Chemical Engineering Commons^™

The Strengthening Mechanisms And Incipient Plasticity Of Additively Manufactured Biomedical Refractory High Entropy Alloys, Changxi Liu, Liqiang Wang, Miao Luo, Kuaishe Wang, Marco De Battista, Ling Zhang, Weijie Lu, Lai Chang Zhang, Di Zhang

Research outputs 2022 to 2026

Owing to the cellular structure that limits dislocation motion upon stress loading, additively manufactured (AM) refractory high-entropy alloys (HEAs) exhibit an excellent strength-plasticity synergy. This work integrates micro/nano-mechanical experiments with statistical physics modeling to examine dislocation nucleation and slip in AM-fabricated TiNbTaZrMo HEA. Computational results indicated that the activation volume for initial dislocation nucleation is about one atomic volume, facilitating dislocation initiation. Nanoindentation and in-situ micro-pillar compression reveal no significant pop-in events, indicating that the cellular structure impedes dislocation slip and thus prevents plasticity reduction from dislocation slipping near grain boundaries. This work provides a thorough investigation into the interplay …

3d Engineered Scaffolds Of Conjugated Polymers/Metal Organic Frameworks For Biomedical Applications, Amin Hosseini Sharifabad, Roham Ghanbari, Mohammad Reza Saeb, Ehsan Nazarzadeh Zare, Filippo Rossi, Mehdi Salami-Kalajahi, Pooyan Makvandi

Research outputs 2022 to 2026

The extracellular matrix can be replicated by 3D scaffolds, providing a favorable environment for cell growth, proliferation, and differentiation. Despite their biocompatibility, biodegradability, and bioactivity, the poor mechanical strength of 3D scaffolds limits their use for heavy loads. This creates a bottleneck in the supply of scaffolds with enhanced mechanical strength and all the previously mentioned characteristics. Conjugated polymers have emerged as a promising option for 3D scaffold construction due to their electrical conductivity, adjustable surface qualities, and ability to transfer bioactive molecules. Moreover, metal-organic frameworks (MOFs) are a rapidly emerging class of nanomaterials due to their uniform porosity, excellent …

Excellent Strength-Ductility Synergy Property Of Wire-Arc Additively Manufactured Mg-Gd-Y-Zr Alloy Investigated By Heat Treatment, Jiamin Li, Meng Huang, Juan Hou, Xingbin Wang, Gaopeng Xu, Yi Yang, Ning Mo, Yun Shi, Laichang Zhang, Weineng Tang

Research outputs 2022 to 2026

In this work, the GW63K (Mg-6.54Gd-3.93Y-0.41Zr, wt.%) alloy wire was utilized as the feedstock material and the thin-walled component was fabricated using wire-arc additive manufacturing technology (WAAM). The microstructural evolution during deposition and subsequent heat treatment was explained through multi-scale microstructural characterization techniques, and the impact of heat treatment on the strength-ductility synergy of the deposited alloy was systematically compared. The results showed that the microstructure of the deposited sample was mainly composed of fine equiaxed α-Mg grains and Mg24(Gd,Y)5 phase. The optimized solution heat treatment (450 °C × 2 h) had little effect on the grain size, but can …

Optimization Of Inverted Perovskite Solar Cells: Simulation Insights Into Nio And Mixed-Cation Integration For Enhanced Efficiency, Bo Yao, Hairul Mardiah Hamzah, Sharifah Fatmadiana Bt Wan Muhammad Hatta, Faiz Arith, Mohammad Nur-E-Alam, Mohammad Aminul Islam

Research outputs 2022 to 2026

Inverted perovskite solar cells are one of the most promising technologies for the next generation of photovoltaics, due to excellent stability and a relatively simple fabrication process. Nevertheless, attaining high efficiency remains a challenge in integrating appropriate materials for HTL and an absorber layer. This work focuses on SCAPS-1D simulations to optimize the design of inverted PSCs using NiO as the HTL and a mixed-cation perovskite, MA₀.₄FA₀.₆PbI₃, as an absorber. By employing a controlled variable method, the thickness of the absorber layer was optimized within the range of 300 nm to 900 nm. The optimal performance was achieved when the …

Determination Of Electrochemical Parameters For Predicting Reaction Mechanism And Algorithmic Approaches To Pain Assessment, Huize Xue

Dissertations

This dissertation introduces novel advancements in electrochemical kinetics and pain assessment, structured into two main parts. The first part focuses on the comprehensive analysis of the kinetic and mechanistic aspects of electrochemical reactions, utilizing a combination of experimental techniques and simulation methods. A new software tool, Envismetrics, was developed using Python to facilitate the analysis of complex electrochemical data, including cyclic voltammetry (CV), chronoamperometry (CA), and hydrodynamic voltammetry (HDV). The software was rigorously tested and validated with well-characterized redox systems such as the ferricyanide/ferrocyanide couple, dimethylamine borane (DMAB), and Per- and Polyfluoroalkyl Substances (PFAS). It was successfully used to determine …

Gas-Generating Reactive Materials: Design, Evaluation And Effect Of Morphology On Their Ignition And Combustion, Purvam Mehulkumar Gandhi

Dissertations

This work investigates optimizing gas-generating reactive materials, focusing on particle morphology's effect on ignition and combustion behavior. Metal-based gas-generating energetic materials (EMs) are promising alternatives to replace traditional CHNO compounds. Design of advanced metal-based EMs requires consistent ways of evaluating how their characteristics affect their ignition and combustion. Many relevant evaluation approaches exist; however, the results may be difficult to compare directly across different studies. Commonly, experimentalists ignite metal-based EMs in enclosed chambers and report pressures, P. However, direct comparison of these pressures is hindered by variations in the chamber volume, V, and the EM mass, m. To standardize the …

Decomposition Of Diisopropyl Methylphosphonate (Dimp) Exposed To Elevated Temperatures And Combustion Products Of Reactive Materials, Elif Irem Senyurt

Dissertations

The safe and efficient destruction of chemical weapon agents (CWAs) stockpiles remains a critical global challenge. Understanding the thermophysical properties, decomposition mechanisms, and interactions of CWAs with their environment is crucial for developing effective strategies to mitigate their threats. Diisopropyl methylphosphonate (DIMP) and Dimethyl methylphosphonate are commonly used nerve agent surrogates. This dissertation focuses on DIMP and DMMP, investigates their properties and behavior under conditions relevant to prompt defeat scenarios.

The thermophysical properties of DIMP and DMMP were experimentally characterized, including vapor-liquid surface tension (3-60 °C) and viscosities of neat and aqueous solutions. Results revealed significant non-ideal behavior in aqueous …

Single-Step Synthesis Of Activated Carbon From Arabica Spent Coffee Ground Using K2co3 As Activator Agent, Ghina Ivana Mieldan, Yuliusman Yuliusman

Journal of Materials Exploration and Findings

Activated carbon is a nanomaterial that is often used as an effective adsorbent. Activated carbon raw materials can use biomass, such as coffee grounds, which can be found along with the growth of public interest in coffee drinks. Chemical activators are used for activation to increase biomass carbon's adsorption capacity. Using K₂CO₃ activator to increase the specific surface area of activated carbon is more harmless than KOH. The use of spent coffee grounds as carbon source and food additive K₂CO₃ as an activator can make food-grade activated carbon that can be used for food. …

Strategic Site Selection For Bio-Lng Plant In Indonesia: A Multi-Criteria Scoring Method Approach, Edma Nadhif Oktariani, Yuliusman Yuliusman

Journal of Materials Exploration and Findings

In Indonesia, the energy sector is still predominantly reliant on fossil fuels, with renewable energy, including liquefied biomethane (Bio-LNG), playing a limited role. Nonetheless, Indonesia has significant potential for Bio-LNG development due to its abundant organic waste resources such as Palm Oil Mill Effluent (POME) from palm oil mills. Having approximately 891 Palm Oil Mills in Indonesia and being spread mostly in Sumatra, this study aims to select a strategic location for a Bio-LNG plant that can enhance logistical efficiency and economic viability for the plant. This study uses Multi-Criteria Decision Making (MCDM) methodologies to assess potential sites based on …

Effect Of Alkyd And Polyester Resin Compositions On Corrosion Resistance, Blistering, And Adhesion In Utilization Of Oily Sludge As Anti-Rust Coating Material, Gerets Land Kakalang, Yohanes David Kristianto, Johny Wahyuadi Mudaryoto

Journal of Materials Exploration and Findings

Oil sludge is a waste derived from upstream and downstream activities of the oil and gas industry which is estimated at 10,000 tonnes generated from all PERTAMINA downstream activities spread across various fields, processing units and depots throughout Indonesia. Oil sludge has the same characteristics as asphalt, where asphalt in previous studies can be used as an anti-rust coating, so that the handling of oily sludge can be topped up by reusing and having its own added value. The purpose of this research is to utilise waste oily sludge as an alternative anti-rust coating material and compare alkyd resin and …

Development Of A Spray Pipe Evaporator For Application On Unproductive Salt Farm Land In Indonesia, Srie Muljani, Ketut Sumada, Alfian Rizki Pradana, Caecilia Pujiastuti

ASEAN Journal of Community Engagement

This article discusses the development of a prototype spray pipe evaporator and its efficiency in producing salt in Indonesia. Due to the length of the salt harvesting season in Indonesia, many salt farmers have closed their business doors, leaving many salt ponds abandoned. The spray pipe evaporator prototype was designed to produce a brine solution with a salinity of 23–24 Be from seawater, which has a salinity of 2.5–3.5 Be, in less than 3 days. This is faster than the conventional process of a brine solution salinity of 24 Be. The prototype spray pipe evaporator was assessed in a 20 …

Black Soldier Fly Larvae (Bsfl) Bioconversion For Circular Economy: A Study In Polaman Village, Siswo Sumardiono, Rizka Amalia, Syaikha Butsaina Dhiya’Ulhaq, Nurika Nazilatul Ilmi, Hermawan Dwi Ariyanto

ASEAN Journal of Community Engagement

Conventional organic waste management methods often lead to environmental degradation and underutilization of valuable resources. In rural areas, such as Polaman Village, limited awareness and inefficient disposal systems exacerbate these issues, thus necessitating innovative and sustainable solutions. This study explores black soldier fly larvae (BSFL) bioconversion as a community-based solution for organic waste management, addresses environmental challenges, and promotes economic empowerment by converting waste into valuable by-products. The study employed a mixed-methods approach, beginning with baseline assessments of waste generation and existing management practices to identify community needs. Educational workshops and hands-on training sessions introduced BSFL bioconversion techniques to local …

Synergic Efficiency Of Organophosphonates In The Synthesis And Corrosion Inhibition Of Zinc Complexonates, Shoyunus Botir Ugli Obidov, Xusniddin Nurboboyevich Raximov, Xasan Irgashevich Kadirov, Satridin Maxamatdinovich Turabdjanov

Technical science and innovation

In this article, the processes of metal complex synthesis are studied in detail. Zinc OEDF+NTF complexation reactions were carried out in the presence of polyhydric alcohols, ethylene glycol, glycerol, and citric acid. For the first time, the synergistic efficiency of a mixture of zinc OEDF+NTF complexes with methyldiethanolamine, used as an inhibitor of mineral salt accumulation, was studied. It was found that when selecting the components in equivalent amounts, the inhibition efficiency of the composition is at least 90%. The high efficiency of inhibiting mineral salt accumulation in the composition is due to the presence of methyldiethanolamine, alkylimidazoline, and their …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Enriched Microbial Consortia From Natural Environments Reveal Core Groups Of Microbial Taxa Able To Degrade Terephthalate And Terphthalamide, Laura G. Schaerer, Sulihat Aloba, Emily Wood, Allison Olson, Isabel B. A. Valencia, Rebecca Ong, Stephen Techtmann

Michigan Tech Publications

Millions of tons of polyethylene terephthalate (PET) are produced each year, however only ~30% of PET is currently recycled in the United States. Improvement of PET recycling and upcycling practices is an area of ongoing research. One method for PET upcycling is chemical depolymerization (through hydrolysis or aminolysis) into aromatic monomers and subsequent biodegradation. Hydrolysis depolymerizes PET into terephthalate, while aminolysis yields terephthalamide. Aminolysis, which is catalyzed with strong bases, yields products with high osmolality, which is inhibitory to optimal microbial growth. Additionally, terephthalamide, may be antimicrobial and its biodegradability is presently unknown. In this study, microbial communities were enriched …

Influence Of Fused Deposition Modeling Process Parameters On The Constitutive Model Of Hyperelastic Thermoplastic Polyurethane, Lucas Gallup, Mohamed Trabia, Brendan O'Toole, Youssef Fahmy

Mechanical Engineering Faculty Research

Thermoplastic polyurethanes (TPUs) are suited for fused deposition modeling (FDM) of parts that require high levels of flexibility and strength. Predicting the deformation of TPU parts produced using FDM may be difficult, especially under large deformations, as their constitutive models depend on the printing process parameters. The lack of understanding led to the absence of constitutive models for TPU parts produced using FDM. This work aims to identify accurate hyperelastic constitutive models. Six groups of uniaxial tensile specimens were produced using FDM. These groups were made with variations in two process parameters, which were infill geometry and extrusion nozzle temperature. …

Determination Of The Kinetic Parameters Of Cholesterol Oxidation Using Cholesterol Oxidase From Streptomyces Sp., Meka Saima Perdani, Heri Hermansyah, Muhamad Sahlan, Dwini Normayulisa Putri, Teguh Pambudi, Anggi Khairina Hanum Hasibuan

Makara Journal of Technology

Cholesterol oxidase (CO) was successfully produced from Streptomyces sp. via the submerged fermentation method, and 69 U/mL enzyme activity was obtained. This study aimed to determine cholesterol oxidation kinetics and the production of CO as a catalyst. The enzyme was diluted to 0.15, 0.075, and 0.00375 U/mL for the oxidation reaction. The substrate was also prepared in three concentrations: 3.23, 6.46, and 12.93 mM. The optimization of conditions for enzymatic cholesterol oxidation was investigated through measurement of the effect of initial cholesterol and enzyme concentrations. Cholesterol concentration was rapidly measured via high-performance liquid chromatography (HPLC). The kinetics of CO were …