Chemical Engineering Commons^™

Kinetics, Thermodynamics, And Biological Characterizations Of Hydrolysates Enzymatically Produced From Proteins Extracted From Microalgae, Hebah Al-Amodi

Theses

This thesis aims to explore the use of Zeolitic Imidazolate Framework-L (ZIF-L) as a support for immobilizing alcalase and its potency in producing protein hydrolysates. ZIF-L was synthesized at room temperature using an aqueous solution, and alcalase was immobilized through adsorption batch experiment. The successful immobilization of alcalase on ZIF-L was confirmed through Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The maximum adsorption capacity of alcalase on ZIF-L was determined to be 672.1 ± 5.5 mg g^-1 at 40°C using an initial protein concentration of 5 mg mL-1. Adsorption equilibrium data …

Biocargos: Capture And Release Gels For Room Temperature Cell Storage., Justin Jacobson

Electronic Theses and Dissertations

Currently, cryovials on dry ice or liquid nitrogen vapor transportation vessels are primary ways utilized to transport mammalian cells from one location to another. Due to the safety concerns of dry ice and liquid nitrogen, associated costly shipping charges, and limitations of proper packaging and labeling of materials, these conventional shipping techniques are unacceptable. It is urgent to develop a safe and environmentally friendly protocol to preserve and ship the biological samples from one place to another. In this research, a method was developed for an ecofriendly and safe protocol to preserve cancer cells. The cell viability of cell line …

The Use Of Peracetic Acid And The Advanced Oxidation Process In Water Purification., Spencer Shipman

Electronic Theses and Dissertations

The Next Round Brewing project was a project that sought to use treated wastewater to make potable drinking water using peracetic acid (PAA) and the advanced oxidation process and break the stigma around reclaimed water. In experiments, PAA was an efficient biocide which reduced the level of pathogens to within EPA standards. When PAA was coupled with the advanced oxidation process all organic matter was also reduced to within acceptable levels, and no biocide was left over in the final product, meaning PAA properly dissociated into harmless byproducts. A series of experiments are presented that vary concentrations of PAA, effluent …

Precision Bottlebrush Polymers: Synthesis, Characterization, And Structure-Property Relationship, Nduka D. Ogbonna

LSU Doctoral Dissertations

Bottlebrush polymers, a type of non-linear polymer characterized by densely grafted side chains on a linear backbone, offer a versatile platform for material design due to their unique thermomechanical and rheological behavior. Addressing the grand challenge of achieving structural precision for bottlebrush polymers remains crucial because traditional disperse mixtures are plagued with batch variability, limiting our ability to control their functions, and correlate theoretical predictions with experiments. To date, narrow-dispersity bottlebrush polymers remain highly heterogeneous, as they are typically synthesized from disperse linear building blocks.

To address this longstanding challenge of structural heterogeneity in brush polymers, the primary objective of …

The Impact Of Film Cooling On The Heat Release Within A Rotating Detonation Combustor, Shreyas Ramanagar Sridhara, Antonio Andreini, Marc D. Polanka, Myles D. Bohon

Faculty Publications

Rotating detonation combustors establish a detonation wave that continuously circulates inside a small annulus. The presence of the detonation wave and the downstream oblique shock within the small annulus coupled with high mass flow induces a high heat load to the combustor wall. Preliminary analysis shows that for higher thermal power, internal air cooling alone is not sufficient to remove the heat out of the walls to maintain them below the maximum temperature of the metal. A possible solution is to use film cooling to reduce the heat flux to the combustor walls. One issue, though, is that the introduction …

Modeling Reversible Volume Change In Automotive Battery Cells With Porous Silicon Oxide-Graphite Composite Anodes, Taylor R. Garrick, Brian J. Koch, Miguel A. Fernandez, Erin Efimoff, Hunter Teel, Matthew D. Jones, Mingjie Tu, Sirivatch Shimpalee

Faculty Publications

Automotive battery manufacturers are working to improve the individual cell and overall pack design by increasing durability, performance, and range, while reducing cost, and active material volume change is a key aspect that needs to be considered during this design process. Recently, silicon oxide-graphite composite anodes are being explored to increase total anode capacity while maintaining a tolerable amount of cell level reversible volume expansion due to the relatively lower reversible volume change of the silicon oxide compared to pure battery grade or metallurgical grade silicon. To predict the blended anode response and contribution to the overall cell volume change, …

Single Nanobubble Formation On Au Nanoelectrodes And Au@Ws2 Nanoelectrodes: Voltammetric Analysis And Electrocatalysis, Xian-Zhun Luo, Xiao-Hu Chen, Yong-Xin Li

Journal of Electrochemistry

Taking advantage of the extremely small size of the gold nanodisk electrode, the single hydrogen nanobubble generated on the surface of the nanoelectrode was studied to evaluate its hydrogen evolution performance. It was found that compared with the bare gold nanodisk electrode, the bubble formation potential of the gold nanodisk electrode modified with tungsten disulfide quantum dots (WS₂ QDs) on the surface was more positive, indicating that its hydrogen evolution activity was higher. Microdynamic model analysis shows that the average standard rate constant of the rate-determining step of the hydrogen evolution reaction of gold nanoelectrodes modified with WS_{2 …}

The Adviser Of Journal Of Electrochemistry Professor Christian Amatore Received The Chinese Government Friendship Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Optimizing In-Situ Upgrading Of Heavy Crude Oil Via Catalytic Aquathermolysis Using A Novel Graphene Oxide-Copper Zinc Ferrite Nanocomposite As A Catalyst, Attia Attia, Ahmed Ashraf Soliman Eng., Mostafa Aboul-Fetouh Prof., Sayed Gomaa Prof., Tarek Aboul-Fotouh Prof.

Petroleum Engineering and Gas

Unconventional resources, such as heavy oil, are increasingly being explored and exploited due to the declining availability of conventional petroleum resources. Heavy crude oil poses challenges in production, transportation, and refining, due to its high viscosity, low API gravity, and elevated sulfur and metal content. Improving the quality of heavy oil can be achieved through the application of steam injection, which lowers the oil’s viscosity and enhances its flow. However, steam injection alone falls short of meeting the growing demand for higher-quality petroleum products. Catalytic upgrading is therefore being investigated as a viable solution to improve heavy oil quality. This …

Goodbye With Tears! Deep Condolences To Academician Zhao-Wu Tian!, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Journal Of Electrochemistry Is Selected To Entering Ici Journals Master List, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Joint Subarray Acoustic Tweezers Enable Controllable Cell Translation, Rotation, And Deformation, Liang Shen, Zhenhua Tian, Kaichun Yang, Joseph Rich, Jianping Xia, Neil Upreti, Jinxin Zhang, Chuyi Chen, Nanjing Hao, Zhichao Pei, Tony Jun Huang

Faculty Publications

Contactless microscale tweezers are highly effective tools for manipulating, patterning, and assembling bioparticles. However, current tweezers are limited in their ability to comprehensively manipulate bioparticles, providing only partial control over the six fundamental motions (three translational and three rotational motions). This study presents a joint subarray acoustic tweezers platform that leverages acoustic radiation force and viscous torque to control the six fundamental motions of single bioparticles. This breakthrough is significant as our manipulation mechanism allows for controlling the three translational and three rotational motions of single cells, as well as enabling complex manipulation that combines controlled translational and rotational motions. …

Tunable Blended Collagen I/Ii And Collagen I/Iii Hydrogels As Tissue Mimics, Paulina M. Babiak, Carly M. Battistoni, Leonard Cahya, Rithika Athreya, Jason Minnich Ii, Alyssa Panitch, Julie C. Liu

School of Chemical Engineering Faculty Publications

Collagen (Col) is commonly used as a natural biomaterial for biomedical applications. Although Col I is the most prevalent col type employed, many collagen types work together in vivo to confer function and biological activity. Thus, blending collagen types can better recapitulate many native environments. This work investigates how hydrogel properties can be tuned through blending collagen types (col I/II and col I/III) and by varying polymerization temperatures. Col I/II results in poorly developed fibril networks, which softened the gels, especially at lower polymerization temperatures. Conversely, col I/III hydrogels exhibit well-connected fibril networks with localized areas of fine fibrils and …

Spatial And Temporal Variations Of Seismic Azimuthal Anisotropy Following The 2019 Ridgecrest Earthquake Sequence In Southern California, Yan Jia, Stephen S. Gao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate the spatial and temporal variations of seismic azimuthal anisotropy in the vicinity of the conjugate fault network activated by the 4 July 2019 (UTC) M6.4 foreshock and the 6 July 2019 M7.1 mainshock in Ridgecrest, California, a total of 1,470 shear wave splitting measurements were obtained from local events recorded by five seismic stations over the period of July 2019 to January 2020. The results suggest a strong asymmetry in anisotropy forming mechanisms across the NW-SE striking Eastern Little Lake Fault, which is the main fault of the area. In the area located to the northeast of the …

Topography Of The 410 And 660 Km Discontinuities Beneath The Tibetan Plateau And Adjacent Areas, Zexin Miao, Stephen S. Gao, Muchen Sun, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To investigate the three-dimensional spatial distribution of subducted oceanic slab segments and their consequential effect on the thermal and hydrous composition of the mantle transition zone (MTZ) beneath the entire Tibetan Plateau, we conducted a comprehensive analysis of approximately 655,000 P-to-s receiver functions (RFs), obtained from 735 broadband seismic stations. These RFs were utilized to delineate the 410 km (d410) and 660 km (d660) seismic discontinuities, which represent the upper and lower boundaries of the MTZ, respectively. The RFs were grouped within circular bins with a radius of 1 degree and stacked to image the discontinuities. The mean apparent depths …

Atomic Layer Deposition Of Ru Nanoclusters On Ba-Laceox: A Highly Efficient Catalyst For Ammonia Synthesis Under Mild Conditions, Kaiying Wang, Baitang Jin, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Ammonia synthesis has significant implications for global energy and environmental issues, driving the need for highly active catalysts that operate under mild conditions. This study reports the successful deposition of uniform ∼1.0 nm metallic ruthenium (Ru) nanoclusters onto Ba-LaCeO_x particles via atomic layer deposition (ALD). The catalytic performance of the ALD-prepared Ru nanoclusters was assessed for ammonia synthesis and compared with two catalysts produced by conventional incipient wetness impregnation. For the ALD-prepared Ru nanoclusters, a pre-reaction H_2-reduction step induced partial encapsulation of suboxide species on Ru sites due to strong metal-support interactions, limiting Ru nanocluster sintering and …

Ir Spectral Analysis Of Broussonetia Papyrefera Plant, Umid Hamroyevich Alamov, Zaytuna Ali Qizi Qurbonaliyeva, Dostonbek Qurbonsho Ugli Shomurodov, Elmurod Abduqodirovich Egamberdiev

Technical science and innovation

in this study, a method for determining the concentration of lignin, cellulose and hemicellulose in plant materials using Fourier-transform IR spectroscopy of Broussonetia papyrefera was developed and tested. The procedure is based on the use of calibration functions that reflect the dependence of the intensity of analytical absorption lines on the concentration of lignin (1512 cm-1) and cellulose (1450 cm-1) in standard samples; indirect correlation was used for hemicellulose. The model samples were ternary mixtures composed of lignin, bacterial cellulose and hemicellulose in different proportions. The proposed method was tested on a wide range of plant biomass samples.

Study Of Technological Parameters On Catalytic Hydroisomerisation Of Aromatic Hydrocarbons Into Alkyl Naphthenic Hydrocarbons, Habibullaeva Mirzaxmatovna Ra'no, Nodira Turobjonovna Torayeva, Temurbek Z. Daminov, Murod Azimovich Eshmukhamedov

Technical science and innovation

The article presents experimental results of the catalytic hydroisomerization of aromatic hydrocarbons into alkyl naphthenic hydrocarbons. Aluminum col-molybdenum with silicon oxides has been studied as a catalytic system, which imparts acidic properties to the catalytic system and stimulates isomerization.

The dehydrogenation reaction of cyclohexane has been studied, which occurs on the active surface of one of the metal oxides to cyclohexene, then the resulting cycloolefin diffuses to the acidic active center - aluminosilicate, where skeletal isomerization occurs and then the isomerized cycloolefin again returns to the active center of the surface of the catalytic system, where it is hydrogenated to …

Nanoparticles In Drilling Fluids: A Review Of Types, Mechanisms, Applications, And Future Prospects, Vasanth Gokapai, Prasad Pothana, Kegang Ling

Petroleum Engineering Student Publications

Nanofluids have gained significant attention as a promising solution to several challenges in drilling operations. Nanoparticles, due to their exclusive properties such as high specific surface area, strong adsorption potential, and excellent thermal conductivity, offer significant potential to improve the efficiency and performance of drilling processes. Regardless of the advancements in drilling fluids and techniques that have improved borehole stability, hole cleaning, and extreme operational condition (HTHP) management, limitations still persist. This review discusses a detailed summary of existing research on the application of nanofluids in drilling, exploring their types, properties, and specific uses in areas such as fluid loss …

Hydrogen Underground Storage For Grid Electricity Storage: An Optimization Study On Techno-Economic Analysis, Yunzhi Chen, Daniel Hill, Blake Billings, John Hedengren, Kody Powell

Faculty Publications

This study performs a techno-economic analysis of hydrogen underground storage systems for grid electricity storage, evaluating their economic viability at the plant scale using dynamic optimization. It explores the feasibility of various system configurations and revenue models in the context of volatile electricity prices and the necessity for multiple revenue streams. The hypothesis tested is that large-scale hydrogen storage, despite its low round-trip efficiency, can be economically viable with the right mix of revenue streams. This study uses scenario-based analysis to assess the impacts of different system configurations, including engaging in time-shifting arbitrage, ancillary service markets and blending hydrogen with …