystals as the end-product. Nafion® 117 cation-selective membranes were used in all experiments. The small electrolytic test cell achieved an average LiOH production rate of 7.5 g/h with 83 % coulombic efficiency and specific electrical consumption of 6.5 kWh/kg LiOH. In the large electrolytic test cell, a higher average LiOH production rate of 11.2 g/h was attained but at lower coulombic efficiency (62 %) and greater specific …

Design And Application Of Redox-Mediated Flow Electrode Electrodialysis For Ion Removal And Recovery, Rongxuan Xie

Theses and Dissertations

To meet the growing demand for freshwater driven by population growth and rising living standards, the first desalination plants were established in the late 1950s. As energy costs have risen over time, research has increasingly focused on reducing the overall cost of water treatment. Electrodialysis (ED), which facilitates the migration of anions and cations across ion exchange membranes under the influence of an electric field, has gained significant attention as a treatment method for saline water and brine due to its simplicity, low cost, and scalability. However, its traditional batch operation mode and the potential for generating flammable gases have …

Electroless Deposition And Galvanic Displacement For The Control Of Supported Nanoparticle Size And Composition, Haiying Zhou

Theses and Dissertations

Catalyst performances can be greatly affected by properties such as particle size, composition, geometry, and cleanliness of the active surface. To achieve optimal catalytic performance, appropriate synthesis methods are required to synthesize the desired structures. Supported metal particle catalysts are usually prepared by impregnation and precipitation methods in industry. Although these two methods are simple, they exhibit poor control over surface morphology, leading to a wide particle size distribution and uncontrolled distribution of different metal components. In this dissertation, three topics on controlling surface morphology are discussed.

For structure sensitive reactions, reactivity and selectivity can be strongly affected by particle …